Beneficial Characteristics Research Articles

Wide and Thin Li Metal Powder Electrodes and Their Electrochemical Performances

Li metal powders are very useful in fabricating wide and thin Li metal electrodes due to its ease applicability to slurry-coating process. Furthermore, not only microstructure but also functional components can be controlled or added in Li metal power electrode. These beneficial characteristics can lead to more stable and robust Li metal electrode comparing to the conventional extrusion/roll-pressed, electroplated, or vacuum evaporated Li metal electrodes. In this work, we introduce how thin and wide the Li metal electrode can be fabricated using the conventional slurry-coating method. And then, it is also included how binder-induced scaffold-like electrode structure can improve the electrochemical performances of Li metal electrode. Furthermore, the role of some inorganic additives like CNTs, LiNO3 or AgNO3 will be also discussed with significant electrochemical performance enhancements. Finally, these Li metal powders are being investigated to lithiate diffusion-dependent electrodes especially for all-solid-state batteries. [References] 1. D. Kang†, D. Jin†, H. Lee*, S.-Y. Ryou*, Y. M. Lee* et al., Chemical Engineering Journal, 452 (2023) 1394092. C. B. Dzakpasu, H. Lee*, S.-Y. Ryou*, Y. M. Lee* et al., Electrochimica Acta, 430 (2022) 1410933. J. Kim†, S. Jung†, Y. M. Lee* et al., Advanced Energy Materials, 12 (2022) 21031084. D. Jin, M.-H. Ryou*, H. Lee*, Y. M. Lee* et al., Advanced Energy Materials, 11(18) (2021) 20037695. D. Jin, M.-H. Ryou*, Y. M. Lee* et al., Chemical Engineering Journal, 406 (2021) 1268346. D. Jin, Y. M. Lee*, M.-H. Ryou* et al., Electrochimica Acta, 364 (2020) 136878

Does globalization suppress social trust?

Globalization has been on the increase during the past 50 years, and there are now signs of a backlash. Part of the reason may be the widely held belief that globalization is harmful, not least for the cultural fabric. Is that the case? We investigate whether globalization has suppressed social trust, arguably one of the most beneficial characteristics of people in a society. By using a sample of first- and second-generation immigrants in 33 primarily European countries, we apply the epidemiological method to rule out reverse causality; and by using the KOF Index of Globalization, we study effects of economic, social and political globalization separately. We find that especially social globalization, and to some extent economic globalization, are positively related to social trust, with a small effect size, while political globalization is largely unrelated to it. Overall, this indicates that globalization does not pose a danger for social trust – at least not for people with a migration background. If anything, people seem to become slightly more trusting with more globalization.

Azetidines with All-Carbon Quaternary Centers: Merging Relay Catalysis with Strain Release Functionalization.

Given the importance and beneficial characteristics of decorated azetidines in medicinal chemistry, efficient strategies for their synthesis are highly sought after. Herein, we report a facile synthesis of the elusive all-carbon quaternary-center-bearing azetidines. By adopting a well-orchestrated polar-radical relay strategy, ring strain release of bench-stable benzoylated 1-azabicyclo[1.1.0]butane (ABB) can be harnessed for nickel-catalyzed Suzuki Csp2-Csp3 cross-coupling with commercially available boronic acids in broad scope (>50 examples), excellent functional group tolerance, and gram-scale utility. Preliminary mechanistic studies provided insights into the underlying mechanism, wherein the ring opening of ABB with a catalytic quantity of bromide accounts for the conversion of ABB into a redox-active azetidine, which subsequently engages in the cross-coupling reaction through a radical pathway. The synergistic bromide and nickel catalysis could intriguingly be derived from a single nickel source (NiBr2). Application of the method to modify natural products, biologically relevant molecules, and pharmaceuticals has been successfully achieved as well as the synthesis of melanocortin-1 receptor (MC-1R) agonist and vesicular acetylcholine transporter (VAChT) inhibitor analogues through bioisosteric replacements of piperidine with azetidine moieties, highlighting the potential of the method in drug optimization studies. Aside from the synthesis of azetidines, we demonstrate the ancillary utility of our nickel catalytic system toward the restricted Suzuki cross-coupling of tertiary alkyl bromides with aryl boronic acids to construct all-carbon quaternary centers.

