Bentonite Research Articles

Preparation of Green Sustainable Cement Paste Mixture Based on Inorganic Additives: An Experimental and Modelling Approach

Using waste materials in the mixture of building materials is an approach aligned with the circular economy, a viewpoint that creates sustainable building industries, especially in developed countries. This study concentrated on the application of laponite (LAP), fly ash (FA), and bentonite (BENT) materials in the mixture of cement pastes. The first step used experimental practices to examine the metrics of toughness, three-point bending, and compressive strength with different percentages of added LAP, FA, and BENT after the characterization of samples by scanning electron microscopy (SEM) and energy-dispersive X-ray spectroscopy (EDS). The next step entailed assessment of cement paste specifications through some regressive equations obtained by the application of 2D curve fitting and sensitive analysis of additive (FA, LAP, and BENT) fluctuations in the structure of cement paste. The results show that linear polynomial equations are the best for the evaluation of cement paste terms as per different percentages of the additives. The environmental impact assessment (EIA) of nine prepared samples demonstrated that LAP created the safest condition in comparison to others. However, the ordered weighted averaging (OWA) computations applied for the sustainability assessment (SA) of the samples showed that the LAP is the most appropriate option for use in the structure of cement paste. Using experimental analysis and mathematical modeling, the behavior of cement paste interacting with mineral additives is evaluated. Sustainable mixtures are then presented based on EIA.

Synergistic performance of magnetic ion-imprinted nanocomposite for selective separation of gadolinium

The separation of rare earth elements (REEs) has been a persistent challenge in the industrial sector. Despite the development of numerous adsorption materials for rare earth element separation, achieving high adsorption capacity and superior separation selectivity from these materials simultaneously has proven difficult. In this study, we synthesized a nanocomposite material called CoFeM@Be_IIM by combining bentonite clay’s good adsorption capacity with cobalt ferrite’s superior magnetic separation performance (CoFe2O4) and ion-imprinted materials’ high target separation selectivity (IIMs). We used surface ion-imprinting technique to create the material. The ion-imprinted material has a maximum adsorption capacity of 87.6 mg/g for Gd(III), with a selectivity of Gd/La ≈ 28.6, Gd/Nd ≈ 22.6, and Gd/Y ≈ 15.2. The Gd(III)-CoFeM@Be_IIM showed good reusability for up to five cycles. Our work presents a new magnetic ion-imprinted nano-adsorbent as a reliable and effective solution for recovering and utilizing REEs from industrial wastewater.

Facile Fabrication of Hydroxyapatite and Bentonite Encapsulated Biopolymeric Hybrid Composites for Selective Removal of Methylene Blue

AbstractDyeing industries release their hazardous dyeing effluents into the environment which affects the human health and ecosystem. Hence, the removal of dye from waste‐water is mandatory one. In this present study, focus on the fabrication of bio‐clay‐ceramic hybrid composites by dispersing bentonite (BT) clay and ceramic hydroxyapatite (HA) into alginate (Alg) and gelatin (Gel) polymeric matrixes by in‐situ method which gives BTHAAlg and BTHAGel hybrid composites for methylene blue (MB) removal. The various adsorption influencing parameters such as shaking time, adsorbent dosage, pH and initial MB concentration were optimized under batch method. The highest MB adsorption capacities of BTHAAlg and BTHAGel composites were found to be 43.70 and 47.50 mg/g respectively with optimized conditions of 100 mg/L of initial MB concentration, 40 min shaking time and 0.1 g dosages. In pH studies, the high MB adsorption capacity of bio‐clay‐ceramic composites were noticed at pH 11. The characterization techniques like FTIR, SEM and EDAX analysis were performed to find the physico‐chemical properties of bio‐clay‐ceramic composites. The equilibrium data of hybrid composites towards MB adsorption was well fitted with Langmuir isotherm model than D‐R and Fruendlich models because of higher r and low sd values. The negative values of ▵Go at three different temperatures (303, 313 and 323 K) indicate that the spontaneous nature of MB adsorption, while positive values of ΔHo and ΔSo revealed that the MB adsorption onto hybrid composites was endothermic in nature and more randomness occurred at solid/liquid interfaces. In kinetic studies, the MB adsorption onto hybrid composites was well fitted with pseudo‐second‐order and intra‐particle diffusion models. The electrostatic attraction and hydrogen bonding plays a dominant role in MB adsorption onto BTHAAlg and BTHAGel bio‐clay‐ceramic composites. The regeneration studies proposed that the hybrid composites can be reusable upto five cycles. Hence, the developed bio‐clay‐ceramic hybrid composites were act as best adsorbents for MB removal.

