Renewable energy is well known for the extreme volatility of power production, and secondary battery-based energy storage systems (BESS) are the key to the novel and safe energy industry to expand the supply of renewable energy. Currently, lithium-ion battery-based ESS is commonly used, but the frequent ignition accidents from these ESSs rather become an obstacle to the growth of the renewable energy field. Among the redox batteries, the flowless zinc-bromine battery (FLZBB) is studied as the alternative since it uses a non-flammable and cost-effective aqueous Zn- Br2 electrolyte. However, its main challenges are that bromine (Br2) and polybromide anions (), formed at the positive electrode during the charging process, cross over to the negative electrode due to the difference in chemical potential between the electrodes. The diffused Br2 oxidizes the zinc metal, electrodeposited on the negative electrode, and causes a self-discharge reaction that consumes the charging active material and Br2 the battery performance and life. Herein, we present a nitrogen-doped mesoporous carbon coated on the pristine graphite felt fibers (NMC/GF). By uniformly forming a nitrogen-doped porous carbon material on the GF fibers through the evaporation-induced self-assembly (EISA) method, it is a simple and cost-effective method to develop the structural and properties of the GF positive electrode to increase the ability of adsorption and storing the active materials, Br2 and polybromide anions (,, and ) generated during the charging process. In addition, it also improved the bromine redox reaction kinetics by having a strong affinity with the aqueous Zn-Br2 electrolyte. This facilitates long-term charge/discharge cycles, enabling high performance and improved durability for Coulombic efficiency over 95% for 5000 cycles in the FLZBB single-cell platform at a current density of 20 mA cm-2 and a high-rate areal capacity of 2 mAh cm-2.