Black Carbon Concentrations Research Articles

Investigation of 200 anthropogenic activities in a representative alpine peatland in the Altay Mountains, northwestern China

Peatlands records can be used to reconstruct and understand the history of environmental evolution, as well as a more accurate reflection of human activities. The black carbon (BC) and polycyclic aromatic hydrocarbons (PAHs) are ideal natural archives of anthropogenic activities. To identify the information of anthropogenic activities recorded by peatlands in the middle and high latitudes of the alpine mountains in the arid and semi-arid regions of China. this study analyzed the concentrations of BC, δ13C ratios of BC, PAHs, and molecular diagnostic ratios of PHAs (including Benzo(a) anthracene (BaA), Chrysene (Chr), fluoranthene (Flt), anthracene (Ant), phenanthrene (Phe), Benzo(a) pyrene (BaP), and pyrene (Pyr) in a 30-cm peat profile from the Altay Mountain, northwestern China. Our results revealed concentrations of BC from 11.71 to 67.5 mg·g−1, and PAHs from 168.09 to 263.53 ng·g−1. The δ13CBC value ranged from − 31.37 to − 26.27‰, with an average of − 29.54‰, indicating that the BC mainly comes from biomass combustion. The ratios of BaA/(BaA + Chr), Flt/(Flt + Pyr), and Ant/(Ant + Phe) exceeded 0.35, 0.5, and 0.1, respectively, revealing that the PAHs pollutants mainly originated from the combustion of biomass and fossil fuel burning. Furthermore, based on these findings and our knowledge of social development in Altay, industrial transport and tourism have influenced the emission, transport, and deposition of BC and PAH in peatlands in the Altay mountains since the 1980s. After 1980, pollutant concentrations decreased with the implementation of environmental policies. The results not only reveal the influence of anthropogenic activities on the sedimentary characteristics of peatlands in the Altay Mountains, but also provide an important theoretical basis for the conservation of fragile mountain peatlands.

History of human activity in South China since 7 cal ka BP: Evidence from a sediment record in the South China Sea

Human modifications of the Earth System have been getting increasing attention and this has resulted in the concept of the “Anthropocene”. A complete sequence of human-environment interactions needs to be reconstructed to define the onset of the Anthropocene. To address the chronological gaps and provide a general history of human impact in South China during the Holocene, we present a comprehensive reconstruction of the vegetation, chemical weathering, and heavy metal emissions in the Pearl River and Hainan catchments since 7.0 cal ka BP, using a continuous record of black carbon, clay minerals, and major and trace element concentrations of sediment in Core ZK001 taken from the northwestern South China Sea. Based on high-resolution sediment records, combined with archaeological and historical documents, we propose that human impact in South China can be divided into three stages: a hunting-gathering age (7.0–2.9 cal ka BP), a transitional period (2.9–2.0 cal ka BP) and an intensive farming age (<2.0 cal ka BP). Climate controlled both the vegetation and chemical weathering intensity before 2.9 cal ka BP, after which forest clearance by human-induced fire became significant. Along with population growth and technological progress, enhanced human activities including deforestation, cultivation, and metallurgical activities, gradually superseded natural processes and profoundly impacted the environment in South China, especially after 2.0 cal ka BP. Combined with previous studies from the Pearl River catchment, the Anthropocene likely commenced at 2−3 cal ka BP at least in South China.

Indoor and outdoor air quality in street corner kiosks in a large metropolitan area

Poor air quality in workplaces constitutes a great concern on human health as a good fraction of our time is spent at work. In Greece, very unique workplaces are the street corner kiosks, which are freestanding boxes placed on sidewalks next to city streets and vehicular traffic, where one can find many consumer goods. As such, its employees are exposed to both outdoor and indoor air pollutants. Very few studies have examined the occupational exposure of kiosk workers to air pollutants, and thus the magnitude of this unique indoor and outdoor exposure remains unknown. The objective of this study is to investigate and compare the levels of indoor and outdoor particulate matter (PM10 and PM2.5), ultrafine particles (UFPs) and black carbon (BC) in different kiosks located in Athens, Greece, in urban-traffic and urban-background environments. Continuous measurements of the above-mentioned pollutants were carried out on a 24-h basis over 7 consecutive days at three kiosks from September to October 2019. Indoor PM10 concentrations in the urban kiosk ranged from 19.0 to 44.0 μg/m3, PM2.5 values ranged from 14.0 to 33.0 μg/m3, whereas BC concentrations ranged from 1.2 to 7.0 μg/m3 and UFPs from almost 9.5 to 47.0 × 103 pt/cm3. Outdoor PM10 and PM2.5 measurements ranged from 29.0 to 59.0 μg/m3 and from 22.0 to 39.0 μg/m3, respectively. BC outdoor concentrations ranged from 1.1 to 2.2 μg/m3. The mean hazard quotient (HQ) for PM10 (4.9) and PM2.5 (4.7) among all participants was >1. The health risk of exposure to PM10 and PM2.5 was found to be at moderate hazard levels, although in some cases we observed HQ values higher than 10 due to high PM10 and PM2.5 concentrations in the kiosks. Overall our study indicates that people working at kiosks can be exposed to very high concentrations on particulate pollution depending on a number of factors including the traffic that strongly depends on location and the time of the day.