Positive Emotions Training (PoET) as an online intervention to improve mental health: a feasibility study

BackgroundPositive psychology interventions are known to have an impact on mental health as well as on a number of beneficial characteristics like optimism, gratitude and self-efficacy. The Positive Emotions Training (PoET) is one of the first holistic training programs covering eleven positive psychology constructs. The goal of this study was to test PoET’s feasibility in the general population and to assess possible effects on positive and negative mental health factors. Additionally, possible effects on optimism, gratitude, happiness, resilience, and self-efficacy were examined.MethodsThe sample (n = 101) was not randomized. Participants were allocated to PoET (n = 55) or control group (n = 46) that did not receive treatment initially. The PoET group completed two training sessions (3.5 h each) that were conducted in an online format with groups of about 30 people. All participants completed positive and negative mental health measures at the beginning of the first training session and at the beginning of the second one as well as 30 days after the second session. Two-factorial repeated measures ANOVAs were conducted to test for possible effects of PoET on mental health.ResultsThe results showed that the contents were comprehensible and that the conduction of the training was feasible overall. In addition, a significant decrease of depression and anxiety symptoms as well as a significant increase of optimism were found in the PoET group. No significant changes were found in the control group.ConclusionsResults indicate that PoET is an applicable intervention for improving mental health in the general population.Trial registrationRetrospectively registered at ClinicalTrials.gov on 21/02/2023 (Identifier/Trial registration number: NCT05737251).

Evaluation of the water absorption of expanded polystyrene after different periods

This work evaluated the results of water absorption tests on specimens of expanded polystyrene (EPS) in the specific masses of 10, 20 and 30 kg/m³ molded in specimens with cubic dimensions of 100 mm. The tests were carried out according to ASTM C272 (2001). Long-term water absorption tests were also performed, which differs from the simple test by the immersion time of the specimens, in which the test bodies were kept submerged for a period of 28 days, seeking to study the behavior of the EPS when exposed or in contact with water for long periods of time. From the results it was observed that the water absorption parameters tend to decrease with the increase of the specific mass, being that the lower density presents significant water absorption, this shows that there is a loss of the beneficial characteristics of the use of EPS with low density. Thus, it is important to provide a waterproofing system in practice that avoids the direct contact of the geoexpandido with the water, as well as an adequate and efficient drainage system to remove the water in contact with the EPS faster in the construction. It is also worth noting that water absorption represents about 4% of the sample volume and the behavior, both in mass and volume, for immersion in a 24-hour period and 28 days remains similar.

Anisotropic Nature of Lightweight Wooden Metamaterials with Mechanical/Thermomechanical Multistability

AbstractNanoengineered wood provides a renewable structural material with 3D micro and nanoarchitectures, exhibiting many beneficial characteristics such as being lightweight in nature, mechanically strong, eco‐friendly, thermally insulation, and low carbon footprint. Most nanocellulose aerogels lack sufficient mechanical strength, while nanowood involves a trade‐off between mechanical strength and insulation performance. Here, a nanowood‐derived product with mechanical/thermomechanical multistability called a wooden metamaterial, which is ultrastiff yet lightweight, is designed and synthesized. The self‐healing behaviors of cellulose nanofibrils originally present in the cell walls and their combination with microscale mechanical constraints are utilized to form directional porous frameworks (porosity ≥98%) and encapsulated empty fiber lumen in predesigned macroscopic architectures. The wooden metamaterials are lightweight, showing ultrahigh specific strength (207.7 MPa cm3 g−1), and ultrahigh anisotropy with an approximate factor of 4. Wooden metamaterials have overcome the mechanical/thermomechanical deficiencies of existing building materials and advanced aerospace thermal insulators, and have great potential for revolutionizing architecture and manufacturing industries, particularly as a lightweight, eco‐friendly, scalable, energy‐efficient, and cost‐effective.

