Behavior Of Gas Research Articles

Understanding flame behaviors under gradient magnetic fields: The dynamics of non-reacting gas jets

Gradient magnetic fields impact fluid dynamics through Kelvin forces, altering flame behavior. Key complexities such as the interaction of magnetic fields with thermal gradients and chemical reactions within flames remain largely unexplored. By isolating variables such as heat release and thermal convection, this study aims to delve into fundamental mechanisms by which gradient magnetic fields affect the fluid dynamics of flames. This research adopts nitrogen, helium, argon and oxygen as jet gases, focusing exclusively on the fluid dynamics of non-reacting flow. Experimental techniques and Computational Fluid Dynamics (CFD) simulations are employed to explore the effects of varying gas species and magnetic field strengths. Results demonstrate that gas density significantly impacts jet behavior, with paramagnetic oxygen concentrating in areas of stronger magnetic fields, and other gases like helium, nitrogen, and argon showing distinct behaviors based on their molar mass. The study also establishes an optimized energy conservation equation that accurately predict jet height, considering factors such as buoyant and Kelvin forces. By studying the flow behavior of non-reacting gases under magnetic fields, the results are ultimately extended to estimate flame heights and elucidate the mechanisms of air-to-fuel diffusion.

Pressure never sucks, pressure only pushes: a physiological exploration of the pushing power of pressure.

The movement of air into and out of the lungs is facilitated by changes in pressure within the thoracic cavity relative to atmospheric pressure, as well as the resistance encountered by airways. In this process, the movement of air into and out of the lungs is driven by pressure gradients established by changes in lung volume and intra-alveolar pressure. However, pressure never sucks! The concept that pressure never sucks, pressure only pushes encapsulates a fundamental principle in the behavior of gases. This concept challenges common misconceptions about pressure, shedding light on the dynamic forces that govern the movement of gases. In this Illumination, we explore the essence of this concept and its applications in pulmonary ventilation. Pressure is one of the most important concepts in physics and physiology. Atmospheric pressure at sea level is equal to 1 atmosphere or around 101,325 Pascal [Pa (1 Pa = 1 N/m2)]. This huge pressure is pushing down on everything all the time. However, this pressure is difficult to understand because we do not often observe the power of this incredible force. We used five readily available, simple, and inexpensive demonstrations to introduce the physics and power of pressure. This extraordinarily complex physics concept was approached in a straightforward and inexpensive manner while still providing an understanding of the fundamental concepts. These simple demonstrations introduced basic concepts and addressed common misconceptions about pressure.NEW & NOTEWORTHY The concept that pressure never sucks, pressure only pushes challenges common misconceptions about pressure, shedding light on the dynamic forces that govern the movement of gases. In this Illumination, we will explore the essence of this concept and its applications in pulmonary ventilation. Specifically, we used five readily available, simple, inexpensive demonstrations to introduce the physics and power of pressure.

An investigation on hydrodynamic behavior of horizontal gas–liquid intermittent flow by S-PLIF and parallel-wire conductance sensors

Horizontal gas–liquid two-phase flows widely exist in a variety of industrial fields such as the environment, chemical industry and energy. Intermittent flow, characterized by the quasi-periodic alternation motion of liquid slugs and large-scale Taylor bubbles, is the most prevalent flow pattern in horizontal gas–liquid two-phase flows. Comprehensive research on the hydrodynamic behavior of gas–liquid intermittent flow is essential for revealing the mass and heat transfer characteristics between phases, thereby establishing physical models of flow parameters. In this study, a structured planar laser-induced fluorescence (S-PLIF) system and paired parallel-wire conductance sensors (PWCSs) are designed to detect the gas–liquid interface structures and the hydrodynamic parameters. The S-PLIF system consists of a laser, a visualization box, a Ronchi ruling-plate and a pair of high-speed cameras. An optical linear prism forms a laser sheet in the transverse direction and the middle of the test section, and the cameras are positioned at 70° and 90° respectively to the plane of the laser sheet, referred to as S-PLIF70 and S-PLIF90. Under the laser excitation, bright and dark stripes generated by the Ronchi ruling-plate are deflected at the gas–liquid interface. The influence of total reflection can be effectively avoided by identifying the deflection position of the stripes, allowing for accurate detection of the gas–liquid interfacial structures. The effects of the interface fluctuations and detached bubbles on the S-PLIF70&90 results are investigated. Fluctuation and evolution characteristics of the gas–liquid interface are analyzed by probability density function (PDF) and power spectral density (PSD). Meanwhile, hydrodynamic parameters, i.e., Taylor bubble nose and tail velocity, Taylor bubble and slug length, and slug frequency, are detected by the PWCSs, and compared with previous correlations. The evolution characteristics of the interfacial structures and hydrodynamic parameters are uncovered as the flow condition changes.

