Basin-wide Scale Research Articles

Assessment of the MODIS global evapotranspiration algorithm using eddy covariance measurements and hydrological modelling in the Rio Grande basin

Remote sensing is considered the most effective tool for estimating evapotranspiration (ET) over large spatial scales. Global terrestrial ET estimates over vegetated land surfaces are now operationally produced at 1-km spatial resolution using data from the Moderate Resolution Imaging Spectroradiometer (MODIS) and the MOD16 algorithm. To evaluate the accuracy of this product, ground-based measurements of energy fluxes obtained from eddy covariance sites installed in tropical biomes and from a hydrological model (MGB-IPH) were used to validate MOD16 products at local and regional scales. We examined the accuracy of the MOD16 algorithm at two sites in the Rio Grande basin, Brazil, one characterized by a sugar-cane plantation (USE), the other covered by natural savannah vegetation (PDG) for the year 2001. Inter-comparison between 8-day average MOD16 ET estimates and flux tower measurements yielded correlations of 0.78 to 0.81, with root mean square errors (RMSE) of 0.78 and 0.46 mm d-1, at PDG and USE, respectively. At the PDG site, the annual ET estimate derived by the MOD16 algorithm was 19% higher than the measured amount. For the average annual ET at the basin-wide scale (over an area of 145 000 km2), MOD16 estimates were 21% lower than those from the hydrological model MGB-IPH. Misclassification of land use and land cover was identified as the largest contributor to the error from the MOD16 algorithm. These estimates improve significantly when results are integrated into monthly or annual time intervals, suggesting that the algorithm has a potential for spatial and temporal monitoring of the ET process, continuously and systematically, through the use of remote sensing data.Editor D. Koutsoyiannis; Associate editor T. WagenerCitation Ruhoff, A.L., Paz, A.R., Aragao, L.E.O.C., Mu, Q., Malhi, Y., Collischonn, W., Rocha, H.R., and Running, S.W., 2013. Assessment of the MODIS global evapotranspiration algorithm using eddy covariance measurements and hydrological modelling in the Rio Grande basin. Hydrological Sciences Journal, 58 (8), 1658–1676.

Conjunctive Use of Surface Water and Groundwater: Application of Support Vector Machines (SVMs) and Genetic Algorithms

Combined simulation-optimization models have been widely used to address the management of water resources issues. This paper presents a simulation-optimization model for conjunctive use of surface water and groundwater at a basin-wide scale, the Zayandehrood river basin in west central Iran. In the Zayandehrood basin, in the past 10 years, a historical low rainfall in the head of the basin, combined with growing demand for water, has triggered great changes in water management at basin and irrigation system level. The conjunctive use model that coupled numerical simulation with nonlinear optimization is used to minimize shortages of water in meeting irrigation demands for four irrigation systems. Constraints guarantee the maximum/minimum cumulative groundwater drawdown and maximum capacity of irrigation systems. A support vector machines (SVMs) model is developed as a simulator of surface water and groundwater interaction model while a genetic algorithm (GA) is used as the optimization model. Conjunctive use model runs for three scenarios. Results show that the accuracy of SVMs as a simulator for surface water and groundwater interaction model is good and that it is possible to decrease the water shortage for irrigation systems with application of proposed SVMs-GA model.

Identification of rock weathering and environmental control in arid catchments (northern Xinjiang) of Central Asia

