Biochar Addition Research Articles

Effect of cyanobacteria biochar addition on humification, fungal dynamics and its mechanism of action in pig manure composting

Aerobic composting is an effective method for resourceful treatment of pig manure (PM). However, traditional composting often suffers from low humification effect and inactive fungal communities. In order to better treat PM, this study applied different doses of cyanobacterial biochar (CB) (T1:0 %; T2:2.5 %; T3:5 %; T4:7.5 %; T5:10 %; and T6:20 %) to PM composting and investigated the effects of biochar additives on the humification of PM composting and fungal communities. The results showed that biochar addition could prolong the thermophilic period (>50°C) by 1–4 days, with T4 being the most effective. Humification analysis showed that biochar increased the degradation of fulvic acid by 4.95–11.19 % and increased the formation of humic acid by 3.43–9.44 %, and final HA/FA ratio of T5 being the highest (2.44) compared to other treatments. The fungal abundance also confirmed that the addition of biochar significantly decreased the number of Ascomycetes at the maturation stage by 15.23 ∼ 89.23 % and increased the number of Basidiomycetes by 7.39 ∼ 119.54 times. Fungal community analysis showed that biochar could promote the birth of dominant fungi in the thermophilic phase and T5 had greater abundance of fungi than the other treatment groups. Network analysis indicated that high doses of CB (10–20 %) could enhance positive interactions among fungi to a greater extent. In conclusion, 10 % CB (T5) can optimize the compost quality to the greatest extent and has the highest application value.

Biochar assisted synthesis of α-MnO2 nanowires with superior performance for non-radical activation of peroxymonosulfate

Non-radical activation of peroxymonosulfate (PMS) is a promising water treatment technology for removing refractory organics, but its mechanism is still ambiguous and the development of highly efficient catalyst is still a challenge. Herein, α-MnO2 nanowires were synthesized by a hydrothermal method with the assistance of biochar and their performance for PMS activation was studied. The characterization results show that the addition of biochar had little effect on the crystal phase and valence state of MnO2 but significantly reduced the size of nanowires. These nanowires had mesoporous structure, high surface area and oxidation ability, resulting in their superior performance for removing organic pollutants with PMS activation. The degradation of phenol by α-MnO2-PMS followed first order kinetics with an activation energy of 14.82 kJ mol−1. Electron paramagnetic resonance and radical scavenging experiments demonstrated that this activation process followed the non-radical mechanism. The quenching effect of scavengers led to the misleading role of singlet oxygen. In fact, surface activated PMS (MnO2–PMS*) rather than singlet oxygen was the reactive species. Weak acidic condition was conducive for the formation of MnO2–PMS* complexes. This catalyst exhibited good reusability and high activity for removing various organic pollutants, and the common substances in real water had little effect on its performance, suggesting its potential application in wastewater treatment.

Variation of microbial necromass carbon and its potential relationship with humification during composting of chicken manure with and without biochar addition

Microbial necromass carbon (MNC) is an important stable organic C component. However, the variation of MNC and its potential relationship with humus components in composting remains uncertain. During a 45-day chicken manure composting study with and without biochar, MNC ranged from 24.9 to 77.9 g/kg and increased significantly by 80.9 % to 133 %. MNC constituted 5.77 % to 21.3 % of total organic C, with bacterial/fungal necromass C ratio ranging from 0.82 to 1.78. The MNC/humus C ratio ranged from 0.15 to 0.55, and humic acid C showed significant positive associations with bacterial necromass C (R2 = 0.72) and fungal necromass C (R2 = 0.51). Biochar addition reduced electrical conductivity and moisture content, increased pH, and induced microbial phosphorus limitation, thereby enhancing MNC content by 29.2 % and promoting humification. Our study is the first to elucidate the relationship between microbial necromass and humus substances, providing fundamental data for advancing the microbial carbon pump theory in composting.