Depressurization-induced production of shale gas in organic-inorganic shale nanopores: A kinetic Monte Carlo simulation

Methane gas production from unconventional reservoirs, such as shale formations, is in high demand due to the global energy needs. However, maximizing production remains challenging due to the ultra-tight porosity, heterogeneity, and complex nature of shale rocks under high pressure. To address this issue, we employ a novel kinetic Monte Carlo (kMC) simulation to investigate the molecular-level behavior of shale gas in both homogeneous and heterogeneous organic-inorganic shale nanopores. This approach not only provides accurate computations of shale gas under high pressure but also aims to uncover the mechanisms of shale gas storage at reservoir pressure and production during pressure drawdown. Our findings indicate that organic shale ultramicropores (pore width < 0.7 nm) contribute significantly to the highest storage capacity of shale gas but pose challenges for production capacity solely through depressurization. In contrast, the free gas zone is the primary source of shale gas production from mesoporous shales, which has a high recovery efficiency but a low production capacity due to less pronounced interaction effects from the shale surface. The heterogeneous nature of shale surfaces leads to asymmetric distributions of density and potential energy across pore widths, with methane molecules favoring locations near organic pore walls due to stronger attractive interactions, while inorganic pore walls facilitate shale gas migration. Interestingly, the optimal ultramicropore size yields the highest recovery efficiency of shale gas via depressurization, characterized by a transition from near-commensurate to incommensurate molecular packing between reservoir and post-drawdown pressures. Based on these detailed molecular simulations, further research is necessary to develop innovative techniques for enhancing shale gas recovery, especially in micropores.

Turbulent Diffuse Molecular Media with Nonideal Magnetohydrodynamics and Consistent Thermochemistry: Numerical Simulations and Dynamic Characteristics

Turbulent diffuse molecular clouds can exhibit complicated morphologies caused by the interactions among radiation, chemistry, fluids, and fields. We performed full 3D simulations for turbulent diffuse molecular interstellar media, featuring time-dependent nonequilibrium thermochemistry coevolved with magnetohydrodynamics (MHD). Simulation results exhibit the relative abundances of key chemical species (e.g., C, CO, OH) vary by more than one order of magnitude for the “premature” epoch of chemical evolution (t ≲ 2 × 105 yr). Various simulations are also conducted to study the impacts of physical parameters. Nonideal MHD effects are essential in shaping the behavior of gases, and strong magnetic fields (∼10 μG) tend to inhibit vigorous compressions and thus reduce the fraction of warm gases (T ≳ 102 K). Thermodynamical and chemical conditions of the gas are sensitive to modulation by dynamic conditions, especially the energy injection by turbulence. Chemical features, including ionization (cosmic ray and diffuse interstellar radiation), would not directly affect the turbulence power spectra. Nonetheless, their effects are prominent in the distribution profiles of temperatures and gas densities. Comprehensive observations are necessary and useful to eliminate the degeneracies of physical parameters and constrain the properties of diffuse molecular clouds with confidence.

Numerical Simulation of Evaporative Gas Behavior Inside Fuel Tank During Fire Extinguishing Process

Numerical Simulation of Evaporative Gas Behavior Inside Fuel Tank During Fire Extinguishing Process

Beliaev Damping in Bose Gas

According to the Bogoliubov theory the low energy behaviour of the Bose gas at zero temperature can be described by non-interacting bosonic quasiparticles called phonons. In this work the damping rate of phonons at low momenta, the so-called Beliaev damping, is explained and computed with simple arguments involving the Fermi Golden Rule and Bogoliubov’s quasiparticles.