Chemical weathering is an integral part of the earth surface processes, whose spatial patterns and controlling factors on continental scale are still not fully understood. Highlands of the Asian continent have been shown having some of the highest observed rates of chemical weathering yet reported. However, the paucity of river gauge data in many of these terrains has limited determination of chemical weathering budget in a continental scale. A dataset of three large watersheds throughout northern Xinjiang in Central Asia is used to empirically identify chemical weathering regimes and interpret the underlying controlling factors. Detailed analysis of major ion ratios and a forward model of mass budget procedure are presented to distinguish the relative significances and contributions of silicate, carbonate weathering and evaporite dissolution. The analytical results show that carbonic acid is the most important weathering agent to the studied watersheds. Silicate weathering contributes, on average, ∼17.8% (molar basis) of total cations on a basin wide scale with an order of Zhungarer>Erlqis>Yili, indicating that silicate weathering, however, does not seem to be intense in the study basins. Evaporite dissolution, carbonate weathering and precipitation input contribute 43.6%, 29.7% and 8.9% of the total dissolved cations on average for the whole catchment, respectively. The three main morphological and hydrological units are reflected in water chemistry. Rivers from the montane areas (recharge area) of the three watersheds are very dilute, dominated by carbonate and silicate weathering, whereas the rivers of piedmont areas as well as the rivers of the sedimentary platform (runoff area) are dominated by carbonate weathering, and rivers of desert plain in the central Zhungarer basin (discharge area) are dominated by evaporite dissolution and are SO4 rich. This spatial pattern indicates that, beside lithology, runoff conditions have significant role on the regional chemical weathering regimes. Chemical weathering processes in the areas appear to be significantly climate controlled, displaying a tight correlation with runoff and aridity. Carbonate weathering are mostly influenced by runoff, which is higher in the mountainous part of the studied basins. The identification of chemical weathering regimes from our study confirmed the weathering potential and complexity of temperate watersheds in arid environment and that additional studies of these terrains are warranted. However, because the dominant weathering reactions in the sedimentary platform of northern Xinjiang are of carbonates and evaporites rather than silicate minerals, and the climatic factors have important role on the rock weathering regimes, we think that weathering at the arid temperate drainage system (Central Asia) is maybe not an important long-term sink for atmospheric CO2, if the future climate has no great change.

Cross-scale variation in the density and spatial distribution of an Amazonian non-timber forest resource

Successful management of tropical forest resources depends upon an understanding of their patterns of density and spatial distribution, since these affect the potential for harvesting. The variation in these patterns across different spatial scales has rarely been explored. We assessed the extent to which different spatial scales are useful in understanding resource distribution, using the example of an economically-significant tropical tree genus, Copaifera, which is valued across Brazilian Amazonia for its medicinal oleoresin. We mapped the spatial distribution of Copaifera trees at three nested spatial scales: basin-wide (across Brazilian Amazonia), landscape (across two contiguous extractive reserves) and local (within a 100-ha plot). Using data from our own study and an Amazon-wide forest inventory (Projeto RADAMBRASIL), we quantified the population distribution, density and size structure at the genus and species level at all three scales, relating these to two environmental variables – forest type and elevation. Spatial statistics were used to further characterize the resource at the landscape and local levels. The distribution, density and adult population structure differed between species and forest types at all three spatial scales. Overall tree densities ranged from 0.37ha–1 (basin-wide scale) to 1.13ha–1 (local scale) but varied between forest types, with várzea containing a Copaifera tree density just 43% of that in terra firme forest at the landscape scale. Spatial distribution analyses showed significant clumping of some species, especially C. multijuga which averaged 61m between neighbouring trees. We compare our cross-scale density estimates and discuss the relative merits of studying the distribution of non-timber forest products (NTFP) at more than one spatial scale. Our results have implications for the management and extraction of this important Amazonian forest resource.

Along‐strike variability of back‐arc basin collapse and the initiation of sedimentation in the Magallanes foreland basin, southernmost Andes (53–54.5°S)

The Patagonian Andes record the Cretaceous demise of the quasi‐oceanic Rocas Verdes back‐arc basin and formation of the Magallanes foreland basin. For >500 km along the strike of the mountains, this tectonic transition is marked by a sandstone‐mudstone package that records the beginning of turbiditic sand deposition and fan growth. Sandstone modal analyses and U‐Pb detrital zircon spectra show changes in rock composition and provenance across the transition on a basin‐wide scale, indicating it has tectonic significance and is related to orogenic uplift and the progressive evolution of the Andean fold‐thrust belt. Spatial variations in transition zone characteristics indicate the foreland basin's central and southern sectors were fed by different sources and probably record separate fans. At Bahía Brookes, on Tierra del Fuego, foreland basin sedimentation began at least after 88–89 Ma, and possibly after ∼85 Ma, several million years after it did ∼700 km away at the northern end of the basin. This event coincided with increased arc volcanism and the partial obduction of the basaltic Rocas Verdes basin floor onto continental crust. By 81–80 Ma, conglomerate deposition and increased compositional and provenance complexity, including the abundance of metamorphic lithic fragments, indicate that the obducted basaltic floor first became emergent and was eroding. The results suggest that the beginning of turbidite sedimentation in the Magallanes foreland basin and the progressive incorporation and exhumation of deeply buried rocks in the Andean fold‐thrust belt, occurred later in southern Patagonia than in the north by a few million years.

