Bond Failure Research Articles

Tensile Bond Strength, Fit Accuracy and Failure Types of Zirconia and Cast Gold Root Copings for Overdentures.

To compare the tensile strength, dislodgement forces, marginal gap and failure types between digitally fabricated zirconia root copings and conventionally manufactured cast gold root copings. Extracted human teeth (N=30) were prepared for the root copings and randomly divided into 2 groups: (1)zirconia root copings(ZC) and gold root copings(GC). The specimens were tested for tensile bond strength and dislodgement forces in a universal testing machine and the types of the coping failures modes were analyzed. In addition, the marginal gap was measured. Data were analyzed using one-way ANOVA and Pearson correlation test. Mean tensile bond strength in the total horizontal adhesive area for ZC group was 7.5±2.8MPa and for GC group 10.5±4.8 MPa(p⟩0.05). The mean dislodgement forces for the ZC and GC groups were 242±107N and 311±118N, respectively and with no significant differences between the groups (p=0.12). The mean vertical marginal gap in the ZC group amounted to 27±11.05μm, while in the GC group it was 35.33±10.49μm, showing no statistically significant difference between the two groups (p=0.058). Mixed failure modes were more common (93%) in both groups. In terms of all tested parameters, the zirconia root copings were comparable to the gold copings.

Evaluation of microtensile bond strength and marginal adaptation of fiber-reinforced composites

Background: Long-term durability of a restoration relies on the marginal integrity and its ability to withstand the occlusal forces. Fiber-reinforced composites (FRCs) exhibited superior properties in terms of fracture toughness, flexural strength, and wear resistance. Aim: The aim of this study was to assess and compare marginal adaptation and microtensile bond strength (µTBS) of posterior FRCs comparing with a condensable composite. Materials and Methods: Standardized mesio- and disto-occlusal cavities were prepared on 60 maxillary molars with 3.5 mm pulpal floor depth, 3 mm buccolingual width, and 1.5 mm axial depth. The mesial cavities were restored with everX Posterior and Build-It FRCs, while distal cavities of all teeth were restored with Alert composite and were thermomechanically aged. Half of the specimens from each group (n = 15) were evaluated for marginal adaptation under scanning electron microscope (SEM), and the other half were sectioned for μTBS testing with Instron testing machine. Bond failure mode was examined under SEM. Results: Marginal microgaps were significantly high for the Alert group than FRC groups. Gingival surface showed more gaps. Mean µTBS values were significantly high for FRCs. Cohesive failures are more among FRCs, and adhesive failures are more in condensable composite. Conclusion: The short FRCs showed superior marginal adaptation and better bond strength than condensable composite.

Exploring the axial performance of protective sheathed rock bolts through large-scale testing

Understanding the axial load transfer mechanism of rock bolts under diverse conditions is essential for optimizing reinforcement in rock structures, advancing our comprehension of rock support, and facilitating the design of robust engineering solutions. This paper reports the outcomes of an extensive experimental investigation, focusing on the axial behavior of protective sheathed rock bolts employed in corrosive environments, assessed through pullout tests. Three distinct testing setups were designed to evaluate comprehensively the performance of these rock bolts in various scenarios. The results indicated that the failure characteristics and axial behaviors of sheathed rock bolts differ significantly from conventional counterparts. The findings revealed two primary failure modes in sheathed rock bolts: bolt rupture and slip at the grout-sheath interface, based on the testing arrangement and encapsulation length. The lack of adhesion and interlocking at the grout-sheath interface prevents shear stress at the bolt-grout interface from reaching its maximum potential strength, resulting in grout damage manifesting as circumferential cracks. This, in turn, initiates crack formation, reducing the system’s bond strength. Additionally, it causes slip at the grout-sheath interface to occur at lower pullout loads. It can be inferred that the inner surface of the plastic sheath lacks the necessary structural integrity to withstand high loads, significantly impacting bond stress distribution and failure modes. The results demonstrate that the protective sheath remains intact up to an axial displacement of 28 mm, irrespective of the testing configuration. Additionally, it was observed that the maximum bond stress at the bolt-grout interface falls within the range of 6–8.7 MPa, which is below the shear strength of the grout. Consequently, achieving failure at the bolt-grout interface is not feasible.

