Biodegradable Components Research Articles

Characteristics of Edible Film from Corn Starch (Zea mays L.) with Additional Glycerol and Variations of Zinc Oxide (ZnO) Nanoparticles

Plastic is one of the most widely used packaging materials. Plastic is made of chemicals that are highly toxic, and its use has produced a lot of waste that is bad for the environment and difficult to decompose. The global community is becoming more and more aware of the value of high-quality food, particularly when it comes to packaging that is safe for human health and the environment. Edible films can be used as an eco-friendly alternative to plastic food packaging options. As a material for packaging, edible film made of biopolymers has been created. This material can be made from biodegradable components and has qualities akin to those of ordinary plastics. When combined with zinc oxide (ZnO), a piezoelectric ceramic with anti-microbial properties, edible film degrades and decomposes readily. This study sets out to identify the effects of variations in zinc oxide nanoparticle concentration properties of edible films made from corn starch (Zea mays L.) and to establish the optimal zinc oxide nanoparticle concentration. ZnO concentrations ranging from 0% to 3% to 9% to 12% were used. The outcomes demonstrated that a concentration of 12% provided the optimal treatment for the properties of edible film. With the addition of 12% ZnO concentration, the edible film's properties improved the most in this investigation, showing 81.94% water resistance, 1.434 MPa tensile strength, and 38.46% elongation percent. The lowest biodegradability value was found in edible film with a concentration of ZnO 12%, within 14 days. The resistivity, tensile strength, and % elongation of the edible film increase with increasing ZnO content.

Towards bio-utilization and energy recovery potential exploration of membrane foulant from membrane bioreactor by using microbial fuel cell-centered technology

The utilization of membrane foulant is expected to push forward the developments of membrane bioreactor (MBR). In this study, the combination of microbial fuel cell (MFC) with bio-electrochemical enhanced hydrolysis process was proposed, and three systems were conducted to utilize the membrane foulant and simultaneously harvest electricity. Polysaccharides (PS), proteins (PN) and humic acid (HA) concentration variations and the fluorescent compound changes in different chambers revealed the biodegradability of membrane foulant. Optimized HRT improved the hydrolysis of membrane foulant while allowing MFC to utilize the biodegradable components efficiently. MFC-MFC system had the highest voltage and satisfactory effluent quality at HRT of 1 d. Microbial community structure analysis indicated that Proteobacteria, Planctomycetes and Bacteroidetes were the majority phyla and network analysis further revealed that Proteobacteria played a key role in membrane foulant utilization. This study suggests that MFC hybrid systems has potential application for synchronous membrane foulant reuse and energy recovery.

Mechanical Properties of 3D Printed Parts and Their Injection Molded Alternatives Subjected to Environmental Aging.

Additive manufacturing is the technology used in medical, industrial, or lifestyle applications. The scientific literature include works reporting various manufacturing parameters' influence on changes in additive manufacturing components' mechanical behavior, especially with fused filament fabrication (FFF). The changes in mechanical strength and toughness of FFF compared to injection molding parts were studied. In the study, the FFF and injection molded parts were aged in buffered saline solution in temperature of 37°C. The results show that by differentiating the orientation of the fibers during fabricating, it is possible to reach strength values similar to injection molded parts. Therefore, it was reported that the mechanical strength and toughness changed significantly after aging, and the FFF components lost strength more quickly than their injected alternatives. The research results can be useful during the fabrication of mechanically stable and biodegradable components, which can be more easily recycled than their injected alternatives when used with warmer temperatures and humidity. This article completes the present state of the art on the problem of environmental aging of parts produced from biodegradable materials. Especially, the research was related to the multilayer laminate structure.