Bentonite-supplemented diets improved fish performance ammonia excretion haemato-biochemical analyses immunity antioxidants and histological characteristics of European seabass Dicentrarchus labrax

The purpose of this research was to examine the potential effects of bentonite (BN) supplemented diets on growth, feed utilization, blood biochemistry, and histomorphology of Dicentrarchus labrax. Six treatments in triplicate were tested: B0, B0.5, B1.0, B1.5, B3.0, and B4.5, which represented fish groups fed diets supplemented with 0, 0.5, 1, 1.5, 3, and 4.5% BN, respectively. For 84 days, juveniles’ seabass (initial weight = 32.73 g) were fed diets containing 46% protein, three times daily at 3% of body weight. With a 5% daily water exchange, underground seawater (32 ppt) was used. Findings revealed significant improvements in water quality (TAN and NH3), growth (FW, WG and SGR) and feed utilization (FCR, PER and PPV) in fish fed BN-supplemented diets, with the best values in favor of the B1.5 group. Additional enhancements in kidney function indicators (urea and uric acid) and liver enzymes were observed in fish of the BN-treated groups along with a decrease in cholesterol level in the B1.5 group. Further improvements in fish innate immunity (hemoglobin, red blood cells, glucose, total protein, globulin, and immunoglobulin IgM), antioxidant activity (total antioxidative capacity and catalase), and decreased cortisol levels in fish of the BN-treated groups. Histological examinations of the anterior and posterior intestines and liver in groups B1.5 and B3 revealed the healthiest organs. This study recommends BN at a concentration of 1.5% as a feed additive in the Dicentrarchus labrax diet.

The studies on dehydration reaction mechanism of irradiated solid acid - nanostructured sodium - bentonite clay

Research findings can offer data and a theoretical framework for a quantitative examination of the bentonite dehydration mechanism. The reasons for changes in pore’ water under the influence of gamma rays in vacuum and in the presence of oxygen was discussed using TGA and DTA, FT-IR spectroscopy. It was revealed that dehydration and pore characteristics are mutually dependent. A question about the associated evolution of dehydration pore‘s water in nanostructured sodium – bentonite clay under the influence of ionizing rays with and without oxygen has been comparatively studied. The article is devoted to a discussion of how ionizing radiation, passing through nanoclays, produces, or rather begins to produce, chemical effects. It was used Infrared spectroscopy as the method for determining structural responses of natural clay from the Alpoid deposit in the Republic of Azerbaijan, to gamma rays exposure. It was found that under influence of ionizing rays in vacuum obtained hydrogen peroxide. It is of great interest for the study of the dehydration reaction mechanism and its role in formation of H2 under gamma irradiation.

Desulfurization of Basra Diesel Fuel by Emulsification – Adsorption Processes

In this study, the combined emulsification–adsorption processes were employed for the desulfurization of Basra diesel fuel. A high sulfur diesel fuel of 1.4538 wt% from the Basra refinery was oxidized effectively with H2O2 and Acetic acid (AcOH) as a catalyst to reduce sulfur content to 1.0875 wt% before being emulsified. The emulsification desulfurization (EDS) process using Alkyl benzene sulfonate (ABS) as a surfactant was optimized by 20 trails according to Response Surface Methodology (RSM). A 0.83886 wt% was achieved at the following optimum conditions: Surfactant concentration 20 wt.%, temperature 57.56 ᵒC, and homogenization speed 5695 rpm. The adsorptive desulfurization (ADS) process using activated bentonite clay was carried out in a batch system. The RSM was applied to determine the effect of contact time (1-10 hr), clay mass (5- 20 gm/50ml), and temperature (30-100 ᵒC) on the sulfur removal. Results showed that the sulfur content of 0.57 wt% was achieved at the following conditions: adsorption time 7.18 hrs., temperature 53.3 ᵒC, and clay mass 15.24 gm/ 50ml. The achieved sulfur removal efficiency was 23% and 32% for EDS and ADS respectively. The diesel fuel quality was studied by GC and IREX.

