Bismuth Sulfide Research Articles

Alkalized MQDs/Bi2S3 Porous Structure for Efficient Photocatalytic CO2 Reduction

AbstractFinding effective and specific catalytic materials for the transformation of carbon dioxide into fuel is indisputably a significant challenge. In this study, 3D porous sphere structure MXene quantum dot/Bi2S3 (MBS) composites were prepared using electrostatic self‐assemblage of protonated Bismuth sulphide nanoparticles (Bi2S3 NSs) with Ti3C2(OH)2 QDs (MQDs‐OH). The optimized MBS material demonstrates an excellent narrow band gap (Eg=1.24 V (vs. NHE)) and high selectivity and efficiency in catalyzing CH3OH, delivering impressive yields of up to 694.7 μmol/g. This study may lead to a new approach to the development of multidimensional photocatalysts for CH3OH production by adsorption of atmospheric CO2.

High-performance Bi2S3 photodetector based on oxygen-mediated defect engineering and its wafer-scale fast fabrication

Bi2S3 with a 2D van der Waals structure has attracted much attention due to its high conductivity, large absorption coefficient, and environmental friendliness. The preparation of tunable optoelectronic devices can be realized by exploiting and tuning Bi2S3 intrinsic defects. In this work, a simple and rapid method for the preparation of bismuth sulfide thin films and successfully prepare Bi2S3 with sulfur vacancies (Svac) (LA-Bi2S3) and oxygen passivated (Svac) (AP-Bi2S3) was presented. The defect state difference of the two devices leads to exhibit different optoelectronic properties. Under 638 nm and 1310 nm illuminations, the LA-Bi2S3 photodetectors exhibit responsivities of up to 2250 and 3.6 mA/W and detectivities of 1.69 × 1012 and 2.6 × 109 cm·Hz1/2 W−1, while the AP-Bi2S3 photodetectors have ultra-fast on/off speeds of 1 ms and 8 ms, and on/off ratio up to 3 × 103. The preparation method of the tunable optoelectronic devices gives a new avenue for defect tuning in metal sulfides and for the preparation and application of optoelectronic devices.

Construction of Methotrexate-Loaded Bi2S3 Coated with Fe/Mn-Bimetallic Doped ZIF-8 Nanocomposites for Cancer Treatment Through the Synergistic Effects of Photothermal/Chemodynamic/Chemotherapy.

A combination of therapeutic modalities in a single nanostructure is crucial for a successful cancer treatment. Synergistic photothermal therapy (PTT) can enhance the effects of chemodynamic therapy (CDT) and chemotherapy, which could intensify the therapeutic efficacy to induce cancer cell apoptosis. In this study, Fe and Mn on a zeolitic imidazolate framework (ZIF-8) (Fe/Mn-ZIF-8; FMZ) were synthesized through ion deposition. Furthermore, bismuth sulfide nanorods (Bi2S3 NRs; BS NRs) were synthesized via a hydrothermal process and coated onto FMZ to generate the core-shell structure of the Bi2S3@FMZ nanoparticles (B@FMZ). Next, methotrexate (MTX) was loaded effectively onto the porous surface of ZIF-8 to form the B@FMZ/MTX nanoparticles. The Fenton-like reaction catalyzes Fe2+/Mn2+ ions by decomposing H2O2 in the tumor microenvironment, resulting in the formation of toxic hydroxyl radicals (·OH), which promotes the CDT effect of killing cancer cells. Furthermore, under 808 nm laser irradiation, these B@FMZ nanoparticles showed a strong PTT effect, owing to the presence of intense BS NRs as a photothermal agent. The B@FMZ nanoparticles exhibited a prominent drug release efficiency of 87.25% at pH 5.5 under near-infrared laser irradiation due to the PTT effect can promote the drug delivery performance. The B@FMZ nanoparticles were subjected to dual-modal imaging, guided magnetic resonance imaging, and X-ray computed tomography imaging. Both in vitro and in vivo results suggested that the B@FMZ/MTX nanoparticles exhibited enhanced antitumor effects through the combined therapeutic effects of PTT, CDT, and chemotherapy. Therefore, these nanoparticles exhibit good biocompatibility and are promising candidates for cancer treatment.

Efficient Catalytic Production of Reactive Oxygen Species through Piezoelectricity in Bismuth Sulfide Rich in Sulfur Vacancies.

