Bed Surface Research Articles

The control on adsorption kinetics and selectivity of formaldehyde in relation to different surface-modification approaches for microporous carbon bed systems

It is perceived that surface modification of microporous carbon is an efficient option to remove light-weight volatile organic compounds (VOCs) like formaldehyde (FA). To adjust textural characteristics with surface functionalities of amine/sulfur and amino-silane, the commercial activated carbon (AC) was treated with dicyandiamide/thiourea (AC-M) and N-[3-(trimethoxysilyl)propyl]ethylenedia (AC-S), respectively, by thermal/microwave-assisted solvothermal methods. The adsorption performance of honeycomb air filters packed with different bed heights of AC-M/-S adsorbents (e.g., 1.38 ± 0.05, 6.36 ± 0.06, 7.99 ± 0.04, and 10.93 ± 0.04 mm) was evaluated (relative to commercial AC-based filters) towards the adsorption removal of FA (10 Pa) in both single and binary mixtures with benzene (at 10 Pa). . Based on the partition coefficient and kinetic metrics, the AC-M/-S based filters showed higher efficacy for FA capture than commercial AC filter with increasing bed height (e.g., ≥ 7.99 ± 0.04 mm) to reflect the increased number of Lewis acid/base active sites on the bed surface. At the highest bed height (10.93±0.04 mm), AC-S was far superior with significantly enhanced selectivity of FA (by 20 times) over benzene with the accelerated mass transfer and acid-base surface interactions at the gas-solid interface. In contrast, AC-M outperformed commercial ACs for benzene adsorption from the binary gas mixture (breakthrough time (τ-value) of 683 min) with the aid of the improved surface porosity (71.8%) through the modification process. The kinematic data also confirmed that the adsorption affinity of modified AC-M/-S adsorbents was unaffected by the feed gas composition (single or binary phase) at the initial BT region. It thus supports the key role of surface modification technique on the enhanced adsorptivity of aldehyde and/or aromatic VOCs. This study is expected to help expand our basic knowledge on the interplay between surface/textural characteristics of modified AC and fixed-bed height to control the adsorptivity of air filter for efficient trapping of FA in either single or mixed phases with non-polar VOCs (like benzene).

Heat absorption characteristics of gas in a directly irradiated solar fluidized bed receiver with tube shaped immersed transmission window

There is a growing interest in directly irradiated solar fluidized bed receivers as solar thermal collector. New method for expanding the energy receiving area is required to improve the utilization efficiency of the solar energy. A solar fluidized bed receiver (50 mm i.d. × 150 mm high) with a tube-type window (23 mm i.d.) inserted into the particle bed was developed for gas-heating applications. The tube-type transmission window extended the solar energy receiving area and efficiently heated the gas inside the entire fluidized bed. In the developed receiver, the bed hydrodynamics of silicon carbide particles and the characteristics of solar heat absorption by the gas were determined under outdoor testing conditions, and the results were compared to those from a conventional receiver with a plate-type window. The tube-type receiver showed high solid holdups in the bed and a low standard deviation of the pressure drop throughout the system. Gas outlet temperature in the tube-type receiver increased up to 156 °C as the gas velocity increased, which is opposite of the plate-type receiver. The temperature increment of gas per irradiance (ΔT/IDNI) increased with increasing gas velocity up to 0.13 m/s, and then maintained a constant value of 0.103. Energy absorption in the plate-type receiver occurs at the bed surface and its freeboard region. In the tube-type receiver, most energy is absorbed inside the bed, which can easily reabsorb scattered energy regardless of the behavior of solids on the freeboard, unlike the plate-type receiver. The thermal efficiency showed a maximum of 30.1% in the tube type. We proposed a solar energy receiving mechanism for each receiver. The developed tube-type receiver has positive operating characteristics in which the ΔT/IDNI is proportional to the efficiency.