Nonthermal Atmospheric Plasma Promotes Bonding Between Adhesive Monomers and Zirconia.

To investigate whether nonthermal atmospheric plasma (NTAP) can promote bonding between commonly used adhesive monomers and zirconia. The zirconia surface and monomers (HEMA, BisGMA, TEGDMA, and MDP) were treated with different NTAP approaches (10 w, 30 s), and the surface characteristics and chemical structures between the zirconia surface and monomers were verified by the contact angle, scanning electron microscopy (SEM), attenuated total reflectance Fourier transform infrared (ATR/FT-IR) spectroscopy, and x-ray photoelectron spectroscopy (XPS). Scotchbond Universal adhesive with two different resin cements, RelyX Ultimate and RelyX Unicem 2, was applied, followed by NTAP-aided clinical procedures, and then microtensile bond strength test (μTBS) and failure mode evaluation were tested for preliminary mechanical properties assessment. One-way ANOVA was employed for the statistical analysis. The contact angle analysis, SEM, and ATR-FTIR confirmed that NTAP can promote the polymerization of BisGMA, TEGDMA, and MDP on the zirconia surface, while XPS confirmed that NTAP can induce a chemical reaction between MDP and zirconia. Nonthermal atmospheric plasma can increase the affinity between selected monomers and zirconia and promote the chemical bonding strength between phosphate monomers and zirconia; besides, it can enhance the bonding strength of two different adhesive systems. The mechanism of how NTAP improved common adhesive monomers interacting with zirconia surfaces was revealed in this study. NTAP, as a relatively high energy-boosting method, could not only improve the surface affinity of zirconia and chemical bonding in-between monomers and zirconia but also enhance the polymerization of different monomers onto zirconia, resulting in improved bonding properties. Thus, further exploration of versatile bonding materials and/or onto different dental substrates could take this into account.

Experimental study on axial compressive properties of bamboo scrimber after high temperature

This study examines the uniaxial compressive mechanical properties of after high temperature bamboo scrimber, taking into account the combined effects of temperature, constant temperature duration, and moisture content. A series of 46 uniaxial compression tests were conducted on bamboo scrimber under various conditions to investigate the failure modes after high temperatures. The analysis focuses on the changes in compressive elastic modulus and peak stress of bamboo scrimber parallel and perpendicular to the grain, in relation to temperature, constant temperature duration, and moisture content. The findings reveal that below 180℃, diagonal shear failure and Y-type shear failure are the primary failure modes for specimens parallel to the grain, while diagonal shear failure predominates for specimens perpendicular to the grain. Above 180℃, bond failure and eccentric crushing become the main failure modes for specimens parallel and perpendicular to the grain, respectively. The peak compressive stress decreases significantly beyond 180℃, with a slower decrease observed as moisture content increases. Constant temperature duration has a notable impact on peak stress, with longer durations resulting in lower peak stress at the same temperature. Although temperature has a lesser effect on the elastic modulus compared to peak stress, empirical formulas were derived to establish the relationship between compressive elastic modulus and peak stress reduction coefficient with variations in temperature, constant temperature duration, and moisture content based on the experimental data.

Effect of Surface Treatments on Shear-bond Strength of Glass Ionomer Cements to Silver Diamine Fluoride-treated Simulated Carious Dentin.

