Base Metal Mineralization Research Articles

Fluid-rock interactions leading to the formation of the epithermal Ag-Pb-Zn veins: A perspective of thermodynamic modeling

Although vein-type silver-lead-zinc ore deposits have been extensively studied, the factors controlling their formation are still poorly understood and their genesis is a matter of ongoing debate. In this contribution, I present new mineralogical data and the results of thermodynamic modeling that constrain the conditions of metal transport and deposition for the Aerhada epithermal Pb-Zn-Ag deposit (reserves of >1,000 t Ag@58 g/t and 1.0 Mt Pb+Zn@5.2%) in NE China. Three primary paragenetic stages have been identified, the second of which (Stage II) is the main base metal and silver mineralization. Freibergite, argentite, pyrargyrite, and canfieldite are the main Ag-bearing minerals and are spatially associated with an alteration assemblage of quartz-muscovite ± chlorite ± epidote. Dissolution textures and evidence of compositional heterogeneity for freibergite suggest that its decomposition may have redistributed the Ag and contributed in part to the high Ag grade ores in the deposit. Thermodynamic calculations indicate that there was extensive silver ore deposition from a strongly reducing (e.g., ∆log fO2 (HM) of <-8.6 to -2.4) and nearly neutral to weakly alkaline (e.g., pH of 5.5 to 6.8) aqueous fluid at temperatures between 220 °C and 170 °C. These calculations reveal that a reduction in fO2 and decreasing temperature, both as a result of fluid-rock interactions, were the key factors leading to silver and base metal mineral deposition. Further path modeling showed that the sole evolution of a magmatic-derived fluid is capable of forming the large Ag-Pb-Zn veins via fluid-rock interactions, which is contrary to the conclusions of some other studies that the mixture of an externally derived fluid is required to explain their formation. The genetic model for Ag-Pb-Zn ore formation developed in this study is applicable to other polymetallic vein-type deposits in comparable geological settings elsewhere.

Micro-fractures in the Ngubevu Gold and Base Metal Mines (Natal Thrust Front, Tugela Terrane, South Africa): Are they consistent with macro-scale deformation, and what do they tell us?

AbstractIn the Natal Thrust Front (NTF) of the Tugela Terrane, there is a lack of multi-scale characterisation of structural controls on shear-zone hosted precious and base metal mineralisation. This paper contributes to the current understanding of the structural controls on shear-zone-hosted precious and base metal mineralisation in the NTF with insight derived from the analyses of micro-fractures at and around the known shear-zone-hosted lode gold and base metal mineralisation in the Ngubevu area of the NTF. Based on the notion that the spatial distribution of stresses that control geological structures is fractal (i.e., possessing scale-invariance or self-similarity properties) across a range of geographic scales, this study (a) determines whether the stresses inferred from micro-fractures in the gold mines in Ngubevu are consistent with the stresses associated with regional- to local-scale geological structures in the NTF, and (b) interprets the mineralisation controls implied by these inferred and known stresses. From rose diagrams showing trends of micro-fractures in oriented vein material samples from Ngubevu, the relative micro-scale stress field per sample based on the maximum horizontal stress (SHmax) and the minimum horizontal stress (SHmin) were inferred. These were then compared to the local- to regional-scale stress field orientations derived from existing studies in the NTF.The north-northeast–south-southwest orientations of SHmax of micro-fractures in samples from Ngubevu are consistent with the north-northwest–south-southeast orientations of SHmax of regional- to district-scale thrust faults in the NTF of the Tugela Terrane. Likewise, the west-northwest–east-southeast orientations of micro-fractures in samples from the eastern part of Ngubevu are consistent with the general east–west orientations of local-scale S1 foliation. These orientations are associated with a D1 thrusting event, which was due to north to north-northeast-directed regional thrust tectonics. The clockwise change from the north-northwest–south-southeast orientations of SHmax of regional- to district-scale thrust faults to the north-northeast–south-southwest orientations of SHmax of micro-fractures in vein material attests to an earlier posited notion of clockwise rotation of regional- to district-scale thrust vergence. These suggest that V1 veins in Ngubevu were likely formed late in the D1 event. The orientations of micro-fractures in samples, mostly from the western part of Ngubevu, depict a strike-slip regime, which is consistent with D2 sinistral transpression that affected the earlier-formed east–west-trending structures. This suggests that some V1 veins in Ngubevu, particularly those in its western part, were affected by the D2 sinistral transpression (e.g., by remobilisation of gold in some of the V1 veins). The novel findings in this study are crucial to geological mapping, recognition of mineralisation controls and mineral prospecting in poorly-explored regions where the geology is permissive (i.e., represents processes that are favourable) for the formation of certain type(s) of mineralisation.

