Limestone Beds Research Articles

Bedding and bedding surfaces in carbonate and mixed carbonate-siliciclastic successions Part 2: processes, identification and implications of diagenetic bedding

Bedding and bedding surfaces in carbonate and mixed siliciclastic-carbonate successions can be diagenetic, not depositional in origin and require interrogation to determine their true origins. This study reviews the different models and implications associated with diagenetic bedding and diagenetic bedding surfaces in such successions. Weathering, especially where strong lithological and mechanical differences occur, can make distinguishing primary and diagenetic bedding more difficult, and criteria are reviewed. Early, shallow diagenetic processes linked to mineral instability of aragonite, mediated by biochemical processes, are capable of producing bedding and bedding surfaces. Zones of early cementation within sediments can produce discrete beds and surfaces exemplified in the formation of limestone-marl alternations (LMAs). Variations in the degree of early cementation (stratified cementation in sense of Bathurst, 1987) in shallow buried argillaceous carbonate sediments, affected by later compaction can produce layering with beds showing little compaction separated by highly compacted, argillaceous fissile interbeds which develop bedding surfaces within those fissile units (“couplets” of Bathurst, 1987). Where such diagenetic limestone beds form intrastratally, as in LMAs, they do not obey the Principle of Superposition, and by virtue of never having been deposited laterally adjacent to their associated deposits, do not comply with Walther's Law of Facies. Bedding surfaces associated with LMAs only become true surfaces when exhumed to produce some types of firmgrounds and hardgrounds.

Middle Paleocene to early Eocene sedimentological evolution of the central-eastern Sirt Basin (Libya): biostratigraphy and depositional environment

AbstractThe depositional history of the central-eastern Sirt Basin of Libya during the Middle Paleocene to Early Eocene is characterised by the deposition of shallow-marine carbonates and hemipelagic claystone and marlstone. To gain a better understanding of the depositional history during this period, we dated the hemipelagic marlstones using planktonic foraminifera and calcareous nannoplankton to refine the stratigraphic relationships with the intercalated shallow-marine limestones. During the Danian, a broad carbonate shelf formed in the eastern sector of the basin. Transgression in the Early Selandian resulted in the deposition of claystones and limestones. The shallow-marine carbonate factory recovered rapidly during the Early-Middle Selandian, forming the Upper Sabil carbonate ramp, however, it became subaerially exposed and eroded in the shallowest areas. The resulting domal structures represent carbonate ramp erosional relics as demonstrated by biostratigraphic results combined with microfacies studies. Whereas in the deeper-water areas of the Upper Sabil carbonate ramp, the deposition was probably continuous throughout the Paleocene–Eocene, the shallow-marine limestones were exposed for about 6 Ma until they were drowned in the Early Eocene. A distinct argillaceous unit, with intercalated shallow-marine limestone beds, was deposited in the basinal areas between the domal structures during the Late Selandian–Thanetian stages. In this study, we define this deposits as the Intisar Formation. The overlying Late Paleocene/Eocene Harash Formation consists of shallow-marine limestones. This trangressive unit infilled the Upper Sabil paleotopography with a 2.5 Ma stratigraphic gap. The hemipelagic marlstone of the Kheir Formation was deposited above the Harash Formation and partly above the Upper Sabil paleotopography during the Ypresian, driven by the major sea-level rise following the Eocene Thermal Maximum-2 (ETM-2). Therefore, a substantial stratigraphic gap of at least 6 Ma is documented on the crest of the domal structures, which were subsequently overlain by the Kheir Formation. Graphical abstract

Structural and Karst Studies Using 3D Digital Outcrop Model: A Case Study in Gunung Keriang, Kedah, Peninsular Malaysia

A digital outcrop model (DOM) of the Permo-Triassic limestone of Gunung Keriang, Kedah, was constructed for structural analysis and karst study. Structural analysis of beddings and fractures within the DOM revealed that the limestone beds are characterized by gently inclined planes with NE ̶ SW and NW ̶ SE strikes, forming an upright N ̶ S trending synclinal fold, and being cross-cut by four steeply-dipping fracture sets (NE ̶ SW, NW ̶ SE, N ̶ S, and E ̶ W). The synthesis of these fracture sets indicates that the NW ̶ SE and NE ̶ SW fractures form a conjugate pattern suggestive of E ̶ W shortening, which aligns with the observed N ̶ S fold. Karst development, including elongated sinkholes and cave paths oriented in the NE ̶ SW direction, correlates with the fracture patterns, highlighting the NE ̶SW fracture network significant role in karst formation. The integrated data supports the hypothesis that these fracture patterns are major factors in the dissolution and development of karst features in the region.