Predição da vazão perdida por jatos de água ascendentes aflorantes no solo

Abstract This paper presents experimental studies to explore the behavior of upward water jets in granular beds. The test conditions included both the cavity and chimney regime. Combining our results with data available in the literature, it was possible to fit a linear relationship to describe the dimensionless upward water velocity at the bed surface (u/U) as a function of kFr, in which Fr is the Froude number and k is a fitting parameter that was linearly related with the medium particle diameter d. A threshold condition (kFr = 1) was also proposed to predict the onset of the chimney regime, which was consistent with published data. Finally, a simple equation based on d, D and H was derived to predict the real-scale leakage flow rate Q from upward water jets bursting at the ground. The results obtained will potentially help water utilities estimate the water loss from underground pipelines.

Heat transfer in a novel microwave heating device coupled with atomization feeding

The heat transfer characteristics of the microwave heating coupled with atomization feeding were investigated using ethanol as the spray medium on a pressure swirl nozzle. The effects of spray height, flow rate and temperature on the sauter mean diameter of atomized droplets were examined. The results showed that the droplet sauter mean diameter was 12-130 ?m, which increased with the spray height and decreased with the flow rate and temperature of spray medium. Through the fitting of the experimental data, the dimensionless correlation of the droplet sauter mean diameter which was based on orifice diameter, Reynolds and Ohnesorge numbers was obtained. The calculated results were basically consistent with the experimental data within 15% error. The heat transfer characteristics of atomized droplets on high temperature surface of SiC bed heated by microwave were then investigated. The effects of spray flow rate, spray height, and spray temperature on the heat transfer characteristics were examined. The power of spray heat transfer decreased with the temperature and increased with the spray flow rate and spray height. The dimensionless correlation to describe the heat transfer characteristics of atomized droplets on the high temperature SiC surface under the microwave heating was obtained which included thermophysical properties of spray medium, spray parameters, and temperatures of the high temperature bed surface and spray medium, with the error of ?20%. These correlations can be used to predict the sauter mean diameter of the atomized droplets and the power of spray heat transfer in the microwave heating process.

Autologous Cultured Bone Marrow-Derived Mesenchymal Stem Cells in a Fibrin Spray to Treat Venous Ulcers: A Randomized Controlled Double-Blind Pilot Study.

We treated a small cohort of venous ulcers that were very unresponsive to standard and advanced therapies with autologous cultured bone marrow-derived mesenchymal stem cells (MSCs). This pilot clinical trial was randomized, controlled, and double-blinded. Subjects were treated with either normal saline (Group A), fibrin spray alone (Group B), or MSCs in fibrin (1 million cells/cm2 of wound bed surface) (Group C). The control and test materials were applied to the wound using a double-barreled syringe with thrombin and fibrinogen (with or without MSCs) in each barrel, or saline alone in both barrels. The MSCs were separated, cultured in vitro, and expanded in a dedicated Good Manufacturing Practice (GMP) facility from 30-50 ml of bone marrow aspirate obtained from the iliac crest in Group C subjects. To ensure that the study remained controlled and blinded, subjects who were randomized to one of the two control arms (saline or fibrin) underwent sham bone marrow aspiration performed by a hematologist who anesthetized the iliac crest area down to and pushing against the periosteum, but without penetrating the bone marrow. Therefore, both the clinician who evaluated wound progress and the study subjects had no knowledge of whether bone aspiration was actually performed and what treatment had been applied to the wound. The study was performed after full FDA investigational new drug (IND) approval. The primary endpoint was the rate of healing (wound closure as linear healing from the wound margins in cm/week), as measured by the Gilman equation. One-way ANOVA was used to calculate the statistical significance of differences between the mean healing rates of each of the 3 treatment groups every 4 weeks and over the 24 weeks of treatment. Overall, treatment with MSCs accelerated the healing rate by about 10-fold compared to those in the saline and fibrin control groups. Although the total number of patients in this pilot study was small (n=11), the statistical significance was surprisingly promising: p<0.01 and f-ratio of 15.9358. No serious adverse events were noted. This small but carefully performed prospective, controlled, randomized, and double-blinded pilot study in a rare population of totally unresponsive patients adds to previous reports showing the promise of MSCs in the treatment of chronic wounds and provides proof of principle for how to approach this type of very demanding clinical and translational research.