A geochemical study of the Sweet Home mine, Colorado Mineral Belt, USA: formation of deep hydrothermal vein–type molybdenum greisen and base metal mineralization

AbstractDeep hydrothermal Mo, W, and base metal mineralization at the Sweet Home mine (Detroit City portal) formed in response to magmatic activity during the Oligocene. Microthermometric data of fluid inclusions trapped in greisen quartz and fluorite suggest that the early-stage mineralization at the Sweet Home mine precipitated from low- to medium-salinity (1.5–11.5 wt% equiv. NaCl), CO2-bearing fluids at temperatures between 360 and 415 °C and at depths of at least 3.5 km. Stable isotope and noble gas isotope data indicate that greisen formation and base metal mineralization at the Sweet Home mine was related to fluids of different origins. Early magmatic fluids were the principal source for mantle-derived volatiles (CO2, H2S/SO2, noble gases), which subsequently mixed with significant amounts of heated meteoric water. Mixing of magmatic fluids with meteoric water is constrained by δ2Hw–δ18Ow relationships of fluid inclusions. The deep hydrothermal mineralization at the Sweet Home mine shows features similar to deep hydrothermal vein mineralization at Climax-type Mo deposits or on their periphery. This suggests that fluid migration and the deposition of ore and gangue minerals in the Sweet Home mine was triggered by a deep-seated magmatic intrusion. The findings of this study are in good agreement with the results of previous fluid inclusion studies of the mineralization of the Sweet Home mine and from Climax-type Mo porphyry deposits in the Colorado Mineral Belt.

The Karavansalija Mineralized Center at the Rogozna Mountains in SW Serbia: Magma Evolution and Time Relationship of Intrusive Events and Skarn Au ± Cu–Pb–Zn Mineralization

The Karavansalija Mineralized Center (KMC) with its Au–Cu skarn mineralization associated with the Rogozna Mountains magmatic suite in southwestern Serbia belongs to the Oligocene Serbo-Macedonian magmatic and metallogenic belt (SMM-MB). Samples from intrusive and volcanic rocks at the KMC show typical arc signatures of subduction-derived magmas through enrichment in large-ion lithophile elements (LILE) and depletion of high–field strength elements (HFSE). The magmas developed a high-K (calc-alkaline) fractionation trend and evolved toward shoshonitic compositions. Whole-rock trace element data suggest plagioclase-absent, high-pressure amphibole ± garnet fractionation that generates adakite-like hydrous magmas during evolution in lower crustal magma chambers. Zircon LA–ICP–MS and high-precision CA–ID–TIMS dating together with zircon trace elements and Hf isotope measurements were carried out in order to couple the geochronologic and geochemical evolution of the KMC. The results suggest that magmatism starts around 29.34 Ma with granitic to rhyodacitic subvolcanic intrusions followed by a more evolved magmatic intrusion that was emplaced into Cretaceous limestone, generating a widespread skarn alteration at ca. 28.96 Ma. After a period of quiescence of about 1.2 My, either another magma body evolved or the same upper crustal magma chamber was recharged and also likely partly reactivated older plutonic rocks as indicated by xenocrysts. The REE ratios shift from apatite, titanite ± amphibole-dominated fractionation of the older magmatic event to crystallization of allanite, efficiently depleting the LREE and Th/U in the younger upper crustal magma. After a lamproite-like melt was injected, the increased heat and fluid pressure led to the expulsion of a quartz-monzonite porphyritic stock at ca. 27.72 Ma, strongly interacting with the skarns and established a fertile hydrothermal system. Soon after a non-mineralized second pulse of some porphyry dykes cut the previous phenocryst-rich “crowded” porphyries and skarns at ca. 27.60 Ma, thus bracketing the maximum timespan of ore mineralization to about 112 ± 45 Ka. Increased contribution of a lamproite-like melt is inferred from the presence of phlogopite micro-phenocrysts, phlogopitization of biotite, and diopside clusters in the latest porphyry dykes. There is a trend of increased crustal assimilation from the oldest volcanic phase to the emplacement of the youngest porphyry dykes recorded by ɛ-Hf of the zircons. Oligocene occurrences of significant base metal mineralization within Serbia, northern Macedonia, and Greece, e.g., Crnac, Rudnik, Veliki Majdan, Stratoniu, or the Cu–Au porphyry at Buchim (northern Macedonia), are all associated with trachy-andesitic (quartz latitic) porphyry dykes, which originated through post-collisional tectonic settings or upper plate extension involving reworking of crustal arc-derived rocks and partial melting of the mantle wedge. This study demonstrates that on the basis of field relationships and the application of high-precision CA-ID-TIMS zircon age data, pulses of porphyry dykes of a 10ka age range can be distinguished, and the timing of mineralization can be parenthized.