Novel granular bentonite-carbon sorbents: textural characterization, adsorption-desorption isotherm, kinetics, and cost estimation.

This research focuses on the synthesis of novel low-cost granular sorbents based on bentonite clay of the Navbahor deposit, dust fraction of Angren brown coal, and agricultural wastes such as straw and sawdust to meet the internal needs of the Republic of Uzbekistan. The impact of the initial mixture ingredients on the structural and textural properties of bentonite-coal sorbents (BCSs) has been studied using X-ray diffraction, Raman spectroscopy, Fourier-transform infrared spectroscopy, optical microscopy, and nitrogen adsorption-desorption analysis. For determining the sorption capacity of BCSs, a standard model substance methylene blue (MB), was applied. It was revealed that the maximum adsorption amount of MB was 5.3 mg∙g-1 during 2 h of contact. Prolonging the contact time to 24 h allowed for more extensive diffusion of dye molecules into the sorbent's pores, increasing the adsorption capacity to 13 mg∙g-1. It was demonstrated that BCSs could be regenerated by strong oxidizing agents such as sulfuric acid and hydrogen peroxide, with sulfuric acid proving more effective. Regeneration fully restores sorption properties, particularly at low dye concentrations (up to 0.2 mg∙ml-1). Despite slight reductions in adsorption capacity over multiple regeneration cycles, the sorbents maintain their structural integrity and durability. It is shown that compared to imported expensive activated carbon, the gross profitability of the in-house production of such granular BCSs within the territory of Uzbekistan increases from 48 to 78%, while the net income increases almost three times.

Combined use of kaolin and bentonite molding clays

The article compares the properties of kaolin and bentonite clays. It has been shown that kaolin clays have high fire resistance, and bentonites have high astringent properties. The experience of specialists from OJSC “MTW” in the joint use of various types of clays is considered. The combination of kaolin and bentonite in the suspension made it possible to increase the strength of the molding sand while maintaining moisture levels. The disadvantage of kaolin clay suspensions is that the moisture content increases with increasing dosage. When preparing bentonite suspensions, their short shelf life should be taken into account.

Dispersive Solid Phase Extraction of Melatonin with Graphene/Clay Mixtures and Fluorescence Analysis in Surfactant Aqueous Solutions.

In this work, the dispersive solid phase extraction (dSPE) of melatonin using graphene (G) mixtures with sepiolite (SEP) and bentonite (BEN) clays as sorbents combined with fluorescence detection has been investigated. The retention was found to be quantitative for both G/SEP and G/BEN 4/96 and 10/90 w/w mixtures. G/clay 4/96 w/w mixtures were selected to study the desorption process since the retention was weaker, thus leading to easier desorption. MeOH and aqueous solutions of the nonionic surfactant Brij L23 were tested as desorbents. For both clays and an initial sample volume of 25 mL, a percentage of melatonin recovery close to 100% was obtained using 10 or 25 mL of MeOH as desorbent. Further, using a G/SEP mixture, 25 mL as the initial sample volume and 5 mL of MeOH or 60 mM Brij L23 solution as the desorbent, recoveries of 98.3% and 90% were attained, respectively. The whole method was applied to herbal tea samples containing melatonin, and the percentage of agreement with the labeled value was 86.5%. It was also applied to herbal samples without melatonin by spiking them with two concentrations of this compound, leading to recoveries of 100 and 102%.