Persulfate activation by biochar and iron: Effect of chloride on formation of reactive species and transformation of N,N-diethyl-m-toluamide (DEET)

Fenton-like processes using persulfate for oxidative water treatment and contaminant removal can be enhanced by the addition of redox-active biochar, which accelerates the reduction of Fe(III) to Fe(II) and increases the yield of reactive species that react with organic contaminants. However, available data on the formation of non-radical or radical species in the biochar/Fe(III)/persulfate system are inconsistent, which limits the evaluation of treatment efficiency and applicability in different water matrices. Based on competition kinetics calculations, we employed different scavengers and probe compounds to systematically evaluate the effect of chloride in presence of organic matter on the formation of major reactive species in the biochar/Fe(III)/persulfate system for the transformation of the model compound N,N‑diethyl-m-toluamide (DEET) at pH 2.5. We show that the transformation of methyl phenyl sulfoxide (PMSO) to methyl phenyl sulfone (PMSO2) cannot serve as a reliable indicator for Fe(IV), as previously suggested, because sulfate radicals also induce PMSO2 formation. Although the formation of Fe(IV) cannot be completely excluded, sulfate radicals were identified as the major reactive species in the biochar/Fe(III)/persulfate system in pure water. In the presence of dissolved organic matter, low chloride concentrations (0.1 mM) shifted the major reactive species likely to hydroxyl radicals. Higher chloride concentrations (1 mM), as present in a mining-impacted acidic surface water, resulted in the formation of another reactive species, possibly Cl2•−, and efficient DEET degradation. To tailor the application of this oxidation process, the water matrix must be considered as a decisive factor for reactive species formation and contaminant removal.

A Field Study to Assess the Impacts of Biochar Amendment on Runoff Quality from Newly Established Green Roofs

Green roofs (GRs) are a widely recognized green infrastructure (GI) strategy that helps reduce runoff volume and runoff pollution caused by the significant increase in impervious urban areas. However, the leaching of several nutrients from GR substrates is a growing concern. Biochar, a carbon-rich material, possesses advantageous properties that can help address such environmental challenges associated with GRs. Therefore, this paper aimed to undertake a field study to investigate the impacts of various biochar application methods, particle sizes, and amendment rates on the quality of runoff from GRs. Observational data of runoff quality were collected over a two-month period from five newly established 1 m × 1 m biochar-amended GR test beds and a control test bed without biochar, with all test beds subjected to artificially simulated rainfall. The results indicated that the addition of biochar did not result in a significant improvement in runoff pH, whereas the electrical conductivity (EC) was higher in runoff from GRs with biochar-amended substrates. When comparing the total nitrogen (TN) concentration in runoff from the non-biochar GR (ranging from 3.7 to 31 mg/L), all biochar test beds exhibited higher TN release (4.8 to 58 mg/L), except for the bed where medium biochar particles were applied at the bottom of the substrate (ranging from 2.2 to 21 mg/L). Additionally, all biochar-amended GRs exhibited higher TP concentrations in runoff (0.81 to 2.41 mg/L) when compared to the control GR (0.35 to 0.67 mg/L). Among the different biochar setups, GR with fine biochar particles applied to the surface of the substrate had the poorest performance in improving runoff water quality. Despite these mixed results, biochar holds significant potential to improve runoff quality by significantly increasing water retention, thereby reducing pollutant loads.

