This study concerns the archaeometric characterization of two artefacts from the medieval site of San Rocco (Castelfranco Veneto, Italy). Both of them belong to a larger set of metallic objects, some being part of tomb ornaments belonging to two very well distinct periods of frequentation of the site. Both items are buckles and they have been selected as representative of two very well-known and established typologies. The older one, at the end of the sixth—beginning of the seventh century AD, is made of silver, although relicts of gold have been found. A number of relevant counterparts of this item have been found in different sites of the Longobard Italy. The main body of the second artefact (second half of the fourteenth century AD) consists of a bent strip of a copper rich alloy, coated on one side with a nearly continuous, decorated, gold layer. This is a so-called lyre-buckle, with a widespread diffusion not only in Italian, but also North European contexts. From the results of the analyses carried out using low-vacuum scanning electron microscopy, energy dispersive X-ray spectroscopy, and X-ray diffractometry, information on manufacturing, gilding technology and materials have been obtained that will be an useful benchmark for the archaeometric characterization of similar items from selected collections. In this way, the already established typological affinity of these two classes of items will be extended to technological and materials aspects, also.
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