Waste to Energy: Review on the Development of Land Fill Gas for Power Generation in Sub-Saharan Africa

This study focused on the development of land fill gas for power generation in Sub-Saharan Africa. In rapidly expanding cities in developing and emerging nations, it has been observed that municipal solid waste (MSW) has increased dramatically, raising public concern about the effects on the environment and public health. In Sub-Saharan Africa today, the garbage of people within this region especially in Nigeria is carelessly disposed. Environmental pollution and its effects on people's quality of life have become more sensitive topics among residents and decision-makers in Sub-Saharan Africa. Additionally, municipal solid waste management (MSWM) is becoming a more important topic on the local political agenda. Local decision-makers routinely debate whether to invest in waste-to-energy technologies as part of their effort to modernize waste management systems. Waste-to-Energy technologies are being promoted more and more as an alluring solution to a number of problems, including the urgent issue of waste disposal. These issues include inadequate power production, a shortage of landfill space, and greenhouse gas emissions from improper waste management. As an alternative to waste burning and composting, landfilling is one of the municipal solid waste (MSW) disposal techniques that are most frequently used. Due to its financial benefits, the sanitary landfill method is still often employed in various nations for the final disposal of solid waste. Landfill gas (LFG) is mostly produced by the anaerobic breakdown of the biodegradable component of municipal solid waste (MSW), specifically kitchen and yard trash, which is disposed of in landfills. Due to the anaerobic breakdown of the organic portion of solid waste, landfill gas is continuously produced. As a result, if an extraction system is not constructed in a landfill, there will be an overpressure that will force the biogas to be released into the atmosphere, which will have an adverse effect on the environment. Methane and carbon dioxide make up the majority of the gases that make up landfill gas, which is a mixture of other gases. Many landfill sites include an operational gas collection system that draws gas from both horizontal and vertical gas wells using a blower. The gas from the landfill was thought to only include carbon dioxide and methane. Methane's typical volume composition is 49%, hence it was believed that carbon dioxide would have a volume composition of 51%. Reviewing the information gathered by numerous studies regarding the volume of waste being dumped in landfills reveals that the waste produced in sub-Saharan Africa is sufficient to power the area with electricity. It was discovered that the quantity of electricity generated will fluctuate over time based on the flow rate of landfill gas. It will initially rise until a peak is attained. A million tons of landfill waste typically emits 434,000 cubic feet of LFG each day, which is sufficient to generate 0.80 MW of power. About 70% of LFG projects use internal combustion engines, gas turbines, and micro-turbines to produce power.

Novel microemulsions formulated from sodium N-Lauroyl sarcosinate as nanocarrier for encapsulation of α-Tocopherol

Oil-in-water (o/w) microemulsions (MEs) are gaining increasing attention as nanocarriers for the encapsulation and delivery of hydrophobic bioactive molecules which has huge applications in cosmetic, pharmacological, food and beverage industries. However, the major challenge is to formulate these MEs from biodegradable and biocompatible components in low concentration to form stable formulations. In the current work, physiochemical characterization of blank and α-tocopherol loaded o/w MEs formulated using the biodegradable amino-acid based sodium N-lauroyl sarcosinate (SNLS) as surfactant was performed. These MEs were utilized as potential nanocarriers to solubilize and encapsulate an antioxidant α-tocopherol. The utilization of o/w MEs increased the solubility of α-tocopherol from 0.1% in 10% SNLS solution to 0.2% and 0.8% in MEs without and with cosurfactant respectively. The effect of cosurfactant, concentration of Smix (SNLS:butanol = 1:1) and oil was evaluated using conductivity, viscosity studies and encapsulation efficiency to select the optimum composition for encapsulation. The Z-average size of blank MEs without and with cosurfactant was 304 nm and 199 nm respectively with low PDI and negative zeta potential values determine the enhanced stability of these MEs. The HRTEM images revealed the spherical shape of o/w MEs with darker oily core and were utilized to study the effect of cosurfactant and encapsulation of α-tocopherol on the size and morphology of o/w ME droplets. Further, FTIR studies showed the molecular interactions in α-tocopherol and in the optimized ME. In addition to this, the in-vitro antioxidant study of α-tocopherol loaded MEs was determined by the DPPH free radical scavenging activity and the IC50 value was 9 mg/mL for the optimized ME containing 0.5% α-tocopherol. The contact angle studies revealed excellent wetting and spreading ability of MEs on the hydrophobic surface. Thus, SNLS based o/w MEs could be utilized as potential nanocarriers for the encapsulation and delivery of α-tocopherol.

