An array of useful N,N′-ethylene-bridged bispyrazole derivatives were achieved with moderate-to-good yields via the electrochemical alkenyl diazolation reaction with no external chemical oxidant or metal catalyst. Critical to this successful process is the usage of anodal direct oxidation, which ensured sufficient activation of alkenes to allow engagement with two equivalents of pyrazoles. The tri- or tetra-substituted alkenes were applicable scaffolds in this transformation.