Bacteriocin-Producing Lactiplantibacillus plantarum YRL45 Enhances Intestinal Immunity and Regulates Gut Microbiota in Mice.

Bacteriocins production is one of important beneficial characteristics of probiotics, which has antibacterial property against intestinal pathogens and is helpful for regulating intestinal flora. To investigate the impact of bacteriocin-producing probiotics on gut microecology, bacteriocin-producing Lactiplantibacillus plantarum YRL45 was orally administered to mice. The results revealed that it promoted the release of cytokines and improved the phagocytic activity of peritoneal macrophages to activate the immune regulation system. L. plantarum YRL45 was conducive to maintaining the morphology of colon tissue without inflammation and increasing the ratio of villus height to crypt depth in the ileum. The gene expression levels of Muc2, ZO-1 and JAM-1 were significantly up-regulated in the ileum and colon, and the gene expression of Cramp presented an upward trend with L. plantarum YRL45 intervention. Moreover, L. plantarum YRL45 remarkably enhanced the levels of immunoglobulins sIgA, IgA and IgG in the intestine of mice. The 16S rRNA gene analysis suggested that L. plantarum YRL45 administration up-regulated the relative abundance of the beneficial bacteria Muribaculaceae and Akkermansia, down-regulated the abundance of the pathogenic bacteria Lachnoclostridium, and promoted the production of acetic acid, propionic acid and total short-chain fatty acids (SCFAs) in mice feces. Our findings indicated that L. plantarum YRL45 had the potential to be developed as a novel probiotic to regulate the intestinal barrier by altering gut microbiota to enhance intestinal immunity and ameliorate intestinal flora balance.

A deep learning-based mathematical modeling strategy for classifying musical genres in musical industry

Abstract Since the beginning of the digital music era, the number of available digital music resources has skyrocketed. The genre of music is a significant classification to use when elaborating music; the role of music tags in locating and categorizing electronic music services is essential. To categorize such a large music archive manually would be prohibitively expensive and time-consuming, rendering it obsolete. This study’s main contributions to knowledge are the following: This article will break down the music into many MIDI (music played on a digital musical instrument) movements, playing way close by analysis movement, character extraction from passages, and character sequencing from movement so that you may get a clearer picture of what you are hearing. The procedure includes the following steps: extracting the note character matrix, extracting the subject and segmentation grouping based on the note character matrix, researching and extracting beneficial characteristics based on the theme of the segments, and composing the feature sequence. It is challenging for the sorter to acquire spatial and contextual knowledge about music using traditional classification techniques due to its shallow structure. This study uses the unique pattern of input MIDI segments, which are used to probe the relationship between recurrent neural networks and attention. The approach for music classification is verified when paired with the testing precision of the same-length segment categorization; thus, gathering MIDI tracks 1920 along with genre tags from the network to construct statistics sets and perform music classification analysis.

Structural characterization of the optical isomers esomeprazole and omeprazole using the JADER and FAERS databases