Waste to energy: An experimental study on hydrogen production from food waste gasification

Though food scarcity realizing in many places in the world, food waste generation still shows its increasing trend because of cultural and habitual changes, as well as technological characteristics. However, food waste comprises a large amount of organic material and biodegradable components, showing that it could be a potential source for producing hydrogen (H2) aiming to satisfy the key goals of diversifying the energy supply and reducing environmental pollution. Indeed, this research addresses the potential possibilities to use food waste for the production of H2 by using a water gasification reactor. In this work, food waste was gasified by varying the operating parameters in the H2 production process and the addition of additives. In this investigation, different additives such as HCl, NaCl, and NaHCO3 were considered to investigate at different reactor temperatures like 300, 350, and 400 °C for different reaction durations like 30, 45, and 60 min. The results revealed that the best average yields of CH4, H2, CO2, CO, and total gas were obtained as 1.5, 12.9, 0.2, 0.1, and 13.9 mol/kg, respectively, when the reaction employed with NaHCO3 additive than the other cases (with HCl, NaCl additives and no additive cases). The H2 production efficiency was estimated as 43%, 34%, 27%, and 30% when the use of NaHCO3, NaCl, HCl, and no additives. Hence, it is found that the NaHCO3 catalyst considerably enhances the gasification process through the improvement of the water-gas shift reaction, and thereby H2 production increases.

시한성 전자소자를 위한 생분해성 기능성 무기/유기 하이브리드 복합재료

The utilization of patch-type components, ranging from attachable disposable devices to implantable medical devices, is accelerating. Biodegradable electronic components are expected to effectively alleviate environmental issues caused by waste and address cost-related concerns associated with recycling operations, serving as environmentally friendly electronic components. Moreover, they mark the starting point for implantable medical devices that do not require removal surgery. In this paper, we comprehensively summarize and discuss the structure, components, examples, fabrication methods, and recent trends in the application areas of biodegradable functional composites, which possess advantages as materials for biodegradable electronic components. Furthermore, we also discuss the prospects and challenges in the development of biodegradable functional composites. This paper is expected to provide an important tool and useful strategies for the design of biodegradable functional composites.

The Effect of the Nature of Biodegradable Components on Biodegradability of Composites Based on Polyethylene

The Effect of the Nature of Biodegradable Components on Biodegradability of Composites Based on Polyethylene

Biodegradable Poly(trehalose) Nanoparticle for Preventing Amyloid Beta Aggregation and Related Neurotoxicity.

Trehalose is a disaccharide that is capable of inhibiting protein aggregation and activating cellular autophagy. It has been shown that a polymer or nanoparticle form, terminated with multiple trehalose units, can significantly enhance the anti-amyloidogenic performance and is suitable for the treatment of neurodegenerative diseases. Here, we report a trehalose-conjugated polycarbonate-co-lactide polymer and formulation of its nanoparticles having multiple numbers of trehalose exposed on the surface. The resultant poly(trehalose) nanoparticle inhibits the aggregation of amyloid beta peptides and disintegrates matured amyloid fibrils into smaller fragments. Moreover, the poly(trehalose) nanoparticle lowers extracellular amyloid β oligomer-driven cellular stress and enhances cell viability. The presence of biodegradable polycarbonate components in the poly(trehalose) nanoparticle would enhance their application potential as an anti-amyloidogenic material.

