Blueschist Unit Research Articles

Dating metamorphic processes and identifying 87Sr/86Sr inheritance using volume-coupled Rb/Sr geochronology and geochemistry of in situ white mica: A demonstration with HP/LT rocks from Syros, Greece

High-pressure/low-temperature rocks from two well-studied outcrops of the Cycladic Blueschist Unit on Syros are used to demonstrate the advantages of volume-coupled 87Rb/87Sr geochronology and geochemistry of in situ white mica. Single-spot Rb/Sr dates are interpreted based on the microstructural position of white mica combined with its chemical information, and the results are discussed within the tectonic framework of the island. The first outcrop on Katerghaki cape exposes rigid blocks of foliated eclogite within well-foliated blueschist, whereas the second outcrop on Delfini peninsula comprises massive eclogitic blocks, likely of metasomatic origin, hosted within blueschist that are interlayered with white mica schists. The rheological contrasts exhibited in both outcrops preserve (near-)peak HP/LT metamorphism/metasomatism (eclogites) followed by retrogression and deformation in lower P-T conditions (blueschist, micaschist). The white mica in eclogite from both outcrops are in equilibrium with the HP/LT mineral assemblages, do not show chemical zoning nor systematic chemical variations, and yield uniform single-spot Rb/Sr dates. Weighted averages of the Rb/Sr dates are 48.2 ± 3.7 Ma (MSWD: 0.9, n: 34; Katerghaki) and 44.5 ± 3.1 Ma (MSWD: 0.7, n: 28; Delfini), interpreted as (near-)peak HP/LT metamorphism and metasomatism, respectively, overlapping with published garnet LuHf and SmNd geochronology of the corresponding outcrops. White mica in the Katerghaki blueschist and the Delfini micaschist exhibit significant chemical zoning and correlations of Ti with major and trace elements (Al, Fe, Mg, Rb, Sr, Zn, Ba, Nb). Weighted age averages were calculated from Rb/Sr dates corresponding to high-Ti and low-Ti white mica compositions. The blueschist yields ages of 56.0 ± 10.6 Ma (MSWD: 2.2, n: 20/80) and 36.3 ± 2.1 Ma (MSWD: 0.9, n: 20/80), whereas the micaschist produced ages of 43.7 ± 3.5 Ma (MSWD: 0.5, n: 14/53) and 31.9 ± 2.7 Ma (MSWD: 1.0, n: 13/53), respectively. These results are interpreted to resolve the timing of fluid-mediated isotopic re-equilibration of white mica during deformation and retrogression (low-Ti), and reflect 87Sr/86Sr inheritance from the earlier HP/LT history (high-Ti). Overall, the results demonstrate that coupling 87Rb/87Sr geochronology with geochemistry of white mica in situ is advantageous for evaluating Rb/Sr datasets that may possess a single mica population (eclogites) or are affected by 87Sr/86Sr inheritance (blueschist, micaschist) in order to interpret geologically meaningful ages.

P–T Evolution of the Cyclades Blueschist Unit: Constraints on the Evolution of a Nascent Subduction System From Zr‐In‐Rutile (ZiR) and Quartz‐In‐Garnet (QuiG) Thermobarometry

AbstractNew results that employ Zr‐in‐rutile thermometry (ZiR) and quartz‐inclusion‐in‐garnet (QuiG) barometry constrain the P–T conditions of garnet formation in blueschists and eclogites from the island of Syros, Greece. QuiG barometry reveals that garnet from different regions across the island formed at pressures ranging from 1.1 to 1.8 GPa and ZiR thermometry on rutile inclusions in garnet constrains the minimum temperature of garnet formation to have been 475–550°C. Most importantly, there is no systematic difference in the conditions of garnet formation from different regions across the island and these results are nearly identical to those obtained from the islands of Sifnos and Ios, Greece. A model is proposed whereby the rocks from all three islands were initially metamorphosed along a relatively shallow geotherm of around 11°C/km to a depth of around 45 km and were then subjected to metamorphism along a geotherm of around 7–8°C/km, which could have been caused by either an increase in the dip of the subduction zone or an increase in the rate of subduction. Garnet formed along this steeper geotherm was accompanied by the release of significant H2O from the breakdown of chlorite over a duration of 1 Ma or less based on thermal and diffusion modeling. It is concluded that rocks from Syros, Sifnos and Ios all followed a similar, roughly counter‐clockwise prograde P–T path and that the present outcrop configuration is largely due to a complex exhumation history.