Mineralogical and geochemical studies of shales from Kopili Formation, Dima Hasao district Assam, North East India: Insights into diagenesis, deposition and provenance

The Eocene Kopili Formation in the Assam foreland basin records sediment sources, tectonic activity and depositional environments following the India-Eurasia collision. Mineralogical and geochemical analysis of these shales exposed near Garampani, Assam, NE India was conducted to study the diagenesis, palaeoweathering, palaeosalinity, redox conditions, tectonic settings and provenance. The Kopili Formation is composed of mainly shale with thin beds of limestone, black shale and sandstone and these units overlie the Upper Sylhet Limestone. The presence of goethite-rich phosphatic nodules, secondary precipitation within the fissile planes of shale and the occurrence of anatase, talc, smectite and chlorite suggest diagenesis. The prevalence of kaolinite and mean Chemical Index of Alteration (CIA), Chemical Index of Weathering (CIW), Al2O3/MgO and Rb/Sr values of 86.73, 97.26, 16.36 and 1.32, respectively indicates extensive source rock weathering in humid tropical climate. The Index of Compositional Variation (ICV) values ranging between 0.47 and 2.38 also signify high weathering and tectonically active basin. The Sr/Ba ratio 0.34 ± 0.27 (mean±2σ) suggest overall freshwater basin. The Ni/Co (2.84 ± 2.29), V/Cr (1.65 ± 0.45) and Ce/Ce∗ (0.97 ± 0.63) suggest fluctuating redox environment. The samples predominantly cluster in continental island arc domain on the Th-Sc-Zr/10, La-Th-Sc and Th-Co-Zr/10 discriminant diagrams. Elemental ratios of Th/Sc, La/Sc, Cr/Th with average 0.91, 3.18, 10.13 respectively and La/Th-Hf plot suggest a felsic source rock. The Kopili shale was deposited in freshwater, continental island arc basin with fluctuating redox conditions, receiving sediments from weathered Himalayan granites and gneisses under a warm and humid climate. Subsequently, they underwent diagenetic alteration by low-pH fluid(s).

Integrated seismic, petrophysical, and geochemical studies for evaluating the petroleum system of the Upper Bahariya-Abu Roash G sequence in the Karama Field, Abu Gharadig Basin, North Western Desert, Egypt

The main aim of this study is to delineate the hydrocarbon potential and evaluate the petroleum system elements of the Cenomanian Abu Roash G (AR/G) and the Upper Bahariya Members in the Karama Field. It lies at the southeast borders of the Abu Gharadig Basin, a well-known basin in the W.D. to the NE of Africa. We accomplish this study by analyzing a total of thirty 2D seismic profiles, a complete data set of well logs for five wells, and their geochemical data. The workflow starts with illustrating the dominant subsurface structural features, defining the main potential reservoirs and their parameters, and checking the maturity of the probable source rocks. The seismic interpretation indicated that the research area had been influenced by a NE-SW anticlinal structure accompanied by a set of WNW-ESE and NW-SE normal faults that are controlled by the positive compression inversion process that dominated during the Late Cretaceous. Analyzing and processing the well log data sets suggest that the reservoirs of the Abu Roash G (AR/G) and the Upper Bahariya Members are characterized by poor to good reservoir settings with net-pay thickness reaching up to 13–50 feet in the different wells (av. Effective porosity (∅eff) = 17.7 % and 15.6% for the AR/G and the Upper Bahariya Members, av. Shale volume (Vsh) = 17.4 % and 13.6 %, av. Water saturation (Sw) = 38.9 % and 39.8 %, while av. Hydrocarbon saturation values (So) = 60.2 % and 61.1%, respectively). The geochemical and maturity analyses assisted in determining the potential mature source rocks of the Jurassic Khatatba Shale (TOC = 0.70–5.67%; S1+S2 = 0.43–5.97 mg/g, Ro = 0.54–1.06 %) with some contribution from the Cretaceous sources (Alam El-Bueib and Bahariya Formations). Studying elements of the petroleum regime of the Karama Field indicates that the trapped hydrocarbons are structurally controlled by three-way dip closures, horst blocks, sealing faults, and vertical sealing by impervious shale and limestone beds. This case study could be applied to similar analogs in other oil fields in the Egyptian Western Desert to delineate their hydrocarbon potential and structural setting.