Optimization of cleaning process in semiconductor gas delivery system by computational fluid dynamics simulation

Purging specialty gas delivery systems in semiconductor industries are essential for ensuring worker safety and complying with stringent environmental regulations. The cleaning process impacts production costs due to the required resources and time. This study introduced and evaluated various purging methods, combining vacuum, vacuum with purge, pressurization, and pressure-gradient purge steps. Considering the density and viscosity of various specialty gases used in semiconductor manufacturing, such as gaseous NH3, HCl, WF6, and SiCl4, were selected as the representative specialty gases for the system. Considering the utilization of the semiconductor industries, ultra-high purity nitrogen was selected to clean all components of the gas delivery system, including gas channels, filters, pressure regulator and diaphragm valves. Efficiency was measured by monitoring residual gas concentration changes during different purge-step configurations, the number of purge configuration, and step durations. The dynamic behavior of specialty gases was analyzed based on geometric factors and chemical properties. Findings indicated that cleaning dead-end zones was particularly challenging and impacting overall system efficiency. Frequent purge with a short step time proved more effective in removing residual chemicals than the present conventional vacuum purge process with a continuous N2 supply. Employing a pressure gradient between the inlet and outlet enhanced cleaning efficiency. These insights provide valuable guidelines for optimizing purging processes to reduce cleaning time and resource consumption in semiconductor manufacturing.

Effect of Initial Temperature and Pressure on the Explosion Characteristics and Intermediate Reaction Products of Formic Acid Mixtures: A Theoretical Study

Formic acid is a promising candidate fuel that can be produced by reacting renewable hydrogen with carbon dioxide. However, the burning safety characteristics of formic acid–air mixtures have not been fully studied. This paper presents an extensive theoretical study of the adiabatic explosion pressure of formic acid–air premixed laminar flames at various initial conditions (composition of formic acid: 17–38% volume; initial pressure: 0.1–1.5 bar; initial temperature: 333–500 K), using the GASEQ software package. GASEQ software calculates chemical equilibria based on ideal gas behavior and is based on the hypothesis of adiabatic expansion inside a closed containment that allows ideal expansion. The influence of the initial conditions (pressure, temperature, and concentration) of formic acid–air mixtures on the adiabatic explosion pressures, maximum flame temperature, and peak concentrations of the main reaction intermediates is investigated and discussed. It is found that the adiabatic peak explosion pressure (calculated equilibrium pressure) of the studied concentrations decreases with increasing initial temperature and increases linearly with increasing initial pressure.

Molecular simulation of the effect of water content on CO2, CH4, and N2 adsorption characteristics of coal

The objective of this work was to investigate the sorption behavior of gases, namely CO2, CH4, and N2, by molecules of coal sampled from Linglu mine under different water inclusion rates. To this end, the adsorption, diffusion, adsorption heat, and potential energy distribution characteristics of the gases in the coal pores at different water inclusion rates were analyzed using molecular dynamics and grand canonical ensemble Monte Carlo methods. The results showed that the adsorption relationship of the coal molecules on CO2, CH4, and N2 exhibited a downtrend followed by an uptrend when the water content was increased from 0 to 3.6%. The adsorption amount of CO2 was approximately twice as much as those of CH4 and N2, indicating that the competitive adsorption advantage of CO2 compared with those of CH4 and N2 was unaffected by the water content. The trend in the average heat of adsorption was generally consistent with the trend in the density of coal molecules under different moisture contents. Under the same conditions, the diffusion coefficient within a coal molecule was negatively related to the water content in the system. The layer spacing of the water molecules (2.875 Å) was greater than the liquid–water layer spacing, indicating the formation of a water molecule layer at this point, which inhibited gas adsorption. This study lays a theoretical foundation for further investigating the microscopic mechanism of coal–water interaction.