The Formation of Magmatic-Hydrothermal Features in Sn-Mineralized and Barren Tasmanian Intrusions, Southeast Australia: Insights from Quartz Textures, Trace Elements, and Microthermometry

Abstract Tasmania is the most important tin province in Australia, having been endowed with &amp;gt;0.65 Mt Sn. Some granitic intrusions in western Tasmania have distinctive tourmaline- and quartz-rich magmatic-hydrothermal features, whether they are mineralized (e.g., Heemskirk Granite) or barren (Pieman Heads Granite). The Devonian Heemskirk and Pieman Heads plutons crop out on the western coast of Tasmania and are characterized by similar mineralogical and geochemical compositions and ages. The magmatic-hydrothermal textural features include tourmaline patches, tourmaline orbicules, and tourmaline-muscovite veins, as well as miarolitic cavities and quartz-fluorite-sulfide veins in the Heemskirk Granite. Cathodoluminescence (CL) imaging, laser ablation-inductively coupled plasma-mass spectrometry, and microthermometric analyses of quartz have revealed the physicochemical evolution of the magmatic-hydrothermal fluids from which these tourmaline- and quartz-bearing assemblages precipitated. High Ti quartz (20–28 ppm) in tourmaline patches, orbicules, and cavities typically have homogeneous CL-bright intensity, whereas CL-dark fractures have cut and/or offset the CL-bright and -gray domains that characterize low Ti quartz (3.4–8.5 ppm) from the tourmaline veins. The earliest fluid inclusion assemblages in the quartz-tourmaline orbicules and cavities have a salinity range from 3 to 14 wt % NaCl equiv with intermediate density and were probably trapped at lithostatic pressures of 1.57 ± 0.2 kbar and temperatures of 550° to 570°C, suggesting a depth of 5.9 ± 0.8 km. Prolonged depressurization and cooling may have led to the evolution of a brine (~39 wt % NaCl equiv salinity) from the primary magmatic liquid, which formed halite-bearing hypersaline inclusions in the tourmaline orbicules. Continuous pressure decrease explains the intense brittle failure and fluid migration outward from the apical portions of the pluton, where magmatic fluids partially mixed with and were cooled by external meteoric water. These mechanisms triggered the formation of tourmaline-muscovite-quartz veins and local cassiterite-bearing greisens from a moderate-salinity fluid (~12 wt % NaCl equiv) at temperatures of ~300°C and hydrostatic pressures of 120 bars. Retrograde dissolution textures evident from CL-bright quartz cores surrounded by oscillatory growth zones with gray CL response characterize the low Ti (&amp;lt;1 ppm) and high Al (500–1,000 ppm) quartz from the fluorite-sulfide veins that precipitated from a low-salinity (5.7 wt % NaCl equiv) acidic fluid at temperatures of 200° ± 25°C and hydrostatic pressures of &amp;lt;50 bars. High Sb concentrations (up to 80 ppm) in quartz may be an indicator of low-temperature base metal mineralization related to granitic intrusions. Abundant fluid percolation, protracted fractional crystallization, and high tin concentrations in exsolved hydrothermal fluids may explain why the Heemskirk Granite is well endowed in Sn and base metal deposits, whereas the Pieman Heads Granite is barren.