Enhanced syngas production from wood biomass by the catalytic packed bed of dolomite, limestone and olivine

Wood biomass was a promising renewable energy source that achieved carbon neutrality and alleviated the energy crisis. To enhance the conversion efficiency of wood to hydrogen, the catalytic combustion system of natural ores (dolomite, limestone and olivine) and wood chips was established. And the effects of the type, location, calcination temperature, content and diameter of catalysts were investigated on the temperature distribution and gas production. The results indicated that the combustion temperature of the hybrid bed was significantly increased with the catalyst addition. The dolomite and limestone particles promoted the hydrogen production, and the mole fractions of hydrogen were improved by 75% and 42%, respectively. When the dolomite was located above the wood layer, the hydrogen fraction was greatly higher than that of mixing with the wood. As the dolomite content increased, both of the hydrogen mole fraction and release time were enlarged obviously. Furthermore, the wood chips and dolomite particles with smaller diameters contributed to syngas production. And the hydrogen decreased with the increasing of air velocity when dolomite addition, which achieved the maximum of 11.2% at the velocity of 2 cm/s.

Influence of thermal intrusion on the Alum Shale from south central Sweden

This study investigates the geochemical and petrological characteristics of solid bitumen in the DBH15/73 core from the Furongian (upper Cambrian) and Miaolingian (middle Cambrian) Alum Shale in Billingen, south central Sweden. At Billingen a > 30 m thick Permian diabase (dolerite sill) intruded approximately 100 m above the Alum Shale that promoting the formation of solid bitumen in the uppermost half of the Alum Shale due to enhanced heat flow. The bitumen has been classified into bituminite/diagenetic solid bitumen (DSB), initial-oil solid bitumen (IOSB), and primary-oil solid bitumen (POSB) based on their genesis, morphology and random solid bitumen reflectance (BRo). The Miaolingian shale, constituting the lower part of the Alum Shale, is immature and contains solely bituminite and DSB, with measured BRo ranging from 0.40% to 0.48%. In contrast, the Furongian shale exhibits enrichment in IOSB and POSB and range from marginally mature to peak oil generation with towards the top of the section. Characteristics of uneven heating is seen in the IOSB (BRo: 0.97–1.08%) including oxidation rims and abnormally high maturity surrounding fractures. The POSB (BRo: 0.63–2.01%) is present not only in the Alum Shale but also in the overlying Ordovician Latorp limestone and the underlying Kakeled Limestone Bed, and shows flow structures which is further evidence for migration. The abundance of POSB and IOSB is determined through maceral point counting, revealing POSB as the dominant bitumen type (1.54–7.13 vol%), while IOSB constitutes the minority (0.05–0.31 vol%) within the Furongian shale. This distribution suggests rapid thermal evolution of organic matter within the oil generation window. Additionally, a reduction in free hydrocarbons (Rock-Eval S1), potential hydrocarbons (Rock-Eval S2), and unexpectedly low Tmax was observed in the Furongian shale. Results indicate that hydrocarbon generation resulting from thermal intrusion contributes to the relatively low S2. Migration of POSB and generated oil to adjacent layers leads to the loss of S1, while the reduced Tmax may be attributed to high uranium content which weakens carbon chain bond energy. These anomalies result in an underestimation when evaluating thermal maturity and kerogen type conversion based on Rock Eval data alone.

Sedimentology and biostratigraphy of the Biancone Limestone Formation of the Tolmin Basin (Southern Alps, NW Slovenia)

The Tolmin Basin constitutes the western part of the Slovenian Basin, a large Mesozoic interplatform basin that was bounded to the north by the Julian Carbonate Platform and to the south by the Dinaric Carbonate Platform. Today, it is found along the structural boundary between the Southern Alps and the External Dinarides in northwestern Slovenia. After the drowning of the Julian Carbonate Platform, the Tolmin Basin was dominated by pelagic deposits, namely the Toarcian marlstones (Perbla Formation), the Aalenian to lower Tithonian siliceous limestones and radiolarites (Tolmin Formation), and the upper Tithonian to the Berriasian Biancone Limestone Formation. In this study, a basin-scale sedimentary evolution and calpionellid biostratigraphy of the latter is presented. The Biancone Limestone Formation is a calpionellid-bearing pelagic limestone typical of all deepened segments of the Adria microplate in this time interval. It is generally monotonous but shows considerable vertical and lateral variations. The lower boundary with radiolarites is sharp, revealing a pronounced and rapid overturn in pelagic sedimentation. The lower Berriasian slumps indicate a tectonic pulse. Rare beds of resedimented limestones, assigned to the middle Berriasian, are similar in composition to those intercalated in the underlying radiolarites. They thus show that the factors that led to a significant shift in pelagic sedimentation had little or no effect on shallow-marine carbonate production. In the upper Berriasian, an increase in clay content is evident in the formation, which is explained by the uplift and erosion of the propagating thrust belt in the Neotethys area, superimposed by humidification.

