Bismuth Glasses Research Articles

Enhanced 3 μm emission in Ho3+/Yb3+ co-doped bismuth-fluoride glasses by Gd2O3

In this work, (100-b)(45Bi2O3-40GeO2-15BaF2)-bGd2O3-2Yb2O3-0.5Ho2O3 glass was prepared to use a high-temperature melting method(where b= 0, 2.5, 5, 7.5, 10). The absorption and fluorescence spectra indicate that the optimal Gd2O3 content is 7.5 mol% (BGBG7.5HY), with an Ω2 value of 6.20×10−20 cm2 for the main glass, which is superior to that of BGBG0HY glass. This suggests that the incorporation of Gd2O3 enhances the mid-infrared emission capacity. Raman spectroscopy studies demonstrate that the introduction of Gd₂O₃ results in a substantial influx of oxygen atoms into the glass network, accompanied by a transition of [BiO₆] to [BiO₃] within the glass mesh. This is evidenced by a notable redshift of the characteristic peaks at 509 cm−1 and 677 cm−1 in comparison to BGB glass. The introduction of Gd2O3 also expands the distance between Ho3+/Yb3+ ions, inhibits rare earth ion clusters, improves the Ho3+ luminescence center environment, and thus enhances the 3 μm emission performance of bismuth fluoride glass. The maximum emission cross section is 1.82 × 10−20 cm2 and the maximum gain coefficient is 3.71 cm−1. The results show that the bismuth fluoride glass prepared in this paper is an excellent gain material for mid-infrared fiber lasers.

Structural, thermal, and radiation shielding properties of B2O3-TeO2-Bi2O3-CdO-Tm2O3 glasses: The role of Tm2O3

This study presents a detailed investigation into the structural, thermal, and radiation shielding properties of a new glass composition, labeled as (50-x)B2O3 + 30TeO2 + 10Bi2O3 + 10CdO + x Tm2O3 (where x = 0, 1, 2, 3, 4, 5 mol %). Various radiation shielding parameters such as mass attenuation coefficient, linear attenuation coefficient, half-value layer, mean free path, effective atomic number, and absorbed equivalent dose rates for neutrons were determined through experimental measurements. The study also employed theoretical calculations to assess the exposure buildup factor and effective removal cross-section for neutrons. Additionally, the SRIM program was utilized to investigate mass stopping power and projected range for proton and alpha particles. The structural characteristics of the glasses were analyzed using XRD and FT-IR, while thermal properties were examined through Differential Thermal Analysis (DTA). FTIR analysis revealed distinctive bands corresponding to Bi—O, B—O—B, and Te—O bonds. Glass transition temperatures (Tg) increased with Tm2O3 content, ranging from 422 °C to 444 °C. The radiation shielding properties of bismuth boro-tellurite glasses showed that a dose of 1.2025 μSv/h emitted from a fast neutron source was absorbed by 35.1574 % in pure glass and 40.0391 % in glass doped with 5 mol% Tm2O3. Incorporating Tm2O3 into the glass matrix significantly improved the shielding and thermal properties, thus enhancing their potential for advanced high-energy radiation absorption. This investigation contributes to a deeper understanding of how Tm2O3 enhances the structural and thermal attributes of these glasses, positioning them as promising materials for radiation shielding applications.

Multifaceted biomedical applications of bismuth oxide-doped bioactive glass: Synthesis challenges, characterization and potential clinical implications