Design and fabrication of magnetic Fe3O4-QSM nanoparticles loaded with ciprofloxacin as a potential antibacterial agent

In this investigation, we have synthesized magnetite nanoparticles (Fe3O4 NPs) coated with quince seed mucilage (QSM) as a natural, biocompatible, and biodegradable component and loaded them with ciprofloxacin (CIP) to act as an antibacterial agent. The structural, magnetic, physicochemical, colloidal, and antibacterial properties of the samples were tested using various characterization tools such as XRD, TEM, FE-SEM, VSM, FT-IR, UV–Vis, DLS, BET, and disk diffusion for testing the antibacterial properties. XRD and VSM results confirmed the fabrication of a highly pure cubic spinel phase for Fe3O4. The results of FE-SEM and TEM analyses indicate a spherical morphology of the magnetite NPs with a mean diameter of about 13 nm, and the results of DLS show a hydrodynamic diameter of 81.9 to 119.2 nm. The zeta potential value for the magnetic Fe3O4 NPs was as high as −55.2 mV, indicating suitable colloidal stability of the NPs for biological applications. The VSM results indicate a high saturation magnetization of the samples as well as a small coercivity and Remanence of the samples, which indicate the superparamagnetic property of the NPs. It was also indicated that the amount of drug adsorbed on the magnetic nanoparticles at different pH values (5.5 to 6.5) is about 85 %. It was likewise detected that the synthesized Fe3O4@QSM-CIP NPs possess antibacterial activity against standard strains of both Gram positive and Gram-negative bacteria (minimum inhibitory concentration = 100 ppm). The overall findings imply that the proposed magnetic NPs with antibacterial activity are promising for biomedical applications.

Metal Oxide Coating On Biodegradable Magnesium Alloys

Magnesium is a biodegradable metal that has potential in orthopaedics. It has several advantages over other metallic materials because it is biocompatible and degradable now being used for biomedical applications, including elimination of stress shielding effects, enhancing degradation properties and enhancing biocompatibility concern in vivo, eliminating the second surgery for implant removal. Bioabsorbable magnesium (Mg) and related alloys have been limited in their usage because of its lower corrosion resistance. Surface alteration and functionality, in addition to basic alloying, is an important technique to deal with Mg and its alloys' reduced corrosion resistance. Magnesium's rapid depreciation however is a double-edged sword because it's critical to match bone renewal to material corrosion. As a result, calcium phosphate coatings have been proposed as a way to slow down corrosion. There are various possible calcium phosphate phases and their coating methods and can give a few distinct properties to various applications. Despite magnesium's lower melting point and greater reactivity, calcium phosphate coatings require precise settings to be effective. Because of their toxicity, non-biodegradability, and much higher cost, the recently used inorganic conversion coatings are less appealing and their application is limited. Conversion coatings are a viable alternative technology that is based on a cost- effective, environmentally friendly, and biodegradable organic component. Surface chelating functional groups in these compounds allow them to link with the magnesium/surface hydroxide layer while also providing anchoring groups for the polymer topcoat. Nanoreservoirs with multilayer inhibitors for active self-healing corrosion resistance thrive in this environment. This study examines the organic conversion coatings for Mg and its alloys in depth.

Glass-Based Biodegradable Pressure Sensor Toward Biomechanical Monitoring With a Controllable Lifetime

A new class of potentially implantable solid-state sensors is demonstrated utilizing biodegradable glass as main structural material. The device behavior is manipulated via chemical decomposition, and then physically disintegrated in a controlled manner. It is based on the capacitive sensing mechanism, comprising an elastic insulator between two borate-rich glass substrates. This meso-scale pressure sensor is characterized over a range of pressure of up to 14 MPa in a phosphate buffer solution environment. The sensor exhibits good sensitivity and reversibility responding to compressive pressures and remains fully functional before a desired, sudden failure caused by dissolution. The operational lifetime can be modified by altering the chemical composition or thickness of the biodegradable glass component. The proposed device concept is a viable option toward various temporary implantable devices without needing an additional surgical procedure to remove them after their duty.

Fibrin-Rhamnogalacturonan I Composite Gel for Therapeutic Enzyme Delivery to Intestinal Tumors.

