Gas-assisted coaxial electrospinning (GACES) is a simple and general method for the mass preparation of coaxial nanofiber membranes, which has great industrial potential. However, in the manufacturing process, due to the bending instability of the jet in the electric field and the pulling effect of the gas flow field, the deposition uniformity of the fiber is still a big problem. Through finite element simulation analysis of the flow field in the manufacturing process and the construction of the jet mechanics model after adding the flow field, the influence mechanism of coaxial auxiliary flow on the fiber deposition area and its uniformity was successfully revealed in this research. Finally, the deposition area and thickness uniformity of coaxial fibers are increased by 3 times (the deposition area: 19.63 cm2 → 78.50 cm2) and 2.34 times (the standard variance: 3 μm2 → 10 μm2) by gas-assisted coaxial electrospinning. At the same time, the coaxial auxiliary gas flow also reduces the coaxial fiber diameter by 36.9% (the average fiber diameter: 241 nm ± 5 nm → 152 nm ± 23 nm) and the distribution range by 66% (the standard variance: 1.5 × 102 nm2 → 51 nm2). This research provides a reliable idea and experimental basis for homogeneous preparation of coaxial nanofiber membranes.
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