Using River Distance and Existing Hydrography Data Can Improve the Geostatistical Estimation of Fish Tissue Mercury at Unsampled Locations

Mercury in fish tissue is a major human health concern. Consumption of mercury-contaminated fish poses risks to the general population, including potentially serious developmental defects and neurological damage in young children. Therefore, it is important to accurately identify areas that have the potential for high levels of bioaccumulated mercury. However, due to time and resource constraints, it is difficult to adequately assess fish tissue mercury on a basin wide scale. We hypothesized that, given the nature of fish movement along streams, an analytical approach that takes into account distance traveled along these streams would improve the estimation accuracy for fish tissue mercury in unsampled streams. Therefore, we used a river-based Bayesian Maximum Entropy framework (river-BME) for modern space/time geostatistics to estimate fish tissue mercury at unsampled locations in the Cape Fear and Lumber Basins in eastern North Carolina. We also compared the space/time geostatistical estimation using river-BME to the more traditional Euclidean-based BME approach, with and without the inclusion of a secondary variable. Results showed that this river-based approach reduced the estimation error of fish tissue mercury by more than 13% and that the median estimate of fish tissue mercury exceeded the EPA action level of 0.3 ppm in more than 90% of river miles for the study domain.

Deep confined karst detection, analysis and paleo-hydrology reconstruction at a basin-wide scale using new geophysical interpretation of borehole logs

summary Deep karst voids can be identified by a new method of geophysical interpretation of commonly used borehole logs in deeply confined carbonate aquifers. We show that deep, buried karst voids can be characterized by combining this geophysical interpretation together with geological and hydrological data, and with known speleological constraints. We demonstrate how this characterization can reveal past hydrological regimes and allow mapping of karst distribution on a basin-wide scale. A combined analysis of geophysical, geological, hydrological, and speleological data in the confined Yarkon–Taninim aquifer, Israel, led us to reconstruct past groundwater levels at different relief and sea levels, with the karst voids as a marker for long-term flow close to the water table. Paleo-canyons along the Mediterranean Sea shoreline strongly affected the region’s paleo-hydrology, by serving as major outlets of the aquifer during most of the Cenozoic. We conclude that intensive karstification was promoted by flow periods of longer duration and/or higher flux and flow velocities close to the aquifer’s past and present outlets. In addition, we suggest that karst voids found under shallow confinement were developed by renewed aggressivity due to hypogene water rising in cross-formational flow becoming mixed with fresh lateral water flow from the east.

Comment on "Orbitally forced climate and sea-level changes in the Paleoceanic Tethyan domain (marl–limestone alternations, Lower Kimmeridgian, SE France) " by S. Boulila, M. de Rafélis, L. A. Hinnov, S. Gardin, B. Galbrun, P.-Y. Collin [ Palaeogeography Palaeoclimatology Palaeoecology 292 (2010) 57–70

A recent paper by Boulila et al. (2010) reports on orbitally-forced cycles recorded as marl-limestone alternations in one Lower Kimmeridgian section, Chateauneuf d'Oze (SE France, Tethyan domain). In an attempt to illustrate the in situ (i.e., pelagic) origin of carbonates in marls and limestones, the authors challenged the results of previous work concerning sections from other Tethyan areas of similar age, which demonstrate that nannofossil abundance is originally higher in marls than in limestones. Boulila et al. (2010) present data acquired with optical and Scanning Electron microscopes estimating nannofossil contribution to the rocks. However, their selected illustrations do not support a high contribution of the nannofossils to the carbonate fraction of their samples or their interpretation of the finest fraction of the rocks (micarbs). Furthermore, according to their data on carbonate content of the rocks, they did not analyse true marl-limestone alternations, but slightly argillaceous limestones and limestones. Boulila et al. (2010) also criticize earlier work providing a sequence stratigraphy interpretation of the Chateauneuf d'Oze section. However, contrarily to these earlier works, they did not consider platform-to-basin correlations that are essential in order to understand the sedimentary dynamics at the basin-wide scale. This comment challenges the work by Boulila et al. (2010) that largely underestimates the role of carbonate production on shallow platforms and its subsequent export basinwards as a major mechanism controlling the sedimentation in epicontinental basins.