Coherent underplating of HP–LT blueschist packages and basement during Hellenic subduction recorded by zircon U–Pb data, Pelion, Greece

Studies of HP–LT metamorphic complexes are crucial in advancing our understanding of subduction processes, such as underplating, metamorphism and exhumation. Detailed new U–Pb zircon data of blueschist facies metasedimentary units at Pelion indicate two distinct stratigraphically upright and coherent structural slices: (1) the South Pelion slice consisting of strata with Permian–Late Cretaceous zircon maximum depositional ages; and (2) the North Pelion slice consisting of strata with Triassic–Late Cretaceous zircon maximum depositional ages. Both slices have Late Cretaceous strata at the top of the section with cosmopolitan detrital zircon signatures. The ages from zircon U–Pb rim overgrowths correlate with existing constraints from subduction metamorphism during the Paleocene–Eocene, with a possible second stage recorded during basal underplating in the Late Eocene–Oligocene. Detrital zircon provenance data and multi-dimensional scaling comparisons demonstrate a tectono-metamorphic linkage between the Pelion rocks and the Cycladic Blueschist Unit, and between the southern Pelion basement and the Cycladic basement. Protolith deposition for Pelion blueschist facies rocks occurred during Permo-Carboniferous intra-arc extension and Adria–Pindos rifting. Our results show that the Pelion blueschist facies rocks, representing lateral equivalents of the Cycladic Blueschist Unit, consist of two separate, coherent upper crustal slivers that were underplated and metamorphosed during Hellenic subduction beneath the Pelagonian margin. Thematic collection: This article is part of the Ophiolites, melanges and blueschists collection available at: https://www.lyellcollection.org/topic/collections/ophiolites-melanges-and-blueschists Supplementary material: Detailed methodology, further provenance and maximum depositional age methods and descriptions, sample location coordinates (Supplementary Table 1), and zircon U–Pb data (Supplementary Table 2). These data are available at https://doi.org/10.5281/zenodo.8300635 and https://doi.org/10.6084/m9.figshare.c.7008123

Deformation Pattern of Well-Preserved High-Pressure Rocks (SE Syros, Cyclades)

New, detailed geological/structural mapping and field-based structural analysis were carried out to investigate the deformation pattern of well-preserved high-pressure rocks of the Blueschist Unit exposed in SE Syros (Cyclades, Greece). Geological mapping revealed the occurrence of extensive alternations between different rock groups, as well as interfingering patterns in map-scale that are possibly the result of folding. The earlier ductile deformation phase recognized in the mapped area is associated with the development of a penetrative foliation, which was formed at eclogite/blueschist-facies conditions under peak metamorphism. The subsequent main deformation phase occurred under blueschist facies conditions synchronous with the early stages of exhumation of the high-pressure rocks. This phase is mainly associated with the formation of WNW-trending folds and a pervasive axial planar foliation linked with ESE-directed shearing. The main deformation ceased under blueschist-facies conditions, and exhumation of the rocks to greenschist-facies conditions took place under very weak and localized deformation. Greenschist retrogression observed in the southwestern part of the mapped area seems to be controlled by fluids, rather than by intense deformation and formation of major syn-greenschist shear zones.

Disruption of a high‐pressure unit during exhumation: Example of the Cycladic Blueschist unit (Thera, Ios and Naxos islands, Greece)