Sulfur (S) vacancies in metal sulfides are of interest in electrocatalysis and photoelectronics, but their effect on the generation of reactive oxygen species (ROS) during mechanical catalysis is unclear. This study investigates the impact of S-vacancies in defective bismuth sulfide (Bi2S3-x) on ROS production under ultrasonic irradiation and organic contaminant decomposition. S-vacancies disrupt the centrosymmetric structure of intrinsic Bi2S3, inducing piezoelectric effects and enhancing the electrical energy in Bi2S3-x. The positively charged S-vacancies in Bi2S3-x promote the separation of ultrasound-activated electron-hole pairs by capturing electrons. As a result, the optimal rate of H2O2 formation and the reaction rate constant for degrading Rhodamine B dye on Bi2S3-x are found to be 1.9 and 37 times higher, respectively, than those on Bi2S3 under ultrasonic irradiation. The nonzero catalytic efficiency in centrosymmetric Bi2S3 is due to the flexoelectric catalytic effect from nonuniform strain. These results guide the piezocatalyst design and elucidate mechanical catalysis mechanisms.

Bismuth Sulfide Nanorod/Vanadium Carbide MXene as Nitrogen Dioxide Gas Sensor Operating at Room Temperature under Ultraviolet-Assisted Recovery

Bismuth Sulfide Nanorod/Vanadium Carbide MXene as Nitrogen Dioxide Gas Sensor Operating at Room Temperature under Ultraviolet-Assisted Recovery

The influence of precursor solutions containing an amount of silver bismuth sulfide nanoparticles (AgBiS2 NPs) on the characteristics of CH3NH3PbI3 perovskites solar cells

The utilization of organo-metal halide perovskites as absorbers in thin-film solar cells has garnered considerable interest from the scientific community in recent times. In this study, we present the introduction of silver bismuth sulfide nanoparticles (AgBiS2 NPs) doped into perovskite thin films composed of CH3NH3PbI3 thin film. Our results demonstrate that the perovskites' morphology and structure were significantly improved. The effects of AgBiS2 NPs concentration on the optical, mechanical, and crystallographic properties of CH3NH3PbI3 perovskite thin films were investigated. The findings from the structure investigations revealed that an increase in the concentration of AgBiS2 NPs resulted in a transition from a low-crystalline to a polycrystalline structure of the perovskite thin films. An elevation in the concentration of AgBiS2 NPs from 2 to 8 mg/mL led to the development of perovskite films of superior quality, consisting entirely of PbI3 and CH3NH3. These films exhibited almost impeccable deposition, compactness, and uniformity, and their particle size reached an approximate value of 1.3 μm. Furthermore, an increase in the optical absorption coefficient (∼105 cm−1) in the visible spectrum and subsequent enhancements in photoluminescence (PL) and ultraviolet–visible (UV–Vis) absorption spectroscopy serve as further evidence of the film's enhanced quality. When AgBiS2 NPs are doped into perovskites, the films' quality is significantly improved; they acquire a uniform surface morphology, an exceptional crystal structure, and enhanced light absorption, all of which contribute to accelerated PL quenching and charge transfer. Power conversion efficiency (PCE) was enhanced across all photovoltaic parameters through the use of larger granules in bulk-heterojunction solar cells, as opposed to undoped heterojunction solar cells. The PCE of the perovskite device with CH3NH3PbI3 base is 17.04 % at the optimal concentration of 6 mg/mL AgBiS2 NPs. These findings indicate that the doping of CH3NH3PbI3 perovskite thin films with AgBiS2 NPs is essential for the achievement of high crystallinity, a large particle size, and a high absorption coefficient. These properties are advantageous for the high-power conversion efficiency of solar cell applications.

Facile Design of Bi2S3‐Doped CeO2/Dihydroxybenzoate Composite as Highly Efficient UV‐Shielding Agents

AbstractIn this study, bismuth sulfide (Bi2S3)‐doped cerium oxide (CeO2) was prepared via hydrothermal method, and by depositing ethyl 3,4‐dihydroxybenzoate (EDHB) on the surface of Bi2S3/CeO2 (Bi2S3/CeO2/EDHB and BCE). The samples were characterized by FTIR, XRD, TEM, and UV–vis absorption spectrum means. According to the characterizations, Bi2S3 was successfully incorporated into the CeO2 structure (Bi2S3/CeO2), and the prepared BCE/PVC composite films display excellent UV‐shielding property. Moreover, the result of thermogravimetric analysis (TGA) tests indicated that BCE also was barely catalytic thermal decomposition of PVC matrix. This work not only paves an attractive way for the design of the CeO2‐based UV‐shielding agent, but also provides valuable insights into the inspiration to construct high‐performance UV‐shielding composites.