Application of the index of marsh bird community integrity to coastal wetlands of Georgian Bay and Lake Ontario, Canada

Ecological indicators have gained increasing attention within the scientific community over the past 40 years. Several taxonomic groups have been used successfully as indicators including most prominently fish, invertebrates, plants, and birds because of their ability to indicate environmental changes. In the Laurentian Great Lakes region, there has been recent concern over the applicability of using indicators on a basin-wide scale due to species range restrictions and lake-based differences. The objective of this study was to determine the ability of the Index of Marsh Bird Community Integrity (IMBCI) to indicate land use disturbance surrounding coastal marshes of Georgian Bay and Lake Ontario. To meet this objective, we surveyed birds and vegetation at 14 marshes in Georgian Bay (low land use disturbance) and Lake Ontario (high land use disturbance). Even though Lake Ontario marshes were surrounded by significantly more altered land than Georgian Bay marshes, and had poorer water quality, we found significantly fewer birds in Georgian Bay marshes (mean = 8.2) compared to Lake Ontario (mean = 13.7) and no significant difference in IMBCI scores. This inconsistency could be due to vegetation differences affecting the strength of the index, because Georgian Bay wetlands had significantly more bulrush ( Schoenoplectus spp.) and floating vegetation, while Lake Ontario wetland vegetation was taller and cattail-dominated ( Typha spp.). These findings suggest that the IMBCI may not be useful on a basin-wide scale in the Great Lakes region in detecting human disturbance surrounding wetlands.

Potential for deep geological sequestration of CO2 in Switzerland: a first appraisal

Possibilities to sequester anthropogenic CO2 in deep geological formations are being investigated worldwide, but the potential within Switzerland has not yet been evaluated. This study presents a first-order appraisal based solely on geological criteria collated from the literature. The Swiss Molasse Basin (SMB) and the adjacent Folded Jura are the only realms of the country where CO2 could conceivably be stored in saline aquifers. Evaluation of geological criteria at the basin-wide scale shows that the SMB–Jura has moderate potential (score of 0.6 on a scale from 0 to 1) when compared to basins elsewhere. At the intrabasinal scale, inspection of the stratigraphy reveals four regional candidate aquifers that are sealed by suitable caprocks: top Basement plus basal Mesozoic sandstones, all sealed by the Anhydrite Group; Upper Muschelkalk sealed by the Gipskeuper; Hauptrogenstein sealed by the Effinger Member, and Upper Malm plus Lower Cretaceous sealed by the Lower Freshwater Molasse. Nine geological criteria are defined to evaluate the storage potential of these and other smaller scale candidates. A numerical scoring and weighting scheme allows the criteria to be assessed simultaneously, permitting the storage potential to be depicted using the 0–1 scale in contoured maps. Approximately 5,000 km2 of the central SMB exhibits potentials between 0.6 and 0.96. The Fribourg–Olten–Luzern area is the most favoured owing to the presence of several sealed aquifers within the preferred 800–2,500 m depth interval, and to its low seismicity, low geothermal gradient, low fault density, and long groundwater residence times. Smaller areas with good potential lie between Zurich and St. Gallen. In contrast, western Switzerland, the Jura and the southern SMB have markedly poorer potential. Considering only the portions of the aquifers with potential above 0.6, the theoretical, effective storage capacity of the basin is estimated to be 2,680 million tonnes of CO2.

Sea ice and wind variability during the Holocene in East Antarctica: insight on middle–high latitude coupling

Micropaleontological and biomarker data from two high-accumulation marine sites from the Coastal and Continental Shelf Zone (CCSZ) off East Antarctica (Adélie Land at ∼140°E and eastern Prydz Bay at ∼77°E) are used to reconstruct Holocene changes in sea ice and wind stress at the basin-wide scale. These data demonstrate congruent increase in sea-ice concentration/persistence and wind stress-related sea-surface turbulence in the two regions since 7 cal ka BP, with a particularly strong signal since 4.5–3.5 cal ka BP. Comparison of these high latitude records with sea ice and turbulence records from the southern mid-latitudes highlights distinctive climatic evolutions according to the different latitudinal bands. Sea-ice persistence and turbulence increase in East Antarctica CCSZ are opposite to sea-surface warming and sea-ice retreat recorded after 4.5–3.5 cal ka BP in the East Atlantic and Indian sector between 55 and 45°S. At the same period, paleodata suggest SST cooling in all major coastal upwelling systems of the southern hemisphere, caused by the northward transport of subpolar surface waters as a response to southern Westerlies reinforcement. We therefore propose, as suggested for the northern hemisphere, that Holocene changes in the latitudinal insolation gradient, primarily forced by obliquity and precession and amplified by sea-ice and glacial-ice expansions in the Antarctic realm, are responsible for the observed contrasted latitudinal patterns of southern latitudes.

