Blend System Research Articles

The Effect of Epoxidized Soybean Oil on the Physical and Mechanical Properties of PLA/PBAT/PPC Blends by the Reactive Compatibilization.

Poly (lactic acid) (PLA)/poly (butylene adipate-co-terephthalate) (PBAT)/poly (propylene carbonate) (PPC) multi-phase blends were prepared by melt processing technique under the presence of compatibilizer with various composition. The effect on the physical and the mechanical property with/without ESO was characterized with spectrophotometric analysis, mechanical properties, thermal properties, rheological properties and barrier properties, and the structure-properties relationship was assessed. ​​The functional groups of PPC were found to effective to improve an interaction with carboxyl/hydroxyl group of PLA/PBAT binary blends to enhance the mechanical and physical properties on multi-phase blend system. The presence of PPC in PLA/PBAT blend affected the reduction of voids on the interface phase resulting in enhancing the oxygen barrier properties. With addition of ESO, the compatibility of ternary blend was found to be enhanced since the epoxy group of ESO reacted with the carboxyl/hydroxyl group of PLA, PBAT, and PPC, and under the condition with critical content of 4 phr of ESO, the elongation behavior dramatically increased as compared to that of blends without ESO while affecting reduction of oxygen barrier properties. The effect of ESO as a compatibilizer was clearly observed from the overall performances of ternary blends, and the potential feasibility of the PLA/PBAT/PPC ternary blends as packaging materials was confirmed at this study.

Optimization of Chitosan: Methylcellulose polyblend to obtain highly amorphous polymer matrix useful for ion transportation

Solid biopolymer blend systems consisting of chitosan (CH) and methylcellulose (MC) have been prepared in various compositions through the solution casting method and are characterized by X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). The XRD data revealed that the blend composed of 30 wt.% of MC is found to be more amorphous. Structural analysis and the extent of interaction between the two polymers, i.e., CH and MC were concluded through FTIR analysis. The dielectric results also show that the blend composed of 70 wt.% of CH shows the highest value of the dielectric constant. The blend system consisting of 70 wt.% of CH and 30 wt.% of MC exhibited good thermal stability and the lowest glass transition temperature ({T}_{g}).Graphical

A New Strategy to Improve the Toughness of Epoxy Thermosets-By Introducing Poly(ether nitrile ketone)s Containing Phthalazinone Structures.

As high brittleness limits the application of all epoxy resins (EP), here, it can be modified by high-performance thermoplastic poly(ether nitrile ketone) containing phthalazinone structures (PPENK). Therefore, the influence of different PPENK contents on the mechanical, thermal, and low-temperature properties of EP was comprehensively investigated in this paper. The binary blend of PPENK/EP exhibited excellent properties due to homogeneous mixing and good interaction. The presence of PPENK significantly improved the mechanical properties of EP, showing 131.0%, 14.2%, and 10.0% increases in impact, tensile, and flexural strength, respectively. Morphological studies revealed that the crack deflection and bridging in PPENK were the main toughening mechanism in the blend systems. In addition, the PPENK/EP blends showed excellent thermal and low-temperature properties (-183 °C). The glass transition temperatures of the PPENK/EP blends were enhanced by approximately 50 °C. The 15 phr of the PPENK/EP blends had a low-temperature flexural strength of up to 230 MPa, which was 46.5% higher than EP. Furthermore, all blends exhibited better thermal stability.

Facile Side Chains Optimization of Y‐series Acceptor Enables High Performance Binary Non‐halogenated Solvent‐Processed Organic Solar Cells with Excellent Fill Factor of 79%

Most cutting‐edge performance binary bulk heterojunction organic solar cells (OSCs) with high power conversion efficiency (PCE) over 18% generally use harmful halogenated solvent systems to guarantee the optimal morphology of active layers, urging more investigations on the non‐halogenated solvent processed OSCs and their further large‐scale devices fabrication. Herein, two BTP‐eC9 analogs, BTP‐eC9‐EH and BTP‐eC9‐HD, were synthesized to investigate the effect of alkyl chain length on the solubility and photovoltaic properties systematically. Despite the subtle side‐chain engineering, the PM6: BTP‐eC9‐HD based device exhibited an outstanding PCE of 17.5% and a remarkable fill factor of 79% in the toluene processing binary blend system, which precedes the toluene processing PM6: BTP‐eC9 based binary blend system (17.1%). The combined investigation provides a valuable insight into the modulation of branched alkyl chains, which can serve as an effective approach for adjusting the aggregation and molecular packing of A‐DA′DA‐type Y‐series based non‐fullerene acceptors to balance the materials solubility and solvents selection, thereby achieving high‐performance large‐scale OSCs processed from non‐halogenated solvents.

