Recent R-matrix calculations of electron impact excitation rates for transitions in C IV are used to derive the theoretical electron temperature-sensitive emission-line ratios R1 = I(312.43 angstrom)/I(419.74 angstrom), R2 = I(3 84.14 angstrom)/I(419.74 angstrom), R3 = I(312.43 angstrom)/I(419.49 angstrom), and R4 = I(384.14 angstrom)/I(419.49 angstrom). A comparison of these with solar observational data obtained with the Naval Research Laboratory's S082A slitless spectrograph on board Skylab reveals good agreement between theory and observation for R2 and R4, which provides experimental support for the accuracy of the atomic data adopted in the analysis. However, most of the observed values of R1 and R3 lie above the theoretical high-temperature limit, which is probably due to blending of the 312.43 angstrom line.