BackgroundIt is unclear whether the s (−) form of esomeprazole (EPZ) has an improved safety profile when compared with its racemic form omeprazole (OPZ). We assessed the potential complications of these optical isomers when combined with cilostazol, clopidogrel, and prasugrel, which are frequently used concomitant medications. MethodsUsing two adverse event spontaneous reporting databases, Japanese Adverse Drug Event Report (JADER) and FDA Adverse Event Reporting System (FAERS), adverse event names for hemorrhage, venous/arterial embolization, and thrombus were obtained from the Medical Dictionary for Regulatory Activities. Reported odds ratios were calculated using a 2 × 2 contingency table, and a signal was considered present if the lower limit of the 95% confidence interval was >1. ResultsIn combination with cilostazol, a hemorrhagic signal for OPZ in JADER and arterial emboli and thrombus signals for EPZ were detected in both databases. In combination with clopidogrel, OPZ showed arterial emboli and thrombus signals in JADER and venous/arterial emboli and thrombus signals in FAERS, while EPZ displayed arterial emboli and thrombus signals in FAERS. In contrast, when in combination with prasugrel, there were no adverse event signals in either database. ConclusionThis study has confirmed using big data, that EPZ, the optical isomer and racemic form of omeprazole, has the beneficial characteristics of being less sensitive to CYP, as was intended by its design.

Getting the first gig: Exploring the affective relations of accessing place-based platform labour

Platform labour has established itself as a new form of work in recent years. The platforms themselves advertise the flexibility and freedom of being an independent contractor as beneficial characteristics of their working arrangements. However, existing studies show that these promises do not always correspond to workers' lived experiences. While manifold research discusses the often precarious working conditions of established platform workers, less is known about gaining access to gig work in the first place. This paper draws attention to onboarding processes in the place-based gig economy. From a feminist geography perspective and building on geographies of affect, this paper analyses the process of getting a first paid gig, focusing on how emotions shape platform workers' daily lives. Through autoethnography, I reflect on my own experiences of trying to establish myself as paid platform worker. Contrary to common assumptions, I argue that access to the place-based gig economy is not necessarily straightforward. The paper shows how the labour mediation processes implemented by the platforms create in- and exclusions from the beginning. By letting the workers chase a first gig, the platform capitalises on extended unpaid labour, which is key in maintaining the value production in the gig economy itself.

Probiotic bacilli incorporation in foods: is really so easy?

Foods containing probiotic bacilli spores are becoming more and more popular because of their resistance to acidic pH, low water activity, and, most importantly, heat processes. Even though spores may engage in some functions, such as immunomodulation, the majority of the beneficial characteristics are unique to vegetative cells. As matter of fact, the development of foods fortified with spores ought to even ensure the germination of the spores along the gastrointestinal tract. In this perspective, vegetative cells derived from spore germination were separately counted on a minimal medium because the traditional approach is based on the use of complex media that allows the spores to germinate independently by stimuli arising from processing or digestion.In more detail, three Bacillus spp. cultures with claimed probiotic properties were added to two entirely unrelated foods (pasta and croissants), and tolerance, as well as germination, was monitored before and after exposure to simulated GIT, as well as at the beginning and end of the products shelf life. For the first time, potential probiotic bacilli were included in a frozen ready-to-bake product. Germination appears to be prevented in this instance, and the impact of baking, matrix and cold storage on spores was examined independently. All of the parameters appeared to contribute, although further research is needed due to the unpredictable behavior exhibited by spores during freezing.

Fundamental Characterization of Antibody Fusion-Single-Chain TNF Recombinant Proteins Directed against Costimulatory TNF Receptors Expressed by T-Lymphocytes.

The costimulatory signal regulated by the members of the tumor necrosis factor receptor (TNFR) superfamily expressed by T cells plays essential roles for T cell responses and has emerged as a promising target for cancer immunotherapy. However, it is unclear how the difference in TNFR costimulation contributes to T cell responses. In this study, to clarify the functional significance of four different TNFRs, OX40, 4-1BB, CD27 and GITR, we prepared corresponding single-chain TNF ligand proteins (scTNFLs) connected to IgG Fc domain with beneficial characteristics, i.e., Fc-scOX40L, Fc-sc4-1BBL, Fc-scCD27L (CD70) and Fc-scGITRL. Without intentional cross-linking, these soluble Fc-scTNFL proteins bound to corresponding TNFRs induced NF-kB signaling and promoted proliferative and cytokine responses in CD4+ and CD8+ T cells with different dose-dependencies in vitro. Mice injected with one of the Fc-scTNFL proteins displayed significantly augmented delayed-type hypersensitivity responses, showing in vivo activity. The results demonstrate that each individual Fc-scTNFL protein provides a critical costimulatory signal and exhibits quantitatively distinct activity toward T cells. Our findings provide important insights into the TNFR costimulation that would be valuable for investigators conducting basic research in cancer immunology and also have implications for T cell-mediated immune regulation by designer TNFL proteins.