Mechanical and Gas Barrier Properties of Poly(Lactic Acid) Modified by Blending with Poly(Butylene 2,5-Furandicarboxylate): Based on Molecular Dynamics

Three blends of Poly(butylene 2,5-furandicarboxylate) (PBF) and Poly(lactic acid) (PLA) blends were modeled using molecular dynamics simulations, with PBF contents of 10%, 20%, and 30%, respectively. The study investigated the compatibilities of the blends, as well as the mechanical and gas barrier properties of the composite systems. The molecular dynamics simulation results show that: (1) PLA and PBF have good compatibility in the blend system; (2) the optimal toughness modification was achieved with a 20% PBF content, resulting in a 17.3% increase in toughness compared to pure PLA; (3) the barrier properties of the blend for O2, CO2, and N2 increased when increasing the PBF content. Compared to pure PLA, the diffusion coefficients of the O2, CO2, and N2 of the blends with 30% PBF decreased by 75%, 122%, and 188%, respectively. Our simulation results are in good agreement with the actual experimental results.

Functionalization of various coffee husk biofibers on the rheological and thermomechanical properties of poly(butylene succinate)-urethane blended composites

Many studies have reported that surface-functionalized biofibers originating from plant waste can be used to improve the compatibility and processability of polymer blend systems. This study investigated the effects of size distribution and surface treatment of coffee husk (CH) biofibers on the rheological and thermomechanical properties of poly(butylene succinate)/thermoplastic polyurethane polymer blend composite. CH is a coffee waste with interlinked complex macromolecular structure of lignocellulose materials like cellulose, hemicellulose, and lignin. It was found that the handling and processability of the composites improved after the CH was surface-functionalized with diisocyanate/methacrylate prior to composite fabrication. Smaller-sized surface-treated CHs showed superior processability owing to the entanglement of fibers through the matrices associated with the improvement of interfacial adhesion. Therefore, the frequency-dependent rheological test revealed an increase in complex viscosity and storage modulus with the surface treatment and size reduction of CHs. Regardless of the size distribution, the degree of crystallinity of poly(butylene succinate) in the composites filled with surface-treated CHs reduced by about 20%. The composites with treated CHs also demonstrated superior thermal stability than their corresponding composites with raw CHs.

Fabrication of 3D Printed Polylactic Acid/Polycaprolactone Nanocomposites with Favorable Thermo-Responsive Cyclic Shape Memory Effects, and Crystallization and Mechanical Properties

In this work, 3D printed polylactic acid (PLA)/polycaprolactone (PCL) nanocomposites with favorable thermo-responsive cyclic shape memory effects (SMEs) and crystallization and mechanical properties were fabricated using a two-step method. First, an isocyanate-terminated PCL diol (PCL-NCO) was synthesized through the reaction between isocyanate groups of hexamethylene diisocyanate and active hydroxyl groups of PCL diol, and its physicochemical properties were characterized. A PLA/PCL blend with a PCL content of 50 wt% was fabricated via fused filament fabrication (FFF) 3D printing, and the influence of the PCL-NCO on the SME of the PLA/PCL blend was studied. The results indicated that the PCL-NCO significantly improved the cyclic shape memory performance of 3D printed PLA/PCL blends and was proved to be an effective interface compatibilizer for the blend system. Subsequently, the structure and properties of 3D printed PLA/PCL nanocomposites were investigated in detail by adding cellulose nanocrystal-organic montmorillonite (CNC-OMMT) hybrid nanofillers with different contents. It was found that the hybrid nanofillers greatly enhanced crystallization and mechanical properties of the nanocomposites due to adequate dispersion. The modification of the PLA/PCL blend and the preparation of the 3D printed nanocomposite can not only prolong the service life of a shape memory polymer product, but also broaden its application scope in advanced fields.