Cretaceous Limestone Dolomitization and Argument of Its Mg2+ Sources: Exampling the Bekhme and Qamchuqa Formations in the Zagros Collision Belt

This study unveils new considerations regarding the dolomitization of the Bekhme and Qamchuqa formations (BQFs), two reefal Cretaceous units in the Iraqi Zagros collisional belt. Previous studies proposed the dolomitization of these formations due to the ascent of Mg-rich hydrothermal solutions through deep faults but lacked substantial supporting evidence. This paper present new considerations suggesting that the dolomitization of the BQFs resulted from the Cretaceous environmental conditions and basin paleogeographic setting of the platform on which these formations were deposited. To justify this consideration, seven proofs presented. First is the occurrence of dolomite as vast layers extending tens of kilometers laterally and bounded between limestone beds, which resemble a strata-bound occurrence. Second is the absence of vertical selective dolomitization such as, hydrothermal mineralization, vertical dolomite dykes, hydrothermal vents, tubes, or zones. Third is the barrenness of most of the fault surfaces and their surrounding rocks with selective dolomitization. Fourth is the sharp boundary between the dolomite and limestone layers, indicating a sudden environmental change from lagoon to reef or forereef. Fifth is the record of dolomitization in the sediments reworked by bioturbation, evident in thalassinoides burrows. Sixth is the succession of BQFs underlain by limestone and green marl devoid of dolomitization and hydrothermal upward movement. Seventh is the contradictory notion of hydrothermal dolomitization among the most recent study published in the Science journal which atributed dolomitization to normal temperate on earth surface. In the present study, the source of the Mg is argued and its presence is attributed to the warmth of the Arabian platform (plate) near the equator during the Cretaceous period. Another source is the connection of the Arabian platform with the Neo-Tethys Sea, which was the locus of Mg-rich mafic volcanism in the form of arcs and mid-oceanic ridge topography, which supplied a voluminous amount of Mg to the Arabian carbonate platform through ocean currents.

The Miocene lacustrine carbonate factory of the Ñirihuau Formation, Ñirihuau Basin, North Patagonian Andes, Argentina

AbstractFacies, microfacies and stable isotope analyses of limestone beds in the northernmost Ñirihuau Basin, North Patagonian Andes, Argentina, document and constrain the past hydrological, sedimentological and climate conditions that prevailed during the deposition of a lacustrine system between ca 15 and 13 Ma. This palaeoenvironment is recorded in the middle section of the Ñirihuau Formation, which holds significance because: (1) It was deposited during a transition from an extensional to a compressional tectonic regime; (2) it spans the Middle Miocene Climatic Optimum and the beginning of the Middle Miocene Climatic Transition; and (3) it contains limestone beds interbedded within a 600 m thick interval of mudstones and siltstones, along with intercalated sandstone and volcaniclastic bodies. Two detailed sedimentary logs were surveyed along the Arroyo Las Bayas, at the western and eastern flank of the David Syncline. Limestones from both stratigraphic sections were sampled as well as isolated limestone beds from two other sites. One facies association was defined and interpreted as a perennial lake associated with a deltaic system and dominated by detrital clastic material. It comprises Facies 1 (Marginal lacustrine) and Facies 2 (Lower delta plain); in both, the presence of grainstones and calcimudstones stands out. Through petrography and cathodoluminescence studies of these continental carbonates, nine microfacies were identified: (a) Intraclastic grainstone, (b) Homogeneous calcimudstone, (c) Silty grainstone, (d) Disrupted micrite, (e) Birds eye micrite, (f) Bioclastic mudstone, (g) Calcimudstone with sparse detrital grains, (h) Fenestral micrite, (i) Stromatolitic boundstone. These indicate mainly bio‐induced subaqueous carbonate precipitation and subordinate deposition by tractive flows with short‐distance transport on a littoral lacustrine environment. Most of these microfacies exhibit very early diagenesis (eogenesis) effects. These features, and the geochemistry results, indicate that they were deposited in a palaeolake system under temperate to warm and humid conditions.