Herewith, the present work reports a facile synthesis method of Bi2O3 doped 70 SiO2.30CaO binary bioactive glass system termed as modified Bi-BG (acronymed as mBi-BG) that indicates successful incorporation of Bi3+ into the silicate glassy network, on prior complex formation of the precursor bismuth nitrate salt with acetyl acetone to address the rapid decomposition rate of precursor bismuth nitrate. The binary bioactive glass composition as above mentioned (70 SiO2.30CaO) is named as BG/Control. The synthesis methodology addresses inherent challenges encountered in traditional sol-gel derived bismuth oxide incorporated bioactive glass (Bi-BG) synthesis wherein yellow coloured bismuth oxide gets separated from the glassy network as confirmed by XRD phase analysis. Next, mBi-BG (modified Bi-BG) was synthesized via modifying the sol gel method by introducing a chelating agent acetyl acetone to stabilize the precursor Bi (NO3)3 salt, and was characterized using XRD, FTIR, FESEM-EDX. TG-DSC and BET isotherm. In vitro bioactivity studies illustrate the formation of hydroxyapatite crystals on mBi-BG surface indicating its potential for bone repair and regeneration. Additionally, mBi-BG exhibits significant effect against Staphylococcus aureus (gram-positive) bacterial strain, highlighting its utility in preventing bacterial infections at surgical sites. Radiographic imaging of mBi-BG reveals excellent radiopacity comparable to human bone, rendering it suitable for image-guided surgeries and fluoroscopic procedures. In summary, mBi-BG emerges as a versatile biomaterial with enhanced bioactivity, antibacterial efficacy and radiopacity, thereby offering novel avenues in medical treatment modalities and patient care.

Simulation and calculation of the radiation attenuation parameters of newly developed bismuth boro-tellurite glass system

This paper presents a comprehensive simulation and calculation study of the radiation attenuation parameters for a newly developed bismuth boro tellurite glass system. Through advanced computational modeling and theoretical analysis, linear and mass attenuation coefficients (μ and μ/ρ), and other key radiation attenuation parameters of the studied glass system are thoroughly investigated across a range of photon energies. Utilizing state-of-the-art simulation techniques and theoretical models, the radiation shielding effectiveness of the glass system is evaluated, offering insights into its potential applications in radiation protection and shielding. We found that the ΣR values for fast neutrons are 0.10013, 0.10221, 0.10953, 0.11347 and 0.11383 cm−1 for BTBiBV-1, BTBiBV-2, BTBiBV-3, BTBiBV-4, and BTBiBV-5, respectively. The results of this study contribute to the understanding of the radiation attenuation properties of bismuth boro tellurite glasses and provide valuable information for their utilization in various fields, including medical imaging, nuclear power, and industrial radiography. Additionally, accurate modeling and characterization of attenuation parameters across different photon energies are crucial for designing effective radiation protection strategies and ensuring the safety of personnel and equipment in radiation environments.

∼2μm luminescence and energy transfer mechanism in highly Ho3+/Tm3+ co-doped bismuth glass

Highly Ho3+/Tm3+ co-doped Bi2O3-B2O3-Al2O3-BaF2 glasses were fabricated using the melt-quenching technique. The emission, radiation, and gain characteristics of the glass samples at the wavelength of 2.0 μm were examined analyzed. An intense and broad 2.0 µm emission, resulting from the 3F4→3H6 transition of Tm3+ and the 5I6→5I7 transition of Tm3+, was detected under the stimulation of 808 nm LD. The gain coefficient of Ho3+ in Ho3+/Tm3+ co-doped glass reaches 7.81 cm−1(at 2050 nm), which is 7.5 times as high as that of tellurite glass. Meanwhile, the large σemi × Δλeff(39.84 × 10-26 cm3) and σemi × τrad(16.10 × 10-21 cm2 ms) indicated BBTH4 glass possessed a large gain property and broadband. The energy transfer process of Tm3+: 3F4 ↔ Ho3+:5I7 was analyzed, the CD-A is 90 times larger than the CA-D. The Ho3+/Tm3+ co-doped Bi2O3-B2O3-Al2O3-BaF2 glasses show potential as broadband mid-infrared emission gain material.

Stabilization of δ-like Bi2O3 Phase at Room Temperature in Binary and Ternary Bismuthate Glass Systems with Al2O3, SiO2, GeO2, and B2O3.

