With the rapid implementation of polymer flooding in Bohai oil field, the produced liquid includes large amount of polymer-containing oily sludge reversed increases year by year. The polymer-containing oily sludge accumulates at the terminal processing plant, which not only obviously degrades the performance of sewage treatment instruments and blocks the oil/water separators, but also has a bad impact on environment. Using thermal chemical treatment technology with dynamical separating agent and optimizing separation conditions, the completed processing technology is obtained as follow: thermal chemical reaction, separation on standing, crude oil recovery and recycling of waste water. The recovery rate of crude oil from the samples treatment is over 94%. The obtained technology plays an important role in recycling of source, environment protection and technical support of increasing produced liquid.