Origin and significance of macroscopic organic aggregates from the lacustrine Aptian Crato Konservat-Lagerstätte

The Crato Konservat-Lagerstätte is one of the main Mesozoic fossil sites from Gondwana, recording a wide diversity of terrestrial and non-marine aquatic fossils of great paleobiological and evolutionary significance. This conservation deposit is recorded in a 9 m-thick interval of laminite, microbialite, and grainstone deposited in a lake system with variable water level, alternating moments of hypersaline and freshwater conditions. Despite numerous studies describing new species of plants, arthropods, fish, pterosaurs, birds, and many others, there remains a significant gap in our understanding of the most common and archetypal fossils, which are the rod-shaped macrofossils found on bedding surfaces in distinct stratigraphic intervals of the Crato Konservat-Lagerstätte. The rod-shaped macrofossils are up to 1.6 cm-long and 0.1 cm-wide, straight to curved compressions that preserve pyritized microfossils. Here we interpret the rod-shaped macrofossils as macroscopic organic aggregates that sank into the lakebed in a process called lake snow. During high organic productivity periods in the epilimnion, planktonic organisms thrived and produced exopolymers responsible for aggregation. Their concentrations in the limestone bedding planes reflect intensity of lake snow and environmental seasonality. Aggregates are prolate particles that are commonly oriented, suggesting their transport as bedload for short distances, which was facilitated by biostabilization by microbes and their exopolymers. Finally, pyritization was mediated by microbial communities living in the lakebed.

PENNSYLVANIAN CONODONTS AND MICROFACIES FROM NORTHEASTERN MEXICO (TAMATÁN GROUP, CIUDAD VICTORIA BLOCK)

The biostratigraphic analysis of the Paleozoic sedimentary successions in Mexico is crucial for understanding their age, depositional setting, and paleogeographic implications. This study examined conodonts and microfacies of calcareous strata within the Del Monte Formation of the Tamatán Group in northeastern Mexico. Field observations have led to the identification of three units within the Del Monte Formation: Unit 1, characterized by calcareous sandstone, bioclastic limestone, shale, occasional conglomerate, and dolomitized beds; Unit 2, consisting of conglomerate and/or breccia associated with debris flows; and Unit 3 including turbiditic sandstone and shale. Conodonts were only recognized in Unit 1, with such genera as Idiognathoides, Neognathodus, Idiognathodus and less frequently, Streptognathodus, Adetognathus, and Diplognathodus. The faunal associations include Idiognathoides cf. Id. corrugatus Harris & Hollingsworth, 1933, Idiognathoides sulcatus sulcatus Higgins & Bouckaert, 1968, Idiognathoides convexus (Ellison & Graves, 1941), Idiognathoides asiaticus Nigmadganov & Nemyrovskaya, 1992, Neognathodus cf. N. atokaensis Grayson, 1984, Neognathodus aff. bothrops Merrill, 1972, Neognathodus nataliae Alekseev & Gerelzezeg, 2001 (in Alekseev & Goreva 2001), Streptognathodus parvus Dunn, 1966, Idiognathodus incurvus Dunn, 1966, and Idiognathodus aff. delicatus Gunnell, 1931, suggesting Morrowan and Atokan (Pennsylvanian) ages for the dolomitic limestone and grainstone beds. Five types of microfacies (MF) and several marine facies zone (FZ) have been detected: MF1-bioclastic grainstone and MF2-wackestone deposited at the platform margin (FZ 6 and FZ 7), MF3-dolomitized wackestone representing an inner restricted platform (FZ 8), MF4-mudstone from a deeper water zone (FZ 4), and MF5-siliciclastic beds with bioclasts indicating a high-energy barrier associated with a platform margin (FZ 6). The findings confirm a shallow to deep platform and imply a connection among Mexican peri-Gondwanan basins, including the Tamatán Basin, indicating similarities in sedimentary facies and/or depositional environments linked to the Rheic Ocean during the Early to Middle Pennsylvanian.

Seismic-aseismic impact on marine depositional dynamics and sedimentary architecture: Study on multilayer-multiscale SSDS in Proterozoic Rohtas Limestone, India

The present study explores a diverse suite of soft-sediment deformation structures (SSDSs) preserved at multiple levels within the Mesoproterozoic carbonate succession of Rohtas Limestone in the Vindhyan Supergroup of India. The carbonate succession shows lithological heterogeneity, characterized by a sharp change of facies association and depositional environment. Three layers of SSDS, traced over 57 km, demarcate the lower lagoonal from upper open shelf deposits. Contorted laminae, load casts and flame structures, convolute laminae, ball and pillow structures, accordion folds and pillar structures within the limestone beds infer liquefaction-fluidization and plastic deformation. The lateral continuity, vertical repetition and confinement of SSDS beds at the interface of lagoon and open shelf deposits indicate the role of seismicity on facies succession. The SSDS beds show lateral variation in thickness and structures, depending on the distance from epicenter. The seismic trigger was accompanied by sudden deepening of the depositional environment and related marine transgression. The coarsening up packages within the lagoonal succession comprise load cast and flame structures, syn-sedimentary faults and intraclastic conglomerates. The open shelf succession shows several fining up cycles, with multiple load and flame structures with intraclastic conglomerate at the top. Origin of SSDS in association of the coarsening up sequence, and fining up cycle infers that intrabasinal tectonics and storms were the triggering agents for lagoon and open shelf successions respectively. The seismite in the studied succession not only reveals the seismicity during the Proterozoic, but also changed the sedimentary facies association, which may use as a diagnostic criterion for the identification of seismite. This study also highlights that seismic and aseismic impacts on sedimentary architecture and paleoceanography evolution.