Recently, it was shown that the nanocrystallization of Bi2O3 glasses with the addition of SiO2 and Al2O3 leads to the stabilization of the δ-like Bi2O3 phase at least down to room temperature, which is significantly below its stability range in bulk form. In this research, we investigated the properties of bismuthate glasses synthesized with various glass-forming agents such as SiO2, GeO2, B2O3, and Al2O3. It was demonstrated that vitrification of all these systems is possible using a standard melt quenching route. Furthermore, we investigated the crystallization processes in pristine glasses upon increasing the temperature and the thermal stability of arising phases using thermal analysis and high-temperature XRD in situ experiments. It was shown that it is possible to stabilize crystallites' isostructures with δ-Bi2O3 embedded in a residual glassy matrix down to room temperature. The temperature range of the appearance of the δ-like phase strongly depended on the nominal composition of the glasses. We postulate that the confinement effect depends on the local properties of the residual glassy matrix and its ability to introduce sufficient force to stretch the structure of the δ-like Bi2O3 phase in the nanocrystallites.

Enhancing 2.7 µm emission of Er3+ in bismuth glass by introducing ZnO

In recent years, 2.7 μm lasers have attracted the attention of many researchers due to their wide application in military, medical, aerospace and other fields. This study investigates the gain effect of ZnO on Er3+-doped bismuthate glasses by partially replacing GeO2 in the glass with ZnO. It is found that under 980 nm pump excitation, with the increase of ZnO, the emission of Er3+ at 1.5 μm and 2.7 μm was enhanced. This result is consistent with the changing trend of J-O parameter Ω2. All these results confirmed that the introduction of ZnO into bismuthate glasses is a reasonable and effective method to enhance the mid-infrared 2.7 μm emission in Er3+-doped bismuthate glasses. Therefore, the current research indicates that an appropriate amount of ZnO in Er3+-doped bismuthate glasses is a suitable materials for 2.7 um fiber lasers.

Preparation and radiation shielding features of high density, transparent borosilicate glasses with different Bi2O3 contents

This work assessed highly effective bismuth borosilicate glasses' nuclear radiation shielding capabilities in terms of different concentrations of Bi2O3. Melt-quenching was the method used to create the glasses. The Phy-X/PSD program was used to compute the μm values. The bismuth borosilicate glasses' nuclear radiation shielding properties were determined in the 0.015–15 MeV energy range. Increasing Bi₂O₃ concentration resulted in an increase in mass attenuation coefficient, linear attenuation coefficient, and effective atomic number. Conversely, the half value layer and mean free path values decreased. The B48Bi17 sample, with its largest Zeff, is a great gamma attenuator. The results of a new study may help to clarify the nature of the Bi2O3 additive used in borosilicate glasses, which are a potential form of shield for use in industrial and medical radiation facilities.

Synthesis, optical, and spectroscopic studies of bismuth boro-tellurite glass system containing BaO and V2O5

A melt quenching technique was used for the preparation of xBaO–(30-x)TeO2–35Bi2O3–33B2O3–2V2O5 (5 ≤ x ≤ 25 mol%) glasses. The structural modifications are studied by X-ray diffraction, DSC, optical, infrared spectroscopy, and Raman as a function of BaO mol%. The progressive incorporation of BaO mol% in the BTBiBV glasses decreases the optical band gap values as the number of free electrons increases with the creation of additional NBOs. The FTIR spectra of the prepared glasses consist of BO3 trigonal and BO4 tetrahedral units while TeO2 changes to TeO3 andTeO4 structural units. The Raman spectra shows that the replacement of BaO with TeO2 decreases the concentration of Te–O–Te linkages within the volume of host glass, which increases the concentration of Ba–O–Te linkages along with BO3 units. Due to this, the overall glass formers connectivity decreases which intern to the creation of NBOs. Moreover, the research highlighted that BTBiBV-5 glasses have exceptional optical properties making them promising materials for photonics, optoelectronics, and optical communication device applications.