Effects of reduction in porosity and permeability with depth on storage capacity and injectivity in deep saline aquifers: A case study from the Mount Simon Sandstone aquifer

The Upper Cambrian Mount Simon Sandstone is recognized as a deep saline reservoir that has significant potential for geological sequestration in the Midwestern region of the United States. Porosity and permeability values collected from core analyses in rocks from this formation and its lateral equivalents in Indiana, Kentucky, Michigan, and Ohio indicate a predictable relationship with depth owing to a reduction in the pore structure due to the effects of compaction and/or cementation, primarily as quartz overgrowths. The regional trend of decreasing porosity with depth is described by the equation: ϕ( d) = 16.36 × e −0.00039* d , where ϕ is the porosity and d is the depth in m. The decrease of porosity with depth generally holds true on a basinwide scale. Bearing in mind local variations in lithologic and petrophysical character within the Mount Simon Sandstone, the source data that were used to predict porosity were utilized to estimate the pore volume available within the reservoir that could potentially serve as storage space for injected CO 2. The potential storage capacity estimated for the Mount Simon Sandstone in the study area, using efficiency factors of 1%, 5%, 10%, and 15%, is 23,680, 118,418, 236,832, and 355,242 million metric tons of CO 2, respectively.

Re–Os geochronology of a Mesoproterozoic sedimentary succession, Taoudeni basin, Mauritania: Implications for basin-wide correlations and Re–Os organic-rich sediments systematics

The exceptionally well-preserved sedimentary rocks of the Taoudeni basin, NW Africa represent one of the world's most widespread (> 1 M km 2) Proterozoic successions. Hitherto, the sedimentary rocks were considered to be Mid Tonian based on Rb–Sr illite and glauconite geochronology of the Atar Group. However, new Re–Os organic-rich sediment (ORS) geochronology from two drill cores indicates that the Proterozoic Atar Group is ∼ 200 Ma older (1107 ± 12 Ma, 1109 ± 22 Ma and 1105 ± 37 Ma). The Re–Os geochronology suggests that the Rb–Sr geochronology records the age of diagenetic events possibly associated with the Pan African collision. The new Re–Os geochronology data provide absolute age constraints for recent carbon isotope chemostratigraphy which suggests that the Atar Group is Mesoproterozoic and not Neoproterozoic. The new Re–Os ORS geochronology supports previous studies that suggest that rapid hydrocarbon generation (flash pyrolysis) from contact metamorphism of a dolerite sill does not significantly disturb the Re–Os ORS systematics. Modelled contact conditions suggest that the Re–Os ORS systematics remain undisturbed at ∼ 650 °C at the sill/shale contact and ≥ 280 °C 20 m from the sill/shale contact. Moreover, the Re–Os geochronology indicates that the West African craton has a depositional history that predates 1100 Ma and that ORS can be correlated on a basin-wide scale. In addition, the Re–Os depositional ages for the ORS of the Taoudeni basin are comparable to those of ORS from the São Francisco craton, suggesting that these cratons are correlatable. This postulate is further supported by identical Os i values for the Atar Group and the Vazante Group of the São Francisco craton.

Simulation-Optimization Modeling of Conjunctive Use of Surface Water and Groundwater

Water resources management in semiarid regions with low precipitation and high potential of evapotranspiration is a great challenge for managers and decision makers. In those regions, both sources of water should be managed conjunctively so as to minimize shortages of water in dry seasons. In conjunctive use, the difficulty increases as one must represent the response of both systems interactions, and develop management strategies that simultaneously address surface water and aquifer regulation. This paper focuses on the simulation-optimization for conjunctive use of surface water and groundwater on a basin-wide scale, the Najafabad plain in west-central Iran. A trained artificial neural network model is developed as a simulator of surface water and groundwater interaction while a genetic algorithm is developed as the optimization model. The main goal of the simulation-optimization model is to minimize shortages in meeting irrigation demands for three irrigation systems subject to constraints on the control of cumulative drawdown of the underlying water table and maximum capacity of surface irrigation systems. To achieve the main goal, three scenarios are presented. Results of the proposed model demonstrate the importance of the conjunctive use approach for planning the management of water resources in semiarid regions.

