The research examines the prospects for using the potential of the agro-industrial complex of Ukraine to study green technology innovations during economic development under martial law. Based on the study, it is proved that technological innovations in the agricultural sector contribute to economic development and improve the quality of agricultural land. The article analyses the successful implementation of the case of LLC Yuzhef-Mykolayiv Biogas Company, which has successfully restructured the production of a sugar plant and produces biogas and digestate with further processing into electricity and fertiliser. The modern capacities of the studied enterprise are highlighted, which allow to produce 2800 m3 of biogas and ensure the production of 5200 kWh of electricity, while consumption does not exceed 150 kW, at a load of 80%. The volume of digestate produced per year is 100,000 tonnes. In the regional context, innovative environmental technologies aimed at improving the quality of agricultural land have been introduced. An effective mechanism of spatial synergy with adaptation of this practice at most sugar factories through restructuring of production - creation of biogas production facilities on the basis of sugar factories - is proposed. As a long-term development perspective, the paper presents further creation of alcohol production facilities to use excess heat energy from mini-thermal power plants for the production of alcohol and bioethanol. Furthermore, this study confirms the non-linear effect of economic development; a significant result shows that the impact of green technology innovations on improving the quality of agricultural land (soil humus content, amount of mineral and organic fertilisers, pesticides, area of land under organic production, etc.) contributes to the increase in the level of regional economic development of the agricultural sector. The article clarifies the intermediary role of economic development of the agro-industrial complex. The results of the study implement the tasks of sustainable development, such as improving the environment through the innovation of green technologies and achieving regional synergy in green development.