Whether short-lived or prolonged duration of multistage combined magmatic and hydrothermal events in the giant Chalukou porphyry Mo deposit, China

The duration (or time scales) of multistage combined magmatic and hydrothermal events provides key information constraining the metallogenic history of porphyry deposits, but the duration (time scale) of the mineralising hydrothermal process remains uncertain. Here, we report zircon U–Pb isotopic age, fluorite Sm–Nd isochron ages, and Ti-in-quartz diffusion chronometry for the giant Chalukou porphyry Mo deposit with reserves of 2.46 Mt @ 0.087 wt% Mo in NE China. The deposit is genetically related to hydrothermal fluids associated with a Late Jurassic (148–147 Ma) porphyritic magmatic event coincident with our new fluorite Sm–Nd isochron age of 148 Ma. Porphyry Mo mineralisation is characterised by the superposition of multiple generations of crosscutting quartz-bearing veins including: quartz veins with minor magnetite and hematite associated with K-silicate alteration (A-veins), quartz-molybdenite veins with K-feldspar alteration halos that host the bulk of the Mo mineralisation (B-veins), and late base-metal mineralisation with phyllic alteration (D-veins), as well as post-mineralisation veins with argillic alteration. Hydrothermal veins from the Chalukou porphyry Mo deposit contain multiple generations of quartz that are distinct in their Ti concentrations and scanning electron microscope-cathodoluminescence images. The A-veins preserve subhedral to euhedral characteristics with alternating CL bright and dark growth zoning. The A-veins probably formed at a near-lithostatic pressure of ∼ 1.35 kbar and contain CL-bright quartz assaying 31–71 ppm Ti with Ti-in-quartz temperatures averaging 603 ± 30 °C, and CL-dark quartz assaying 6–25 ppm Ti with Ti-in-quartz temperatures averaging 496 ± 36 °C. The mineralised B-veins also CL-dark quartz, although they display less growth zoning with lower Ti assays of 0.4–27.9 ppm. These veins have near 0.7 kbar pressure and Titanium-in-quartz temperature averaging 390 ± 79 °C. The D-veins are dominated by CL-dark quartz and systematically lower Ti concentrations of 0.4–8 ppm, being lower than the relatively latter vein generations, formed at a temperature of 348 ± 58 °C and pressure of 0.4 kbars. The Ti diffusion in quartz has become a successful method constraining time scales and duration of magmatic and hydrothermal processes. Ti diffusion modelling indicates that the A-veins were deposited and cooled in a period between 2500 and 50,000 years. This shows that the earliest magma-related hydrothermal fluids activities formed within tens of thousands of years.

Genesis and mechanisms of metal enrichment in the Baimazhai Ni-Cu-(PGE) deposit, Ailaoshan Orogenic Belt, SW China