Facile one-pot synthesis of Bi2S3 nanorod @ N, S co-doped carbon composite for high performance lithium ion batteries

Bismuth sulfide is favoured in lithium ion batteries due to its high specific capacity of 625 mAh/g. However, the Bi2S3 anode faces severe volume expansion problems during the lithium intercalation process, resulting in continuous electrode fragmentation and rapid degradation of lithium storage performance. In this study, Bi2S3 nanorod@N, S co-doped carbon composite prepared by a simple sintering method was used as the anode material for lithium ion batteries. 1D Bi2S3 nanorods with a length of 1 μm and a diameter of 50 nm were loaded in situ on 2D N, S co-doped carbon nanosheets. This unique structure can not only alleviate the volume change of bismuth sulfide, but also effectively shorten the diffusion distance of lithium ions, thereby improving the cycling stability and rate capability at the same time. The discharge capacity of Bi2S3@N, SC remained at 583.4 mAh g –1 after 400 cycles at 0.5 A g–1. Even at a high current density of 2 A/g, the discharge capacity of Bi2S3@N, SC still reached 374.3 mAh g –1. This simple method also can be extended to the preparation of other metal sulfide composites.

Cu-doped Bi2S3 nanorod films via chemical synthesis for improved photoelectrochemical water splitting

Bismuth sulfide (Bi2S3) is a promising photoelectrochemical (PEC) material due to its favorable optoelectronic properties. However, its overall PEC performance is limited by slow charge transport and high electron–hole recombination at the Bi2S3-electrolyte interface. In this study, we have intentionally introduced Cu into Bi2S3 photoelectrodes to enhance both their physical properties and PEC performance. Cu-doping concentrations ranging from 0 to 8.4 at.% were incorporated into Bi2S3 films synthesized via chemical bath deposition followed by annealing. The undoped Bi2S3 photoelectrodes exhibited nanorods with lengths of 50–100 nm, a direct bandgap of 1.26 eV, and a photocurrent density of 4.7 mA/cm2 at 1.5 V. As the Cu-doping concentration increased from 1.0 to 4.4 at.%, the nanorod length extended to 200–400 nm, with a corresponding increase in density, leading to an enhanced photocurrent density of 6.8 mA/cm2. However, further increasing the Cu-doping concentration to 8.4 at.% resulted in a reduction in film thickness, nanorod density, and a decrease in photocurrent to 6.0 mA/cm2. These results demonstrate that Cu-doping in Bi2S3 significantly increases nanorod density and improves both the physical and PEC properties, offering a promising approach for developing more efficient PEC water-splitting devices.

Synthesis, Characterization and Electrochemical Performance of Bi2S3/Rice Husk-Based Activated Carbon Composites As Lithium Ion Battery Anodes

This study investigates the impact of hydrothermal duration on bismuth sulfide/activated carbon composites (Bi2S3/AC) by varying the duration to 8, 24, and 48 hours. The primary aim is to delineate the composite characteristics and electrochemical performance of Bi2S3/AC composites, aiming to produce anodes for lithium-ion batteries with high capacity, excellent cyclic stability, and minimal volume expansion. Activated carbon derived from rice husks was synthesized via a carbonization process and chemical activation using H3PO4 as an activator. Subsequently, the synthesis of Bi2S3/AC composites used bismuth nitrate pentahydrate and thiourea precursors through the hydrothermal method that involved three variations of hydrothermal duration: 8, 24, and 48 hours, denoted as BC8, BC24, and BC48, respectively. The FTIR test indicates the presence of Bi-S, C=C, and C-O groups in the three composite products, signifying the existence of bismuth sulfide and activated carbon. The XRD result reveals orthorhombic crystal forms in the composites, while the SEM-EDX mapping illustrates particle morphologies resembling flower-like shapes. These compositions comprise Bi 74.16%, S 11.37%, and C 10.43%. The GSA test suggests a mesoporous pore size in these composites. In final result, BC24 exhibits the highest electrical and ionic conductivity, measuring 2.12 × 10−3 S.cm−1 and 2.057 × 10−4 S.cm−1, respectively. The CV data of the BC24 composite indicates two reduction and oxidation peaks in the first cycle. Charge-discharge test on the BC24 composite exhibits a specific charge capacity of 445.51 mAh/g and a discharge capacity of 364.24 mAh/g.