AbstractReconstructing the original geometry of a high‐pressure tectonic unit is challenging but important to understand the mechanisms of mountain building. While a single nappe is subducted and exhumed, nappe‐internal thrusts may disrupt it into several subunits. The Middle‐CBU nappe of the Cycladic Blueschist Unit (Hellenide subduction orogen, Greece) shows evidence of such disruption along a Trans‐Cycladic‐Thrust (TCT), however, the timing of this thrusting is unknown. Here, we report multi‐petrological and geochronological data from the Middle‐CBU nappe from the Thera and Ios islands (Greece). Using Zr‐in‐rutile thermometry coupled with quartz‐in‐garnet elastic barometry, average P–T and phase equilibrium thermodynamic modelling, we show that garnet growth in Ios occurred during prograde metamorphism at 6.7 ± 1.4 kbar to 13.0 ± 1.6 kbar and 326 ± 20°C to 506 ± 13°C (2σ uncertainty) followed by early exhumation to 10.1 ± 0.6 kbar and 484 ± 14°C and a greenschist facies overprint at 5.7 ± 1.2 kbar and 416 ± 14°C. For Thera, we constrain peak HP conditions of 7.6 ± 1.8 kbar and 331 ± 18°C, followed by exhumation and equilibration at ~2 kbar and ~275°C using average P–T and phase equilibrium thermodynamic modelling. For Ios, Uranium‐Pb garnet geochronology provides ages of 55.7 ± 5.0 Ma (2σ uncertainties) for prograde and 40.1 ± 1.4 Ma for peak HP metamorphism. Combining our new P–T–t data from Thera and Ios islands with existing data from Naxos island, we conclude that the studied nappe segments represent remnants of a former coherent nappe. The P–T–t data define an Eocene subduction rate of 2.1 ± 1.0 km/Ma, which is distinctly slower than the current subduction rate of 40–45 km/Ma. After subduction, the exhumation of the Middle‐CBU nappe occurred during the Oligocene at different rates for different localities. The Middle‐CBU nappe of Naxos was exhumed at a rate of ~6 km/Ma, contrasting with the exhumation rate of ~3 km/Ma calculated for Ios. This result suggests that the Middle‐CBU nappe of Naxos rocks was thrust on the Ios one during the Oligocene. Using P–T–t data and assuming realistic subduction angles during the Eocene and the Oligocene, we present a 2D structural reconstruction of the Middle‐CBU nappe of these islands. This reconstruction helps to understand the mechanisms of subduction of a continental margin and its disruption during exhumation.

The jadeitites from Syros and Tinos, Cycladic Blueschist Unit, Greece: field observations, mineralogical, geochemical and geochronological characteristics

AbstractThis study illustrates the field relationships of jadeitite-bearing block-in-matrix sequences on Syros and Tinos, Cycladic Blueschist Unit, and adds additional U–Pb zircon ages for jadeitites to the geochronological database. The results confirm the importance of Cretaceous (c. 80 Ma) and Eocene (c. 50 Ma) processes in their geological evolution. Interpretations suggesting that the jadeitites were formed by complete metasomatic replacement of a pre-existing rock are not fully supported by field observations. In at least some cases, the formation of jadeitite is likely due to precipitation from Na-Al-Si-rich aqueous fluids, which also caused variable metasomatic alteration of the host rock. Unambiguous age constraints for formation of the Syros and Tinos jadeitites are not available. A relationship to Eocene blueschist facies metamorphism recorded in the associated metamafic rocks seems plausible. However, since high-pressure overprinting of pre-Eocene jadeitite is also conceivable, there is a much larger time window for jadeitite formation, framed by Cretaceous (c. 80–76 Ma) protolith ages of various mélange blocks and the waning stages of blueschist facies metamorphism (c. 40 Ma). Field observations are consistent with the interpretation that the mélange-like occurrences on Syros and Tinos record, to varying extent, multi-stage processes that include detachment of mafic rocks from the subducting plate, local infiltration of Na-Al-Si-rich aqueous fluids, exhumation via a serpentinitic matrix in a subduction channel and reworking of the primary block-in-matrix fabric by sedimentary or tectonic processes during accretionary wedge formation.

Zircon and Apatite U‐Pb Constraints on the Tectonic Affinity and Metamorphic History of the Blueschist‐Facies Ambelakia Unit, Mt. Ossa, Greece

AbstractIn the Aegean region, the Cycladic Blueschist Unit (CBU) and the Ambelakia unit (Mt. Ossa, Thessaly, Greece) represent early Cenozoic subduction‐related HP‐LT metamorphic complexes exhumed in the back‐arc of the Hellenic subduction zone. The Ambelakia unit has been linked to the classic CBU in the Cyclades; however, the tectonic affinity, structural position, nature of the protolith, or timing of metamorphism for these rocks in eastern Thessaly remains largely unresolved. This study provides detailed new insights into both the provenance, protolith age, and tectonic affinity of the Pelagonian, Ambelakia, and Olympos‐Ossa tectonic units by integrating U‐Pb detrital zircon (DZ) and detrital apatite (DA) data in a structural context. DZ results suggest the existence of distinct metasedimentary units, spanning in depositional age from Carboniferous to Late Cretaceous, with provenance signatures that support a correlation with the classic CBU and strengthen the argument for a similar pre‐subduction tectonic relationship. Depth‐profiling analysis reveals metamorphic rims that record HP‐LT metamorphism in the Ossa Ambelakia during the Paleocene‐Eocene. Apatite U‐Pb data from the metasedimentary units preserve a detrital signature similar to the DZ signatures, indicating that apatites were not reset (<450 C) nor recrystallized during subduction metamorphism. These new data suggest that the Ambelakia unit is a lateral equivalent of the CBU subduction complex; however, this unit experienced distinctly lower pressure and temperature conditions during metamorphism than the along‐strike classic CBU.