A Critical Review on the Advancement of the Development of Low-Cost Membranes to Be Utilized in Microbial Fuel Cells

Microbial fuel cells provide a promising solution for both generating electricity and treating wastewater at the same time. This review evaluated the effectiveness of using readily available earthen membranes, such as clayware and ceramics, in MFC systems. By conducting a comprehensive search of the Scopus database from 2015 to 2024, the study analyzed the performance of various earthen membranes, particularly in terms of wastewater treatment and energy production. Ceramic membranes were found to be the most effective, exhibiting superior power density, COD removal, and current density, with values of 229.12 ± 18.5 mW/m2, 98.41%, and 1535.0 ± 29 mW/m2, respectively. The review emphasizes the use of affordable resources like red soil, bentonite clay, CHI/MMT nanocomposites, and Kalporgan soil, which have proven to be effective in MFC applications. Incorporating earthen materials into the membrane construction of MFCs makes them more cost-effective and accessible.

Modification of Bentonite Clay Using Recycled Glass Powder and Polypropylene Fiber

Modification of Bentonite Clay Using Recycled Glass Powder and Polypropylene Fiber

Ciprofloxacin adsorption onto Pumice-bentonite composites: Modeling, kinetics, equilibriums and reusability studies

BackgroundA new Bentonite-loaded Pumice adsorbent (P-BNT3) was successfully synthesized as an efficient adsorbent for CIP removal from aqueous solutions. MethodsIn the present study, P-BNT3 composite synthesized by hydrothermal technique (24 h @160 °C) was loaded with Bentonite (BNT) using ultrasonication (20 min @25 °C) to remove CIP antibiotic. P-BNT3 composite was characterized by FTIR, XRD, BET, TGA, SEM, and TEM analyses. XRD, SEM, and TEM analyses indicate effective coupling of Pumice/ BNT strong layers with highly porous heterogeneous structure. Adsorption of CIP is studied as a function of pH, dosage, contact time, initial CIP concentration, and temperature in a batch reactor to obtain the maximum adsorption capacity (qm). Significant FindingsA MFSO kinetic model (R2= 0.983) and Langmuir and Dubinin–Radushkevich isotherm model (R2= 0.989 and 0.986) provide good fits to the experimental. The highest amount of CIP adsorbed is 54 mg/g at pH=2.0, which is 5 folds higher than pristine Pumice. The adsorption equilibrium was attained in 240 min with P-BNT3 for a CIP concentration of 30 mg/L. The characterization of spent composites after CIP adsorption suggested that CIP adsorption onto P-BNT3 composite is governed by π-π interaction, chemical complexation, and surface interactions. Based on thermodynamic investigation over the temperature range of 298 ̶ 318 K, CIP adsorption on P-BNT3 was a spontaneous (-ΔG°) and endothermic (ΔH°=+5.313) phenomenon. Furthermore, the adsorption-desorption procedure demonstrated that the composite could be efficiently reused up to 5 times. However, expensive desorption costs and the inevitable secondary effluent are a challenge in the practical implementation. Based on the findings, the P-BNT3 composite has great potential for the removal of other pharmaceutical compounds.

Structural Modification of Fine Powders of Overburden Rocks of Saponite-Containing Bentonite Clay

Structural Modification of Fine Powders of Overburden Rocks of Saponite-Containing Bentonite Clay

Bentonite Clays as Adsorbent Material for Mycotoxins and the Hematological Parameters Involved in Tilapia Species: A Systematic Review

Bentonite Clays as Adsorbent Material for Mycotoxins and the Hematological Parameters Involved in Tilapia Species: A Systematic Review

Barrier properties of polyhydroxybutyrate/ethyl cellulose-blend-coated paper through the incorporation of organo-modified nanoclay as a coating component

A sodium bentonite product (nanoclay) was added to a polyhydroxybutyrate/ ethyl cellulose (PHB/EC) blend coating agent, and the impact of the nanoclay content on the properties of the coated paper was investigated. The organically treated nanoclay exhibited enhanced compatibility with the PHB/EC blend, ensuring uniform dispersion within the coating layer and improving the barrier properties of the coated paper. The mechanical properties of the PHB/EC blend-coated paper with nanoclay demonstrated ductile behavior, reducing the tensile strength and increasing the elongation. However, at higher nanoclay loadings, specifically up to 25%, aggregation among nanoclay particles occurred. This hindered the enhancement of barrier properties, thereby decreasing the degree of elongation. Incorporating nanoclay as a filler in the PHB/EC blend at suitable levels showed potential for further enhancing the barrier properties and ensuring economic feasibility in the production of packaging paper.