Three-dimensional particle-scale investigation of transient gas–solid flow characteristics in the propulsion system with a complex charge structure

This work is focused on researching the particle behavior of the transient gas–solid flow in the propulsion system with the modular charge structure, which has a great effect on the temporal-spatial distribution of energy release. Based on the coupling method of computational fluid dynamics and the discrete element method, an efficient three-dimensional unsteady gas–solid model is developed to provide a detailed means of capturing particle behavior in the propulsion system with a complex structure. Comparisons of the particle distribution of simulation results are done with experimental research, and a reasonable match has been obtained. Furthermore, the particle behavior characteristics can be divided into three stages. In the first stage, the particle behavior is dominated by the high-pressure, high-speed gas from the igniter. In the other two stages, the particle behavior is dominated by the complex gas flow generated by the opening of the module and the groove structure of the vehicle. The results show that the distribution of particles consists of slope accumulation and horizontal accumulation. The slope accumulation with a large gradient contains 84% of the total particles, and the height of the slope accumulation is increased exponentially along the axis.

Computational study of momentum interactions between fluid and a static particle under the impact of anisotropic Stefan flow

The microscale gas–particle interaction is the determining process for the macroscopic flow behaviors of gas–particle systems. Anisotropic Stefan flow is often manifested at the surface of the biomass particle when thermally decomposed. However, the influence of the anisotropic Stefan flow on the gas–particle interactions is not well understood. To this end, particle-resolved direct numerical simulations were carried out in this research to explore the momentum interactions between the gas flow and a static particle emitting mass flux at its surface. A signed distance function based immersed boundary method is first extended to account for the Stefan flow at the gas–particle interface and successfully validated by comparing with literature results in the case of no Stefan flow or uniform Stefan flow. It is found that the presence of the outward uniform Stefan flow leads to an expanded wake formation and the intensity of the vortex (Re ≥ 40) is enhanced as result of the Stefan flow. Subject to the impact of anisotropic Stefan flow parallel to the main flow, the low-speed region in the front and rear of the particle is reduced when the Stefan flow goes inwards, resulting in the increase in the drag coefficient. As the Stefan flow is outward, the low-speed region in the front of the particle is pushed forward by the emitting gas and the velocity magnitude in the wake region is increased, which behaves like an enlargement of the gas cushion and leads to a significant reduction of the drag coefficient comparing with a uniform Stefan flow. In contrast, the impact of anisotropic Stefan flow with the direction perpendicular to the main flow on the fluid–particle drag interaction is less significant due to the fact that the flow structure in the front and rear regions is not significantly disturbed.

Enhanced cooling performance of blade tip slot cooling: Effect of slot open length

Addressing the critical challenge of thermal load-induced damage in turbine blade tips, this study aims to elucidate the effects of slot open length on film cooling effectiveness (FCE) across turbine blade tips with Pressure Side (PS) and Suction Side (SS) slots considering the application of additive manufacturing to turbine blade tips. Employing a linear cascade setup and the pressure sensitive paint (PSP) technique, we examined and quantified cooling performance across turbine blade tips with PS or SS slots at various slot open lengths. We revealed that while short slot open lengths enhance FCE at the leading edge (LE) due to increased averaged blowing ratios, they fail to adequately cover the trailing edge (TE) region. This decrease in cooling performance is largely attributable to the mixing of coolant with hot gas. In contrast, longer slot open lengths achieve a consistent FCE distribution across the blade tip despite a slight decrease in FCE at the LE region. The study suggests that integrating additional thermal design strategies, such as partition walls with slots, could effectively manage hot gas behaviors, thus enhancing the overall cooling design of turbine blade tips. This research makes a significant contribution to the field of turbine blade tip cooling design, providing insights into optimizing cooling performance through advanced slot configurations enabled by additive manufacturing technologies.

