Charge transfer and valence unstable materials exhibit numerous ground states as functions of doping, pressure, and temperature. Multiscale inhomogeneity is typical for most of these materials, e.g., relaxor ferroelectrics, manganites, cuprates, tungstates, and related compounds. Here, we show that the strong anharmonicity in all these systems allows for a distinct form of inherent, dynamic inhomogeneity dictated by ``discrete breather'' formation, where lattice, charge, and elasticity are intimately coupled. The spatial extent of the breather is governed by the strength of anharmonicity it carries and can vary considerably, defining length scales of inhomogeneity. The coupling of the breather to the host lattice prevents a lattice instability and induces a collapse of the elastic constants and an excess specific heat and entropy as soon as the discrete breather modes emerge from the continuum of the optic modes. Then a coexistence of local, dynamically distorted patterns with the regular lattice is manifested, defining a two-component system with very different dynamics and a strong analogy to glasses: A self-organization of multiple breathers into patterns takes place as a function of temperature and breather density.
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