Significant changes in the physicochemical properties of BC-containing particles during the cold season in Beijing

The ambient air quality has improved significantly under strict emission controls in Beijing, China over the last decade. Black carbon (BC), as a short-lived climate forcer in ambient aerosols, profoundly impacts the air quality and climate. Previous studies have demonstrated a decline in the mass concentration of BC. In this study, we characterized the chemical compositions and size distributions of BC-containing particles during the cold season of 2022 in Beijing using state-of-the-art instruments capable of exclusively measuring BC-containing particles. The optical properties of BC-containing particles were further calculated based on the Mie theory. Moreover, we compared the properties of BC-containing particles in 2022 with the results of previous studies. The results showed that the diameters of BC cores became larger while the coating thickness of BC-containing particles became thinner in 2022. For the coating materials, the mass fraction of nitrate increased obviously, and even replaced organic matter as the dominant component during the peak of the pollution period. Variations in chemical compositions and size distributions resulted in lower mass absorption cross-sections (MAC) of BC-containing particles from 10.5 ± 1.1 m2/g in 2016 to 7.3 ± 0.8 m2/g in 2022, reduced by 30.5%. Our results demonstrate the synergistic benefits of air pollution control in improving air quality and mitigating climate change. Therefore, the MAC of BC adopted in climate models should vary with the changing air pollution levels. This study emphasizes that it is imperative to conduct long-term observations of BC-containing particles to better estimate BC's climate effects.

Measuring and modeling of residential black carbon concentrations in two megacities, China

Indoor exposure to black carbon (BC) may differ greatly from ambient concentrations measured at stationary monitoring stations. This study characterized the variation between measured indoor and outdoor levels of BC and developed models to predict BC exposures within residences. Indoor and outdoor PM2.5 filter samples were collected for five consecutive days from 66 residences in Beijing (BJ) and Nanjing (NJ), China, across two seasons. City-specific indoor BC models were developed using liner mixed effect models and assessed by R2 and root mean square error (RMSE). The mean (SD) of indoor BC concentrations in BJ and NJ were 3.0 μg/m3 (0.6 μg/m3) and 3.2 μg/m3 (0.5 μg/m3), respectively. Both the indoor and outdoor BC concentrations were significantly higher during heating season than non-heating season. In general, indoor levels of BC were strongly associated with outdoor measurements (BJ: rs = 0.74, p < 0.001; NJ: rs = 0.76, p < 0.001), but were often lower. The critical determinants influencing indoor BC exposures varied by city, including outdoor BC concentration, window opening time, presence of indoor smoking, and the volume of the room where the indoor monitor was placed. The final models accounted for 66.4%–86.5 % (RMSE: 0.070–0.106) of the variance in residential-indoor BC exposures. By incorporating the key BC exposure determinants identified here, this modelling approach can improve the estimates of BC exposure and better link BC exposure to health risk assessment.

