Biomass charcoal combustion is a complex process, significantly influenced by various operating parameters. Among these parameters, air supply emerges as a critical factor affecting combustion efficiency, gas emissions, and thermal dynamics. In this study, we explored these complex interdependencies using a novel combination of mid-wavelength infrared (MWIR) hyperspectral imaging and long-wavelength infrared (LWIR) thermal imaging, under different airflow rates. Our findings demonstrated that while increased airflow accelerated the overall combustion rate, it simultaneously decreased combustion efficiency. Specifically, the thermal profiles showed an increased surface temperature at a low flowrate (0.5 L/min) while decreasing in temperature with higher flowrates. The decreased system temperature led to a lower combustion efficiency because of the reduced conversion rate from combustible gases (CH4 and CO) into CO2 and H2O. Additionally, the results also demonstrated that cooling effects of the high flowrates primarily impeded the solid-phase combustion stage. This is further corroborated by the temporal and spatial variation in the emissions of key gas species (H2O vapor, CH4, CO, and CO2) observed through hyperspectral imaging. The emission evolution of these gases displayed the different stages of the gas-phase and solid-phase combustion. The spatial distribution of the trace gases showed a decreased distribution radius due to the enhanced diffusion to the fuel surface when the airflow increases, aligning well with the two-film model established in the literature. Furthermore, we utilised spectral radiance ratios (CO/CO2, CH4/CO2, H2O/CO2) to gain additional insights into the combustion dynamics. These ratios evidenced the decrease in combustion efficiency at high airflow rates. Finally, the increased H2O/CO2 ratio further demonstrated the impeded char combustion and a shift towards pyrolysis at higher airflow rates because of the decreased thermal equilibrium of the system. The findings from this study provide critical insights into the dynamics of biomass charcoal combustion and illuminates the path for optimising energy efficiency and assessing the environmental implications from burning biomass fuels.
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