Coherent scattering of an electron beam by the Kapitza-Dirac effect from a standing laser wave which comprises two frequency components is studied. To this end, the Schr\"odinger equation is solved numerically with a suitable ponderomotive potential. Besides, an analytical solution for electron diffraction in the asymptotic domain of large field amplitudes is obtained and a mathematical model in reduced dimensionality for the scattering amplitude in the Bragg regime is presented. We demonstrate distinct interference signatures and relative phase effects when the standing wave contains a fundamental frequency and its second harmonic. The influence of the relative field intensities on the Rabi oscillation dynamics is also discussed.