Fabrication and Properties of Polycaprolactone/Poly(Butylene Succinate) Blends Based on Electrospinning

Electrospinning technology is famous for its simple preparation, and accurate and easy control of process parameters. It is widely used in ultrafine filtration membrane and biological tissue engineering support. Polycaprolactone (PCL) and poly(butylene succinate) (PBS) have good biocompatibility and are commonly used materials in electrospinning. In this study, the relationship between the electrospun sample, process parameters, and spinning solution of PCL/PBS blend system was systematically studied in an electrospinning experiment. The morphology characteristics, thermodynamic properties, and microstructure of the electrospun sample were screened by scanning electron microscopy, thermogravimetric analysis, differential scanning calorimetry, and X-ray diffraction. The optimum conditions of electrospinning with high practical value were obtained.

Carbon Nanotube Migration in a Compatibilized Blend System, Leading to Kinetically Induced Enhancement in Electrical Conductivity and Mechanical Properties

Kinetic factors that facilitate carbon nanotube (CNT) migration in a polymer blend from a high-density polyethylene (HDPE) phase to a poly (p-phenylene ether) (PPE) phase were studied, with the objective to induce CNT migration and localization at the interface. Herein, a CNT filler was pre-localized in an HDPE polymer and then blended with PPE at different blend compositions of 20:80, 40:60, 60:40, and 80:20 of PPE/HDPE at a constant filler concentration of 1 wt%. The level of CNT migration was studied at different mixing times of 5 and 10 min. The electrical conductivity initially increased by 2-3 orders of magnitude, with an increase in the PPE content up to 40%, and then it decreased significantly by up to 12 orders of magnitude at high PPE content up to 100%. We determined that the extent of migration was related to the difference in the melt viscosity between the constituent polymers. A triblock copolymer styrene-ethylene/butylene-styrene (SEBS) was used to improve the blend miscibility, and 2 wt% copolymer was found to be the optimum concentration for the electrical properties for the two blend compositions of 20:80 and 80:20 of PPE/HDPE, at a constant filler concentration of 1 wt%. The introduction of the SEBS triblock copolymer significantly increased the conductivity almost by almost four orders of magnitude for PPE/HDPE/80:20 composites with 1 wt% CNT and 2 wt% SEBS compared to the uncompatibilized blend nanocomposite. The mechanical strength of the compatibilized blend nanocomposites was found to be higher than the unfilled compatibilized blend (i.e., without CNT), uncompatibilized blend nanocomposites, and the pristine blend, illustrating the synergistic effect of adding nanofillers and a compatibilizer. SEM and TEM microstructures were used to interpret the structure-property relationships of these polymer blend nanocomposites.

Preparation of skim natural rubber and polypropylene blends via melt blending: A study on physico-mechanical properties

High percentage of non-rubbers in Skim Natural Rubber (SNR) has restricted its use in manufacture of advanced rubber products. SNR were melt blended with polypropylene (PP) at different blend ratios to generate thermoplastic elastomers (TPEs). Standard Lanka Rubber (SLR) and PP blends were also prepared for the purpose of comparison. Tensile, hysteresis, hardness, water absorption, and dynamic mechanical properties of unvulcanized (UV) and dynamically vulcanized (DV) SNR/PP and SLR/PP blends were compared. Stress-strain behavior and TPE characteristics of both blends were similar. Tensile strength and modulus of SNR/PP blends decreased with the increase of SNR percentage. Elongation at break showed a decrease in UV blends and maxima at 50:50 blend ratio for DV blends. Dynamic vulcanization of the rubber phase improved tensile properties and hardness of the blends. Water absorption studies showed significantly higher equilibrium moisture content in SNR/PP blends, while difference in this property diminished with the increase of rubber phase. Water absorption and equilibrium moisture content decreased with dynamic vulcanization of rubber phase. Dynamic mechanical analysis confirmed multi-phase microstructure of the blends. Both blend systems showed similar dynamic mechanical properties and almost comparable thermo-mechanical properties confirming the potential of SNR as an alternative to SLR for selected applications.