Correlation of TL layers for the synchronous paleoceanographic events in the East Sea (Sea of Japan) during the Late Quaternary

TL layers (i.e., dark mud layers), either thin or thick, as determined by the L* values with lithologic observation, are distinct paleoceanographic signatures in the East Sea (Sea of Japan), which were formed in response to the global eustatic sealevel fluctuations between interglacials and glacials during the Late Quaternary. These lithologic markers were consistently correlated among the three sediment cores (MD01-2407, 05GCRP21, and KR05-09PC1) collected from the Oki Ridge of the southern Yamato Basin, the South Korea Plateau of the northern Ulleung Basin, and the Matsumae Plateau of the northeastern Japan Basin, respectively. Reconstruction of age models for cores 05GCRP and KR05-09PC1 was aided in a good way by the AMS 14C ages of planktonic foraminifera and identification of the tephra layers, and mainly by lithostratigraphic correlation with TL layers of well-dated core MD01-2407, based on the L* values. The correlation of TL layers among the three sediment cores was remarkable, indicating that the East Sea (Sea of Japan) experienced the synchronous and basin-wide scale paleoceanographic events during the Late Quaternary. Our study exemplifies the significant usefulness of these lithologic markers for further Late Quaternary paleoceanographic investigation.

Exposure modeling on a river basin scale in support of risk assessment for chemicals in european river basins

Following the 2000 European Water Framework Directive and recent insights into sediment management on a river basin scale, we discuss in this paper an exposure model aiming to support a risk assessment for chemicals on a basin-wide scale. It establishes spatial relations between causes (pollution sources) and effects (ecological risk), taking into account the geometry, hydrology, and fine sediment dynamics of European river basins. The model, called EXPOBASIN, explicitly takes into account the interaction of chemicals with fine sediment particles, which is important for many policy-relevant chemicals, such as trace metals and polycyclic aromatic hydrocarbons, and it addresses the potential release of historically polluted sediments as a result of extreme floods, which is a major concern in different European river basins. Bioavailability and bioaccumulation are included in the assessment. As a result, the exposure can be quantified not only in terms of water concentrations, but also in terms of sediment concentrations and concentrations in biota. The primary question to be answered by EXPOBASIN is how chemicals, pollution sources, or both rank quantitatively and objectively on a basin-wide scale. Near the end of 2009, the tool will become available to all European water managers and their technical advisors, as a result of the European Union 6th Framework Programme project MODELKEY. The calibration and validation of EXPOBASIN has only just started and will be completed in 2008/2009. Applications to 3 case study areas are planned in this respect. This paper presents the key building blocks of EXPOBASIN and shows some sample results illustrating the raking of pollution sources and chemicals. At the end of the paper, some perspectives for future developments are outlined.

Temporal fluctuations in Amazonian deforestation rates

Tropical deforestation is one of the most important components of global change. Rates of deforestation in Brazil, the nation with the single largest concentration of tropical forest on Earth, have fluctuated widely over the last twenty years. Based on local knowledge, such fluctuations have been variously attributed to a wide range of factors such as the expansion of cattle ranching and soybean farming, infrastructural expansion and the proliferation of paved and unpaved roads, macroeconomic shocks to the Brazilian economy and international exchange rates. Many, if not all, of these arguments are plausible explanations for temporal variation in deforestation rates, but have to date not been subjected to rigorous statistical testing; this study investigates the potential impact of these variables on Brazilian tropical deforestation over the period 1990–2005. When analysed at the basin-wide scale, nearly all variables were highly inter-correlated through time and were also closely correlated with deforestation rate, but appropriate time-series analysis found no statistical evidence that any of the variables have systematically caused variation in deforestation rates. Power analysis showed that the variables may exert small or medium influences on deforestation rates, but the impacts, if present, are not strong. Future analyses of time series data at finer spatial scales that exploit spatiotemporal variation in deforestation rates and in the hypothesized predictor variables may find significant causal processes that are overlooked when analysed at the basin-wide scale.