This study investigated the effect of different surface treatments on the shear bond strength (SBS) and failure modes of self-cured (SC) and light-cured (LC) high-viscosity glass ionomer cements (HVGICs) to silver diamine fluoride (SDF)-treated simulated carious dentin (SCD). Extracted human premolars were sectioned and pH cycled for 10 days to simulate carious dentin. The demineralized specimens were treated with 38% SDF (Riva Star) for 2 minutes, washed, stored in deionized distilled water at 37°C for 2 weeks, and subjected to the following surface treatments (n=14): T1 - no treatment (control); T2 - 10 seconds polyacrylic acid (PAA); T3 - 5 seconds phosphoric acid (PPA); T4 - 5 seconds PPA plus universal adhesive (Zipbond); and T5 - 5 seconds PPA plus resin-modified GIC adhesive (Riva bond LC). SC (Riva Self-cure HV) and LC (Riva Light-cure HV) HVGICs were applied to the conditioned specimens and stored in artificial saliva at 37°C for 1 week. SBS and failure modes were subsequently determined. Statistical analyses were performed using Kruskal-Wallis/post-hoc Mann-Whitney U and Chi-square tests (α=0.05). The highest SBS was observed when SC and LC were restored with T2 and T5, respectively. Significant differences in SBS were as follows: SC - T2, T1 > T5, T3; LC - T5, T4, T3 > T2. SC generally exhibited adhesive failures, while LC presented both adhesive and mixed failures. The preferred method for preparing SDF-treated carious dentin before restoration application is PAA for SC and PPA plus RMGIC adhesive for LC HVGICs.

Cracking evolution and failure mechanism of brittle rocks containing pre-existing flaws under compression-dominating stresses: Insight from numerical approach

Comprehending the cracking evolution and failure mechanism of flawed rocks under compression-dominating stresses is essential to evaluating the stability of rock engineering. In this work, a newly developed geometry-constraint-based non-ordinary state-based peridynamic (GC-NOSBPD) theory that can eliminate the numerical oscillation is applied to predict the development of new cracks of flawed rocks under compression-dominating stresses. The failure of bonds between particles is judged by the bond-associated stress-based fracture criteria. The cracking evolution trajectories of semi-disc and disc specimens containing flaws are traced. The effects of flaw inclination angle on the cracking trajectories are analyzed. The cracking evolution paths of rock-like specimens with two flaws under uniaxial and biaxial compression are molded. The effects of confining stress on the growth of new cracks are investigated. The confining stress restrains the propagation of tensile cracks, but it is easy to promote the growth of shear cracks. The concentration and transfer effects of stress can plainly revel the failure mechanism of flawed rocks. The present numerical method is reasonable to predict the tensile and shear failure modes of flawed specimens under compression-dominating stresses.

Effect of mechanical and chemical surface treatments on the repairing of milled and 3D-printed denture bases.

Ensuring a strong bond between chairside autopolymerized acrylic resin to denture base is essential for denture repair and reline procedures. However, there is no established protocol to enhance bond strength between autopolymerizing resin and computer-aided design and computer-aided manufacturing (CAD-CAM) denture base materials. The purpose of this study was to determine shear bond strength of CAD-CAM denture bases and autopolymerizing acrylic resin after mechanical and chemical surface treatments compared with heat-polymerized acrylic resin. Heat-polymerized, milled, and 3-dimensional (3D) printed denture bases were divided into 4 surface treatment protocols: none (control), airborne-particle abrasion (APA), tetrahydrofuran, and Vitacoll application. Autopolymerizing acrylic resin cylinders were bonded to denture surface. Shear bond strength and failure modes were determined after thermocycling. Denture base surfaces were assessed for surface roughness, surface morphology, and microhardness before and after surface treatment. Data was analyzed using two-way ANOVA and multiple comparison tests. The results showed that APA significantly increased shear bond strength and surface roughness of all denture base materials. Tetrahydrofuran and Vitacoll application improved shear bond strength of heat-polymerized acrylic resin, but did not reach the level achieved by APA. Conversely, tetrahydrofuran application improved bond strength of 3D-printed denture to the level of APA. Tetrahydrofuran and Vitacoll application significantly reduced denture base hardness, compared with control and APA. In conclusion, mechanical surface treatment using APA enhances the adhesion of autopolymerizing acrylic resin to heat-polymerized and CAD-CAM denture bases. Tetrahydrofuran and Vitacoll chemical surface treatment improved adhesion to heat-polymerized acrylic resin, with only tetrahydrofuran enhancing bond strength of 3D-printed denture to the level of APA. Without surface treatment, the highest bond strength was shown in 3D-printed denture base material.