High-reactive silica nanosheets as compatibilizers for immiscible PLLA/PBAT polymer blends

While nanoparticles were considered to be the most promising compatibilizers for immiscible polymer blends, high-efficient nanoparticle-based compatibilizers were still under development. Herein, a high-reactive silica nanosheet (HRN) compatibilizer with excellent compatibilization effect was synthesized and its compatibilization effect was investigated. The HRN compatibilizer was fabricated by skillfully melt-blending amino functionalized silica hollow spheres (AHS) and the poly(styrene-co-glycidyl methacrylate) (PSGMA) with average ten reactive epoxy groups per chain. During the mixing, the AHS were crushed to nanosheets upon the strong shearing and simultaneously grafted PSGMA chains on nanosheets via the reaction of epoxy and amino groups. The PSGMA with high epoxy groups content endowed the HRN with high reactivity. To demonstrate the compatibilization efficiency of our high-reactive compatibilizer, different amounts of HRN were incorporated into the immiscible polylactic (l-acid)/polybutylene adipate terephthalate (PLLA/PBAT) blend, a blend system widely applied in packing and agricultural films, to investigate and compare the changes in morphologies and mechanical properties. Only 3 wt% addition of HRN compatibilizer could significantly decrease the droplets size and dramatically improve the tensile strength and elongation at break of the blend by 1.4 and 23 times. The present work provided a new idea for the development of nanoparticle-based compatibilizer with high compatibilization efficiency.

Rheological characterization of linear low‐density polyethylene–Fischer–Tropsch wax blends

AbstractThe thermal and rheological behavior of blends of a Fischer–Tropsch (F‐T) wax with linear low‐density polyethylene (LLDPE) were investigated by differential scanning calorimetry and cone‐and‐plate rheometry. F‐T wax is used as a possible low‐cost processing aid alternative for LLDPE masterbatch applications. The melting‐ and crystallization thermograms indicated a two‐phase solid‐state morphology and full compatibility in the fully molten material. Both the high‐melting and low‐melting phase contained co‐crystalized wax and polymer. Rheological data of F‐T wax‐LLDPE blends over the full composition range was also obtained. The zero‐shear viscosity data was adequately predicted by the Friedman and Porter mixing rule: with α = 3.4. This implies that the melt viscosity is dominated by the effects of polymer chain entanglement and that the main consequence of adding the wax is to reduce the concentration of the polymer present. The complex viscosity also fitted this model albeit with α = 4.81. All Han plots, that is, plots of the logarithm of the storage modulus (G') against the logarithm of the loss modulus (G"), were linear. Within the experimental uncertainty, they were essentially unaffected by variations in blend composition, temperature and the applied angular frequency. Additionally, Cole–Cole plots were also in agreement that wax‐LLDPE blends are miscible at melt state. This supports full miscibility of the F‐T wax‐LLDPE blend system down to temperatures as low as 120°C.

Improvement of fresh and hardened properties of a sustainable HFRSCC using various powders as multi-blended binders

Hybrid fiber-reinforced self-compacting concrete (HFRSCC) has been very popular in recent years due to its high mechanical, durability and flexural performance. HFRSCC properties are also closely related to its workability properties. Therefore, a high proportion of binder material is required to provide a uniform distribution of the fibers in the matrix. The use of mineral admixtures replaced by cement has a vital importance to improve especially the workability of HFRSCC mixtures, resulting in reduction of CO2 emission because the production of 1 ton Portland cement releases about 1 ton of CO2. For this reason, in this study, the effects of multi-blended (binary, ternary and quaternary) binders containing Portland Cement (PC), fly ash (FA), ground granulated blast furnace slag (BS) and limestone powder (LP) on the workability (Slump-flow, T500, J-ring and V-funnel) and hardened (compressive, splitting tensile and flexural tensile strength) properties of HFRSCC as well as flexural performance for 7, 28 and 90 days are investigated. The first of three group mixtures in this study consists of only control mixture (Control) without fiber and mineral admixture blends (MAB), in second group there are four SCC mixtures with only MAB replaced by cement as binary, ternary, quaternary SCC-MAB and the last group also includes four SCC mixtures with both mineral admixtures same as second group and hybrid fiber (HFRSCC-MAB). The total binder amount, water/binder ratio, fine aggregate/all aggregate ratio and fiber hybridization are kept constant while the mineral admixture type and blending system are variable parameters. According to the test results, among the HFRSCC-MAB blends, the quaternary blend system performed the best in terms of workability, followed by the binary blends containing FA. In addition, when it came to ultimate strengths, hybrid fiber-reinforced samples with ternary blends performed best for compressive strength, while hybrid fiber-reinforced samples with binary blends containing FA performed best for splitting tensile and flexural tensile strengths. Finally, it has been seen that the use of various powders as multi-blended binders is a successful solution to obtain high workability for uniform distribution of fibers in HFRSCC as well as high compressive strength and flexural performance, resulting in economical, eco-friendly and sustainable composite.