Joining high volume fraction SiC particle reinforced aluminum matrix composites using Bi2O3-B2O3-ZnO-BaO-Na2O glass

This paper designs a bismuthate glass 58Bi2O3-25B2O3-13ZnO-2BaO-2Na2O in mol%(BBZ) and uses it to join 65 % volume fraction SiC particle reinforced aluminum matrix composites (65 vol%SiCp/ZL102) in an atmospheric environment. The thermal properties of BBZ glass were studied, and the effect of the brazing process on the mechanical properties of the joint was explored. The results show that the glass transition temperature of the glass is 344.6 °C, and the two crystallization temperatures are 464.7 °C and 544.3 °C. The oxidation of the parent material can improve the mechanical properties of the joint. The increase in welding temperature and the extension of holding time make the mechanical properties of the joint first increase and then decrease. When brazing at 490 °C for 30 min, the pre-oxidized composite material was brazed, the joint was defect-free, and the shear strength of the joint was 19.4 MPa. The analysis of the shear fracture showed that the fracture mainly occurred in the glass brazing material, which is a brittle fracture.

The Study on the Decolorization and Properties of Bismuth Glass

PbO glass has an adverse effect on the environment; the bismuth glass has a high refractive index, low melting temperature, softening temperature, and glass transition temperature (Tg), so that it can be used as a lead-free glass, used in optoelectronics, electronics, optics, and other components, which bismuth glass has been proved to be an important replacement material. Due to the higher melting temperature, Bi3+ ions tend to partially reduce to the low valence state of Bi0, which in turn causes coloration of the glass. In this experiment, the absorption peaks of glass oxidized brown color were observed at about 470 nm at 1,100°C (Bi2O3 = 40, 45 mol%) and 1,000°C (Bi2O3 = 40 mol%) for these three curves. The bismuth glass produced by high-temperature melting is not suitable for optical applications; by adding an oxidant (Sb2O3), which inhibits the reduction reaction of bismuth ions and maintains the ions in the state of Bi3+, the glass becomes more transparent in appearance and the transmittance is also improved and raised to approximately 75%–80%, which proves that appropriate additives are sufficient to greatly improve the application of bismuth glass for optical components. In the research process, the density and molar volume were measured by Archimedes method, Raman analysis was used to explore the influence of its structural changes, UV/Vis spectroscopy was used to measure the transmittance and absorption spectra for analysis and discussion, and TMA was used to observe the thermal properties, in the hope of developing a good optical properties of the glass, and the present experiments have confirmed that the addition of a small amount of Sb2O3 changes the color of the glass from black to a light yellow, which can be better used in the optical glass.

Bismuthate Glass as Backing for Gas Sensors

Bismuthate Glass as Backing for Gas Sensors

Effect of ion implantation on physical, optical properties and gamma-ray shielding capacity of boro-zinc bismuthate glasses

Effect of ion implantation on physical, optical properties and gamma-ray shielding capacity of boro-zinc bismuthate glasses

Lead-free bismuth glass system towards eco-friendly radiation shielding applications