Visible light photodetectors based on the Bi2S3 flower-like 3D microrods with Schottky emission

This work presents a holistic approach to the fabrication of bismuth sulfide (Bi2S3) photodetectors, with a particular emphasis on material structure and morphology. Bi2S3 particles were synthesized using a microwave-assisted method, employing bismuth nitrate and L-cysteine as the sulfur source. Polyvinylpyrrolidone with two different molecular weights was used as a viscosity modifier to control the size and morphology of the particles. The as-synthesized powders were drop-casted onto interdigitated gold electrodes from an ethanol suspension and evaluated using different light sources. The results demonstrate that submicrometric material with a slightly higher aspect ratio generated a higher photocurrent under the same conditions, attributed to enhanced carrier transport due to the reduced rod diameter, photogating effects, and Schottky emission. Bi2S3 lamellar microrods exhibited responsivity of 0.93, 0.21, and 0.40 mA/W for red (628 nm), green (517 nm), and blue (468 nm) light, respectively. This resulted in detectivity in the range of 1.17–5.32 × 10¹⁰ Jones for the visible light spectrum.

Endocytic pathways and metabolic fate of colloidal bismuth subcitrate in human renal cells

Bismuth compounds, particularly colloidal bismuth subcitrate (CBS), have been widely used in the treatment of gastrointestinal diseases. However, overdose of CBS has been linked to cases of acute renal failure, primarily due to the intracellular accumulation of bismuth in the kidney. To date, the detailed mechanisms of CBS internalization and its metabolic fate remain unclear. In this study, CBS was characterized as a type of nano-object using transmission electron microscopy and dynamic light scattering. Renal cells internalized CBS primarily via clathrin-mediated endocytosis in an active transport manner. Gene knockdown techniques revealed that CBS binds to the transferrin receptor likely through complexing with transferrin before cellular uptake. Once internalized, CBS was sorted into early endosomes, late endosomes, and lysosomes, mediated by microtubules and the Golgi apparatus. Additionally, differentially expressed genes analysis revealed that CBS endocytosis stimulated oxidative stress, significantly affecting the metabolism of glutathione and cysteine within cells. This led to the formation of black bismuth sulfide particles as a result of CBS conjugating with intracellular glutathione. These findings provide crucial insights into the cellular mechanisms underlying excessive CBS exposure, which is essential for understanding and potentially mitigating the risks associated with the use of bismuth compounds in medical treatments.

Degradation of Organic Dye Congo Red by Heterogeneous Solar Photocatalysis with Bi2S3, Bi2S3/TiO2, and Bi2S3/ZnO Thin Films

In this work, bismuth sulfide (Bi2S3) thin films were deposited by a chemical bath deposition (CBD) technique (called soft chemistry), while titanium dioxide (TiO2) nanoparticles were synthesized by sol–gel and zinc oxide (ZnO) nanoparticles were extracted from alkaline batteries. The resulting nanoparticles were then deposited on the Bi2S3 thin films by spin coating at 1000 rpm for 60 s each layer to create heterojunctions of Bi2S3/ZnO and Bi2S3/TiO2. These materials were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), and energy dispersive X-ray spectroscopy (EDX). The optical and contact angle analyses were undertaken by UV–Vis spectroscopy and a contact microscopy angle meter, respectively. The calculated band gap values were found to be between 1.9 eV and 2.45 eV. The Bi2S3 presented an orthorhombic structure, the TiO2 nanoparticles presented an anatase structure, and the ZnO nanoparticles presented a wurtzite hexagonal crystal structure. Furthermore, heterogeneous solar photocatalysis was performed using the Bi2S3, Bi2S3/ZnO, and Bi2S3/TiO2 thin film combinations, which resulted in the degradation of Congo red increasing from 8.89% to 30.80% after a 30 min exposure to sunlight.

PH and redox dually responsive micelles loaded with anti-cancer drug and OA-Bi2S3 nanodots for chemo-photothermal synergistic treatment of cancers

In order to achieve the effective therapy of cancer through targeting and synergistic strategy, methyl-capped poly(ethylene glycol)-poly(caprolactone) block copolymers modified with imine and disulfide bonds (mPEG-imine-SS-PCL) was designed and synthesized, which encapsulated the therapeutic agent, doxorubicin (DOX) and oleic acid-coated bismuth sulfide nanodots (OA-Bi2S3), into the hydrophobic core to form composite micelles by self-assembly in aqueous solution. The imine and disulfide bonds in the composite micelles structure remain stable in the normal physiological environment, but can be broken in the weakly acidic and reducing tumor micro-environment, causing disruption of the micelle structure and release of the therapeutic agent for chemo-photothermal synergistic therapy.