Miocene ductile thinning below the Folegandros Detachment System, Cyclades, Greece

AbstractFolegandros island lies between the established SW‐directed West Cycladic and S‐directed Santorini detachment systems. Preserving shear‐sense indicators with opposing kinematics, the geodynamics and timing of kinematics are debated. Using white mica 40Ar/39Ar geochronology complemented by structural data, we report a new Miocene top‐to‐S detachment system, the Folegandros Detachment System (FDS), that is coupled with pure‐shear flattening and juxtaposes the Cycladic Blueschist Unit below Early Cretaceous to early Eocene low‐grade marble and quartzitic‐phyllitic sequences, topped by a metaflysch. Chronostratigraphic correlation and detrital zircon geochronology reveal the low‐grade rocks from the hanging wall of the FDS likely belong to the Pelagonian Zone. Middle Miocene zircon and apatite (U‐Th)/He cooling ages correspond to the latest stages of exhumation. Observations of opposing kinematics on Sikinos, Ios and now Folegandros reveal that ductile thinning played a more significant role in accommodating Miocene exhumation of high‐pressure rocks in the southern Cyclades than previously postulated.

Constraints on the thermal evolution of metamorphic core complexes from the timing of high-pressure metamorphism on Naxos, Greece

Metamorphic core complexes are classically interpreted to have formed during crustal extension, although many also occur in compressional environments. New U−(Th)−Pb allanite and xenotime geochronologic data from the structurally highest Zas Unit (Cycladic Blueschist Unit) of the Naxos metamorphic core complex, Greece, integrated with pressure−temperature−time (P−T−t) histories, are incorporated into a thermal model to test the role of crustal thickening and extension in forming metamorphic core complexes. Metamorphism on Naxos is diachronous, with peak metamorphic conditions propagating down structural section over a ∼30−35 m.y. period, from ca. 50 Ma to 15 Ma. At the highest structural level, the Zas Unit records blueschist-facies metamorphism (∼14.5−19 kbar, 470−570 °C) at ca. 50 Ma, during northeast-directed subduction of the Adriatic continental margin. The Zas Unit was subsequently extruded toward the SW and thrust over more proximal continental margin and basement rocks (Koronos and Core units). This contractional episode resulted in crustal thickening and Barrovian metamorphism from ca. 40 Ma and reached peak kyanite-sillimanite−grade conditions of ∼10−5 kbar and 600−730 °C at 20−15 Ma. Model P−T−t paths, assuming conductive relaxation of isotherms following overthrusting, are consistent with the clockwise P−T−t evolution. In contrast, extension results in exhumation and cooling of the crust, which is inconsistent with key components of the thermal evolution. Barrovian metamorphism on Naxos is therefore interpreted to have resulted from crustal thickening over a ∼30−35 m.y. time period prior to extension, normal faulting, and rapid exhumation after a thermal climax at ca. 15 Ma.

Coeval Miocene exhumation of the Cycladic Blueschist Unit and the Cycladic Basement in the southern Cyclades, Ios and Sikinos, Greece

AbstractMiocene extension in the back arc of the retreating Hellenic subduction zone resulted in metamorphic core complex formation and exhumation of the Cycladic HP‐LT rocks. The extension was accommodated by bivergent detachment systems, generally occupying the interface between the Cycladic Blueschist Unit (CBU) and overlying Pelagonian units. However, the nature and kinematic history of the contact between the CBU and underlying Cycladic Basement (CB) in the southern Cyclades remains debated due to the presence of both top‐to‐the‐N and top‐to‐the‐S kinematics and ambiguities dating the final exhumation stages. Zircon and apatite (U‐Th)/He data and thermal modelling for the CB and CBU on Ios and Sikinos show that both units were likely exhumed as a coherent footwall block in response to rapid slip along the bivergent Miocene Santorini and Naxos‐Paros detachment systems.