Analytical and numerical modelling of laser powder bed fusion (L-PBF) of polymers – a review of the key areas of focus of the process

The uptake of laser powder bed fusion for polymers has remained limited mainly because the interaction between material properties and process parameters is not well understood. The constraints of experimentally determining the optimal process parameters for new polymers in laser powder bed fusion include high expense, time-consumption, errors, and considerable effort. Hence, the need for using analytical and numerical models as alternatives. This paper starts with a summary on laser powder bed fusion of polymers, reviews the aspects of the process requiring the use of analytical and numerical tools, limitations, and possible improvements of the existing studies on the analytical models, and finally briefly explores approaches for numerical modelling of laser powder bed fusion of polymers. Some of the key aspects of the process that have been identified as being amenable to modelling include powder spreading and deposition of the layers, interaction between the laser beam and powder particles, melting and fusion of the particles, powder bed surface temperature, heat transfer through the powder, cooling phase, and the properties of printed parts. It is suggested in the study that the existing analytical and/or numerical models can be improved by increasing relevant variables (process parameters and material characteristics) used in them.

Biomass woodchip tracking by image analysis in a model of a fixed bed combustor

Energy sector sustainability is one of the main concerns in the recent years. Biomass, in form of woodchips, is interesting for direct combustion in external combustion cycles (e.g. supercritical CO2 Brayton cycles) due to the opportunity of using low quality and low environmental impact fuels. In this study, a direct combustion system working with biomass woodchips is investigated by means of an image analysis technique. The system is made up by a screw conveyor and a fixed bed, where the woodchips are processed. The analysed device operates in cold-condition, and woodchips are partially coloured according to their dimensional class to be traced once these reached the bed surface. A proper algorithm was developed to identify the particles size, define and detect macroparticles centres, and evaluate the main particles motion pattern by comparing the centre positions during time. The results were particularly useful to understand potential inefficiencies of the combustion system due to an uneven woodchips distribution. In addition, the results achieved with the proposed test rig and the adopted methodology can also be used to validate results from Discrete Element Modelling (DEM) simulations.

Discrete Element Simulation on Sand-Bed Collision Considering Surface Moisture Content

The process of aeolian sand transport is an important mechanism leading to the formation and evolution of local landforms in coastal areas and desert lakes. For a long time, the role of surface moisture in incipient motion of sand grains by wind stress has been extensively studied but, in fact, sand-bed collision is the main mechanism in steady aeolian sand flow. At present, the lack of understanding of surface moisture content on sand-bed collision limits the application of aeolian sand transport models in wet coastal areas. In this paper, we adopt numerical simulations to discuss and analyze the effect of cohesive forces formed by surface moisture content on the sand-bed collision process based on discrete element method. High density contact forces appear with the surface moisture increasing, and form a closed structure around the edge of crater to resist the avulsion in horizontal direction. Under high moisture condition, even though the ejected sand grains saltate away from the surface, the tension forces will prevent from leaving. The ejected number trend with incident velocity shows some nonlinear characteristics due to the unequally distributed force chains and liquid bridges in the unsaturated sand bed surface.

Powder Surface Roughness as Proxy for Bed Density in Powder Bed Fusion of Polymers.

Powder bed fusion of polymers is becoming increasingly adopted by a variety of industries to tailor the strength, weight and functionality of end-use products. To meet the high standards of the modern manufacturing industry, parts built with powder bed fusion require consistent properties and to be free of defects, which is intrinsically connected to the quality of the powder bed prior to melting. The hypothesis of this work is that the roughness of the top surface of an unmelted powder bed can serve as a proxy for the powder bed density, which is known to correlate with final part density. In this study, a laser line scan profilometer is integrated onto the recoater arm of a custom powder test bench, which is able to automatically create layers of powder. A diverse group of polymers was investigated including polyamide 12 (PA12), polyamide 11 (PA11), polypropylene (PP), and a thermoplastic elastomer (TPU) under different recoating speed in order to increase the variance of the dataset. Data analytics were employed to compare roughness to measured powder bed density and a statically significant correlation was established between them.

Keyhole Formation by Laser Drilling in Laser Powder Bed Fusion of Ti6Al4V Biomedical Alloy: Mesoscopic Computational Fluid Dynamics Simulation versus Mathematical Modelling Using Empirical Validation.