In this study, the gamma-ray photon, electron, proton, helium ion, carbon ion, thermal neutron, and fast neutron interaction parameters of the (70-x)(Bi2O3 + ZnO) + x(V2O5 + TeO2) + 20B2O3 + 6.5SiO2 + 2.5Al2O3 + 1(CeO2 + Sb2O3) glass system were estimated with the aim of assessing their radiation shielding potentials. The mass attenuation coefficients (MACs) of the glasses were estimated for photon energies between 0.015 and 15 MeV using the PHITS simulation code and XCOM software. The stopping powers of charged radiation such as electrons, protons, α-particles, and carbon ions were also estimated by Monte Carlo simulation of particle transport using PHITS. The narrow beam transmission simulated using PHITS yielded values of MAC that were not so different from those from XCOM. The MACs of B/V-ZBVSA1 vary from 0.039–90.747 cm2/g, while those of B/V-ZBVSA2, B/V-ZBVSA3, and B/V-ZBVSA4 vary from 0.035–69.724, 0.036–73.088, and 0.037–70.597 cm2/g, respectively. The HVL of the glasses varied from 0.011–2.56 cm, 0.019–3.69 cm, 0.017–3.31 cm, and 0.017–3.36 cm for B/V-ZBVSA1 – B/V-ZBVSA4, respectively The effective atomic number varied within the limits: 28.36–76.06, 19.67–67.91, 22.14–68.70, and 22.39–68.08 for BV-ZBVSA1 – BV-ZBVSA4, respectively. The stopping powers (Sp) of electrons in BV-ZBVSA1, BV-ZBVSA2, BV-ZBVSA3, and BV-ZBVSA4 were in the range 1.219–8.043 MeVcm2/g, 1.295–9.306 MeVcm2/g, 1.264–8.859 MeVcm2/g, and 1.257–8.793 MeVcm2/g correspondingly. Comparatively, the Sp of protons, α-radiation, and carbon ions follows the order: BV-ZBVSA2 > BV-ZBVSA3 > BV-ZBVSA4 > BV-ZBVSA1. Also, the value of ΣR for BV-ZBVSA1, BV-ZBVSA2, BV-ZBVSA3, and BV-ZBVSA4 was 0.1171, 0.1126, 0.1133, and 0.1103 cm−1 accordingly, while the corresponding total cross-section of thermal neutrons was 67.6227, 46.8356, 59.1179, and 56.6994 cm−1. The present glasses showed superiority in absorbing photons and neutrons compared to some existing shields and previously recommended glasses. The present glassy samples, thus, can be adopted for radiation protection purposes, among others in radiation facilities.

XRD, FTIR and ultrasonic investigations of cadmium lead bismuthate glasses

Cadmium lead bismuthate glasses in the system xCdO–(1−x)[0.5PbO + 0.5Bi2O3](40 mol% ≤ x ≤ 90 mol%) were successfully prepared by melt-quenching method. The structural and elastic properties have been investigated using XRD, FTIR and ultrasonic pulse–echo techniques. The XRD patterns confirmed the amorphous nature of the samples prepared. Density and ultrasonic velocity data were used to evaluate various elastic properties. Addition of CdO gave rise to decreased density and molar volume and increased elastic moduli, micro-hardness, and Debye temperature. The FTIR analysis revealed that increasing CdO content enhances the BiO6 octahedral sites at the expense of the BiO3 and PbO4 units. This results in the formation of Pb–O–Bi(6) and Bi(3)–O–Bi(6) linkages in the glass network, which stiffen the structure and improve the elastic properties. A correlation between elastic and compositional parameters was achieved on the basis of theories and approaches in the field.

APPLICATION OF BISMUTHATE GLASSES AS A SUBSTRATE FOR GAS SENSORS

The synthesis of bismuth-borate glasses was carried out Composition (mass content, %): 70 Bi2O3, 2 GeO2, 25 B2O3, 3 MoO3; 70 Bi2O3, 17 GeO2, 10 B2O3, 3 MoO3 and bismuth glasses. Composition (mass content, %): 80 Bi2O3, 4 GeO2, 5 MoO3, 11 SiO2; 80 Bi2O3, 8 GeO2, 8,5 SiO2, 3,5 MoO3. Processes have been developed for forming a layer based on glass receptors using the method of ultrasonic spraying of interacting components and applying a water-insoluble polymer film obtained by a chemical reaction between a poly-N,N-dimethyl-3,4-dimethylenepyrrolidinium chloride polymer and a modifier potassium hexacyanoferrate (II). The sensors obtained on the basis of glasses make it possible to determine the content of hydrogen sulfide and water vapor in the air with an error of 2 – 4 %.