Arbuscular Mycorrhizal Fungal Interacted with Biochar and Enhanced Phosphate-Solubilizing Microorganism Abundance and Phosphorus Uptake in Maize

In agricultural production, it is crucial to increase the availability of phosphorus (P) in cultivated soil to solve the P limitation. Arbuscular mycorrhizal fungi (AMF) have been proven to promote crop nutrient absorption effectively, while biochar can lead to improvements in soil properties. However, the possible synergistic effect of AMF and biochar on P uptake by crops as well as its underlying mechanisms are unclear. In this study, we conducted a pot experiment to explore the effects of biochar and AMF (Glomus etunicatum) on the community of rhizospheric phosphate-solubilizing microorganisms (PSMs) of maize (Zea mays L. Xianyu-335) using metagenomic methods. The experiment used 0 mg P2O5 g·kg−1 soil (P0) and 30 mg P2O5 g·kg−1 soil (P30) application rates. Each P application rate included 0 (NC), 20 g·kg−1 biochar (BC) addition, inoculation AMF, and without AMF treatments (NM) for a total of eight treatments. During the experiment, both the P uptake and the biomass of maize were measured. The study found that the combination of AMF and biochar significantly increased the mycorrhizal colonization rate of maize roots, regardless of P application level. It was observed that the P uptake by maize was significantly increased when exposed to a combination of AMF and biochar. The increase in P uptake in P0 treatments was 67% higher than the sum of the effects of biochar and AMF inoculation alone. The increase was only 35% higher in P30 treatments, demonstrating a substantially higher interactive effect under P0 than under P30 conditions. The AM-BC treatments significantly increased the abundance of Streptomyces, Bacillus, and Pseudomonas, genera that are known to contain PSMs. In addition, the abundance of genes related to P-cycling (gcd, phoD, and ugpQ) in PSMs increased significantly by 1.5–1.8 times in AM-BC treatments compared with NM-BC and AM-NC treatments under P0 conditions. This increase was significantly and positively correlated with the P uptake. Overall, the results suggest that biochar can help AMF colonize the roots, increasing the functional roles of PSMs in the rhizosphere, which in turn promotes P uptake and biomass in maize. This study provides a new way to improve P-use efficiency and reduce the need for P-fertilizer application in agricultural production.

Microbial life-history strategies and particulate organic carbon mediate formation of microbial necromass carbon and stabilization in response to biochar addition

Microbial necromass carbon (MNC) contributes significantly to the formation of soil organic carbon (SOC). However, the microbial carbon sequestration effect of biochar is often underestimated and influenced by nutrient availability. The mechanisms associated with the formation and stabilization of MNC remain unclear, especially under the combined application of biochar and nitrogen (N) fertilizer. Thus, in a long-term field experiment (11 years) based on biochar application, we utilized bacterial 16S rRNA gene sequencing, fungal ITS amplicon sequencing, metagenomics, and microbial biomarkers to examine the interactions between MNC accumulation and microbial metabolic strategies under combined treatment with biochar and N fertilizer. We aimed to identify the critical microbial modules and species involved, and to analyze the sites where MNC was immobilized from various components. Biochar application increased the MNC content by 13.9 %. Among the MNC components, fungal necromass contributed more to MNC, but bacteria were more readily enriched after biochar application. The microbial life-history strategies that affected MNC formation under the application of various amounts biochar were linked to the N application level. Under N added at 226.5 kg ha−1, communities such as Actinobacteria and Bacteroidetes with high-growth yield strategies were prevalent and contributed to MNC production. By contrast, under N added at 113.25 kg ha−1 with high biochar application, Proteobacteria with strong resource acquisition strategies were dominant and MNC accumulation was lower. The mineral-associated organic carbon pool was rapidly saturated with the addition of biochar, so the contribution of fungal necromass carbon may have been reduced by reutilization, thereby resulting in the more rapid preservation of bacterial necromass carbon in the particulate organic carbon pool. Overall, our findings indicate that microbial life history traits are crucial for linking microbial metabolic processes to the accumulation and stabilization of MNC, thereby highlighting the their importance for SOC accumulation in farmland soils, and the need to tailor appropriate biochar and N fertilizer application strategies for agricultural soils.

Amendments promote Douglas-fir survival on Formosa Mine tailings.