Therapy of colorectal cancer with protein drugs, including targeted therapy using monoclonal antibodies, requires the preservation of the drug's structure and activity in the gastrointestinal tract or bloodstream. Here, we confirmed experimentally the fundamental possibility of creating composite protein-polysaccharide hydrogels based on non-degrading rhamnogalacturonan I (RG) and fibrin as a delivery vehicle for antitumor RNase binase. The method is based on enzymatic polymerization of fibrin in the presence of RG with the inclusion of liposomes, containing an encapsulated enzyme drug, into the gel network. The proposed method for fabricating a gel matrix does not require the use of cytotoxic chemical cross-linking agents and divalent cations, and contains completely biocompatible and biodegradable components. The process proceeds under physiological conditions, excluding the effect of high temperatures, organic solvents and ultrasound on protein components. Immobilization of therapeutic enzyme binase in the carrier matrix by encapsulating it in liposomes made from uncharged lipid made it possible to achieve its prolonged release with preservation of activity for a long time. The release time of binase from the composite carrier can be regulated by variation of the fibrin and RG concentration.

Fully Bio-Based Composites of Poly (Lactic Acid) Reinforced with Cellulose-Graft-Poly-(ε-Caprolactone) Copolymers

Due to the increasing demand for modified polylactide (PLA) meeting “double green” criteria, the research on sustainable plasticizers for PLA has attracted broad attentions. This study reported an open-ring polymerization method to fabricate cellulose (MCC)-g-PCL (poly (ε-caprolactone)) copolymers with a fully sustainable and biodegradable component. MCC-g-PCL copolymers were synthesized, characterized, and used as green plasticizers for the PLA toughening. The results indicated that the MCC-g-PCL derivatives play an important role in the compatibility, crystallization, and toughening of the PLA/MCC-g-PCL composites. The mechanical properties of the fully bio-based PLA/MCC-g-PCL composites were optimized by adding 15 wt% MCC-g-PCL, that is, the elongation at break was 22.6% (~376% higher than that of neat PLA), the tensile strength was 47.3 MPa (comparable to that of neat PLA), and the impact strength was 26 J/m (~130% higher than that of neat PLA). DSC results indicated that MCC-g-PCL reduced the Tg of the PLA blend. When the addition amount was 15 wt%, the Tg of the blend was 58.4°C. Compared with MCC, MCC-g-PCL polyester plasticizer has better thermal stability, T5% (°C) can still be maintained above 300°C. The rheological results showed that MCC-g-PCL acted as a plasticizer, the introduction of PCL flexible chain increased the mobility of PLA molecular chain, and decreased the complex viscosity, storage modulus and loss modulus of PLA blends. The MCC-g-PCL derivatives, as a new green plastic additive, have shown an interesting prospect to prepare fully bio-based composites.

Photolithography-Based Microfabrication of Biodegradable Flexible and Stretchable Sensors.

Biodegradable sensors based on integrating conductive layers with polymeric materials in flexible and stretchable forms have been established. However, the lack of a generalized microfabrication method results in large-sized, low spatial density, and low device yield compared to the silicon-based devices manufactured via batch-compatible microfabrication processes. Here, a batch fabrication-compatible photolithography-based microfabrication approach for biodegradable and highly miniaturized essential sensor components is presented on flexible and stretchable substrates. Up to 1600 devices are fabricated within a 1 cm2 footprint and then the functionality of various biodegradable passive electrical components, mechanical sensors, and chemical sensors is demonstrated on flexible and stretchable substrates. The results are highly repeatable and consistent, proving the proposed method's high device yield and high-density potential. This simple, innovative, and robust fabrication recipe allows complete freedom over the applicability of various biodegradable materials with different properties toward the unique application of interests. The process offers a route to utilize standard micro-fabrication procedures toward scalable fabrication of highly miniaturized flexible and stretchable transient sensors and electronics.