Stretched Thin: Oligocene Extrusion and Ductile Thinning of the Basal Unit Along the Evia Shear Zone, NW Cyclades, Greece

AbstractWe present field‐based structural, geochronological, and petrological evidence for a major new Oligocene extensional shear zone, the Evia Shear Zone (ESZ), on the island of Evia in the NW Aegean Sea. Strain related to this structure occurs in a diffuse zone structurally underlying the nappe contact between the Cycladic Blueschist Unit and Basal Unit, within rock previously attributed to the Tsakei Unit or Basal Unit metaflysch. Structures within the ESZ record stretching in both the X and Y directions under ductile and brittle‐ductile conditions, indicative of a component of oblate coaxial strain during overall top‐to‐E general shear. New white mica 40Ar/39Ar geochronology from the ESZ shows that the structure was accommodating ductile deformation in the late Oligocene. Thermodynamic modeling shows that rock within the ESZ records greenschist facies retrogressive conditions of 310 ± 15°C and 7 ± 1 kbar. Zircon (U‐Th)/He thermochronology demonstrates that both the CBU and Basal Unit had exhumed into the brittle crust by the middle Miocene, slightly earlier than indicated by low‐temperature thermochronology for the HP‐LT units throughout the Aegean. We interpret these data as evidence that the Basal Unit underwent rapid exhumation via syn‐orogenic processes persisting until at least the early Miocene, facilitated in part by normal‐sense displacement along the ESZ. The occurrence of structures representative of coaxial deformation in the shear zone alludes to a major role for ductile thinning in controlling exhumation of HP rocks in the Cyclades, perhaps influencing the relative rates of exhumation observed across the region.

Hygrochronometry of punctuated metasomatic events during exhumation of the Cycladic blueschist unit (Syros, Greece)

AbstractThe spatiotemporal scales at which fluid flow events occur along the subduction interface remain poorly constrained. This study illustrates the benefit of using in‐situ Rb/Sr dating on metasomatic white mica to constrain the timing of metasomatic events, taking advantage of the well‐studied reaction zones of the Kampos‐Lia unit of Syros, Greece. This unit is a subducted block‐in‐matrix structure corresponding to a preserved fragment of a discontinuous, slow‐spreading oceanic domain. Results reveal that the main metasomatic event took place at ~36 Ma, coincident with the transition from blueschist to greenschist facies and syn‐ to post‐orogenic exhumation in the Cyclades marking the end of a first exhumation stage along the subduction interface. Results highlight that fluid–rock interaction along the subduction interface cannot be treated as the result of continuous fluid influx, but rather reflect punctuated, heterogeneously distributed events (both in time and space) tied to specific tectonometamorphic episodes.

Rapid, paced metamorphism of blueschists (Syros, Greece) from laser-based zoned Lu-Hf garnet chronology and LA-ICPMS trace element mapping

Unravelling the timing and rate of subduction-zone metamorphism and H2O release requires linking time to the compositional changes of petrogenetic indicator minerals in blueschists and eclogites. Garnet is a key mineral in this regard, as it forms by, and records, H2O-releasing mineral reactions that can be linked to pressure and temperature conditions. These can be placed in time using chronology. Bulk-or multi-grain ages are the norm in garnet chronology. While these ages provide important and precise time constraints on reactions across both facies, the duration, rates and style of growth—crucial parameters in the petrological and geochemical evolution of subducting oceanic crust—remain unconstrained. Domain dating, i.e., dating of individual growth zones, is necessary to investigate these aspects, but is generally impeded in “common”-sized garnet grains due to sample size requirements. To overcome these limitations, we use a low-loss micro-sampling by laser cutting combined with Lu-Hf chronology. We used this approach to precisely date multiple growth zones in a 1-cm garnet grain from glaucophane-bearing micaceous schist of the Cycladic Blueschist Unit (CBU), Syros Island, Greece. The analysis was combined with major- and trace-element mapping (EPMA, LA-ICPMS) to investigate garnet petrogenesis. Garnet core and mantle zones are chemically comparable and identical in age within 0.1 Myr precision (2σ), indicating an initial growth pulse at 51.8 ± 0.1 Ma (MSWD = 1.13). The two rim zones, which are chemically distinct, were resolvably younger at 51.3 ± 0.2 Ma (MSWD = 0.67). Integrated with compositional data, these age constraints provide a time-resolved record of extremely fast, pulsed garnet growth and fluid-release reactions, such as chloritoid breakdown. These reactions can be considered near-instantaneous on subduction time scales, indicating that re-equilibration far outpaces changes in pressure and temperature conditions. The analysed sample is associated with the upper-subunit of the CBU with oceanic affinities, which does not share the last part of the prograde history with the rest of the CBU, i.e., the margin sub-unit. We interpret our sample as a sliver that became attached to the base of the ophiolitic sub-unit and was thrusted onto the lower margin unit at high-pressure. Beyond providing insights into the timing of subduction-zone processes, our new protocol for zoned garnet Lu-Hf geochronology of “common-sized” garnet opens new possibilities for constraining the causes and rates of garnet growth and the pace of tectonic processes in general.