Properties of bismuth based Bi2A3 (A = S, Se, Te) chalcogenides for optoelectronic and thermoelectric applications

Structural, electronic, optical, mechanical, thermoelectric and dielectric properties of binary Bi2A3 (A = S, Se, Te) chalcogenide semiconductors are studied by first-principles approach. Bismuth sulfide (Bi2S3) is found to be structurally stable in orthorhombic structure while bismuth selenide (Bi2Se3) and bismuth telluride (Bi2Te3) are stable in trigonal structure. Calculated mechanical properties reveal that all three Bi2A3 (A = S, Se, Te) compounds fulfil the mechanical stability criteria. Band structure calculations reveal that the Bi2S3 exhibits direct optical band gap (Eg = 1. 58 eV) which lies in the near-infrared (NIR) region, while the calculated Eg of Bi2Se3 and Bi2Te3 are found to be 0.53 eV and 0.35 eV, respectively lying in the far-infrared region. For Bi2S3 and Bi2Se3 compounds, the calculated dielectric properties show strong anisotropic behavior, while negligible anisotropic dielectric behavior is observed for Bi2Te3. Calculated optical properties show that all three Bi2A3 compounds possess high absorption coefficient (> 104 cm−1). For all three Bi2A3 (A = S, Se, Te) compounds, the calculated optical conductivity show prominent peak corresponding to the occurrence of optical conduction at energies 3.36 eV, 2.65 eV and 2.02 eV respectively. Calculated optical results support the results deduced from band structures and density of states spectra. Optical properties and dielectric behavior suggest that the Bi2S3 compound has suitable band gap and has potential to use for photovoltaic applications while Bi2A3 (A = Se, Te) compounds could be used in infrared detectors and other optical devices. Calculated thermal properties reveal that the Bi2A3 (A = S, Se, Te) chalcogenides could be potential materials for thermoelectric applications.

Facile green synthesis of Bi2S3 nanoparticles: Applications in simultaneous dye degradation and seed germination of fenugreek seeds

In this work, Bi2S3 nanoparticles (NPs) have been synthesized by the green combustion method at 500 °C for 10 min using C.argentae. The structure, optical, and morphological studies of the synthesized material were analysed using PXRD, FTIR, UV, PL, and SEM spectroscopy techniques. The PXRD pattern of the material demonstrates that the obtained particles are of bismuth sulphide with an orthorhombic structure. The FTIR spectrum of it shows a characteristic peak at 606.8 cm−1. In the UV–visible spectrum, on extrapolating the linear portion of the curve, the band gap on the X-axis is found to be 3.17 eV. PL intensity peaks show excitation and emission ranges of 384 nm and 532 nm respectively. SEM studies of the material show that the nanoparticles are in granular shape. Further, by using synthesized nanomaterials, photocatalytic degradation is carried out for methylene blue dye with different variations, and scavenger activity is carried out using K2Cr2O7, EDTA, ascorbic acid, and TBA. Seed germination activity is also carried out for fenugreek seeds with synthesized material and dye, with dye, and with a mixture of dye and nanoparticles, along with the simultaneous study of dye degradation.

Bismuth Sulfide Nanoflowers Facilitated miR339 Delivery to Overcome Stemness and Radioresistance through Ubiquitin-Specific Peptidase 8 in Esophageal Cancer.

Despite the superior efficacy of radiotherapy in esophageal squamous cell carcinoma (ESCC), radioresistance by cancer stem cells (CSCs) leads to recurrence, metastasis, and treatment failure. Therefore, it is necessary to develop CSC-based therapies to enhance radiotherapy. miR-339-5p (miR339) is involved in stem cell division and DNA damage checkpoint signaling pathways based on ESCC cohort. miR339 inhibited ESCC cell stemness and enhanced radiation-induced DNA damage by targeting USP8, suggesting that it acts as a potential CSC regulator and radiosensitizer. Considering the limited circulating periods and poor tumor-targeting ability of miRNA, a multifunctional nanoplatform based on bismuth sulfide nanoflower (Bi@PP) is developed to efficiently deliver miR339 and improve radioresistance. Intriguingly, Bi@PP encapsulates more miR339 owing to their flower-shaped structure, delivering more than 1000-fold miR339 into cells, superior to free miR339 alone. Besides being used as a carrier, Bi@PP is advantageous for dynamically monitoring the distribution of delivered miR339 in vivo while simultaneously inhibiting tumor growth. Additionally, Bi@PP/miR339 can significantly enhance radiotherapy efficacy in patient-derived xenograft models. This multifunctional platform, incorporating higher miRNA loading capacity, pH responsiveness, hypoxia relief, and CT imaging, provides another method to promote radiosensitivity and optimize ESCC treatment.