In the laser powder bed fusion (LPBF) process, the operating conditions are essential in determining laser-induced keyhole regimes based on the thermal distribution. These regimes, classified into shallow and deep keyholes, control the probability and defects formation intensity in the LPBF process. To study and control the keyhole in the LPBF process, mathematical and computational fluid dynamics (CFD) models are presented. For CFD, the volume of fluid method with the discrete element modeling technique was used, while a mathematical model was developed by including the laser beam absorption by the powder bed voids and surface. The dynamic melt pool behavior is explored in detail. Quantitative comparisons are made among experimental, CFD simulation and analytical computing results leading to a good correspondence. In LPBF, the temperature around the laser irradiation zone rises rapidly compared to the surroundings in the powder layer due to the high thermal resistance and the air between the powder particles, resulting in a slow travel of laser transverse heat waves. In LPBF, the keyhole can be classified into shallow and deep keyhole mode, controlled by the energy density. Increasing the energy density, the shallow keyhole mode transforms into the deep keyhole mode. The energy density in a deep keyhole is higher due to the multiple reflections and concentrations of secondary reflected beams within the keyhole, causing the material to vaporize quickly. Due to an elevated temperature distribution in deep keyhole mode, the probability of pores forming is much higher than in a shallow keyhole as the liquid material is close to the vaporization temperature. When the temperature increases rapidly, the material density drops quickly, thus, raising the fluid volume due to the specific heat and fusion latent heat. In return, this lowers the surface tension and affects the melt pool uniformity.

A Rapid Method for Modeling Transient River Response Under Stochastic Controls With Applications to Sea Level Rise and Sediment Nourishment

AbstractRecent analysis of equilibrium and quasi‐equilibrium channel geometry in engineered (fixed‐width) rivers has successfully shown that two temporal scales can be distinguished, with quasi‐static (long‐term) and dynamic (short‐term) components. This distinction is based on the fact that channel slope cannot keep pace with short‐term fluctuations of the controls. Here we exploit the distinction between the two temporal scales to model the transient (so time‐dependent) phase of channel response, which is the phase wherein the channel approaches its new equilibrium. We show that: (a) besides channel slope, also the bed surface texture cannot keep pace with short‐term fluctuations of the controls, and (b) mean transient channel response is determined by the probability distributions of the controls (e.g., flow duration curve rather than flow rate sequence). These findings allow us to set up a rapid numerical method that determines the mean transient channel response under stochastic controls. The method is based on distinguishing modes (i.e., sets of controls) and takes the probability density of each mode into account. At each time step, we compute the mode‐specific flow, sediment transport rate, and corresponding change in bed level and surface texture. The net change within the time step is computed by weighting the mode‐specific changes in bed level and surface texture with the probability density of each mode. The resulting mean transient channel response is a deterministic one, despite the controls being stochastic variables. We show that the proposed method provides a rapid alternative to Monte Carlo analysis regarding the mean time‐dependent channel response.

Investigation of single particle devolatilization in fluidized bed reactors by X-ray imaging techniques

A non-intrusive X-ray imaging technique has been used to investigate the behaviour of solid feedstock particles in a lab-scale fluidized bed reactor operated at temperatures up to 650 °C. Beech wood and polypropylene particles of different sizes have been chosen to represent the main constituents of typical thermochemical processes feedstock. The experiments were conducted under either oxidizing or inert conditions. The presence of oxygen showed a strong effect on the overall devolatilization time, which was found to be in the range of 30–112 s and 40–174 s for beech wood and polypropylene, respectively. Surprisingly, the oxidizing nature of the fluidizing medium appears to have no influence on the volatiles release within the bed in form of the so-called endogenous bubbles. These volatiles bubbles are responsible for a lift force acting on the feedstock particle itself, which ultimately encourages the segregation towards the bed surface. A one-dimensional physical model has been developed to predict particle axial location over time, taking into account both dynamic and thermal conversion behaviour of a single feedstock particle. A revised version of the model has been proposed due to new knowledge of endogenous bubbles size provided by a novel X-ray imaging approach. Results showed very accurate predictions of the 1D model for biomass particles, which segregate towards the bed surface according to the multiple bubble segregation pattern. However, the model fails in describing plastics behaviour, possibly due to different mechanisms of reactions. The observations reported in this work show the importance of investigation at single particle level and may serve to promote new methods to gain a better understanding of plastics thermal decomposition in fluidized beds, whose mechanism is still uncertain.

