Ladle treatment of hot metal by magnesium-bearing powder wire is in increasing use at metallurgical enterprises, since it does not involve large capital and operating expenses and it ensures effective desulfurization, stability of the results, and considerably reduced toxic emissions [1]. This technology is used today at OAO Mariupol’skii Metallurgicheskii Kombinat im. Il’icha, OAO Tulachermet, OAO Lipetskii Metallurgicheskii Zavod Svobodnyi Sokol (LMZSS), and elsewhere [2, 3]. At OAO LMZSS, ladle treatment of hot metal by magnesium-bearing powder wire is included in the production cycle for commercial cast iron and cast-iron pipe. In the blast-furnace shop, a push-rod system is installed in the region of the casting machines; both commercial iron cast in pigs and hot metal sent to the pipe-casting shop for further treatment in induction furnaces and pipe casting undergo desulfurization in 100-t ladles. In the mixer department of the pipe-casting ship, where necessary, the hot metal undergoes desulfurization in 30-t ladles to ensure a sulfur content of less than 0.012%. In the modification section, the hot metal is treated in 7-t ladles for 5‐10 min after discharge from the induction furnaces. After treatment, the ladle with the hot metal is sent on a trolley directly to the section for centrifugal pipe casting [4]. The technology ensures a stable residual-magnesium content of more than 0.025% throughout the pipe-casting cycle, permits considerably more efficient use of the magnesium, and significantly reduces the costs of modification; the pipe obtained meets all the standard requirements regarding microstructure and mechanical properties. Magnesium‐staurolite wire is used for desulfurization, and ferrosilicon‐magnesium wire is used for modification. The characteristics of ladle desulfurization of hot metal by magnesium‐staurolite/ferrosilicon‐magnesium wire in 30-, 100-, and 140-t ladles are shown in the table. (The data for 140-t ladles are taken from [4].) The results indicate that desulfurization is highly effective when using magnesium-bearing powder wire. Ladle treatment of hot metal by magnesium‐silicon alloy considerably improves the efficiency of magnesium utilization. The cost of removing 0.01% S is $0.5‐ 1.0/t if the initial content is ≥ 0.03% S, and $1.2‐1.6/t if the initial content is ≤ 0.02%. The degree of magnesium assimilation for the different groups of hot metal at OAO LMZSS is 90.2‐98%; the coefficient of magnesium utilization in sulfur removal K Mg‐S is 28.8‐46.4%; the magnesium consumption is 0.3‐0.5 kg/t. In steel production, treatment of the melt with calcium-bearing reagents is very effective and, in view of non-Russian experience, essential. In the production of high-quality metal for major gas and oil pipelines, shipbuilding, and the construction industry, ladle treatment with calcium-bearing powder wire is a key part of steel production and an effective means of improving the properties of liquid and solid steel. Calcium has a significant influence of the kinetics of steel reduction, refining, modification, and microalloying [2, 5]. At metallurgical enterprises where the melt is treated with calcium, the casting of steel reduced by aluminum is not a problem. The negative influence of alumina in the melt and in the final product is eliminated; the content of harmful impurities, oxides, and sulfides is reduced; and the composition and shape of the nonmetallic inclusions are modified. This improves the steel quality. The relative elongation is increased by 10‐15%, and the impact strength of thick rolled sheet is increased (by a factor of 1.5‐1.8), with simultaneous increase in strength (by 5‐10%) and decrease in the cold-brittleness threshold (by 15‐20 ° C). The surface
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