In this paper, we study the $\mathcal{C}$-enriched pre-Lie operad defined by Calaque and Willwacher for any Hopf cooperad $\mathcal{C}$ to produce conceptual constructions of the operads acting on various deformation complexes. Maps between Hopf cooperads lead to maps between the corresponding enriched pre-Lie operads; we prove criteria for the module action of the domain on the codomain to be free, on the left and on the right. In particular, this implies a new functorial Poincaré–Birkhoff–Witt type theorem for universal enveloping brace algebras of pre-Lie algebras.