Air quality on UK diesel and hybrid trains

Concentrations of particulate matter (PM10, PM2.5), ultrafine (UFP), particle number (PNC), black carbon (BC), nitrogen dioxide (NO2) and nitrogen oxides (NOX) were measured in train carriages on diesel and bi-mode trains on inter-city and long-distance journeys in the United Kingdom (UK) using a high-quality mobile measurement system. Air quality on 15 different routes was measured using highly-time resolved data on a total of 119 journeys during three campaigns in winter 2020 and summer 2021; this included 13 different train classes. Each journey was sampled 4–10 times with approximatively 11,000 min of in-train concentrations in total. Mean-journey concentrations were 7.552 µg m−3 (PM10); 3.936 µg m−3 (PM2.5); 333–11,300 # cm−3 (PNC); 225–9,131 # cm−3 (UFP); 0.6–11 µg m−3 (BC); 28–201 µg m−3 (NO2); and 130–3,456 µg m−3 (NOX). The impact of different factors on in-train concentrations was evaluated. The presence of tunnels was the factor with the largest impact on the in-train particle concentrations with enhancements by a factor of 40 greater than baseline for BC, and a factor 6 to 7 for PM and PNC. The engine fuel mode was the factor with the largest impact on NO2 with enhancements of up to 14-times larger when the train run on diesel compared to the times running on electric on hybrid trains. Train classes with an age < 10 years observed the lowest in-train PM, BC and NOX concentrations reflecting improvements in aspects of rail technology in recent years. Air quality on UK diesel trains is higher than ambient concentrations but has lower PM2.5 and PNC than most other transport modes, including subway systems, diesel and petrol cars. This paper adds significantly to the evidence on exposure to poor air quality in transport micro-environments and provides the industry and regulatory bodies with reference-grade measurements on which to establish in-train air quality guidelines.

Optical properties and radiative forcing of carbonaceous aerosols in a valley city under persistent high temperature

Carbonaceous aerosols were collected in the valley city of Baoji city in Northern China in August 2022. The light absorption characteristics and influencing factors of black carbon (BC) and brown carbon (BrC) were analyzed, and their radiative forcing was estimated. The results showed that the light absorption of secondary brown carbon [AbsBrC,sec (370)] was 7.5 ± 2.4 Mm−1, which was 2.5 times that of primary brown carbon [AbsBrC,pri (370), 3.0 ± 1.2 Mm−1]. During the study period, the absorption Ångström exponent (AAE) of aerosol was 1.6, indicating that there was obvious secondary aerosol formation or carbonaceous aerosol aging in the valley city of Baoji. Except for secondary BrC (BrCsec), the light absorption coefficient (Abs) and mass absorption efficiency (MAE) of BC and primary BrC (BrCpri) during the persistent high temperature period (PHT) were higher than those during the normal temperature period (NT) and the precipitation period (PP), which indicated that the light absorption capacity of black carbon and primary brown carbon increased, while the light absorption capacity of secondary brown carbon decreased under persistent high temperature period. Secondary aerosols sulfide (SO42−), nitrate (NO3−) and secondary organic carbon (SOC) are important factors for promoting the light absorption enhancemen of BC and BrCpri and photobleaching of BrCsec during persistent high temperature period. The Principal Component Analysis-Multiple Linear Regression (PCA-MLR) model showed that traffic emissions was the most important source of pollution in Baoji City. Based on this, the secondary source accelerates the aging of BC and BrC, causing changes in light absorption. During PHT, the radiative forcing of BC and BrCpri were enhanced, while the radiative forcing of BrCsec was weakened, but the positive radiative forcing generated by them may aggravate the high-temperature disaster.

Fifty years of firn evolution on Grigoriev ice cap, Tien Shan, Kyrgyzstan

Abstract. Grigoriev ice cap, located in the Tien Shan mountains of Kyrgyzstan, has a rich history of firn and ice core drilling starting as early as 1962. Here we extend the exceptional record and describe an 18 m firn core, drilled in February 2018 on the summit of Grigoriev ice cap, at 4600 m a.s.l. The core has been analyzed for firn stratigraphy, major ions, black carbon, water stable isotope ratios and total β activity. We find that the core covers 46±3 years and overlaps by 2 to 3 decades with legacy cores. A good agreement is found in major ion concentrations for the overlapping period. Concentrations of black carbon and major ions are reduced since the early 2000s, indicating the onset of meltwater runoff. Nevertheless, general concentration trends of these species are consistent with observations and Central Asian ice core records, since emissions were highest during periods when melt influence was negligible. The record of water stable isotopes does not reflect the strong increase of air temperatures during the last decades, implying that water stable isotope ratios ceased to be proxies of temperature variations at this site. Apart from runoff evidence, however, the firn's thermal regime appears remarkably unchanged. Firn temperatures in 2018 were the highest on record (∼-1.6 °C at ∼17 m depth). However, temperatures in 2023 are again similar to the early 2000s at ∼-2.5 °C. Furthermore, we find little change in net accumulation since the 1980s. We hypothesize (i) that firn temperatures are stabilized by the removal of latent heat through lateral meltwater runoff, and (ii) that mass loss by runoff is compensated by an increase in accumulation. Data from a nearby weather station support the latter hypothesis.