Methane emissions from lake Onego sediments

We studied the methane content in Lake Onego bottom sediments and bottom water and revealed a wide variation of its concentrations among different parts of the lake. Methane concentrations were the highest in the pockmarked area of Petrozavodsk Bay, where hydrocarbon gases rise to the lake bed surface from the depth. Methane emissions from Lake Onego sediments were estimated. We show that in addition to the geological and geomorphological characteristics of the basin, the flux rate depends on how the lake sediments are forming under the uneven human pressure and climate oscillations of today.

Carnauba (copernicia prunifera) straw as an alternative bedding material for dairy cows housed in a Compost barn system

ABSTRACT The replacement of bedding in compost dairy barns (CB) comprises a recurrent management practice, but bedding materials are often not readily available in all regions and the choice of alternative materials is necessary. The objective was to evaluate the thermal attributes of carnauba straw (CS) bedding in compost dairy barn facilities. Environmental monitoring operations were performed at a commercial farm located in Northeast Brazil. Mini weather stations were used to evaluate environmental variables. The THI was evaluated as one of the comfort parameters. Analysis of the spatial distribution of bed surface temperature (BST) in the CB was performed using geostatistical techniques. The cows remained out of the comfort zone according to THI results. The BST indicated satisfactory performance and from the thermal point of view can be used as alternative bedding material in CB facilities. However, it was observed that the CS showed fast biomass degradation compared to conventional materials, widely known. In addition, inadequate temperature values (&lt; 45°C) were found in the deeper of the CS bed, signaling higher risks of pathogenic microbial activity. Additional studies are needed for searching the proper management plans that increase the life span of the bed formed by carnauba straw.

Experimental insights into the effect of event sequencing and sediment input texture on step‐pool channel evolution

AbstractWe conducted flume experiments in a step‐pool channel with different sediment supply regimes to explore how the sequencing and the grain‐size of sediment pulses affect channel evolution. Our results show that the sequencing of events is not a primary control as the trends in flow characteristics, bedload transport, sediment storage, step evolution, and step frequency were similar in feed phases with different sequencing of sediment pulses. Channel adjustment and step stability in a short timescale (i.e., in a 4‐h run) were mostly controlled by the magnitude and frequency of sediment pulses. A coarser sediment feed mixture led to a coarser bed surface which increased both sediment storage in the channel and step stability. Our experiments show that channel evolution in a step‐pool channel is primarily controlled by the magnitude and frequency of sediment pulses and the grain size of sediment supply rather than the event sequencing of sediment pulses.

Response of the gravel–sand transition in the Yangtze River to hydrological and sediment regime changes after upstream damming

AbstractIn the Yangtze River, the Three Gorges Dam (TGD) has altered the flow‐sediment regimes, resulting in channel degradation and bed surface coarsening, which have been reported in recent years. However, there has been no systematic study on the impacts of the TGD on the downstream gravel–sand transition (GST). Based on detailed field observations and numerical modelling, this study fills this gap and reveals significant adjustments in the GST and the leading causes. The results show that after operation of the TGD began, the GST migrated 49.5 km downstream during 2003–2010 due to a reduction in the suspended‐load supply (grain size &lt; 0.5 mm) and then remained stable from 2010 to 2015 under the control of a braided river morphology. In addition, as channel degradation continued, the steepening bed profile upstream of Chenjiawan and the lowering of the downstream water level caused some gravel within the GST to become more frequently mobile during low‐flow periods (discharge &lt;15,000 m3/s). Combined with the effects of the TGD‐induced prolonged low‐flow season and reduced frequency of large floods (discharge ≥ 40,000 m3/s), the GST exhibited a poorly understood phenomenon in which gravel was mainly transported downstream during low‐flow periods. However, these processes affected only localized sediment movement, contributing little to overall GST migration in the Yangtze River. The results also show that when a low sediment supply persists long term, additional GST migration after transient downstream migration depends primarily on the river morphology. This article has implications for the channel regulation and evolutionary processes of GSTs below dams.