Longitudinal patterns of dissolved organic matter quality and bacterial community degradation function along the mainstream of Three Gorges Reservoir during impoundment period

Longitudinal patterns of dissolved organic matter (DOM) influence the biogeochemical cycle in river ecosystems. Yet, linkages between DOM quality and bacterial degradation of emerging contaminants over a river continuum are unclear. In combination with DOM characterization, bioassay, and microbial analysis, this study unraveled the spatial variations of DOM composition and biodegradability as well as bacterial community structures, which determined the estrone biodegradation potential (EBP) along the mainstream in Three Gorges Reservoir during impoundment period. While urban and agricultural utilization increased the protein-like and biodegradable DOM components (BDOC%) in upstream, the in-situ biotransformation preferentially utilized tryptophan-like substances followed by tyrosine-like substances, resulting in the accumulated recalcitrant DOM with higher aromaticity, molecular weight, and humic-like components in downstream. Due to the promotion of biodegradable DOM on bacterial abundances, a significant and positive correlation was constructed between BDOC% and EBP (P < 0.001, R2 = 0.56), both of which were controlled by the ratio of fresh- to humic-like fluorescence. Nevertheless, a higher biomass-normalized EBP was found under recalcitrant conditions in downstream, demonstrating that the degradation function was also associated with the biogeographical distribution of bacterial communities. Results of microbial ecology revealed that the in-situ transformation of aromatic and humic-like DOM exhibited more correlations with bacterial taxa than protein-like DOM, leading to increased diversity and decreased niche breadths along the mainstream. The triggered deterministic selection of community assemblages in downstream favored potential estrone-degraders and up-regulated their specific metabolic capacity. These findings will provide critical insights toward understanding the crucial role of DOM in biogeochemical cycles and the self-purification of emerging contaminants along the river continuum.

Peelable Nanocomposite Coatings: "Eco-Friendly" Tools for the Safe Removal of Radiopharmaceutical Spills or Accidental Contamination of Surfaces in General-Purpose Radioisotope Laboratories.

Radioactive materials are potentially harmful due to the radiation emitted by radionuclides and the risk of radioactive contamination. Despite strict compliance with safety protocols, contamination with radioactive materials is still possible. This paper describes innovative and inexpensive formulations that can be employed as 'eco-friendly' tools for the safe decontamination of radiopharmaceuticals spills or other accidental radioactive contamination of the surfaces arising from general-purpose radioisotope handling facilities (radiopharmaceutical laboratories, hospitals, research laboratories, etc.). These new peelable nanocomposite coatings are obtained from water-based, non-toxic, polymeric blends containing readily biodegradable components, which do not damage the substrate on which they are applied while also displaying efficient binding and removal of the contaminants from the targeted surfaces. The properties of the film-forming decontamination solutions were assessed using rheological measurements and evaporation rate tests, while the resulting strippable coatings were subjected to Fourier-transform infrared spectroscopy (FTIR), thermogravimetric analysis (TGA), differential scanning calorimetry (DSC), and tensile tests. Radionuclide decontamination tests were performed on various types of surfaces encountered in radioisotope workspaces (concrete, painted metal, ceramic tiles, linoleum, epoxy resin cover). Thus, it was shown that they possess remarkable properties (thermal and mechanical resistance which permits facile removal through peeling) and that their capacity to entrap and remove beta and alpha particle emitters depends on the constituents of the decontaminating formulation, but more importantly, on the type of surface tested. Except for the cement surface (which was particularly porous), at which the decontamination level ranged between approximately 44% and 89%, for all the other investigated surfaces, a decontamination efficiency ranging from 80.6% to 96.5% was achieved.

Optimization of the modular reinforced bone scaffold for customized alveolar bone defects

A modular reinforced bone scaffold with enhanced mechanical properties has recently been developed by our group. It includes: 1) A load-bearing module: a skeleton which is made of a slowly degradable material, undertaking mechanical necessities of the scaffold, and 2) A bio-reactive module: a porous and biodegradable component undertaking biological necessities of the scaffold. The load-bearing module is placed into the bio-reactive module to reinforce it. This paper is dedicated to optimizing the load-bearing module for a certain customized alveolar bone defect. More specifically, a 3D-printed skeleton, made of polycaprolactone (PCL), is optimized based on the boundary conditions of the defect shape using the finite element method (FEM) to minimize the weight (to minimize the amount of PCL) and maximize the mechanical properties and porosity of the skeleton. Gelatin foam has been incorporated into the optimized skeleton through the aminolysis process to form the bio-reactive module. The mechanical characterization confirmed that the optimized load-bearing module has a bridge-like shape and can significantly improve the mechanical properties of the scaffold. Also, in vitro studies showed that the fabricated scaffold can improve cell proliferation and osteogenesis. This kind of scaffold can be useful for the treatment of critical-sized defects.