South and Southeast Asia controls black carbon characteristics of Meili Snow Mountains in southeast Tibetan Plateau

South and Southeast Asia (SSA) emitted black carbon (BC) exerts potential effects on glacier and snow melting and regional climate change in the Tibetan Plateau. In this study, online BC measurements were conducted for 1 year at a remote village located at the terminus of the Mingyong Glacier below the Meili Snow Mountains. The Weather Research and Forecasting model coupled with Chemistry (WRF-Chem) was used to investigate the contribution and potential effect of SSA-emitted BC. In addition, variations in the light absorption characteristics of BC and brown carbon (BrC) were examined. The results indicated that the annual mean concentration of BC was 415 ± 372 ngm−3, with the highest concentration observed in April (monthly mean: 930 ± 484 ngm−3). BC exhibited a similar diurnal variation throughout the year, with two peaks observed in the morning (from 8:00 to 9:00 AM) and in the afternoon (from 4:00 to 5:00 PM), with even lower values at nighttime. At a short wavelength of 370 nm, the absorption coefficient (babs) reached its maximum value, and the majority of babs values were < 20 Mm−1, indicating that the atmosphere was not overloaded with BC. At the same wavelength, BrC substantially contributed to babs, with an annual mean of 25.2 % ± 12.8 %. SSA was the largest contributor of BC (annual mean: 51.1 %) in the study area, particularly in spring (65.6 %). However, its contributions reached 20.2 % in summer, indicating non-negligible emissions from activities in other regions. In the atmosphere, the SSA BC-induced radiative forcing (RF) over the study region was positive. While at the near surface, the RF exhibited a significant seasonal variation, with the larger RF values occurring in winter and spring. Overall, our findings highlight the importance of controlling BC emissions from SSA to protect the Tibetan Plateau against pollution-related glacier and snow cover melting.

Aircraft observations of aerosol and BC during the East Asian dust storm event: Vertical profiles, size distribution and mixing state

The vertical structure of meteorological elements, black carbon (BC), and aerosols were in situ characterized by the King Air 350 aircraft measurements over the northeast of China during an East Asian dust storm event from April 10 to 13, 2023. The main causes of this dust storm event were the strong winds generated by the Mongolian cyclone, the cold front on the ground provided dynamic conditions, and the unstable atmospheric state provided thermal conditions and less precipitation in the dust source areas led to exposed the ground surface. The number concentrations of BC and aerosol had significant vertical distribution. The number concentration of aerosol in the dust storm (DS) layer increased rapidly with height, while the number and mass concentrations of BC were higher and varied slightly with height. The BC core mass median diameters (MMD) first increased with height, reaching a maximum value of 0.24 μm at 3000 m; and it rapidly decreased to 0.18 μm at 3200 m and then varied slightly with height above 3200 m. BC's bulk relative coating thickness (coated diameter divided by uncoated core diameter Dp/Dc) first decreased with height, reaching a minimum value of 1.16 at 3000 m, then increased with height, reaching a maximum of 1.38 (4250 m). A wind shear layer (7.9 m s−1 at 1850 m) with a sudden drop in temperature (the cooling rate can reach 7.4 °C·(100 m)−1) at 1900 m hinders the transportation of dust particles to the ground, allowing the dust particles to be transported at long-term distances. There were two stratifications in the dust storm layer: DS1 (1700–3000 m, the vertical wind speed was downward, the horizontal wind speed was small) and DS2 (3000–4500 m, the vertical wind speed was upward, the horizontal wind speed was large). The distinct atmospheric flow field conditions between DS1 and DS2 led to different BC and aerosol pollution characteristics. In DS2, the number concentrations of BC and aerosol were higher, the aging ratio of BC particles was higher, and the size of the core particle of BC was smaller. The concentrations of BC, aerosol, Dp/Dc, and MMD in DS2 were 1.1, 59.0, 1.02, and 0.84 times higher than those in DS1, respectively. Dust particles transported over long distances were primarily small. The number concentrations of aerosols at 0.1–0.12 μm and 0.1–0.24 μm were higher in DS1 and DS2, respectively. Still, the number concentration of aerosol at 0.12–0.28 μm in DS1 was lower than in the planetary boundary layer (PBL) and residual layer (RL).