Numerical Simulation of Adsorption and Heat Transfer in Porous Media Using Lattice Boltzmann Method

An adsorption model for fluid flow, heat, and mass transfer of the adsorbent bed was established. Based on the single relaxation time lattice Boltzmann method, a dual-distributed lattice Boltzmann model of density and concentration was established to solve the fluid flow and mass transfer process in the surface area of the adsorbent bed. The adsorption and heat transfer process on the surface of the adsorbent bed was incorporated into the dual-distributed lattice Boltzmann model by the fourth-order Runge-Kutta finite difference method. The multiphysics fields under Poiseuille flow were simulated by the presented model, and the adsorption capacity and temperature distribution during the adsorption process were investigated.

Differences of turbulence modulation by heavy particles on solid wall and erodible bed surface

In this paper, wall-resolved large-eddy simulation of turbulence, Lagrangian point-force model of particle tracking, and two-way coupling approach are used to simulate the particle-laden flow over a rigid wall. The flow is a turbulent open channel flow with the particle-free friction Reynolds number of Reτ=4200. Together with the simulated results over an erodible bed from Zheng et al. [J. Fluid Mech. 918, 1–27 (2021)], the influence of the lower boundary condition of particle motion with the wall-normal gravity on turbulence modulation is thoroughly compared. It is found that high-inertia (St+=244.5) particles studied in this work moving over a rigid wall increase the mean fluid velocity and the scales of turbulence structures away from the wall, suppress turbulence fluctuations and Reynolds stress, and reduce the scales of turbulence structures near the wall as compared with the particle-free flow. Gravitational settling of particles accounts for most of the changes, and the crossing trajectory caused by particles bouncing near the rigid wall is responsible for the reduction of the scales of the near-wall turbulence structures. On the contrary, the splashing process of particles over the erodible bed leads to the decrease in the mean fluid velocity, the anisotropic variation of turbulent kinetic energy, the shrink of the outer turbulence structure, and the enlargement of the near-wall streaks. The results reveal the significance of the near-wall particle motion (rebound or splashing) on turbulence modulation.

Experimental Study on the Near-Bed Flow Characteristics of Alluvial Channel with Seepage

This paper aims to analyze the turbulent structure of flows over beds undergoing downward seepage under clear-water conditions. Laboratory experiments in this regard were carried out in a straight rectangular channel that was 17.20 m long and 1.00 m wide. A sandy bed with median grain size d50 = 0.50 mm and sediment gradation σg = 1.65 (i.e., slightly non-uniform sediment) was used for the channel bed. The 3D instantaneous velocities of water were measured with an Acoustic Doppler Velocimeter (ADV) at the working test section. In the vicinity of the bed surface with seepage, measurements revealed that the flow longitudinal velocities (i.e., velocities in x direction) were higher than those in the case of a bed without seepage. Moreover, the variations inthe Reynolds shear stresses increased for the bed with seepage, indicating a higher exchange of flow energy towards the boundary and vice versa. Therefore, it was found that seepage processes influence the turbulence intensity, with a prominent magnitude in the streamwise and vertical directions. The paper also focuses on the third-order moment (skewness) and the kurtosis of velocity fluctuations and the governance of sweep events within the near-bed flow in cases where seepage was observed.

Critical Shear Stress for Erosion of Sand-Mud Mixtures and Pure Mud

The erosion threshold of sand-mud mixtures is investigated by analyzing the momentum balance of a sand particle or a mud parcel in the mixture bed surface, and a formula for the critical shear stress of sand-mud mixtures is developed, which also applies for pure sand and mud. The developed formula suggests that the variation of the critical shear stress of sand-mud mixtures over mud content is mainly caused by the varying dry bulk density of the mud component in the mixture. The developed formula reproduces well the variation of the critical shear stress of sand-mud mixtures over mud content and can predict the critical shear stress of both sand-mud mixtures and pure mud in the process of consolidation. The developed formula promises to be convenient for application by relating the critical shear stress to mud content and the dry bulk density of sediment.