Comparison of bond failure with resin-modified glass ionomer cement and visible light-cured composite bonding systems in orthodontic patients: A split-mouth randomized controlled trial.

Resin-modified glass ionomer cement (RMGIC) is considered a fluoride-releasing bonding agent. The aim of the study was to evaluate the rate of bracket bond failure with light-cured composite (LCC) and RMGIC, and to evaluate factors that contribute to the rate of bracket failure with both bonding agents. A randomized controlled trial was conducted on a sample size of 33 patients. The patients were randomly allocated for bonding with visible LCC (control group) or RMGIC (intervention group) using the lottery method. The study was double-blinded. The rate of bracket bond failure was assessed after a follow-up of minimum 3 months and evaluated using the survival regression analysis, taking into account the effects of bonding agents and other factors influencing bracket bond failure. A total of 33 participants were recruited for the study, and 66 quadrants for the intervention and control groups were randomly selected and analyzed. The data was normally distributed and the mean age of the subjects was comparable between both bonding systems. The results of the regression analysis indicated that there was no statistically significant difference between the rate of bracket bond failure with RMGIC and LCC (p = 0.081). However, after analyzing the mean days of survival, it was found that bracket survival was negligibly low with RMGIC, with a mean of 216.00 ±133.72 days as compared to LCC, with a mean survival of 224.11 ±124.59 days. No adverse effects were observed during the course of the trial. There was no difference in the rate of bracket bond failure between the intervention and control groups. The survival rate of brackets treated with RMGIC was found to be comparable to that of LCC, with a minimal difference.

Experimental and Chitosan-Infused Adhesive with Dentin Pretreated with Femtosecond Laser, Methylene Blue-Activated Low-Level Laser, and Phosphoric Acid.

Aim: To prepare experimental adhesive (EA) with 1% and without chitosan nanoparticles on dentin conditioned with a conventional technique phosphoric acid (PA) compared with two different contemporary techniques: photodynamic therapy (PDT) and femtosecond laser (FSL). Method: The methodology consisted of synthesis of EA and 1% chitosan-modified adhesive (CMA). Scanning electron microscopy, dentin adhesive interface assessment, energy-dispersive spectroscopy, shear bond strength (SBS), degree of conversion (DC), and bond failure were assessed. Teeth were selected, disinfected, and mounted in acrylic up to the cementoenamel junction. Occlusal enamel was removed and teeth were randomly allocated into groups and conditioned. These included Group 1: samples treated with PA; Group 2: specimens conditioned with methylene blue photosensitizer (MBP) activated by PDT; and Group 3: samples conditioned with FSL. Following different conditioning regimes, specimens were bonded using 1% CMA and EA. The composite buildup was followed by SBS testing and a bond failure assessment. DC was assessed for both EA and CMA. Analysis of variance and Tukey's post hoc test were used to compare the mean and standard deviation of SBS and DC in different experimental groups, with a significance level of p < 0.05. Results: Dentin pretreated with etch and rinse demonstrated the highest bond strength with 1% CMA. Dentin conditioned with MBP activated by PDT and bonded to EA showed the lowest bond scores. Overall SBS values of 1% CMA were better than EA irrespective of the conditioning regime of dentin. The DC was higher in EA adhesive. This was followed by DC in 1% CMA. DC in EA was found to be comparable with 1% CMA. Conclusions: PA remains the gold standard for dentin conditioning. The incorporation of 1% chitosan in adhesive improves SBS and results in no change in DC. The use of FSL in dentin conditioning can be used as an alternative approach as it results in SBS within acceptable limits. The study was approved by the ethical board of King Saud University.