Characterizing sedimentary black carbon in the Pearl River Estuary, Southern China

Sedimentary black carbon in coastal regions plays an important role in global carbon cycles due to its refractory nature in sediments. In this study, we conducted the first comprehensive investigation on black carbon (BC) in surface sediments of the Pearl River Estuary (PRE), a large tropical estuary system in China. We used two different analytical methods: IMPROVE-A thermal optical reflectance (TOR) and chemothermal oxidation (CTO-375) to constrain the distribution, and TOR can further constrain the composition (i.e., char and soot). The BC concentration determined by the TOR method (BCTOR) ranged from 0.07 to 7.13 mg/g, with char and soot contents ranging from 0.04 to 6.98 mg/g and 0.03–0.43 mg/g, respectively. The BC concentrations measured by the CTO-375 method (BCCTO) ranged from 0.27 to 1.88 mg/g. Char was the predominant constituent (87%) of sedimentary BCTOR in the PRE. Both char and soot had higher concentrations locating near the outlets and on the Shenzhen coast, indicating that they were sourced through direct fluvial transport and surface runoff. Soot particles were transported farther from fluvial sources than char particles. We estimated that the burial flux of BCTOR in the PRE sediments was 2.97 ± 1.61 mg/cm2/yr, acting as an important sink of BC. This study implies that large river estuaries are hotspots for BC burial, sinking a large amount of organic carbon from terrestrial reservoirs.

Hyper-local source strength retrieval and apportionment of black carbon in an urban area

Neighborhood-scale air pollution hotspots have recently been identified through detailed field campaigns, including the 100x100 Black Carbon Experiment which took place in West Oakland, CA, in 2017. Here, high-resolution nested atmospheric simulations are used together with a Bayesian inversion framework to estimate source apportionment at the hyper-local scale for a neighborhood in West Oakland. Forward simulations are performed with the Weather Research and Forecasting (WRF) model using 6 grid nests from 11.25 km to 2 m horizontal resolution. On the finest grid, building geometries are resolved using the immersed boundary method. Seven point sources and four line sources at known locations are included in the forward simulation for two 1-h periods during the 2017 field campaign. Data from 12 black carbon sensors are used to perform source inversion using a Markov Chain Monte Carlo approach, which provides a probability distribution for each of the 11 source strengths. From this, a most-likely plume can be created using the peaks of the distributions, and source apportionment can be estimated for each sensor. In addition, a composite plume can be constructed to indicate 90% confidence that concentrations are above or below a specified value. With this probabilistic analysis, it is possible to determine that more than half of the neighborhood has black carbon concentrations of higher than 0.4 μg/m3, with some areas higher than 3 μg/m3 during the time periods studied.

Source apportionment of black carbon using an advanced Aethalometer model in a typical industrial city of China

Black carbon (BC) aerosol can lead to adverse health effects and drive climate change; therefore, the characteristic research and identification of BC sources are essential for lowering emissions. In this study, equivalent black carbon (eBC) measurement was performed using a seven-wavelength Aethalometer (AE33) at an urban site in a typical industrial city (Zibo) of Northern China for the first time. The monitoring was performed from February 2021 to January 2022. The mass absorption cross-section (MAC) of AE33 was optimised using the online elemental carbon (EC) data, and eBC was corrected using the MAC. The corrected annual BC concentration was 1.72 ± 1.18 µg/m3. The diurnal variation of BC depicted a bimodal distribution. Furthermore, the BC concentration on weekends was 18 % lower than on weekdays. The diurnal variation and weekend effect reflect the critical contributions of traffic emission to BC concentration. The source apportionment of BC was calculated by a constraining Aethalometer model, which restricted the Ångström exponent using the online potassium ions. The results revealed that BC was not significantly affected by biomass burning (BCbb) in Zibo. The relative contribution of BCbb was higher in winter than in other seasons. The daily morning peak of BC was primarily influenced by traffic sources, whereas the contribution of biomass burning increased after 17:00 in the evening peak. Our findings suggest that it is more important to control fossil fuel sources for BC emission reduction in Zibo, while it is necessary to strengthen the control of biomass combustion sources in winter.

Submicron aerosol pollution in Greater Cairo (Egypt): A new type of urban haze?