Subduction, Underplating, and Return Flow Recorded in the Cycladic Blueschist Unit Exposed on Syros, Greece

AbstractExhumed high‐pressure/low‐temperature (HP/LT) metamorphic rocks provide insights into deep (∼20–70 km) subduction interface dynamics. On Syros Island (Cyclades, Greece), the Cycladic Blueschist Unit preserves blueschist‐to‐eclogite facies oceanic‐ and continental‐affinity rocks that record the structural and thermal evolution linked to Eocene subduction. Despite decades of research, the metamorphic and deformation history (P‐T‐D) and timing of subduction and exhumation are matters of ongoing discussion. We suggest that Syros comprises three coherent tectonic slices and that each slice underwent subduction, underplating, and syn‐subduction return flow along similar P‐T trajectories, but at progressively younger times. Subduction and exhumation are distinguished by lineations and ductile fold axis orientations, and are kinematically consistent with previous studies that document top‐to‐the‐S‐SW shear (prograde‐to‐peak subduction), top‐to‐the‐NE shear (blueschist facies exhumation), and then E‐W coaxial stretching (greenschist facies exhumation). Amphibole zonations record cooling during decompression, indicating return flow above a cold slab. Multi‐mineral Rb‐Sr isochrons and compiled metamorphic geochronology show that the three slices record distinct stages of peak subduction (53–52, ∼50, and 45 Ma) that young with structural depth. Retrograde blueschist and greenschist facies fabrics span ∼50–40 and ∼43–20 Ma, respectively, and also young with structural depth. Synthesized data sets support a revised tectonic framework for Syros, involving subduction of structurally distinct coherent slices and simultaneous return flow of previously accreted tectonic slices in the subduction channel shear zone. Distributed, ductile, dominantly coaxial return flow in an Eocene‐Oligocene subduction channel proceeded at rates of ∼1.5–5 mm/yr and accommodated ∼80% of the total exhumation of this HP/LT complex.

The timing of blueschist-facies metamorphism in the Makrotantalon Unit on Andros Island, Greece: Cretaceous and Eocene high-pressure/low-temperature events?

AbstractThis study corroborates interpretations suggesting that the Makrotantalon Unit on Andros represents a tectonic slice with Pelagonian affinity in the nappe stack of the Cycladic Blueschist Unit. Previously reported Cretaceous 40Ar–39Ar dates of a garnet-glaucophane schist from the Makrotantalon Unit could not be reproduced by Rb–Sr geochronology, but this is not an indication of contamination with excess Ar. Instead, the newly dated samples record disturbance of the Rb–Sr isotope system by partial recrystallization. Subsets of these phengite populations, representing the smaller grain-size fractions, yielded low-precision dates ranging from c. 21 to c. 15 Ma that document deformation-related resetting and recrystallization of a presumably Cretaceous white mica population. Although these Miocene dates cannot be linked with blueschist-facies metamorphism, they provide time constraints on the formation of shear zones that overprinted the original thrust contact during exhumation. The geological relevance of a Cretaceous high-pressure event is confirmed by a Rb–Sr date of c. 121 Ma for an epidote-glaucophane schist collected further away from the tectonic contact. The occurrence of a second blueschist-facies event in the Eocene is verified by Rb–Sr dates of two epidote-glaucophane schists (c. 40 Ma and c. 44 Ma) that can unambiguously be assigned to the Makrotantalon Unit.

Development and passive exhumation of high-pressure shear zones (Blueschist Unit, Syros): Insights from quartz and columnar calcite microstructures

Quartz and columnar calcite microstructures in two major high-pressure (HP) shear zones (Syros Island, Greece), which carry meta-igneous rocks over calcite marbles, were studied to investigate the deformation conditions associated with their development and exhumation. Quartz-rich bands within the hanging-wall of the shear zones record the deformation during the operation of the shear zones under HP conditions at slightly decreasing temperatures (from 500 °C to 450 °C). At HP conditions, the shear zones are associated with (E)SE-directed shearing under plane strain conditions, as well as with a temporal increase in strain rate of one order of magnitude (from ∼10−12 to ∼10−11). Well-preserved columnar calcite within marbles of the footwall indicates that ductile shearing along the shear zones should have abruptly ceased during the early stages of exhumation, passing to a period of relative quiescence within the stability field of aragonite at temperatures ∼430–450 °C. Progressive exhumation and cooling below 400 °C are associated with weak and distributed (E)NE-directed shearing with strain rate slower than ∼10−14. Our results from north(east) Syros indicate a change in transport direction from (W)NW-(E)SE at the deep subduction levels to (W)SW-(E)NE during exhumation. This change is linked to a change in deformation, from localized to weak and distributed revealing that the Blueschist Unit in north(east) Syros was exhumed as a nearly rigid body.