Geochemistry of Brown Detrital Limestone BedswWithin Sarmord Formation, Sulaimani, Kurdistan Region, Iraq: Implication for Depositional Environment, Provenance and Tectonic Setting

Fifteen samples of brown detrital limestone beds within the Sarmord Formation from the Imbricated Zone (Qaiwan and Barzinjah sections) and High Folded Zone (Zewe section), Kurdistan region, NE-Iraq were analyzed. The analysis includes the major oxides, trace elements, and rare earth elements (REEs) to find out their provenance, tectonic setting, and depositional environment. These beds are mainly composed of detrital limestone in which calcite and traces of quartz are confirmed by XRD and the microscopic study. Al2O3/TiO2, La/Sc, La/Co, Th/Sc, Cr/Th and Th/Cr ratios and {(TiO2 + V2O3) - (MgO/ (MgO + Al2O3)}, (TiO2 - Ni), (La/Th - Hf), (La/Sc - Co/Th) diagrams reveal sourcing from the mixed carbonate platform and felsic rocks. The ratios of major, trace, and REE with PAAS values fall within the range of felsic rocks, which agree with Cretaceous western Iraq (present Western Desert) as a source of these beds. The (Rb – Sr – Ba) ternary diagram and (Sr/Ba-Sr/Rb) diagram display the distribution of the samples between the continental margin and inland field. Tectonically, these detrital limestones are transported from the erosion of the interior of the Arabian platform into deep marine and interbedded with the green marl. The V/Cr, U/Th, Ni/Co, and Sr/Ca ratios and diagram of Al2O3-V indicate deposition under shallow marine oxic to the dysoxic environment and transported to the deep marine. The paleoclimate index C-value, Sr/Cu ratio, and SiO2 - (Al2O3 + K2O + Na2O) diagram indicates hot arid conditions. Paleosalinity ratios Rb/K and Sr/Ba imply brackish to marine water conditions.

Ichnological response to the Middle Eocene Climatic Optimum (MECO) in the Bartonian deposits of Kutch Basin, India

The Middle Eocene Climatic Optimum (MECO) represents a short-lived interval of global warming that disrupted the long-term cooling episode extending from the middle to late Eocene time. Biostratigraphically the MECO corresponds to the upper interval of planktic foraminiferal zones E11–E12 and the shallow benthic zone 17. Both the planktic and benthic foraminiferal zones are well-documented within the Bartonian mixed siliciclastic‑carbonate sequence of the Kutch Basin in western India. This case study aims to investigate the impact of MECO on the endobenthic community using ichnology as a proxy. The studied sequence comprises the underlying Harudi Formation, consisting of the marine green and grey shale and bioclastic limestone beds, and the overlying Fulra Limestone characterized by benthic foraminifera-rich limestones. The Harudi Formation is bereft of trace fossils except in one bioturbated firmground and two bioeroded hardground horizons. The MECO corresponds to the thin carbonate packstone, the middle green shale, and the Nummulites obtusus rudstone occurring at the middle to upper part of the Harudi succession, established earlier by a concurrent negative δ13Corg isotopic excursion. The shelly limestone or bivalve coquina bed deposited immediately prior to the beginning of the MECO consists of a monospecific firmground ichnofabric characterized by Balanoglossites triadicus. Out of two bioeroded beds, the lower one coincides with the earliest MECO interval and is marked by a brown carbonate hardground colonized with two ichnospecies of Gastrochaenolites. The upper bioeroded horizon corresponding to the end of the MECO is characterized by a series of top- and side-bioeroded (with Gastrochaenolites, Entobia, and Oichnus) carbonate nodules containing multigenerational septarian cracks. The upper hardground demarcates the top of the Nummulites obtusus coquina bed and the starkest basin-wide sediment starvation, making it a major condensed horizon that developed following a steady glacio-eustatic rise during the warming event. The MECO prompted the subsequent deposition of shallow-marine platform carbonates of the Fulra Limestone by accelerating a sharp rise in the sea-level and proliferation of diverse Larger Benthic Foraminifera in a warm oligotrophic seawater.