Greater Cairo, the largest megacity of the Middle East North Africa (MENA) region, is currently suffering from major aerosol pollution, posing a significant threat to public health. However, the main sources of pollution remain insufficiently characterized due to limited atmospheric observations. To bridge this knowledge gap, we conducted a continuous 2-month field study during the winter of 2019–2020 at an urban background site, documenting for the first time the chemical and physical properties of submicron (PM1) aerosols. Crustal material from both desert dust and road traffic dust resuspension contributed as much as 24 % of the total PM1 mass (rising to 66 % during desert dust events), a figure not commonly observed in urban environments. Our observations showed significant decreases in black carbon concentrations and ammonium sulfate compared to data from 15 years ago, indicating an important reduction in both local and regional emissions as a result of effective mitigation measures. The diurnal variability of carbonaceous aerosols was attributed to emissions emanating from local traffic at rush hours and nighttime open biomass burning. Surprisingly, semi-volatile ammonium chloride (NH4Cl) originating from local open biomass and waste burning was found to be the main chemical species in PM1 over Cairo. Its nighttime formation contributed to aerosol water uptake during morning hours, thereby playing a major role in the build-up of urban haze. While our results confirm the persistence of a significant dust reservoir over Cairo, they also unveil an additional source of highly hygroscopic (semi-volatile) inorganic salts, leading to a unique type of urban haze. This haze, with dominant contributors present in both submicron (primarily as NH4Cl) and supermicron (largely as dust) modes, underscores the potential implications of heterogeneous chemical transformation of air pollutants in urban environments.

Glaciological studies in Mexico, 60 years of academic work: A summary

Glaciers have played a very important role in controlling the climate during most of the geologic history of our planet Earth. Of course, the glaciers have always been at higher latitudes (north and south), and some on high-altitude mountains. Current glaciers in Mexico are those inherited from the Last Glacial Maximum, (26000 - 19000 years before the present), increasing in size during the period of the Little Ice Age (1300 to 1850 common era), and they are unique in several ways; they are located at 19° north latitude, and they received snow precipitation from both the Pacific Ocean and the Gulf of Mexico (Atlantic Ocean). Research on glacial chronology, physical glaciology, and glacial geochemistry at Universidad Nacional Autónoma de México has provided valuable information on climate and environmental changes at different time scales, from millennial to decadal, and even annual. The first part of this work deals with the reconstruction of the glacial history in Mexico and establishing a glacial chronology from the Last Glacial Maximum to the Little Ice Age. The second part of this work focuses on monitoring recent changes (the last 60 years, 1960s to 2023) of the glacier extent on Iztaccíhuatl, Popocatépetl, and Citlaltépetl (the three highest mountains in Mexico), as well as having an updated inventory of all the glaciers at those mountains. Changes in glacier extent and thickness of ice are directly related to the increase in air temperature, variation in precipitation patterns, and glacier dynamics on some of the last glaciers of the northern tropics. The third part or this work focuses on a compilation of geochemical data from 17 years (from 2006 to 2013) of sampling ice (shallow ice cores) and snow at Iztaccíhuatl and Citlaltépetl glaciers. This database has the potential for providing interesting and useful information on natural and anthropogenic-induced changes related to the occurrence of heavy metals in tropical glaciers in the northern hemisphere of North America. Black carbon concentrations analyzed in snow and glacier ice, and preliminary data on stable isotopes of Zn, also add information on natural vs. anthropogenic sources of heavy metals in central Mexico.

Long-Term Exposure to Air Pollution and Risk of Acute Lower Respiratory Infections in the Danish Nurse Cohort.