Laponite-Based Nanocomposite Hydrogels for Drug Delivery Applications.

Hydrogels are widely used for therapeutic delivery applications due to their biocompatibility, biodegradability, and ability to control release kinetics by tuning swelling and mechanical properties. However, their clinical utility is hampered by unfavorable pharmacokinetic properties, including high initial burst release and difficulty in achieving prolonged release, especially for small molecules (<500 Da). The incorporation of nanomaterials within hydrogels has emerged as viable option as a method to trap therapeutics within the hydrogel and sustain release kinetics. Specifically, two-dimensional nanosilicate particles offer a plethora of beneficial characteristics, including dually charged surfaces, degradability, and enhanced mechanical properties within hydrogels. The nanosilicate-hydrogel composite system offers benefits not obtainable by just one component, highlighting the need for detail characterization of these nanocomposite hydrogels. This review focuses on Laponite, a disc-shaped nanosilicate with diameter of 30 nm and thickness of 1 nm. The benefits of using Laponite within hydrogels are explored, as well as examples of Laponite-hydrogel composites currently being investigated for their ability to prolong the release of small molecules and macromolecules such as proteins. Future work will further characterize the interplay between nanosilicates, hydrogel polymer, and encapsulated therapeutics, and how each of these components affect release kinetics and mechanical properties.

Preliminary Study of Cesium Immobilization in a Geopolymer Matrix

Geopolymers are modern synthetic materials that have many beneficial characteristics, e.g. excellent mechanical properties, fire- and heat-resistance, minimal shrinkage and can be molded into shape. Given their aforementioned characteristics, geopolymers could be applicable as conditioning materials, e.g. to handle hazardous waste and radioactive materials. However, their long-term applicability needs to be investigated.The aim of this study is to investigate the mobility of Cs-137 radionuclides in embedding materials. Different geopolymeric matrices - namely kaolinite, bentonite, zeolites and red mud - were tested. The leach test was performed according to the ASTM C1308-08(2017) standard and the activity concentration of Cs-137 isotopes was measured by gamma spectrometry using a high-purity germanium (HPGe) semiconductor detector. According to our preliminary results, the matrices that resulted in the most significant immobilization effect were those in which bentonite, cement, fly ash and 8M NaOH were used, releasing approximately 10% of the cesium.

Safety Assessment of the Ammonia Bunkering Process in the Maritime Sector: A Review

One of the main goals of the shipping industry is to decarbonize the fuels used in maritime transportation. Ammonia is thought to be a potential alternative for hydrogen storage in the future, allowing for CO2-free energy systems. Ammonia’s beneficial characteristics with regard to hydrogen storage include its high volumetric hydrogen density, low storage pressure, and long-term stability. However, ammonia is characterized by toxicity, flammability, and corrosiveness, making safety a challenge compared to other alternative fuels. In specific circumstances, leakage from ammonia bunkering can cause risks, dispersion, and unsafe areas due to its flammability and toxicity. Based on an analysis of 118 research papers and 50 regulations and guidelines, this review report evaluates various aspects of the hazards associated with the ammonia bunkering processes, considering both current and future implications. This report also includes the latest advancements and potential developments related to the safety of ammonia as a marine fuel. Several related regulations and standards for ammonia supply systems are discussed. This paper examines experiments and numerical investigations conducted using different methods of ammonia bunkering, such as terminal-to-ship, ship-to-ship, and truck-to-ship transfers. This review shows that the toxicity of ammonia is more relevant to the topics of vapor cloud dispersion and ammonia bunkering than its flammability. Finally, the main challenges and recommendations for the implementation of ammonia bunkering and further development of ammonia as a marine fuel are proposed. This review suggests new directions to overcome the disadvantages and research gaps associated with the leakage of ammonia during bunkering periods.