Reconstructing the southern Pelagonian domain in the Aegean Sea: Insights from U-Pb detrital zircon analysis, lithostratigraphic and structural study, and zircon (U-Th)/He thermochronology on Amorgos Island (SE Cyclades, Greece)

In the Attic-Cycladic Crystalline Complex (Aegean Sea, Greece), following early syn-convergence exhumation processes, the extensional tectonics resulted in the extreme denudation of the upper plate, preserved today in a few places. The Cycladic Blueschist Unit (CBU) and the underlying Cycladic Basement and the Basal Units have been exhumed in the footwall of detachment systems, juxtaposed against the Pelagonian-derived hanging wall fragments. Traditional views accept that Amorgos Unit occupies a structurally lower position, correlated to the Basal Unit. This study presents lithostratigraphic and structural data, integrated with detrital zircon MDA, provenance analyses, and (U-Th)/He ages, showing a new investigation of the paleogeographic and structural position of Amorgos in the Cycladic archipelago.The low-grade metamorphosed Amorgos Unit presents a tripartite lithostratigraphy: a basal metaconglomerate, a middle carbonate sequence with shallow-water to pelagic facies, and an Eocene (meta)flysch. An HP/LT metabasite huge block is incorporated within the metaconglomerate either by gravitational movements as an isolated olistolith or tectonic processes as a slice during the early deformation stage. Detrital zircon U-Pb analysis on the meta-siliciclastic deposits revealed that the basal metaconglomerate shows a dominant Ediacaran input with Mid-Permian and Precambrian MDAs for the matrix and the high-grade clasts, respectively. The metaflysch shows Paleozoic affinity (e.g., mainly Pelagonian-sourced) and Triassic-Jurassic MDAs. The deformation history of Amorgos includes an early-stage top-to-NW thrusting in the retro-wedge setting of the Late Eocene–Oligocene subduction zone and a late-stage top-to-SE extensional low- and high-angle normal faulting. Zircon (U-Th)/He ages reveal an Early–Mid Miocene (18–14 Ma) exhumation below ∼ 200 °C. Similarities on lithostratigraphy, structural inventory, exhumation history, and structural position of Amorgos Unit with the Santorini Detachment System Pelagonian hanging wall imply their close spatial relationship. From all the above, we propose that Amorgos belongs to the upper plate of the CBU and is paleogeographically located at the southern Pelagonian margin.

The Jurassic meta-ophiolitic rocks of Cape Steno, Andros, Greece: a high-pressure/low-temperature m\xe9lange with Pelagonian affinity in the Cycladic Blueschist Unit?

This study aims at clarifying the relationship between the Cape Steno mélange, southern Andros, and the main tectonic units of the Attic-Cycladic Crystalline Belt. Jurassic protolith ages and geochemical characteristics indicate a Pelagonian affinity and point to a correlative relationship with the Tsiknias Ophiolite on Tinos Island. However, jadeitites and high-Si phengite in the gneisses clearly indicate a high-pressure metamorphic overprint that is unknown from the Tsiknias outcrop and other occurrences of the Upper Cycladic Unit. A correlation with the Cycladic Blueschist Unit (CBU) is an obvious assumption, but initially seemed difficult to reconcile with the Cretaceous protolith ages of meta-ophiolitic rocks from the CBU and distinct geochemical characteristics of associated jadeitites. The Jurassic ages of the Cape Steno rock suite either document a broader spectrum of source rocks than previously known from the CBU, or the existence of a distinct tectonic unit. We assume that the geological and tectono-metamorphic evolution of the Cape Steno occurrence is similar to that of the Makrotantalon Unit of NW Andros, which represents a Pelagonian subunit in the nappe stack of the CBU, with abundant slices of serpentinites, rare meta-gabbro and a metamorphic history comprising both Cretaceous and Eocene HP/LT episodes.