Lower Devonian vertebrate microfossils from Turkey

A small sample of vertebrate fish scales, predominantly those of a thelodont agnathan, the turiniid Turinia sp. cf. T. nachoi, and a few from the acanthodian gnathostome Nostovicina laticristata, have been found in the Lower Devonian Güneyyaka Formation in the Ovacik slice of the Tahtalidağ Nappe north of Alanya (Antalya Unit) in the Antalya region, southwest Anatolia, southern Turkey. The area is considered to have been on the northern Gondwana margin at that time. The fish microfossils support a Lochkovian to possible early Pragian at youngest (Early Devonian) age for the limestone beds, and are amongst the oldest known Turkish vertebrate fossils. Yakut Göncüoglu [yigtjpc@gmail.com], Kafkas Sitesi 2481. Sok. No 65 Umitköy-Ankara, Turkey; Carole J. Burrow [carole.burrow@gmail.com], Queensland Museum Geosciences, 122 Gerler Road, Hendra Queensland 4011, Australia; Susan Turner [paleodeadfish@yahoo.com], Queensland Museum Geosciences, 122 Gerler Road, Hendra Queensland 4011, Australia; Philippe Janvier [philippe.janvier@mnhn.fr], Muséum national d’Histoire naturelle, 75005 Paris, France; M. Cemal Göncüoglu [mcgoncu@metu.edu.tr], Middle East Technical University (METU), Department of Geological Engineering, 06531 Ankara, Turkey.

Microfacies analysis and depositional environment of Shiranish Formation in Selected Sections, Kurdistan Region, NE Iraq

Shiranish Formation in both Smaquli and Rawanduz sections is composed of an alternation of marly limestones, limestone and marl beds with fissile shale beds. Depend on color, lithology and other sedimentological criteria during field observations of the studied sections, the Shiranish Formation is divided lithologically into lower, middle and upper units. Planktonic Foraminiferal Lime Mudstone Microfacies (Shf1), Lime Wackestone (Shf2) and Planktonic Foraminiferal Lime Packstone Microfacies (Shf3) have been defined as three distinct microfacies with four submicrofacies ((Keeled Planktonic Foraminiferal Lime Wackestone submicrofacies (Shf2b), Globular Chamber Planktonic Foraminiferal Lime Wackestone submicrofacies (Shf2a), Bioclastic Lime Wackestone submicrofacies (Shf2c), Planktonic Foraminiferal Lime Wackestone submicrofacies (Shf2d)). The major microfacies in both sections was lime wackestone which is dominated in middle and upper units in both sections. Sedimentological and paleontological evidences suggest that the Formation was deposited in the outer shelf setting and progressed to the upper bathyal setting, in addition to that the microfacies changed from packstone to mudstone meaning deeping upward sequence.

A Pliocene lacustrine system in the Nellis basin, southern Nevada, USA: implications for the Colorado River drainage system

ABSTRACT Lacustrine basins and the sediments in them provide a critical component of regional tectonic development and climate history. Each sub-basin in the landscape records the interplay between active tectonism and shifting climate. Many of the basins in southern Nevada that contain deposits of the Muddy Creek Formation were closed fluvio-lacustrine systems during the latest Miocene and into the Pliocene. They were subsequently integrated into the regional Colorado River system. Lacustrine deposits of the Muddy Creek Formation are exposed along the trace of the Las Vegas Valley shear zone in the Nellis Dunes Recreation Area (NDRA), northeast of Las Vegas, Nevada. The Muddy Creek Formation in NDRA consists of approximately 130 m of mixed carbonates and clastics, and new tephrochronology suggests an early to late Pliocene age (∼ 4.7 to ∼ 2.6 Ma) for the lowermost lacustrine deposits and an unknown, but younger, age for the uppermost spring-fed lacustrine deposit. These sediments were deposited in an arid to semiarid lake (Lake Nellis) and alluvial floodplain system based on the interpretation of lithologies and facies associations. The stratigraphic succession coarsens upward and reflects establishment of a lacustrine carbonate system overlain by a clastic succession of peripheral lake sediments of alluvial and floodplain origin. The peripheral lake deposits consist of spring-fed and fluvial wetland mudflats of brown claystone and siltstone. This brown claystone is capped by a succession of yellow and red sandstones deposited by fluvial and minor eolian processes. The second, and youngest, freshwater limestone, likely disconformably, overlies the yellow and red sandstones, and is thought to be temporally and depositionally distinct from the underlying Muddy Creek deposits. The transition from the lower lacustrine carbonates to clastic fluvial channel and flood-plain deposits indicates desiccation of Lake Nellis and possibly occurs soon after ∼ 2.7 to ∼ 2.6 Ma based on the ages of tuffs occurring in the uppermost limestone and marl beds. This is consistent with an interpreted increase in regional aridity after ∼ 2.8 Ma (Smith et al. 1993). The second limestone deposit at the top of the section represents an even younger spring-fed lacustrine deposit of unknown age. Throughout the lower carbonate section, three tuffs were identified, and geochemically correlated, using a discriminant-function analysis, to the tuff of Napa (≤ 4.70 ± 0.03 Ma), the Putah Tuff (∼ 3.3 Ma), and the lower tuffs of the Badlands (∼ 2.7 to ∼ 2.6 Ma). The timing of deposition of Lake Nellis sediments postdates the integration of the three major lake systems in this region (Lake Grand Wash, Lake Hualapai, and Lake Las Vegas) into the Colorado River drainage (5.6–4.9 Ma), and also postdates the full integration of the river to sea level (4.8–4.63 Ma) (Howard et al. 2015; Crow et al. 2021). Lake Nellis represents an isolated lake basin that was one, and maybe the last, lacustrine system to be fully integrated into the Colorado River drainage in this region.

