Bio-polymer composites are emerging as a feasible substitute for conventional polymers in various major fields of applications. In the current research, the impact of hybridization of inter and intra-woven natural engineering fibers namely, brown flax, white flax, and jute of different amalgamations along with commingled SCF and novel nano IW filler has been studied. The composites are manufactured by hand layup process and physical and thermomechanical characteristics of the composites are experimentally studied. The composites mingled with IW filler demonstrated better dimensional stability and mechanical properties such as maximum tensile strength of 36.74 MPa, bending strength of 82.53 MPa, and hardness of 84.89 D compared to other composites. However, elastic and flexural modulus are maximum for composite without any filler. The composites mingled with SCF filler demonstrated the highest impact strength, energy absorption, and elongation. Thermogravimetric analysis and thermal conductivity study demonstrated that the composite with SCF filler exhibited better thermal stability and thermal resistance than the other hybrid composites. Fourier transform infrared spectroscopy study confirms the interaction of hydrogen bonds with different polymers, matrices, and fillers. It is established that the weaving pattern and the filler types greatly influences the mechanical and thermal characteristics of the composites. Filler addition and fabric hybridization optimizes the catastrophic failures and enhances the thermal stability, hence becoming more suitable for small interior structural components in aerospace and automobile applications.