Spectral method for solving fractal fractional differential equations

Lately introduced fractal fractional Caputo - Fabrizio operator. By substituting the single kernel at the classic derivative of fractal fractional Caputo with the ordinary kernel This modern operator was derived. We introduce some beneficial characteristics relied on the qualifier of fractal fractional Caputo - Fabrizio. Here, we extend Caputo-Fabrizio for nonlinear fractal fractional differential equations. We apply Legendre operational matrix relied on this modern operator and then, we employ it to solve the differential equations determined in the sense of fractal fractional Caputo-Fabrizio. To show the simplicity and precision of the suggested technicality Some numerical examples are given.

Integrative transcriptome and metabolome revealed the molecular mechanism of Bacillus megaterium BT22-mediated growth promotion in Arabidopsis thaliana

Plant growth-promoting rhizobacteria (PGPR) can promote plant growth and protect plants from pathogens, which contributes to sustainable agricultural development. Several studies have reported their beneficial characteristics in facilitating plant growth and development and enhancing plant stress resistance through different mechanisms. However, there is still a challenge to study the molecular mechanism of plant response to PGPR. We integrated the transcriptome and metabolome of Arabidopsis thaliana (Arabidopsis) to understand its responses to the inoculation with an isolated PGPR strain (BT22) of Bacillus megaterium. Fresh shoot weight, dry shoot weight and leaf number of Arabidopsis were increased by BT22 treatment, showing a positive growth-promoting effect. According multi-omics analysis, 878 differentially expressed genes (296 up-regulated, 582 down-regulated) and 139 differentially expressed metabolites (66 up-regulated, 73 down-regulated) response to BT22 inoculation. GO enrichment results indicate that the up-regulated genes mainly enriched in the regulation of growth and auxin response pathways. In contrast, the down-regulated genes mainly enriched in wounding response, jasmonic acid and ethylene pathways. BT22 inoculation regulated plant hormone signal transduction of Arabidopsis, including auxin and cytokinin response genes AUX/IAA, SAUR, and A-ARR related to cell enlargement and cell division. The contents of nine flavonoids and seven phenylpropanoid metabolites were increased, which help to induce systemic resistance in plants. These results suggest that BT22 promoted Arabidopsis growth by regulating plant hormone homeostasis and inducing metabolome reprogramming.

Copper-oxide nanoparticles exert persistent changes in the structural and functional microbial diversity: A 60-day mesocosm study of zinc-oxide and copper-oxide nanoparticles in the soil-microorganism-nanoparticle system

Recent advances in nanotechnology and development of nanoformulation methods, has enabled the emergence of precision farming – a novel farming method that involves nanopesticides and nanoferilizers. Zinc-oxide nanoparticles serve as a Zn source for plants, but they are also used as nanocarriers for other agents, whereas copper-oxide nanoparticles possess antifungal activity, but in some cases may also serve as a micronutrient providing Cu ions. Excessive application of metal-containing agents leads to their accumulation in soil, where they pose a threat to non-target soil organisms. In this study, soils obtained from the environment were amended with commercial zinc-oxide nanoparticles: Zn-OxNPs(10−30), and newly-synthesized copper-oxide nanoparticles: Cu-OxNPs(1−10). Nanoparticles (NPs) in 100 and 1000 mg kg-1 concentrations were added in separate set-ups, representing a soil-microorganism-nanoparticle system in a 60-day laboratory mesocosm experiment. To track environmental footprint of NPs on soil microorganisms, a Phospholipd Fatty Acid biomarker analysis was employed to study microbial community structure, whereas Community-Level Physiological Profiles of bacterial and fungal fractions were measured with Biolog Eco and FF microplates, respectively. The results revealed a prominent and persistent effects exerted by copper-containing nanoparticles on non-target microbial communities. A severe loss of Gram-positive bacteria was observed in conjunction with disturbances in bacterial and fungal CLPPs. These effects persisted till the end of a 60-day experiment, demonstrating detrimental rearrangements in microbial community structure and functions. The effects imposed by zinc-oxide NPs were less pronounced. As persistent changes were observed for newly synthesized Cu-containing NPs, this work stresses the need for obligatory testing of nanoparticle interactions with non-target microbial communities in long-term experiments, especially during the approval procedures of novel nano-substances. It also underlines the role of in-depth physical and chemical studies of NP-containing agents, which may be tweaked to mitigate the unwanted behavior of such substances in the environment and preselect their beneficial characteristics.

