Abstract Hydrogen (H₂) and nitrogen (N₂) are both critical components in gasification processes, making efficient conversion of carbonaceous feedstocks into valuable gases with reduced environmental impact indispensable. This study demonstrates a state-of-the-art approach to predictive modeling for these quantities at high accuracy while allowing cost-effective solutions under a variety of operational conditions, enhancing safety, and enabling data-driven optimization. This work develops a new framework that incorporates the radial basis function model with two state-of-the-art optimization algorithms, namely the Zebra Optimization Algorithm (ZOA) and Flow Direction Algorithm (FDA), to enhance the predictive accuracy of gasification processes. This is a new frontier in optimizing the sustainable conversion of carbonaceous feedstocks, demonstrating the potential of data-driven methodologies in process efficiency and environmental sustainability. The RBFD model resulted in outstanding anticipation capability for H2, reaching an exceptional R 2 value of 0.997 during the whole period of testing. On the other hand, the RBZO framework proved to be the strongest predictor for N2 anticipation, presenting an outstanding R 2 of 0.994 during the testing and validation phases. The RBFD and RBZO frameworks showed significantly higher productivity compared to the conventional RBF model, as evidenced by accuracy metrics like MSE, RMSE, and WAPE.
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