Sustainable production of recycled rubber waste composites with various epoxy systems: A comparative study on mechanical and thermal properties

In this study, ethylene-propylene-diene monomer rubber (EPDM) and tire waste powder (TW) were selected as filling materials for toughening various epoxy matrices, lowering composite materials costs and converting these wastes into valuable resources. Two types of bisphenol-A epoxy resins (ER1 and ER1diluted), and three types of epoxy resin blend systems with ER1diluted, CTBN rubber modified (ER2), and polyurethane modified (ER3) epoxies in 1:1 wt ratio were used as matrices. The effects of the rubber ratio and type, also the epoxy matrix on the composite properties were investigated. The TW composites' mechanical and thermal properties were higher than those of the EPDM composites. The best results for resin mixtures were obtained with ER3. The most suitable filling ratio of EPDM and TW varied between 20% and 30% by weight, depending on the matrix type. TW addition increased the impact strength of the ER1diluted and ER3-ER1diluted epoxy matrices. In terms of mechanical properties, the low ambient temperature was found to be more suitable than an aqueous medium.

Bio-based polymer blend with tunable properties developed from paramylon hexanoate and poly(butylene succinate)

Paramylon hexanoate (PaHe) is an ester derivative of paramylon, a storage polysaccharide photosynthesized by Euglena. In this study, PaHe was blended with poly(butylene succinate) (PBS) by melt-extrusion and characterized for its physical properties. Although the blend was immiscible even in low loading of PaHe (2.5–10 wt%), the elongation at break (from 611 to 980%) and modulus of toughness (from 1260 to 2248 MPa) improved compared to neat PBS. This was attributed to the unique micro-bead morphology in blends with low PaHe loading revealed using selective enzymatic etching technique. In addition, the hydrophobicity of PBS was enhanced as a result of inclusion of hydrophobic acyl groups in the blend system. Furthermore, X-ray analyses of uniaxially stretched films showed high degree of orientation (94–96%) with tensile strengths up to 244 MPa. PBS/PaHe blends also had good thermal stability making it viable for sustainable packaging and mulch-film applications.

High moisture extrusion of meat analogues using mung bean (Vigna radiata L.) protein and flour blends: investigations on morphology, texture and rheology

SummaryHigh moisture meat analogues (HMMA) from the blends of mung bean protein isolate (MPI) and mung bean flour (MF) at different MF contents (10%, 20% and 30%) were prepared using high moisture extrusion (HME) and die texturisation. Pure MPI could not be extruded and texturised. Therefore, MF was added to improve the extrudability and to assist in the texturisation of HMMA. Rheological analysis performed under a range of simulated conditions in the cooling die demonstrated the decrease in both storage and loss moduli of the blend systems as compared to pure MPI, which explained the flow capability and extrudability of the blends during die texturisation. The effect of blend compositions on morphology and texture of the extrudates was investigated. All blend extrudates showed an anisotropic layer structure with a less pronounced velocity profile with increasing MF content. The microstructure of these extrudates revealed the presence of a multiphase system of the remaining MF fragments dispersed in a continuous protein matrix, thereby facilitating phase separation, loosening the protein structure and decreasing textural properties of HMMA as MF content increased. The results demonstrate that the blend of MPI and MF is a promising ingredient to prepare mung bean‐based HMMA with the customised texture properties.

Development of soft polymer blend for copper ion detection by electrochemical route

AbstractIn the present work, we have prepared polymer blend of polyvinyl butyral (PVB) and poly(3,4‐ethylenedioxythiophene):poly(styrene sulfonate) (PEDOT:PSS) by solution casting route. Blends were tested for various structural, morphological, and electrochemical techniques. Structural properties were investigated by XRD technique exploring the contribution conducting polymer in host system PVB exhibit amorphous nature. COO functional group contributed in blend configuration was confirmed by FTIR technique. Clustering of PEDOT:PSS in blend system were observed by scanning electron microscopy. Subatomic surface topology and increased roughness due to blending concentration of conducting polymer were analyzed by probe microscopy techniques. Increased softness of blends was confirmed by shore “A” durometer test. PVB/PEDOT:PSS blend was drop casted on glassy carbon electrode and employed for detection of various metal ions. It was deployed for electrochemical sensing of Cu2+ion. Electrochemical sensing investigation was done by differential pulse voltammetry technique. Performance of blends at 4.5 pH, 200 s deposition time and −1.2 V deposition potential was more accurate and sensitive toward detection of Cu2+ion. The developed electrochemical sensor exhibited rapid sensing response in the range of 1.6 to 8.3 μm.Furthermor,e an influence of many analytical parameters such as pH, deposition time and deposition potential on Cu2+ion investigation were disclosed. This investigation may be feasible to construct a very simple, fast, and efficient electrochemical sensing system for toxic heavy metals at low‐level concentration.