Development of ternary nanoformulation comprising bee pollen-thymol oil extracts and chitosan nanoparticles for anti-inflammatory and anticancer applications

Due to the beneficial nutritional and medicinal characteristics of bee honey and thymol oil as antioxidants, anti-inflammatory agents, and antibacterial agents, they have been used since ancient times. The current study aimed to construct a ternary nanoformulation (BPE-TOE-CSNPs NF) through the immobilization of the ethanolic extract of bee pollen (BPE) with thymol oil extract (TOE) into the matrix of chitosan nanoparticles (CSNPs). The antiproliferative activity of new NF (BPE-TOE-CSNPs) against HepG2 and MCF-7 cells was investigated. The BPE-TOE-CSNPs showed significant inhibitory activity for the production of the inflammatory cytokines in HepG2 and MCF-7, with p < 0.001 for both TNF-α and IL6. Moreover, the encapsulation of the BPE and TOE in CSNPs increased the efficacy of the treatment and the induction of valuable arrests for the S phase of the cell cycle. In addition, the new NF has a great capacity to trigger apoptotic mechanisms through caspase-3 expression upregulation in cancer cells by two-fold among HepG2 cell lines and nine-fold among MCF-7 which appeared to be more susceptible to the nanoformulation. Moreover, the nanoformulated compound has upregulated the expression of caspase-9 and P53 apoptotic mechanisms. This NF may shed light on its pharmacological actions by blocking specific proliferative proteins, inducing apoptosis, and interfering with the DNA replication process.

Berry Seeds—A By-Product of the Fruit Industry as a Source of Oils with Beneficial Nutritional Characteristics

Proper management of waste is one of the major challenges for the food industry. Fruit seeds are an example of by-products that are rich in bioactive substances and generated in significant amounts during fruit processing. Oils, including those obtained from seeds, should meet certain requirements to be allowed for human consumption. The aim of this study was to determine the quality of oils from black currant, strawberry and cranberry seeds by determining the following parameters: fatty acid composition by gas chromatography, distribution of fatty acids between sn-2 and sn-1,3 positions of triacylglycerols by partial enzymatic hydrolysis, oxidative stability by pressure differential scanning calorimetry and melting characteristics by differential scanning calorimetry. Additionally, health indices of atherogenicity (IA), thrombogenicity (IT) and hypocholesterolemic/hypercholesterolemic (HH) ratio were calculated. It was found that the oils studied were a rich source of unsaturated fatty acids. Linoleic acid was found to occupy the internal position of triacylglycerols in the highest proportion. Black currant and strawberry seed oils were of lower oxidative stability and, in the case of cranberry seed oil, high oxidative stability was determined. The shape of melting curves for black currant and strawberry seed oils indicated the presence of low-melting fractions of triacylglycerols containing polyunsaturated fatty acids. It can be concluded that cranberry seed oil, with low values of IA and IT, high values of HH index and the highest oxidative stability, can be considered the most favorable from a nutritional point of view concerning human health.