While mining provides valuable metals and minerals to meet societal demands, it can cause environmental contamination from the residuals (i.e., tailings) of mining. Tailings are often acidic, laden with heavy metals, and lacking adequate nutrients and physical conditions for plant growth, precluding the establishment of plant cover to reduce the offsite movement of mining wastes. This paper describes a case study at the Formosa Mine in Douglas County, Oregon, where tailings were amended with a mixture of lime, biosolids, biochar, and microbial inoculum to facilitate establishment of Douglas-fir (Pseudotsuga menziesii [Mirbel] Franco) seedlings. Results show that the tailings pH increased, and Douglas-fir seedlings survived and grew with these amendments. After 2years, pH did, however, decrease in some downslope locations and was associated with an increase in tree mortality. This suggests that tailings conditions should be monitored, and amendments should be reapplied as needed, particularly in areas receiving acidic runoff from unamended upslope tailings, until the seedlings are fully established. This study not only provides a prescription for the addition of biochar and other amendments to enhance plant growth for revegetation purposes in low-pH, metal-contaminated mine tailings, but it also demonstrates a method that can be used to address similar problems at other mine sites.

Magnetic biochar enhanced microbial electrolysis cell with anaerobic digestion for complex organic matter degradation in landfill leachate

Combining microbial electrolytic cells with anaerobic digestion (MEC-AD) was considered as an important method for enhancing complex organic matter degradation. However, the magnetic biochar (MBC) addition would be an effective approach for enhancing biodegradation in MEC-AD. By designing orthogonal experiments, the optimal parameters of MBC-enhanced MEC-AD system for landfill leachate treatment were determined. The results indicated that the optimal conditions were identified as HRT of 72 h, electrode spacing of 2.5 cm, and applied voltage of 0.8 V. Under these conditions, the COD removal efficiency reached a maximum of 54.7 %. Additionally, the UV–vis, 3D-EEM, and GC–MS indicated the macromolecules 13-Docosenamide (Z), Bis(2-ethylhexyl) benzene-1,4-dicarboxylate and bis(2-ethylhexyl) phthalate were degraded. 13-Docosenamide (Z) was almost completely removed under the conditions of 0.8 V applied voltage, 2.5 cm electrode spacing and 24 h HRT, with a removal efficiency of 99.91 %. Significant differences were observed in the microbial core genera among the MEC-AD systems. The core genera in the anodic and cathodic biofilms were primarily fermentative and electroactive bacteria, including Soehngenia (2.2 % - 32.1 %, 3.2 % - 26.4 %) and Desulfomicrobium (1.1 % - 10.2 %, 2.0 % - 29.3 %). Fermentative bacteria, norank_f__Bacteroidetes_vadinHA17, established cooperative relationships with electroactive bacteria Acinetobacter. The enrichment of electrochemically active bacteria optimized microbial interactions, thereby synergistically enhancing the biotransformation of complex organic matter in landfill leachate.

Use of rice straw nano-biochar to slow down water infiltration and reduce nitrogen leaching in a clayey soil

Biochar exhibits numerous advantages in enhancing the soil environment despite a few limitations due to its lower surface energy. Nanomodified biochar combines the advantages of biochar and nanoscale materials. However, its effects on water infiltration and N leaching in a clayey soil remain unclear. Therefore, this study prepared rice straw nano-biochar by a ball milling method, and investigated its physicochemical properties and effects of bulk biochar and nano-biochar at various addition rates (0 %, 0.5 %, 1 %, 2 %, 3 %, and 5 %) on wetting peak migration, cumulative infiltration, water absorption and retention, and N leaching. The results showed that, compared with bulk biochar, nano-biochar presented a more abundant pore structure with an increase in specific surface area of approximately 1.5 times, accompanied by a 20 % increase in acid functional groups. Compared with those for clayey soil without biochar addition, the wetting front migration time was increased by 10.2 %–123.9 % and 17.0 %–257.9 %, and the cumulative infiltration volume at 60 min was decreased by 26.0 %–48.4 % and 14.1 %–62.4 % for bulk biochar and nano-biochar, respectively. The parameter S of Philip model and the parameter a of Kostiakov model for nano-biochar were lower than those for bulk biochar, whereas the parameter b of Kostiakov model was greater, indicating that nano-biochar decreased initial soil infiltration rate and increased attenuation degree of the infiltration rate. Nano-biochar increased water absorption by 8.03 % and subsequently enhanced water retention capacity relative to bulk biochar. In addition, bulk biochar and nano-biochar reduced NH4+-N leaching by 3.0 %–13.1 % and 5.7 %–39.2 %, respectively, and NO3−-N leaching by 2.7 %–3.6 % and 9.0 %–43.3 %, respectively, by decreasing N concentration and leachate volume relative to those with no biochar addition. This study provides new knowledge for nano-biochar application in a clayey soil.