A peridynamic compensated critical energy density criterion for mixed-mode fracturing in quasi-brittle materials

This study integrates a compensated critical energy density criterion (CCED) into the ordinary state-based peridynamics framework to enable detailed analysis of mode I, mode II, and mixed-mode fracturing. The proposed bond failure criterion builds upon the advantages of the traditional critical energy density (CED) to enable precise calculation of strain energy density. Additionally, the critical bond rotation criterion (CR) is employed to account for shear bonds that the CED might overlook. Using the peridynamic differential operator (PDDO) format in formulating the entire computational framework enhances both accuracy and numerical stability. The model’s validation is conducted through benchmark examples, including the mode I double cantilever beam test, the mode II compact shear test, and a mixed-mode mechanical fracturing test in pre-notched specimens with central borehole loading. Convergence studies, comparative analyses with finite element method simulations and theoretical solutions thoroughly examine the proposed model’s performance and accuracy.

The bending of 3D-printed bio-inspired sandwich panels with wavy cylinder cores

Beetle Elytron Plates (BEPs) represent a new class of biomimetic sandwich cores with excellent mechanical properties inspired by the microstructure of the beetle elytra. The cores have a hexagonal centre-symmetric configuration with through-thickness cylinders in the unit cell. In this work, we describe the behaviour of sandwich panels with novel BEP core configurations possessing wavy cylinders under four-point bending tests. Full-scale simulations are also carried out to validate the experimental data. The results show that all the sandwich panels produced with face skins adhesively bonded have material failure earlier than the adhesive bond failure. BEPs with wavy cylinders have larger peak loads compared to those with straight cylinders, and all BEPs show higher peak loads than those of sandwich panels with classical hexagonal honeycombs. Additionally, all the BEPs exhibit an enhanced ductility compared to honeycomb sandwich panels.

Repair Strength and Bond Failure of Aged CAD/CAM Hybrid Ceramic after Different Surface Treatments

Repair Strength and Bond Failure of Aged CAD/CAM Hybrid Ceramic after Different Surface Treatments

Antimicrobial Effects of Orthodontic Molar Tube Coated with ZnO Nanoparticles Using Electrophoretic Deposition Method: A Randomized Clinical Trial.

This study aimed to evaluate the antimicrobial effect of coated orthodontic molar tubes (COMT) with zinc oxide nanoparticles (ZnO NPs) using an electrophoretic deposition method (EPD) and to evaluate the orthodontic molar tubes (OMT) bond failure rate. Seventy-two orthodontic molar tubes (OMTs) for second molars were divided into two groups 36 each; one group coated with ZnO NPs and the other control negative uncoated. The OMT was coated using the EPD method with ZnO NPs in a concentration of 10g/l. The OMTs were randomly allocated using a split-mouth, cross-quadrant design. After 2weeks of appliance placement, swabs were taken from the surface of the OMTs for microbial assessment against Streptococcus mutans, Lactobacillus acidophilus, and total bacterial counts; additionally, plaque and gingival indices were assessed. The patient was followed for 3months to evaluate the bond failure rate. The COMT showed a statistically significant reduction in total bacterial accounts, S. mutans, and L. acidophilus compared to UOMT (P < 0.001). Furthermore, the plaque and gingival indices near COMT were significantly less than that of UOMT. The bond failure rate was not significant between the COMT and UOMT. The COMT with ZnO NPs has potent antibacterial activity against the tested pathogens with a reduction in the amount of plaque accumulation. The use of the EPD method was feasible without adverse effects on theorthodontic molar tubes bond failure rate.

Study on bonding properties and constitutive model of steel bar and nano-SiO2 reinforced recycled aggregate concrete