Evaluation of hydraulic conductivity and self-healing potential of punctured geosynthetic clay liner

ABSTRACT An experimental study was conducted on the modified geosynthetic clay liner (GCL) specimen by replacing encapsulated Sodium Bentonite (Na-B) with different percentages of locally available black cotton soil (BCS). The specimens with punctured hole sizes of 4, 8, and 12 mm in diameter were tested for hydraulic conductivity and self-healing capacity assessed by improved triaxial apparatus. The flowing permeant was prepared with the heavy metals: iron, zinc, nickel, and total chromium based on the results of the chemical analysis of leachate collected from the municipal solid waste site (MSW). The experiment results were observed at 24, 48 and 72 hours. The results were analysed to identify the best specimen mix (Na-B and BCS) regarding the lowest hydraulic conductivity and highest self-healing potential. The results demonstrated that BCS can be utilized in modified GCL as an impermeable barrier for leachate percolation at the MSW dump site.

Valorization of Cherry By-Products as Coagulant/Flocculants Combined with Bentonite Clay for Olive Mill Wastewater Treatment

In this study, two by-products resulting from the processing of cherry (stems and pits) were used as natural coagulants to promote the valorization of these wastes and treat olive mill wastewater (OMW). The efficacy of the plant-based coagulants (PBCs) in the coagulation–flocculation–decantation process (CFD) was evaluated through the removal of turbidity, total suspended solids (TSS), total polyphenols (TPh), and dissolved organic carbon (DOC). The CFD process was demonstrated to be effective in turbidity and TSS reduction in OMW. Using cherry stems (CSs), these reductions were 65.2% of turbidity and 58.0% of TSS, while cherry pits (CPs) achieved higher reductions, 78.6% of turbidity and 68.2% of TSS. To improve the effectiveness of OMW treatment, mainly regarding the removal of TPh and DOC, the CFD process was complemented with the adsorption process (using bentonite clay). The adsorption capacity of bentonite was higher in acidic conditions (pH 3.0) and, with a dosage of 3.0 g L−1, reached 17.3 mg of DOC and 13.8 mg of TPh per gram of bentonite. Several adsorption isothermal models were assessed, and the Langmuir (r2 = 0.985), SIPS (r2 = 0.992), and Jovanovic models (r2 = 0.994) provided the best fittings. According to the optimal operational conditions defined throughout the present work, the combination of CFD and adsorption removals were as follows: (1) 98.0 and 91.3% of turbidity, (2) 80.8 and 81.2% of TSS, (3) 98.1 and 97.6% of TPh and (4) 57.9 and 62.2% of DOC, for CSs and CPs, correspondingly. Overall, the results suggest that cherry by-products can be used as low-cost natural coagulants and, when combined with another natural, abundant, and cheap material, such as bentonite clay, can be a sustainable alternative for treating OMW.

Improving Water-Based Drilling Mud Performance Using Biopolymer Gum: Integrating Experimental and Machine Learning Techniques.