Biochar as an Alternative Litter Additive to Mitigate Gaseous Emissions from Broiler Housing and Subsequent Storage

Broiler farming is a significant source of gaseous emissions. The aim of this study was to assess the effects of different litter additives on the emission of NH3, N2O, CO2, and CH4 during broiler housing and subsequent manure storage. The gaseous emissions from the housing facilities were evaluated during one fattening cycle in environmentally controlled rooms with three different additives applied to the litter material (10% w/w aluminum sulphate or biochar and 2.50 mg m−2 urease inhibitor), as well as a control. A storage experiment was conducted under laboratory conditions for 90 days to evaluate the influence of these three additives on gaseous losses. During broiler housing, the results indicated that NH3 emissions were reduced significantly (40–60%) by litter additives, while global warming potential (GWP) emissions were reduced significantly (31%) by Alum. The addition of Biochar (a 58% reduction) had the same significant effect as Alum (a 60% reduction) to mitigate these losses. The re-application of Urease (a 41% reduction) may be required to reach an equal or higher reduction. During storage, NH3 and GWP emissions were not significantly affected by the litter additives. During broiler housing and subsequent manure storage, NH3 emissions were reduced significantly (22–41%) by litter additives, whereas GWP emissions did not decrease significantly. Globally, it can be concluded that Biochar appears to be a good alternative to Alum due to its equal effectiveness in mitigating NH3 losses, without increasing the GWP potential in the housing and avoiding pollution swapping.

Plant-soil hydraulic interaction and rhizosphere bacterial community under biochar and CO2 enrichment

The increasing atmospheric CO2 concentration is a global concern that affects the plant-bacteria-soil system. Previous studies have investigated plant growth and bacteria activity under CO2 enrichment. However, the effects of coupled elevated CO2 and biochar amendment on the interactions of soil and medicinal plants are not well understood. This study aims to investigate the medicinal plant-soil hydraulic interactions and rhizosphere bacteria communities under coupled CO2 enrichment and biochar conditions. Two levels of CO2 concentration (400, 1000 ppm) and two biochar dosages (3%, 5% by mass) were considered. Pseudostellaria heterophylla was used as the tested medicinal plant. During plant growth, coupled CO2 enrichment and biochar at 3% and 5% dosage increased the volumetric water content at a matric suction of 33 kPa by 97% and 82% respectively, which indicates enhanced water retention. The transpiration rate of P. heterophylla was slightly reduced by 11–30% with an increase in biochar dosage due to higher total suction, while it was significantly reduced by up to 57% due to CO2 enrichment. In the rhizosphere of P. heterophylla, elevated CO2 (1000 ppm) coupled with 3% biochar dramatically increase the relative abundance of Thaumarchaeota, which played an important role in C and N cycles. Moreover, coupled CO2 enrichment and biochar addition resulted in the highest bacterial richness, while 3% biochar at ambient CO2 induced the highest bacterial diversity. This study provides a basis for understanding the medicinal plant-bacteria-soil system under CO2 enrichment and biochar conditions.