A Comparative Analysis and Environmental Interpretation of the First Cycle of Nfayil Formation in Two Distinct Southern Desert Locations, Iraq

Nfayil Formation (Middle Miocene) is considered the equivalent of Fatha Formation; it is exposed in the western and southern Desert of Iraq with two members: a carbonate Lower Member that is composed of three cycles of limestone and marlstone intercalation and an Upper clastic Member of sandstone and claystone with thin layers of limestone. It extends from the western to the southern desert with a systematic succession of two or three cycles of lower members each one consisting of an interbedding of soft olive-green marl with medium tough shelly limestone rich with oyster shells. The upper member disappears in many localities due to erosion activity. From the field observation this succession was normally exposed in the southern Desert at the western parts of Al-Muthanna Governorate to the south of Dewaniyah Governorate, while in the eastern part of Al-Muthanna Governorate to the south of Al-Nasiriya Governorate, the beds showed a different lithology and fossil content. The olive-green marl turned to be rusty red with a higher content of fossils, the shelly limestone bed rich with oyster shells became red in colour, rusty and the oyster shells were substituted by pelecypods shells with the same concentration. A microfacies analysis study supported by chemical and X-ray analysis was carried out to predict the depositional environment and deposition circumstances in both sections. The thin section, chemical analysis and X-ray analysis were accomplished at the laboratories of the Iraq Geological Survey. Chemical analyses showed a high ratio of MgO oxide in Nasiriya section compare with Samawa section, that result was supported by X-ray analyses which refer to calcite mineral as the only mineral exists in Samawa beds wile in Nasiriya minerals of dolomite, quartz, feldspar and clay minerals were appeared.Environments extracted from thin section study showed more local fluctuations in sea level in Samawa section.

Upper Cambrian–Lower Ordovician conodonts from the southern margin of the Kopet-Dagh Basin, Saluk Mountains, Iran

A detailed Furongian to Tremadocian conodont biostratigraphy is established from the Saluk Mountains located in southern Kopet-Dagh, northeast Iran. Thirty species assigned to 17 genera were recovered from decimetre-scale limestone beds in a fine-grained siliciclastic succession, deposited in an intraplate rift system. The following biozones are established for the region, in ascending order: Proconodontus muelleri, Eoconodontus, Cordylodus intermedius, Cordylodus lindstromi, Cordylodus angulatus, Paltodus deltifer and Acodus triangularis interval zone. This low-to medium-richness conodont fauna comprises cosmopolitan euconodont species of Proconodontus, Eoconodontus, Cordylodus, Teridontus nakamurai, Semiacontiodus nogamii and a few long- ranging proto- and paraconodont species, which inhabited a narrow marine basin flanked by landmasses and formed by active rifting. It lacks shallow water tropical taxa and probably belongs to the Cold Domain of the Shallow Sea Realm. The occurrence of conodonts of the Paltodus deltifer Biozone in the uppermost part of the Qyzlar Formation in the Ghelli section suggests that the major episode of flood basalt volcanism in south Kopet-Dagh commenced in the late Tremadocian. Hadi Jahangir [Jahangir.hadi@nigpas.ac.cn] and Guanzhou Yan [gzyan@nigpas.ac.cn], State Key Laboratory of Palaeobiology and Stratigraphy, Nanjing Institute of Geology and Paleontology, Chinese Academy of Sciences, Nanjing 210008, PR China.