Closed-form calculation rules for thermal responses of composite slabs with profiled steel decking are provided in EC4, which are only applicable to a specified range of slab geometries available in the 1990s and are unchanged for two decades. This paper aims to gain an insight into the thermal behavior of composite slabs, and to investigate the applicability of EC4 calculation rules to a wider practical range nowadays (usually beyond the specified range). Parametric studies are conducted to study the influence of moisture content and slab geometry on the temperature distribution in composite slabs. The results show that the calculation methods in EC4 are not applicable to composite slabs with geometries beyond the specified range. It is found that the insulation-based fire resistance of composite slabs is governed by the maximum temperature rather than the average temperature. The EC4 calculations overestimate the fire resistance and a reduction factor of 15% is recommended. The moisture content has a significant effect on the temperature distribution in composite slabs, and improvement to EC4 is proposed by considering its the effect in a rate of 5 min per 1% increase of moisture content. Tabulated results are given to determine the temperature of reinforcement in the thin portion and temperature distribution in the composite slabs.