Linking soil nutrients, microbial community composition, and enzyme activities to saponin content of Paris polyphylla after addition of biochar and organic fertiliser

The application of organic fertilisers and biochar has become widespread in agroforestry ecosystems to enhance the yield and quality of crops and medicinal plants. However, their specific impact on both the yield and quality of Paris polyphylla (P. polyphylla), along with the underlying mechanisms, remains unclear. In this study, we investigated the distinct effects of organic fertiliser (at concentrations of 5% and 10%) and biochar application (at levels of 2% and 4%) on P. polyphylla saponin content. This content is intricately regulated by available soil nutrients, enzyme activities, and microbial community compositions and activities. Our results clearly demonstrated a significant increase in the saponin content, including total saponin, polyphyllin I (PPI), polyphyllin II (PPII), polyphyllin VI (PPVI), and polyphyllin VII (PPVII), in P. polyphylla following the application of both biochar and organic fertiliser. Moreover, in comparison to the control group, the addition of biochar and organic fertiliser led to a considerable rise in the activity of glycosyltransferase enzyme (GTS) and cycloartenol synthase (CAS) in P. polyphylla. Additionally, it increased soil available potassium (AK) and soil organic matter (SOM) concentration, along with the activity of urease, acid phosphatase, and catalase, although biochar amendment resulted in a decrease in nitrate nitrogen (NO3−-N) concentration. Crucially, our findings revealed a positive correlation between total saponin content and the activity of CAS in P. polyphylla, soil AK, SOM concentration, and the activities of urease, acid phosphatase, and catalase. Conversely, there was a negative correlation with NO3−-N content. Furthermore, the application of organic fertiliser and biochar significantly influenced microbial community structures and specific microbial taxa. Notably, total saponin content exhibited a positive relationship with the relative abundances of Dehalococcoidia, Saccharomycetes, and Agaricomycetes taxa while showing a negative correlation with the abundance of Verrucomicrobiae. In conclusion, the observed increase in saponin content can be attributed to the modulation of specific microbial taxa in soils, as well as alterations in soil nutrients and enzyme activities resulting from the application of biochar and organic fertiliser. This study identifies a potential mechanism for enhancing saponin content in the artificial cultivation of P. polyphylla.

Co-application of biochar and potassium fertilizer improves soil potassium availability and microbial utilization of organic carbon: A four-year study

Biochar is a promising amendment for improving soil carbon (C) sequestration and supplying potassium (K). However, the interrelationship between soil organic carbon, potassium availability, and microbial functions under the co-application of biochar and exogenous K remains largely unknown. Therefore, we conducted a four-year experiment that involved four K fertilizer application rates (0%, 60%, 80%, and 100% of conventional K fertilizer, respectively) combined with two doses of biochar rate (0% and 2%). We utilized a combination of high-throughput sequencing and GeoChip technology to examine the microbial responses to changes in soil organic C and K pools. The results revealed that biochar had the potential to replace 40% of conventional K fertilizer. The simultaneous application of biochar and conventional K fertilizer increased soil available K content by 192.3% and enhanced citrus growth. Additionally, soil organic matter, humus components, and aromatic C groups were significantly influenced by the addition of biochar. Soil enzyme activities associated with C cycling improved by 31.9%–84.4%. Furthermore, altered microbial communities, higher bacterial diversity, and enhanced microbial carbon source utilization capacity were observed in soil treated with the combined application of biochar and K fertilizer. The improvement of soil K availability induced by the co-application of biochar and K fertilizer resulted in a 35.2% increase in the microbial functions responsible for liable C degradation. Overall, the 4-years of co-application of biochar and K fertilizer increased the availability of soil potassium and the storage of organic carbon by 2.9- and 1.8-fold, respectively, which is conducive to promoting sustainable agricultural development.

Integration of Digestate-Derived Biochar into the Anaerobic Digestion Process through Circular Economic and Environmental Approaches-A Review.

