The generalized mutual information (GMI) of bit-interleaved coded modulation (BICM) systems, sometimes called the BICM capacity, is investigated at low signal-to-noise ratio (SNR). The combinations of input alphabet, input distribution, and binary labeling that achieve the Shannon limit <formula formulatype="inline" xmlns:mml="http://www.w3.org/1998/Math/MathML" xmlns:xlink="http://www.w3.org/1999/xlink"><tex Notation="TeX">${- 1.59}\;{\rm dB}$</tex></formula> are completely characterized. The main conclusion is that a BICM system with probabilistic shaping achieves the Shannon limit at low SNR if and only if it can be represented as a zero-mean linear projection of a hypercube. Hence, probabilistic shaping offers no extra degrees of freedom to optimize the low-SNR BICM-GMI, in addition to what is provided by geometrical shaping. The analytical conclusions are confirmed by numerical results, which also show that for a fixed input alphabet, probabilistic shaping can improve the BICM-GMI in the low and medium SNR range.