Space Charge Contributions to the Dielectric Response and Breakdown Strength of High-Temperature Poly(ether imide)/Polyimide Blends

Dielectric properties of poly(ether imide)/polyimide blends, prepared by the solution casting method, were measured over broad frequency and temperature ranges and compared to the response of pristine polymers. While the intrinsic dielectric permittivity only slightly decreases, the electrical conductivity of blends is approximately 40% lower than the conductivity of poly(ether imide) and polyimide. A detailed low-frequency investigation revealed a significant reduction of accumulated space charges in blend systems and thus confirmed that the enhancement of their breakdown strength occurs due to strong electrostatic interactions between the differently charged phenyl groups in poly(ether imide) and polyimide chains. Because a notable influence of absorbed water on the overall dielectric response was found, particularly in the presence of γ relaxation, the impact of high-temperature annealing on the dielectric breakdown strength was also examined.

β-Sheet Structure Formation within Binary Blends of Two Spider Silk Related Peptides.

Intrinsically disordered proteins (IDPs) play an important role in molecular biology and medicine because their induced folding can lead to so-called conformational diseases, where β-amyloids play an important role. Still, the molecular folding process into the different substructures, such as parallel/antiparallel or extended β-sheet/crossed β-sheet is not fully understood. The recombinant spider silk protein eADF4(Cx) consisting of repeating modules C, which are composed of a crystalline (pep-c) and an amorphous peptide sequence (pep-a), can be used as a model system for IDP since it can assemble into similar structures. In this work, blend films of the pep-c and pep-a sequences were investigated to modulate the β-sheet formation by varying the molar fraction of pep-c and pep-a. Dichroic Fourier-transform infrared spectroscopy (FTIR), circular dichroism, spectroscopic ellipsometry, atomic force microscopy, and IR nanospectroscopy were used to examine the secondary structure, the formation of parallel and antiparallel β-sheets, their orientation, and the microscopic roughness and phase formation within peptide blend films upon methanol post-treatment. New insights into the formation of filament-like structures in these silk blend films were obtained. Filament-like structures could be locally assigned to β-sheet-rich structures. Further, the antiparallel or parallel character and the orientation of the formed β-sheets could be clearly determined. Finally, the ideal ratio of pep-a and pep-c sequences found in the fibroin 4 of the major ampullate silk of spiders could also be rationalized by comparing the blend and spider silk protein systems.

Effect of titanium dioxide on the structural, thermal, and electrical properties of chlorinated natural rubber/poly (indole) blend nanocomposites for flexible nanoelectronic devices

AbstractThe synthesis of highly flexible conductive rubber blend nanocomposites using a conductive polymer with metal oxide is a new and promising approach. In this work, the effect of titanium dioxide (TiO2) on the performance of chlorinated natural rubber/polyindole (Cl‐NR/PIN) blend nanocomposites was systematically studied. Fourier‐transform infrared spectra revealed the successful incorporation of nanoparticles in the blend system. UV analysis assessed the increased absorption spectra of the nanocomposite compared to the pure blend. The X‐ray diffraction confirms the presence of TiO2 nanostructure in the blend. The high resolution transmission electron microscope results exhibited the uniform dispersion of TiO2 in the blend. Differential scanning calorimetry and thermogravimetric analysis show the increased glass transition temperature and thermal stability of the blend nanocomposite with an increase in TiO2 concentration. The linear low‐frequency AC conductivity demonstrated the occurrence of electrode polarization and the exponential increase in AC conductivity after a threshold frequency illustrated the semiconducting behavior of the composites. The maximum dielectric constant and AC conductivity were measured for the composite with 5 wt% filler loading, as the threshold level for the maximum interfacial contact. The hopping conduction, activation energy, improved conductivity and dielectric properties suggest that these blend nanocomposite films are promising candidates for the development of flexible energy storage devices.