Analytic thermodynamic properties of the Lieb-Liniger gas

We present a comprehensive review on the state-of-the-art of the approximate analytic approaches describing the finite-temperature thermodynamic quantities of the Lieb-Liniger model of the one-dimensional (1D) Bose gas with contact repulsive interactions. This paradigmatic model of quantum many-body-theory plays an important role in many areas of physics-thanks to its integrability and possible experimental realization using, e.g., ensembles of ultracold bosonic atoms confined to quasi-1D geometries. The thermodynamics of the uniform Lieb-Liniger gas can be obtained numerically using the exact thermal Bethe ansatz (TBA) method, first derived in 1969 by Yang and Yang. However, the TBA numerical calculations do not allow for the in-depth understanding of the underlying physical mechanisms that govern the thermodynamic behavior of the Lieb-Liniger gas at finite temperature. Our work is then motivated by the insights that emerge naturally from the transparency of closed-form analytic results, which are derived here in six different regimes of the gas and which exhibit an excellent agreement with the TBA numerics. Our findings can be further adopted for characterising the equilibrium properties of inhomogeneous (e.g., harmonically trapped) 1D Bose gases within the local density approximation and for the development of improved hydrodynamic theories, allowing for the calculation of breathing mode frequencies which depend on the underlying thermodynamic equation of state. Our analytic approaches can be applied to other systems including impurities in a quantum bath, liquid helium-4, and ultracold Bose gas mixtures.

Magnon Sensing of NO, NO2 and NH3 Gas Capture on CrSBr Monolayer.

Air pollution and greenhouse emissions are significant problems across various sectors, urging the need for advanced technologies to detect and capture harmful gases. In recent years, two-dimensional (2D) materials have attracted increasing attention due to their large surface-to-volume ratio and reactivity. Herein, we investigate the potential of single-layer CrSBr for gas sensing and capturing by means of first-principles calculations. We explore the adsorption behaviour of different pollutant gases (H2S, NH3, NO, NO2, CO and CO2) on this 2D ferromagnet and the impact of intrinsic defects on its magnetic properties. Interestingly, we find that Br vacancies enhance the adsorption of NH3, NO and NO2 and induce a selective frequency shift on the magnon dispersion. This work motivates the creation of novel magnonic gas sensing devices based on 2D van der Waals magnetic materials.

Effect of particle diameter and void fraction on gas–solid two-phase flow: a numerical investigation using the Eulerian–Eulerian approach

AbstractSudden expansion pipes are crucial in fluid dynamics for studying flow behavior, turbulence, and pressure distribution in various systems. This study focuses on investigating the behavior of a two-phase flow, specifically a gas–solid turbulent flow, in a sudden expansion. The Eulerian–Eulerian approach is employed to model the flow characteristics. The Eulerian–Eulerian approach treats both phases (gas and solid) as separate continua, and their interactions are described using conservation equations for mass, momentum, and energy. The study aims to understand the complex phenomena occurring in the flow, such as particle dispersion, turbulence modulation, and pressure drop. The governing equations are solved using house developed code called FORTRAN, a widely used programming language in scientific and engineering simulations. The results of this study will provide valuable insights into the behavior of gas–solid two-phase flows in sudden expansions, which have important applications in various industries, including chemical engineering, energy systems, and environmental engineering. A parametric study of the impact of particles diameters (20, 120, 220, 500 µm), the solid volume loading ratios $$(0.005, 0.008, 0.01)$$ ( 0.005 , 0.008 , 0.01 ) and area ratios (2.25, 5.76, 9) effect of sudden expansion on the streamlines, local skin friction, pressure, velocity, turbulent kinetic energy, and separation zone.

Multi-fractal characteristics of pore system in deep organic-rich shales of the Wufeng-Longmaxi formation in the Sichuan Basin and their geological significance

The heterogeneity of pore system of deep shale reservoir determines the occurrence, enrichment and migration behavior of shale gas within shales. In this study, multi-fractal analysis was applied to analyze CO2 and N2 adsorption data for obtaining multi-fractal parameters including Hurst index and multi-fractal spectrum (D5--D5+) of the deep Wufeng-Longmaxi shales collected from the Sichuan Basin, China, in order to study the connectivity and heterogeneity of micropore pores and meso-macropores as well as their influencing factors. The results showed that pore system of the Wufeng-Longmaxi deep shale exhibits distinct multifractal nature. There exists significant differences in the pore volume (PV) of micropores (&amp;lt;2 nm), mesopore (2–50 nm), and macropore (&amp;gt;50 nm) across different shale lithofacies due to their differences in TOC content and mineral composition. The heterogeneity and connectivity of micropores and meso-macropores within deep shales in the Sichuan Basin are controlled by multiple factors including shale lithofacies, burial depth, and pressure coefficients. Notably, siliceous shale (SL) and calcareous/argillaecous siliceous shale (C/ASL), known as sweet spot for current shale gas exploitation, exhibits characteristics such as relative low micropore connectivity, high micropore heterogeneity, high micropore PV and low meso-macropore connectivity. These suggest that isolated pressure-sealing compartment is easier formed within the overpressured SL and C/ASL. Thus, pressure in these shales is less likely to release during the Yanshanian-Xishanian tectonic uplift process, favoring the preservation of organic matter (OM) pores and residual interparticle pores, which is conducive to the accumulation of deep shale gas dominated by free gas.