Structural Study and Detrital Zircon Provenance Analysis of the Cycladic Blueschist Unit Rocks from Iraklia Island: From the Paleozoic Basement Unroofing to the Cenozoic Exhumation

Detailed mapping and structural observations on the Cycladic Blueschist Unit (CBU) on Iraklia Island integrated with detrital zircon (DZ) U-Pb ages elucidate the Mesozoic pre-subduction and the Cenozoic orogenic evolution. Iraklia tectonostratigraphy includes a heterogeneous Lower Schist Fm., juxtaposed against a Marble Fm. and an overlying Upper Schist Fm. The contact is an extensional ductile-to-brittle-ductile, top-to-N shear zone, kinematically associated with the Oligo-Miocene exhumation. The DZ spectra of the Lower Schist have Gondwanan/peri-Gondwanan provenance signatures and point to Late Triassic Maximum Depositional Ages (MDAs). A quartz-rich schist lens yielded Precambrian DZ ages exclusively and is interpreted as part of the pre-Variscan metasedimentary Cycladic Basement, equivalent to schists of the Ios Island core. The Upper Schist represents a distinctly different stratigraphic package with late Cretaceous MDAs and dominance of Late Paleozoic DZ ages, suggestive of a more internal Pelagonian source. The contrast in the DZ U-Pb record between Lower and Upper Schist likely reflects the difference between a Paleotethyan and Neotethyan geodynamic imprint. The Triassic DZ input from eroded volcanic material is related to the final Paleotethys closure and Pindos/CBU rift basin opening, while late Cretaceous metamorphic/magmatic zircons and ~48–56 Ma zircon rims constrain the onset of Neotethyan convergence and high-pressure subduction metamorphism.

Manganese metallogenesis in the Hellenic arc: Case studies from a Triassic rift-related volcaniclastic succession of the Cycladic Blueschist Unit, Greece

The Triassic volcaniclastic sequence in the Cycladic Blueschist Unit (CBU) of Greece is known to contain several occurrences of metamorphosed Mn mineralization. Despite previous literature reports, a comprehensive and holistic review of the origin of these occurrences is hitherto lacking. Here we revisit the Mn metallogenic system of the CBU through a comprehensive study of Mn mineralisation at Varnavas area, Northern Attica, and its correlation with a similar occurrence at Mparades Hill, Andros island. Manganese mineralogy at both localities is manifested in a typical high-P metamorphic silicate assemblage dominated by piemontite, spessartine garnet, and minor pyroxmangite (rhodonite). Whereas at Andros Mn-rich subdomains contain brecciated braunite micronodules, preservation of tetravalent Mn oxides in a similar nodular form is documented from Varnavas, comprising dominant todorokite along with lesser hollandite, pyrolusite, and minor Mn-bearing hematite. The contrasting Mn oxide mineralogy and comparable textural characteristics at the two sites are tentatively interpreted as the result of locally incomplete reduction of precursor Mn(IV) phases during metamorphism. Bulk Mn concentrations of the studied materials generally do not exceed the value of 10 wt% Mn, unless small-scale subsampling of Mn-rich domains is undertaken. Key geochemical characteristics of the Mn-rich rocks include low transition metal concentrations (sum of Co + Ni + Cu + Zn between 0.02 and 0.06 wt%); positive-sloping, PAAS-normalised REE spidergrams at a maximum Ndsn/Ybsn ratio of 0.3; positive Ce anomalies, albeit of variable magnitude across individual samples; and high As (up to 1930 ppm) and Ba (up to 2767 ppm) contents. A combination of structural, geochemical and mineralogical evidence from the two localities along with published results from similar occurrences elsewhere (e.g., Kythnos) suggest that Mn-oxide accumulation in the CBU is genetically linked to hydrothermal venting in a back-arc rift setting during the Triassic. The geochemical variability recorded is attributed primarily to the variable mixing of a hydrothermal-sourced, hydrogenous metalliferous component that precipitated broadly contemporaneously with the deposition of the host tuffs. Low transition metal contents coupled with substantial enrichments in elements such as Ba, As, Pb and REY, attest to the felsic/intermediate character of back-arc magmatism/volcanism and associated hydrothermal activity. Primary Mn precipitates are thought to have been in the form of tetravalent Mn assemblages, which may locally be partially preserved through metamorphism, as appears to be the case in the Varnavas occurrence. The fully oxic and hydrogenous character of the precursor Mn(IV) oxy-hydroxides is supported by the consistently positive Ce anomalies observed in practically all samples from both sites. Although the Mn concentrations and distribution of the studied assemblages are sub-economic at best, we consider possible that their geographically widespread occurrence may still hold untapped potential for future discovery of commercially viable Mn ores sensu stricto, both in the Hellenic arc and in other regions of similar geotectonic and metallogenic activity.