The growing energy consumption and the need for a circular economy have driven considerable interest in the anaerobic digestion (AD) of organic waste, offering potential solutions through biogas and digestate production. AD processes not only have the capability to reduce greenhouse gas emissions but also contribute to the production of renewable methane. This comprehensive review aims to consolidate prior research on AD involving different feedstocks. The principles of AD are explored and discussed, including both chemical and biological pathways and the microorganisms involved at each stage. Additionally, key variables influencing system performance, such as temperature, pH, and C/N ratio are also discussed. Various pretreatment strategies applied to enhance biogas generation from organic waste in AD are also reviewed. Furthermore, this review examines the conversion of generated digestate into biochar through pyrolysis and its utilization to improve AD performance. The addition of biochar has demonstrated its efficacy in enhancing metabolic processes, microorganisms (activity and community), and buffering capacity, facilitating Direct Interspecies Electron Transfer (DIET), and boosting CH4 production. Biochar also exhibits the ability to capture undesirable components, including CO2, H2S, NH3, and siloxanes. The integration of digestate-derived biochar into the circular economy framework emerges as a vital role in closing the material flow loop. Additionally, the review discusses the environmental benefits derived from coupling AD with pyrolysis processes, drawing on life cycle assessment investigations. Techno-economic assessment (TEA) studies of the integrated processes are also discussed, with an acknowledgment of the need for further TEA to validate the viability of integrating the biochar industry. Furthermore, this survey examines the techno-economic and environmental impacts of biochar production itself and its potential application in AD for biogas generation, aiming to establish a more cost-effective and sustainable integrated system.

Biochar Blended with Alkaline Mineral Can Better Inhibit Lead and Cadmium Uptake and Promote the Growth of Vegetables.

Three successive vegetable pot experiments were conducted to assess the effects on the long-term immobilization of heavy metals in soil and crop yield improvement after the addition of peanut shell biochar and an alkaline mineral to an acidic soil contaminated with lead and cadmium. Compared with the CK treatment, the change rates of biomass in the edible parts of the three types of vegetables treated with B0.3, B1, B3, B9, R0.2 and B1R0.2 were -15.43%~123.30%, 35.10%~269.09%, 40.77%~929.31%, -26.08%~711.99%, 44.14%~1067.12% and 53.09%~1139.06%, respectively. The cadmium contents in the edible parts of the three vegetables treated with these six additives reduced by 2.08%~13.21%, 9.56%~24.78%, 9.96%~35.61%, 41.96%~78.42%, -4.19%~57.07% and 12.43%~65.92%, respectively, while the lead contents in the edible parts reduced by -15.70%~59.47%, 6.55%~70.75%, 3.40%~80.10%, 55.26%~89.79%, 11.05%~70.15% and 50.35%~79.25%, respectively. Due to the increases in soil pH, soil cation-exchange capacity and soil organic carbon content, the accumulation of Cd and Pb in the vegetables was most notably reduced with a high dosage of 9% peanut shell biochar alone, followed by the addition of a low dosage of 1% peanut shell biochar blended with 0.2% alkaline mineral. Therefore, the addition of a low dosage of 1% peanut shell biochar blended with 0.2% alkaline mineral was the best additive in increasing the vegetable biomass, whereas the addition of 9% peanut shell biochar alone was the worst. Evidently, the addition of 0.2% alkaline mineral can significantly reduce the amount of peanut shell needed for passivating heavy metals in soil, while it also achieves the effect of increasing the vegetable yield.