Optimizing design and ensuring the structural safety of recycled aggregate concrete (RAC) structures requires a thorough understanding of the bond-slip mechanism between steel bars and RAC. Previous studies have demonstrated the significant enhancement of the microscopic properties of RAC and its bond with steel bars due to nano-SiO2. However, the structural bonding mechanism between the steel bar and nano-SiO2-enhanced RAC remains unclear. Therefore, this study investigates the influence of nano-SiO2 on the bond performance between RAC and steel bars, elucidating the enhancement mechanism through microscopic techniques. Additionally, various factors affecting the bond-slip performance of RAC specimens are analyzed, leading to establishing a multifactorial coupling formula considering thickness-to-diameter ratio, concrete strength, and relative anchorage length. Furthermore, slip index correction formulas and a constitutive model are developed, considering these factors. Acoustic emission (AE) technology monitors the bonding process, clarifying the evolution of AE digital signals and bond damage history. Employing the finite element method, a numerical model of bond-slip behavior is established, revealing specimens' changing bond strength and failure modes. Experimental results indicate that increasing nano-SiO2 content reduces structural porosity, leading to denser and more homogeneous microstructures, thereby enhancing RAC's mechanical properties and bonding performance. Moreover, AE techniques effectively monitor bond damage at different stages. Finally, a bond-slip constitutive model is proposed for steel bar and nano-SiO2 reinforced RAC, offering insights for numerical calculations and engineering designs.

Factors Related to Bracket Bond Failure during Orthodontic Treatment: A Single-Centre Single-Operator Study.

This study aimed to investigate the influence of various patient-specific and bracket location-specific factors on bracket survival rates during comprehensive fixed appliance orthodontic treatment. A total of 197 patients (116 females, 81 males; mean age 16.3 years) having completed orthodontic treatment were included in this retrospective cohort study. Patients were treated using stainless steel non-self-ligating brackets, and the treatment duration was 23.7 months on average. The primary outcome was bracket bond failure. Potential predictors for bracket bond failure recorded included age, sex, oral hygiene, treatment duration, and several pre-treatment cephalometric characteristics such as overjet, overbite, and sagittal and vertical skeletal relationships. Factors associated with bracket failure were analysed with Cox regression, and proportional hazard assumptions were assessed using Kaplan-Meier tests. The overall failure rate was 4.4%. Bracket bond failure rates varied among tooth types and seemed to occur more on posterior teeth and on the right side of the arch. Bracket failure was more common in male patients and those with poor oral hygiene. Concerning dentofacial characteristics, bracket failure of anterior teeth was more common in those with an increased overjet and overbite.

Explainable ensemble learning graphical user interface for predicting rebar bond strength and failure mode in recycled coarse aggregate concrete

Novel study deploys robust machine learning algorithms using newly built comprehensive dataset to predict reinforcing rebar-to-recycled coarse aggregate concrete (RCA) bond strength and failure mode. Prior investigations have solely concentrated on bond strength, resulting in a limited comprehension of the bond failure pattern. Considering the increasing significance of sustainable construction methods, it is crucial to examine both the failure pattern and bond strength to expand the versatility of RCA in various reinforced concrete structures. Accordingly, XGBoost, CatBoost, Random Forest, and LightGBM were trained for this purpose. Model performance was appraised using various statistical metrics, while failure classification performance was assessed using accuracy, recall, and precision indicators. Model performance was ranked using Copeland's algorithm. Feature importance was quantified using SHAP. Coefficient of determination of 0.91 was achieved by XGBoost in predicting bond strength, outperforming other nine analytical models in literature. Failure mode was predicted with accuracy of 94% by CatBoost, XGBoost, and LightGBM. Embedment length and compressive strength features had greatest influence on bond strength and failure mode, respectively. User-friendly graphical interface was developed to harvest ML models in real-world engineering practice. Online free access accurately assigns to any given combination of input features corresponding accurate rebar bond strength and failure mode.

Evalution of shear bond strength of brackets bonded using different hydrophobic and hydrophilic adhesives: An invitro study