Comparisons of Greenhouse Gas Observation Satellite Performances Over Seoul Using a Portable Ground‐Based Spectrometer

AbstractSatellites provide global coverage for monitoring atmospheric greenhouse gases, crucial for understanding global climate dynamics. However, their temporal and spatial resolutions fall short in detecting urban‐scale variations. To enhance satellite reliability over urban areas, this study presents the first comprehensive analysis of long‐term observations of column‐averaged dry air mole fractions of CO2, CH4, and CO (XCO2, XCH4, XCO) using two ground‐based fourier transform infrared spectrometers, EM27/SUNs, in a megacity. With over 2 years of observations, our study shows that EM27/SUN measurements can effectively capture the daily and seasonal variability of XCO2, XCH4, and XCO over Seoul, a megacity with complex topography and various emission sources. In addition, we use the advantage of having multiple greenhouse gas satellites targeting Seoul to compare with the EM27/SUNs. Our study highlights the importance of EM27/SUN observations in Seoul to identify the need for improvements in satellites to monitor greenhouse gas behaviors and emissions in urban areas.

Weakly q-deformed Heisenberg algebra and non-Hermitian Hamiltonians: Application in statistical physics

We have investigated a weakly q-deformed algebra, which leads to non-Hermitian operators. It has been explicitly shown that the harmonic oscillator Hamiltonian is quasi-Hermitian, and that the corresponding physical Hilbert-space metric Θ differs from that obtained in Ref. [1], by hermitizing the position operator. The reality of the Hamiltonian eigenvalues has been illustrated by analytically computing the first order correction to the energy spectrum of the harmonic oscillator (HO). Furthermore, we have shown that this q-deformation leads to a GUP with minimal uncertainties in both position and momentum measurements. Moreover, the physical implications of this q-deformation, have been investigated by studying the thermostatistics of a system of HOs and an ideal gas. For both systems, we computed the partition function, and then we derived some thermodynamic functions. In addition, for the ideal gas, a modified equation of state and a generalized Mayer's equation, consistent with the real behavior of gases, have been established. The obtained results show that the impact of this model would be significant at high temperatures. However, unlike earlier research, we observe that this q-deformation induced the similar corrections regardless of the system under study.

Depth profile study of LaAl1‐xCrxO3/SrTiO3 (x = 0, 0.2, 0.6, and 1) using time of flight secondary ion mass spectrometry (TOF‐SIMS)

The conducting two‐dimensional electron gas (2DEG) behavior in LaAlO3 (LAO)/SrTiO3 (STO) and their associated mechanisms from various aspects have brought tremendous attention in the concerned area of research. To correlate the 2DEG behavior with their compositions, we have performed time of flight secondary ion mass spectrometry (TOF‐SIMS) depth profile analysis of thin films of Cr‐doped LAO/STO system as LaAl1‐xCrxO3 (x = 0, 0.2, 0.6 and 1) deposited over TiO2 terminated STO substrate, which includes two parent compounds LAO/STO (metallic) and LCO/STO (insulating). The uniform decrease of La and Al concentration at the interface of LAO/STO (metallic) system and in the contrary the nonuniformity of La and Cr concentration in LCO/STO (insulating) system have been highlighted. The uniform variation of ionic concentration at the interface of LAO/STO may increase the career concentrations to make the system metallic. The upward and downward diffusion at the interfaces of intermediate compositions varies differently from their parent ones due to the mixing of Al and Cr. Our results may help to understand the conducting nature of LAO/STO system for future developments and applications in such system.