Effects of rhamnolipid pretreatment on DOM dissolution characteristics and anaerobic fermentation acid production of waste activated sludge

ABSTRACT In this paper, the change characteristics of DOM (dissolved organic matter) and acid production characteristics of anaerobic fermentation in waste activated sludge(WAS) pretreated with rhamnolipid (RL) were studied. The results showed that RL at the dose of 80 mg/gTS could significantly promote the disintegrating of EPS (extracellular polymers) and cell wall in WAS, and a large number of proteins and carbohydrates were dissolved. Three dimensional fluorescence parallel factor analysis showed that the addition of RL enhanced the dissolution and biodegradability of humus-like substances. LC-OCD (Liquid chromatography – organic carbon detection) analysis showed that RL promotes the dissolution of biodegradable components such as Biopolymer, Building Blocks and LMW Neutrals, and ensures the increase of VFA (volatile fatty acids) production in the process of anaerobic fermentation. Under the RL dose of 80 mg/gTS, the maximum VFA production of WAS was obtained at 108 h of anaerobic fermentation, which was 2699.39 mg/L. Acetic acid and propionic acid were the main components in the WAS fermentation broth pretreated by RL. The concentration of butyric acid increased with the increase of RL dose. The RL dose can significantly affect the composition of VFA in WAS fermentation broth.

An estimation of bio-methane and energy project potentials of municipal solid waste using landfill gas emission and cost models

PurposeThe purpose of the study is to analyse municipal solid waste (MSW) disposed of in Jimeta-Yola metropolis for landfill gas (LFG), methane and project viability potential.Design/methodology/approachThe data was collected daily from landfills for four weeks. About 7,329.55 Mg/year of waste was analysed. These waste were separated into bio-degradable components i.e. paper and textile (263.66 Mg), non-food organic (681.45 Mg), wood and straw (189.50 Mg) and food and kitchen waste (1797.20 Mg). Non-degradable components include plastics, polythene bags, metals, sand, stones, cans etc. (4397.73 Mg). The component's characteristics such as a number of samples, weight, volume, landfill age etc. were measured. The waste, methane (CH4) and energy potential were also analysed using LFG energy cost model.FindingsThe landfills received 15 Gg/year of MSW and emit 0.31 Gg/year of LFG having CH4 content of 82.95 Mg in 2016. These can produce 33.78 GWh of heat energy equivalent to 10.14 GWh of electricity analytically. Therefore, between 2016 and 2022, about 2.24 Gg CH4 and 5201.32 MWh of electricity were wasted. Henceforth, proper management of these waste substances can produce 186.4 Gg CH4 which will generate 432.52 GWh of electricity. The most economically viable project is an electricity project generating 418 kW/year at a sale price of $1.14/kWh (58.38/kWh) and a payback period of 11 years.Practical implicationsRaw LFG collected can be used in heating brick kilns, boilers, furnaces and greenhouses. When treated, the LFG can produce renewable natural gas (RNG), which is used in energy generation and various domestic, vehicle and industrial applications.Social implicationsThe analytical energy generation can provide gross revenue of ₦19.46bn at an average of ₦192.71million/year. Using Landfill Gas Emissions Model (LandGEM) model, the gross and net revenue will be $0.42m and $0.28m yearly, respectively. The project can provide jobs and economic boost to the immediate community through associated ripple effect.Originality/valueThe research is a pre-feasibility study for LFG to gas or electricity projects in Jimeta-Yola. The study contributed to the body of knowledge as a source of literature for further studies locally and globally.