Rationale: Air pollution is a major risk factor for chronic cardiorespiratory diseases, affecting the immune and respiratory systems' functionality, but epidemiological evidence in respiratory infections remains sparse. Objectives: We aimed to assess the association of long-term exposure to ambient air pollution with the risk of developing new and recurrent acute lower respiratory infections (ALRIs), characterized by persistently severe symptoms necessitating hospital contact, and identify the potential susceptible populations by socioeconomic status, smoking, physical activity status, overweight, and comorbidity with chronic lung disease. Methods: We followed 23,912 female nurses from the Danish Nurse Cohort (age >44 yr) from baseline (1993 or 1999) until 2018 for incident and recurrent ALRIs defined by hospital contact (inpatient, outpatient, and emergency room) data from the National Patient Register. Residential annual mean concentrations of fine particulate matter, nitrogen dioxide (NO2), and black carbon were modeled using the Danish Eulerian Hemispheric Model/Urban Background Model/Air Geographic Information System. We used marginal Cox models with time-varying exposures to assess the association of 3-year running mean air pollution level with incident and recurrent ALRIs and examined effect modification by age, socioeconomic status, smoking, physical activity, body mass index, and comorbidity with asthma or chronic obstructive pulmonary disease (COPD). Results: During a 21.3-year mean follow-up, 4,746 ALRIs were observed, of which 2,553 were incident. We observed strong positive associations of all three pollutants with incident ALRIs, with hazard ratios and 95% confidence intervals of 1.19 (1.08-1.31) per 2.5 μg/m3 for fine particulate matter, 1.17 (1.11-1.24) per 8.0 μg/m3 for NO2, and 1.09 (1.05-1.12) per 0.3 μg/m3 for black carbon, and slightly stronger associations with recurrent ALRIs. Associations were strongest in patients with COPD and nurses with low physical activity. Conclusions: Long-term exposure to air pollution at low levels was associated with risks of new and recurrent ALRIs, with patients with COPD and physically inactive subjects most vulnerable.

Roles of water-soluble aerosol coatings for the enhanced radiative absorption of black carbon over south asia and the northern indian ocean

Black Carbon (BC), formed by incomplete combustion, absorbs solar radiation and heats the atmosphere. We investigated the enhancement in optical absorption of BC due to coatings of water-soluble (WS) species in the polluted South Asian atmosphere. The BC Mass Absorption Cross-section (MAC; 678 nm) was estimated before and after removal of the WS components. Wintertime samples were collected from three South Asian receptor observatories intercepting large-footprint outflow: Bangladesh Climate Observatory Bhola (BCOB; integrating outflow of the Indo-Gangetic Plain), Maldives Climate Observatories at Hanimaadhoo (MCOH) and at Gan (MCOG), both reflecting outflow from the South Asian region. The ambient MAC observed at BCOB, MCOH and MCOG were 4.2 ± 1.4, 7.9 ± 1.9 and 7.1 ± 1.5 m2 g−1, respectively.The average enhancement of the BC MAC due to WS coatings (i.e., ws-EMAC) was identical at all three sites (1.6 ± 0.5) indicating that the anthropogenic aerosols had already evolved to a fully coated morphology at BCOB and/or that subsequent aging involved two compensating evolution processes of the coating. Inspecting the key coating component sulfate; the sulfate-to-BC ratio increased threefold when transitioning from BCOB to MCOH and by about 1.5 times from BCOB to MCOG. Conversely, both WS organic carbon (WSOC)/BC and water-insoluble OC (WIOC)/BC ratios declined with distance: WSOC/BC diminished by 84 % from BCOB to MCOH and by 80 % from BCOB to MCOG, while WIOC/BC dropped by about 63 % and 59 %, respectively. Such declines in WSOC and WIOC reflect a combination of photochemical oxidation and more efficient washout of OC compared to BC. The observed changes in the SO42−/BC and WSOC/BC ratios across South Asia highlight the significant impact of aerosol composition on the optical properties of Black Carbon (BC). These findings emphasize the need for detailed studies on aerosol composition to improve climate models and develop effective strategies for reducing the impact of anthropogenic aerosols on the climate.

Investigating the influence of platform design on the distribution of traffic particulate matter at the bus stop

Passengers waiting at bus stops are regularly exposed to vehicle emissions from nearby roads. Thus, comprehending the pollution levels within the stop is crucial for devising measures to improve the waiting environment. Here, we measured PM2.5 and black carbon (BC) concentrations at bus stops and simulated the effects of different bus platforms on particle distribution under varying winds. The main findings are: (1) Particle concentrations were higher in the front of the bus stop than in the rear. The exit area of the bus stop at downwind of the road showed the highest concentration, especially for BC, with a maximum increase of 58% compared to other front locations, likely attributed to increased emissions from road vehicles interfered by departing buses. PM2.5 concentrations at the stop increased by 21–38% in the evening compared to the morning, while BC concentrations decreased by about 27% due to a reduction in diesel vehicles and increased wind speeds. (2) As wind-road angle increased, turbulence caused particles from the road to migrate towards the stop and its rear. A 45° wind-road angle facilitated particle diffusion, while higher wind speeds brought an overall reduction in particulate matter. These results varied among the three simulated bus platforms, with differences more pronounced for PM2.5 than for BC. (3) Enhancements in the front enclosures of the bus stop promoted a significant decrease in particles behind the stop, particularly in BC compared to PM2.5. Therefore, installing closed or semi-enclosed front barriers, considering prevailing wind conditions, has the potential to improve air quality within the bus stop.