PH‐Universal Electrocatalytic CO2 Reduction with Ampere‐Level Current Density on Doping‐Engineered Bismuth Sulfide

AbstractThe practical application of the electrocatalytic CO2 reduction reaction (CO2RR) to form formic acid fuel is hindered by the limited activation of CO2 molecules and the lack of universal feasibility across different pH levels. Herein, we report a doping‐engineered bismuth sulfide pre‐catalyst (BiS‐1) that S is partially retained after electrochemical reconstruction into metallic Bi for CO2RR to formate/formic acid with ultrahigh performance across a wide pH range. The best BiS‐1 maintains a Faraday efficiency (FE) of ~95 % at 2000 mA cm−2 in a flow cell under neutral and alkaline solutions. Furthermore, the BiS‐1 catalyst shows unprecedentedly high FE (~95 %) with current densities from 100 to 1300 mA cm−2 under acidic solutions. Notably, the current density can reach 700 mA cm−2 while maintaining a FE of above 90 % in a membrane electrode assembly electrolyzer and operate stably for 150 h at 200 mA cm−2. In situ spectra and density functional theory calculations reveals that the S doping modulates the electronic structure of Bi and effectively promotes the formation of the HCOO* intermediate for formate/formic acid generation. This work develops the efficient and stable electrocatalysts for sustainable formate/formic acid production.

PH-Universal Electrocatalytic CO2 Reduction with Ampere-Level Current Density on Doping-Engineered Bismuth Sulfide.

The practical application of the electrocatalytic CO2 reduction reaction (CO2RR) to form formic acid fuel is hindered by the limited activation of CO2 molecules and the lack of universal feasibility across different pH levels. Herein, we report a doping-engineered bismuth sulfide pre-catalyst (BiS-1) that S is partially retained after electrochemical reconstruction into metallic Bi for CO2RR to formate/formic acid with ultrahigh performance across a wide pH range. The best BiS-1 maintains a Faraday efficiency (FE) of ~95 % at 2000 mA cm-2 in a flow cell under neutral and alkaline solutions. Furthermore, the BiS-1 catalyst shows unprecedentedly high FE (~95 %) with current densities from 100 to 1300 mA cm-2 under acidic solutions. Notably, the current density can reach 700 mA cm-2 while maintaining a FE of above 90 % in a membrane electrode assembly electrolyzer and operate stably for 150 h at 200 mA cm-2. In situ spectra and density functional theory calculations reveals that the S doping modulates the electronic structure of Bi and effectively promotes the formation of the HCOO* intermediate for formate/formic acid generation. This work develops the efficient and stable electrocatalysts for sustainable formate/formic acid production.

A novel electropolymerized molecularly imprinted dual-mode sensor for bisphenol AF detection in pond mud

Recently, bisphenol AF (BPAF) as most commonly used bisphenol A analogs had the increasing higher level in the environment with unknown risks. Herein, a synchronous dual-mode sensor had been established based on differential pulse voltammetry (DPV) and electrochemiluminescence (ECL) for the detection of BPAF in pond mud. Firstly, the sensing molecularly imprinted polymer (MIP) films were prepared by electrochemical polymerization procedure with 3,4-ethoxylene dioxy thiophene (EDOT) as the functional monomer, BPAF as the template molecule and MXene as the supporting electrolyte. Due to unique characters of PEDOT and MXene, the constructed MIP films were stable and highly conductive. Meanwhile, zinc-doped bismuth sulfide quantum dots (Zn-Bi2S3 QDs) were synthesized as a nano-emitter to generate strong ECL signals in the MIP film. In the sensing process, a pulsed voltage applied to the PEDOT/MXene MIP film to generate both DPV and ECL signals for simultaneous dual-mode detection. Additionally, the liquid-liquid extraction with deep eutectic solvent (menthol: octanol 1:1) was used for the pre-concentration of the BPAF in the pond mud. Based on the sensing system, the ECL and DPV response showed the good linear relationships with the concentration of BPAF with the ranges of 0.01 μM–50 μM and 0.1 μM–50 μM and the detection limits of 0.0060 μM and 0.059 μM, respectively.