Bismuth-Germanate Glasses: Synthesis, Structure, Luminescence, and Crystallization

Bismuth-germanate glasses, which are well known as a promising active medium for broadband near-infrared spectral range fiber lasers and as an initial matrix for nonlinear optical glass ceramics, have been synthesized in a 5–50 mol% Bi2O3 wide concentration range. Their structural and physical characteristics were studied by Raman and FT-IR spectroscopy, differential scanning calorimetry, X-ray diffraction, optical, and luminescence methods. It has been found that the main structural units of glasses are [BiO6] and [GeO4]. The growth in bismuth oxide content resulted in an increase in density and refractive index. The spectral and luminescent properties of glasses strongly depended on the amount of bismuth active centers. The maximum intensity of IR luminescence has been achieved for the 5Bi2O3-95GeO2 sample. The heat treatment of glasses resulted in the formation of several crystalline phases, the structure and amount of which depended on the initial glass composition. The main phases were non-linear Bi2GeO5 and scintillating Bi4Ge3O12. Comparing with the previous papers dealing with bismuth and germanium oxide-based glasses, we enlarge the range of Bi2O3 concentration up to 50 mol% and decrease the synthesis temperature from 1300 to 1100 °C.

Effect of different carbon materials on the structure and glass crystallization temperature, wettability, and expansion coefficient properties of glass

Bismuthate glasses have garnered increasing attention in the fields of optics, packaging, and electronic pastes due to their remarkable stability and high visible light transmission. Nevertheless, high sealing temperature, high expansion coefficient, and poor wettability remain significant challenges in their application. Herein, we report a carefully designed approach that begins with bismuthate glasses of well-defined composition and coats them with various carbon materials to form different C@aminated glass composites by hydrothermal synthesis. This work investigates the effects of different carbon materials on the glass structure and properties, such as melting temperature, crystallinity, wettability, and expansion coefficient, and establishes the redox reaction mechanism involved in glass crystallization formation. Graphene oxide, with its different number of functional distributions and oxygen content, exhibits the largest decrease in softening point and softening-to-melting point temperature difference, the highest increase in wettability, and the greatest reduction in expansion coefficient compared to other carbon materials. In addition, different carbon materials promote a greater variety and strength of crystallization. GO@glass exhibits the most moderate reactivity and generates a significant amount of crystallization at the interface when co-sintered with Si substrates, indicating that the inclusion of crystalline phases can improve the bond strength of the glass. This work provides new insights into designing high-performance bismuthate glasses and promoting their applications.

Effect of gamma ray irradiation on optical and luminescence properties of CeO2 doped bismuth glass

High lead oxide based Radiation Shielding Window (RSW) glass is highly toxic in nature and thus health hazardous. Therefore, a new way to design environmental friendly non-toxic lead-free RSW glass for nuclear application is very much required. In this work, a lead-free non-toxic glass based on multi-component Bi2O3–BaO–B2O3–ZnO–As2O3–MgO–Na2O system has been studied with different concentrations of cerium oxide (CeO2) as doping agent for enhancing radiation shielding effect. The optical properties of cerium doped bismuth based lead-free radiation shielding glass after exposure to gamma radiation up to 105 rad have been studied. The densities of glass varied from 4.59 to 5.05 g/cc on varying concentrations of bismuth oxide and boron trioxide in glass system. The transmission properties in visible regions from 400 to 1000 nm are investigated through UV–visible spectrometer after exposure to gamma radiation on developed glass using 60Co Gamma Chamber GC5000. The structure of glass as characterized by Raman spectroscopy, XRD, Photoluminescence (PL), FESEM with EDAX, refractive index measurement and dilatometry test has been correlated with its properties. The developed bismuth glass could find its application as lead-free RSW glass in nuclear reactors as an alternative to high lead containing glass.

Solar photocatalytic abatement of pollutant over BiOBr derived from in situ synthesis of bismuth glass

Solar photocatalytic abatement of pollutant over BiOBr derived from in situ synthesis of bismuth glass