Burial of organic carbon and carbonate on inner shelf of the northern South China Sea during the postglacial period

Two vibrocores from the inner shelf off Hong Kong are investigated to compare the contents of organic and inorganic carbon in postglacial sediments. The compositions of organic elements and carbonate are highly variable in the core sediments, but overall drop within the compositional ranges of modern seabed sediments in the Zhujiang estuarine and its shelf area. The Holocene sediments in the inner shelf have never been subject to subaerial exposure and the organic matter and carbonate can be preserved well. The burial of carbon in river-dominated shelf environments is highly dependent on the river flux with time. Nevertheless, it is difficult to establish a simple relationship between carbon burial in sediments in relation to climatic changes of basin-wide scale due to complex controls of production, transport and deposition of organic matter and carbonate. Our study suggests that the organic carbon to nitrogen ratio can not reliably identify the sources of depositional organic matters because of selective decomposition of organic matter components during humification and sedimentation. Caution is therefore needed in using organic elemental compositions as indicators of organic matter sources and paleoenvironmental changes in the East Asian continental shelves where intense river-sea interaction and variable carbon flux in geologic record occur.

Geochemical characteristics and fluxes of organic carbon in a human-disturbed mountainous river (the Luodingjiang River) of the Zhujiang (Pearl River), China

This study aims to investigate the state of the riverine organic carbon in the Luodingjiang River under human impacts, such as reforestation, construction of reservoirs and in-stream damming. Seasonal and spatial characteristics of total suspended sediment (TSS), dissolved organic carbon (DOC) and particulate organic carbon (POC), as well as C/N ratios and the stable carbon isotopic signatures of POC ( δ 13C POC) were examined based on a one-year study (2005) in the basin-wide scale. More frequent sampling was conducted in the outlet of the river basin at Guanliang hydrological station. DOC and POC concentrations showed flush effects with increasing water discharge and sediment load in the basin-wide scale. Atomic C/N ratio of POC had a positive relationship with TSS in the outlet of the basin, indicating the reduced aquatic sources and enhanced terrestrial sources during the high flood season. However, the similar relationship was not observed in the basin-wide scale mainly due to the spatial distributions of soil organic carbon and TSS. δ 13C POC showed obvious seasonal variations with enriched values in the period with high TSS concentration, reflecting the increased contribution from C 4 plants with enhanced soil erosion. The specific flux of the total organic carbon (2.30 t km − 2 year − 1 ) was smaller than the global average level. The ratio of DOC to POC was 1.17, which is higher than most rivers under Asian monsoon climate regime. The organic carbon flux was estimated to decline with decreasing sediment load as a result of reforestation, reservoir construction and in-stream damming, which demonstrates the impacts of human disturbances on the global carbon cycle.

Sediment source changes over the last 250 years in a dry-tropical catchment, central Queensland, Australia

Rivers draining to the Great Barrier Reef are receiving increased attention with the realisation that European land use changes over the last ∼ 150 years may have increased river sediment yields, and that these may have adversely affected the reef environment. Mitigation of the effects associated with such changes is only possible if information on the spatial provenance and dominant types of erosion is known. To date, very few field-based studies have attempted to provide this information. This study uses fallout radionuclide ( 137Cs and 210Pb ex) and geochemical tracing of river bed and floodplain sediments to examine sources over the last ∼ 250 years for Theresa Creek, a subcatchment of the Fitzroy River basin, central Queensland, Australia. A Monte Carlo style mixing model is used to predict the relative contribution of both the spatial (geological) sources and erosion types. The results indicate that sheetwash and rill erosion from cultivated basaltic land and channel erosion from non-basaltic parts of the catchment are currently contributing most sediment to the river system. Evidence indicates that the dominant form of channel erosion is gully headcut and sidewall erosion. Sheetwash and rill erosion from uncultivated land (i.e., grazed pasture/woodland) is a comparatively minor contributor of sediment to the river network. Analysis of the spatial provenance of floodplain core sediments, in conjunction with optical dating and 137Cs depth profile data, suggests that a phase of channel erosion was initiated in the late nineteenth century. With the development of land underlain by basalt in the mid-twentieth century the dominant source of erosion shifted to cultivated land, although improvements in land management practices have probably resulted in a decrease in sediment yield from cultivated areas in the later half of the twentieth century. On a basin-wide scale, because of the limited spatial extent of cultivation, channel sources are likely to be the largest contributor of sediment to the Fitzroy River. Accordingly, catchment management measures focused on reducing sediment delivery to the Great Barrier Reef should focus primarily on decreasing erosion from channel sources.