Drilling through shale formations can be expensive and time-consuming due to the instability of the wellbore. Further, there is a need to develop inhibitors that are environmentally friendly. Our study discovered a cost-effective solution to this problem using Gum Arabic (ArG). We evaluated the inhibition potential of an ArG clay swelling inhibitor and fluid loss controller in water-based mud (WBM) by conducting a linear swelling test, capillary suction timer test, and zeta potential, fluid loss, and rheology tests. Our results displayed a significant reduction in linear swelling of bentonite clay (Na-Ben) by up to 36.1% at a concentration of 1.0 wt. % ArG. The capillary suction timer (CST) showed that capillary suction time also increased with the increase in the concentration of ArG, which indicates the fluid-loss-controlling potential of ArG. Adding ArG to the drilling mud prominently decreased fluid loss by up to 50%. Further, ArG reduced the shear stresses of the base mud, showing its inhibition and friction-reducing effect. These findings suggest that ArG is a strong candidate for an alternate green swelling inhibitor and fluid loss controller in WBM. Introducing this new green additive could significantly reduce non-productive time and costs associated with wellbore instability while drilling. Further, a dynamic linear swelling model, based on machine learning (ML), was created to forecast the linear swelling capacity of clay samples treated with ArG. The ML model proposed demonstrates exceptional accuracy (R2 score = 0.998 on testing) in predicting the swelling properties of ArG in drilling mud.

Oily wastewater treatment using low-cost and highly efficient natural and activated Iraqi bentonite

One of the most dangerous organic compounds to the environment is gasoline emulsions, discharged without prior treatment by most oil refining industries. This study focuses on the modification of bentonite clays by acid and thermal activation to maximize their adsorption capacity for treating refinery wastewater. The surface properties and porous structure of the adsorbents were investigated with the use of BET, SEM, FTIR, XRD, XRF, EDX, and MAP methods. Based on the results of BET analysis, the surface area of the raw bentonite (RB) and activated bentonite (AB) was (17.57, 69.72) m2 /g. The four independent variables, namely the initial gasoline concentration (200–1000 mg/L), solution pH (3−9), contact time (30–120 min), and adsorbent dosage (ranging from 0.05 to 0.15 g/L). According to the results, the maximal adsorption capacity (74.6.38, 138 mg/g) by RB and AB was achieved using the following optimized conditions: initial COD gasoline concentration of 1000 mg/L, pH= 6 for RB and pH= 3 for AB, contact time 120 min, and adsorbent dosage 0.15 g for RB and AB. Additionally, the kinetic and equilibrium studies demonstrated that the present adsorption process's kinetics and equilibrium behavior were adequately represented by the pseudo second-order kinetic model and the Langmuir isotherm. The data by Langmuir isotherm showed that the maximum adsorption capacity for RB and AB was equal to 83 and 140.84 mg/g, respectively. Furthermore, thermodynamic studies demonstrated that the present adsorption procedures were both spontaneous and endothermic. The mechanism of gasoline adsorption onto RB and AB was effectively investigated with the assistance of characterization techniques. The current study demonstrates that RB and AB can be utilized as adsorbents for the elimination of gasoline with high efficiency.

Hydraulic conductivity of bentonite-polymer geosynthetic clay liners to aggressive solid waste leachates

Hydraulic conductivity of conventional mock sodium bentonite (Na–B) and bentonite-polymer (B–P) geosynthetic clay liners (GCLs) were evaluated with three synthetic leachates that are chemically representative of aggressive leachates from coal combustion product (CCR) (I = 3179 mM), mining waste (MW) (I = 2127 mM, pH = 2.0), and municipal solid waste incineration ash landfill (MSWI) (I = 2590 mM). The mock B–P GCLs were created by dry mixing bentonite with branched, linear, or crosslinked polymer. The polymer loading of mock B–P GCLs ranged from 3 to 15%. Comparative tests were also conducted with Na–B GCLs. The mock Na–B GCLs cannot maintain low hydraulic conductivity to aggressive CCR, MW, and MSWI leachates. Mock B–P GCLs with 10% branched polymer had low hydraulic conductivity (< 1.0 × 10−10 m/s) to synthetic MW and MSWI leachates at 20 kPa effective confining stress, whereas the hydraulic conductivity of mock B–P GCLs with 10% linear or crosslinked polymer ranged from 1.5 × 10−9 to 1.4 × 10−7 m/s. As the effective stress increased, the B–P GCLs branched polymer showed a faster decreasing trend than that of Na–B and B–P GCLs with linear or crosslinked polymer.