Impact of Biochar Addition Levels on Remediation of Uranium-Stressed Soil: Evidence from 16S rDNA and Metabolomics

Impact of Biochar Addition Levels on Remediation of Uranium-Stressed Soil: Evidence from 16S rDNA and Metabolomics

Properties of biochars derived from different straw at 500℃ pyrolytic temperature: Implications for their use to improving acidic soil water retention

Climate change cause extreme weather effects with temperature increases and drops in humidity, such as drought and heatwaves, which will lead to more evaporation in arid and semi-arid lands. The application of biochar made from crop straw without burning to farmland can effectively improve the water retention capacity of soil. A testing program has been carried out in a climate simulation laboratory to study the effects of different straw biochars on the cracking and evaporation of soils due to drying. Biochar from wheat straw (WS), corn straw (CS) and rice straw (RS) is produced at a pyrolysis temperature of 500℃. Thermogravimetric analysis and elemental analysis are carried out to obtain the properties of the biochar. Five percent of WS, CS and RS biochar by weight is added to acidic soil. Digital camera and digital image processing technology are used to analyze the crack morphology of the samples during evaporation. The results indicate that the RS biochar has the highest ash content (32.5 %), CS biochar has the highest content of volatile solid (25.36 %) and WS biochar has the highest content of fixed carbon (55.38 %). Biochar can effectively improve the water retention capacity of soil. The final water contents of the WS, CS and RS biochar soil samples are 132.3 %, 101.0 %, and 20.7 % respectively higher than that of the soil without biochar. Moreover, biochar can effectively reduce the degree of soil cracking. The addition of WS, CS and RS biochar can reduce soil cracking by 9.21 %, 16.57 %, and 7.46 %, respectively. WS contains more total cellulose than CS and RS, so WS biochar is the best choice to improve soil water retention ability. Therefore, biochar technology helps to optimize soil water retention while avoiding environmental pollution from straw burning.

Performance and Environmental Assessment of Biochar-Based Membranes Synthesized from Traditional and Eco-Friendly Solvents.

Water contamination resulting from coal spills is one of the largest environmental problems affecting communities in the Appalachia Region of the United States. This coal slurry contains potentially toxic substances, such as hydrocarbons, heavy metals, and coal cleaning chemicals, and its leakage into water bodies (lakes, rivers, and aquifers) can lead to adverse health effects not only for freshwater bodies and plant life but also for humans. This study focused on two major experiments. The first experiment involved the use of biochar to create a biochar-polysulfone (BC-PSf) flat-sheet multifunctional membrane to remove organic contaminants, and the other major experiment compared eco-friendly (gamma-valerolactone-GVL; Rhodiasolv® PolarClean-PC) and petroleum-derived solvents (i.e., N-methyl-pyrrolidone-NMP) in the fabrication of the biochar-polysulfone membranes. The resulting membranes were tested for their efficiency in removing both positively and negatively charged organic contaminants from the collected water at varying pH values. A comparative life cycle assessment (LCA) with accompanying uncertainty and sensitivity analyses was carried out to understand the global environmental impacts of incorporating biochar, NMP, GVL, and PC in the synthesis of PSf/NMP, BC-PSf/NMP, PSf/GVL, BC-PSf/GVL, PSf/PC, and BC-PSf/PC membranes at a set surface area of 1000 m2. The results showed that the addition of biochar to the membrane matrix increased the surface area of the membranes and improved both their adsorptive and mechanical properties. The membranes with biochar incorporated in their matrix showed a higher potential for contaminant removal than those without biochar. The environmental impacts normalized to the BC-PSf/GVL membrane showed that the addition of biochar increased global warming impacts, eutrophication, and respiratory impacts by over 100% in all the membrane configurations with biochar. The environmental impacts were highly sensitive to biochar addition (Spearman's coefficient > 0.8). The BC/PSf membrane with Rhodiasolv® PolarClean had the lowest associated global environmental impacts among all the membranes with biochar. Ultimately, this study highlighted potential tradeoffs between functional performance and global environmental impacts regarding choices for membrane fabrication.

Effect of biochar addition on nutritional status, maturity, and phytotoxicity of cow dung-fortified kitchen waste

Effect of biochar addition on nutritional status, maturity, and phytotoxicity of cow dung-fortified kitchen waste