A review of the long history of orthodontic bonding adhesives shows that many evolutional developments have occurred from the first chemically-cured composite resins to the most recently introduced light-cured color-change adhesives. An ideal orthodontic adhesive should have adequate bond strength while maintaining unblemished enamel after debonding. Therefore, researchers have been working hard to achieve the best quality and gentlest materials for bonding orthodontic brackets.To evaluate the shear bond strength of brackets bonded using four different adhesives in both dry and in moist environment.A total of 80 orthodontically extracted premolars will be selected. They are divided into 4 equal groups of different adhesives which are further sub-divided into 2 group each (dry and in presence of moisture). All the selected teeth will be cleaned and store in saline until it use. All teeth will be mounted on acrylic block. The shear bond strength will be measured by Lloyd’s Universal testing machine. The obtained data will be statistically evaluated using SPSS22 for Windows using ANOVA test at statistical significance.: The shear bond strength of the four groups were tested with Instron universal testing machine; breaking load at which bond failure occurred was recorded and bond strength was calculated. Data obtained was compiled on MS Office Excel Sheet (2007, Microsoft Redmond Campus, Redmond. Washington, United States.)Data was subjected to statistical package for social sciences (SPSS v 21).Statistically significant difference seen between the hydrophobic and hydrophilic adhesives. In the present study we did Tukey’s post hoc test for pairwise comparison of different hydrophobic and hydrophilic adhesives. It show highly significant values. : The greatest bond strength values were achieved with TransbondXT in both dry and saliva contamination condition. These values were significantly greater than those achieved with Greengloo, RMGIC and Aqualine LC. The overall study conclude that TransbondXT was considered the feasible adhesive material for orthodontic bonding followed by Aqualine LC.

Impact of repair protocols on the bond strength to composite resin.

This study evaluated the impact of different repair protocols on a composite resin substrate using distinct bonding agents submitted or not to artificial aging. Unopened sets of a single-step universal adhesive system (UA) and silane-coupling agents, a single-step pre-hydrolyzed (PH) or a two-step immediately hydrolyzed (IH), were used. Half of the sets were subjected to artificial aging being stored at 48°C for 30days, while the other half remained unaged. The composite resin substrates were prepared and aged in distilled water, sandblasted (Al2O3), and cleaned. Then the different repair protocols were applied according to the groups. UA was used without a previous silane layer, while PH and IH were applied followed by a single-step etch-and-rinse adhesive system. Adhesive systems were light-activated, and four composite resin cylinders were formed over the substrate. After 24h, the specimens were subjected to microshear bond strength (μSBS) test and failure mode analysis. The μSBS data were subjected to two-way ANOVA followed by Tukey HSD; Kruskal-Wallis analysis was used for failure mode distribution (α = 0.05). After aging the products, UA showed higher bond strength, while PH had significantly lower results, and IH showed no significant differences (p = 0.157). No significant differences were found for bond strength among the repair protocols when using non-aged products (p > 0.05). The protocols using UA and IH showed no significant differences between aged and non-aged bottles, whereas PH exhibited lower bond strength whencomparing aged and non-aged products. More cohesive failures were observed in the resin substrate for the IH groupwithout aging.

Molecular dynamics simulation of nanocellulose and cement matrix composites

The interfacial properties of nanocellulose and cement matrix are the key factors affecting the mechanical properties of composite materials. However, it is challenging to study the interface combination through conventional experiments and microscopic characterization techniques. Molecular dynamics simulation (MD), as a nanoscale analytical method, can be used to calculate and analyze the strength, deformation, destruction and interfacial interaction of materials on the atomic scale. Since the existing methods of C-S-H modeling and fiber pull-out from the matrix in molecular dynamics simulations were not suitable for cellulose/C-S-H composite models. In this paper, a molecular dynamics simulation method for nanocellulose cement matrix composites was proposed. Based on the embedded composite model, the tensile stress-strain, interfacial interaction energy, hydrogen bond, and interface failure mode were studied when cellulose was pulled out of the matrix. The results showed that adding cellulose could improve the local ductility and tensile strength of cement matrix materials. The interfacial interaction energy between cellulose and C-S-H was approximately −1.09 J/m2, which was much higher than that between carbon nanotubes and C-S-H. Cellulose would adsorb hydrogen and oxygen atoms on H2O, OH− and silica tetrahedron in C-S-H. In the pull-out simulation of cellulose in C-S-H, C-S-H on the surface of cellulose would be destroyed and attached to the cellulose surface and moved along with it, indicating that cellulose could play a good bridging role in the matrix. The simulation results revealed the action mechanism of cellulose in cement matrix materials.