This paper presents an experimental approach to studies of the sorption and diffusion properties of wood. Five timber species - three African tropical hardwoods, Padauk, Okoume and Iroko, and two temperate softwoods, Silver fir and Douglas fir - were studied in adsorption mode. Specimens with 10- and 20-mm longitudinal (L) and transverse (RT) thickness were waterproofed on their sides to force diffusion in those directions. After kiln drying the specimens were hung with nylon wires under cover in a home-made box in which salt solutions provided constant relative humidity (RH), and conditioned at 43, 55, 75, 84 and 97% RH in successive steps. Temperature was maintained between 20 and 24°C. During the equilibration steps the samples were periodically weighed without altering the environmental conditions imposed, by hanging the nylon wire to a spring gauge through a small hole in the box cover. The sorption isotherm properties and diffusion parameters were obtained using an inverse method based on optimization of a 1D finite difference model. The parameters obtained show a decreasing correlation between diffusion coefficient and density, as observed by several authors in the literature. They also illustrate the impact of extractives on the sorption isotherm parameters. These results show that tropical species with high density or many extractives behave very differently to European softwoods, which impedes the application of Eurocode 5 equilibrium standards for these species.
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