The current trend of industrial concrete leans more towards the use of self-compacting concrete. These must have fresh properties well defined as fluidity, filling ability and resistance to segregation. However, to ensure the rheological stability, use mineral fines is required. In this work, powder of calcined pyrophyllite (CP) was used as cement substitution at level of 10% and 20% by weight. The interest is focused on the role played by the calcined pyrophyllite to produce SCC with reduced impact environmental.. Calcination of pyrophyllite powder was carried out at 750 °C. Its effect on the workability and mechanical properties of self-compacting concrete is analyzed. The results show that the properties of workability of SCC containing 10% of calcined pyrophyllite tested at fresh state (Slump Flow, T50, passing ability and segregation resistance) are almost identical to those of the control SCC. Furthermore, the calcined pyrophyllite increases the compressive strength, tensile and flexural strength of SCC approaching without exceeding those of the control SCC. It seems that 10 % of calcined pyrophyllite is the optimum replacement rate which improves mechanical strength compared to 20%. Replacing cement with the calcined pyrophyllite aims to save cement and reduce the CO2 emissions released during the manufacture of cement.