Long-term trends of black carbon and particle number concentrations and their vehicle emission factors in Stockholm

Black carbon (BC) and particle number (PN) concentrations are usually high in cities due to traffic emissions. European mitigation policies, including Euro emission standards, have been implemented to curb these emissions. We analyzed BC and PN (particle diameter Dp > 4 nm) concentrations in Stockholm spanning the years 2013–2019 (BC) and 2009–2019 (PN) measured at street canyon and rooftop sites to assess the effectiveness of the implemented policies. Combining these data with inverse dispersion modeling, we estimated BC and PN emission factors (EFBC and EFPN) for the mixed fleet, reflecting real-world driving conditions. The pollutants showed decreasing trends at both sites, but PN concentrations remained high at the canyon site considering the World Health Organization (WHO) recommendations. BC concentrations declined more rapidly than PN concentrations, showing a −9.4% and −4.9% annual decrease at the canyon and −7.2% and −0.5% at the rooftop site in the years 2013–2019. The EFBC and EFPN trends showed that the mitigation strategies for reducing particulate emissions for on-road vehicles were successful over the study period. However, the introduction of biofuels in the vehicle fleet —ethanol and later rapeseed methyl ester (RME)— increased the concentrations of particles with Dp < 10 nm before the adoption of particulate filters in the exhausts. Stricter Euro emission regulations, especially with diesel particulate filters (DPF) in Euro 5, 6, and VI vehicles, led to 66% decrease in EFBC and 55% in EFPN. Real-world EFBC surpassed HBEFA (Handbook Emission Factors for Road Transport) database values by 2.4–4.8 times; however, direct comparisons between real-world and HBEFA EFPN are difficult due to differences in lower cut-off sizes and measurement techniques. Our results underscore the necessity for revising the HBEFA database, updating laboratory testing methods and portable emission measuring systems (PEMS) measurements to account for liquid condensate contributions to PN measurements.

End-to-end simulations to optimize imaging spectroscopy mission requirements for seven scientific applications

CNES is currently carrying out a Phase A study to assess the feasibility of a future hyperspectral imaging sensor (10 m spatial resolution) combined with a panchromatic camera (2.5 m spatial resolution). This mission focuses on both high spatial and spectral resolution requirements, as inherited from previous French studies such as HYPEX, HYPXIM, and BIODIVERSITY. To meet user requirements, cost, and instrument compactness constraints, CNES asked the French hyperspectral Mission Advisory Group (MAG), representing a broad French scientific community, to provide recommendations on spectral sampling, particularly in the Short Wave InfraRed (SWIR) for various applications.This paper presents the tests carried out with the aim of defining the optimal spectral sampling and spectral resolution in the SWIR domain for quantitative estimation of physical variables and classification purposes. The targeted applications are geosciences (mineralogy, soil moisture content), forestry (tree species classification, leaf functional traits), coastal and inland waters (bathymetry, water column, bottom classification in shallow water, coastal habitat classification), urban areas (land cover), industrial plumes (aerosols, methane and carbon dioxide), cryosphere (specific surface area, equivalent black carbon concentration), and atmosphere (water vapor, carbon dioxide and aerosols). All the products simulated in this exercise used the same CNES end-to-end processing chain, with realistic instrument parameters, enabling easy comparison between applications. 648 simulations were carried out with different spectral strategies, radiometric calibration performances and signal-to-noise Ratios (SNR): 24 instrument configurations × 25 datasets (22 images + 3 spectral libraries).The results show that spectral sampling up to 20 nm in the SWIR range is sufficient for most applications. However, 10 nm spectral sampling is recommended for applications based on specific absorption bands such as mineralogy, industrial plumes or atmospheric gases. In addition, a slight performance loss is generally observed when radiometric calibration accuracy decreases, with a few exceptions in bathymetry and in the cryosphere for which the observed performance is severely degraded. Finally, most applications can be achieved with a realistic SNR, with the exception of bathymetry, shallow water classification, as well as carbon dioxide and methane estimation, which require the optimistic SNR level tested. On the basis of these results, CNES is currently evaluating the best compromise for designing the future hyperspectral sensor to meet the objectives of priority applications.