ABSTRACT The ∼259 Ma Baimazhai Ni-Cu-(platinum-group element) deposit is located in the Ailaoshan-Red River fault zone on the southwest margin of the Yangtze Plate in the Jinping area of southeastern Yunnan Province. The intrusion is lenticular (∼530 m long × 190 m wide × 24–64 m thick) and concentrically zoned (margin to core) from gabbro through pyroxenite to peridotite. It contains ∼50 kt of Ni-Cu-(platinum-group element) mineralization, concentrically zoned (margin to core) from disseminated through net-textured to massive sulfides with an average grade of 1.03 wt.% Ni, 0.81 wt.% Cu, and 0.02∼0.69 ppm Pd+Pt. The sulfide assemblage comprises pyrrhotite, chalcopyrite, and pentlandite, with lesser magnetite, violarite, galena, and cobaltite. The mineralization is enriched in Ni-Cu-Co relative to the platinum-group elements and the host rocks are enriched in highly incompatible lithophile elements relative to moderately incompatible lithophile elements with high Th/Yb and intermediate Nb/Yb ratios. These host rocks, and those at most other Ni-Cu-platinum-group element deposits in the Emeishan Large Igneous Province, have high γOs and intermediate εNd values, indicating that they crystallized from a magma derived from a subduction-modified pyroxenite mantle source and modified by crustal contamination. The initial concentrations of metals in the primary magma are estimated to have been on the order of 200 ppm Ni and 100 ppm Cu, but only 0.4 ppb Pd, 0.2 ppb Pt, 0.005 ppb Rh, 0.02 ppb Ru, and 0.01 ppb Ir. The δ34S values of ores and separated sulfides range from 5.8‰ to 8.6‰, between the ∼10‰ value of sulfides in the metasedimentary country rocks and the 0 ± 0.5‰ value expected for magmas derived from MORB-type mantle, or the –2.5 ± 0.3‰ value expected for subduction-modified mantle, consistent with equilibration at magma:sulfide mass ratios (R factors) of 100–1000. Variations in Ir100 and Pd100 (metals in 100% sulfide) are consistent with 40–60% fractional crystallization of monosulfide solid solution to form Ni-Co-intermediate platinum-group element (Ru, Os, Ir)-rich massive ores and Cu-palladium/platinum-group elements (Pt, Pd, Rh)-Au-rich residual sulfide liquids. This process is also recorded by magnetite: Type I (early magmatic), type II (late magmatic), and type III (secondary) magnetites exhibit progressively lower Cr-Ti-V concentrations. The platinum-group element contents in base-metal minerals are low, and only pentlandite, violarite, and cobaltite contain detectable concentrations of Pd, Rh, and Ru. There is abundant textural evidence for metamorphic-hydrothermal alteration of sulfides in the Baimazhai intrusion, with secondary violarite, chalcopyrite, and pentlandite being enriched (Ag, Sb, Au, Pb) or depleted (Sn) in more mobile chalcophile elements. The different tectonic and petrogenetic settings of the Baimazhai and other deposits in China highlight the potential of Ni-Cu-platinum-group element deposits to occur in subduction or post-subduction settings and demonstrate that the key controls are magma flux and access to crustal S. Exploration potential remains for the Ailaoshan orogenic belt to host additional magmatic Ni-Cu deposits.

Evaluation of heavy metal (Cu, Pb, Zn) distribution in base metal mining area at Sangkaropi: implication for land use planning

Settling-pond treatment systems have been applied in the base-metal mining area at Sangkaropi, South Sulawesi, Indonesia, before being discharged into the Koyan River through the agriculture area. This study aims to conduct a valuation of pollutant Pb, Cu and Zn in areas impacted by base-metal mining in sediment materials as a sensitive indicator for monitoring contaminants in the aquatic environment. Sediment sampling location, the first is in the upstream before the mining location, the second is located in the mining area to settling pond, and the third is in the area after settling-pond to the agriculture area. The concentrations of heavy metal were analyzed using uses AAS method. The assessment is performed based on the value of contamination degree, enrichment of heavy metal pollutant and ecological risk. The arrangement of the average frequency of heavy metal concentrations is Pb>Cu>Zn, which Cf and I-geo values have the almost same behavior. All metal in the upstream and agriculture site is classified as a low category, the Cu on the second and third sites is moderate. The assessment results from this study represent that Pb has a considerable ecological risk category value. However, polluted-Cu are categorized moderately need to be cautious, because metal enrichment comes from mineralization bedrock in the river. Therefore, the result of this study shows that geologic data, especially mineralized bedrocks associated the heavy metal concentration, should be taken into consideration in land-use planning policy in areas that have been impacted by mining and in the assessment of environmental health impacts.

Lithogeochemistry of various hydrothermal alteration types associated with precious and base metal epithermal deposits in the Tarom-Hashtjin metallogenic province, NW Iran: Implications for regional exploration

In this study, the styles, types, and degrees of hydrothermal alteration associated with Pb-Zn-Cu-Ag-Au epithermal deposit systems in the Tarom-Hashtjin metallogenic province are evaluated using petrographic studies, as well as mass changes and molar elements ratios (MER), in order to examine regional exploration implications. The MER plots show that the hydrothermally altered rocks were most affected by various types of K-metasomatism, mainly characterized by K gains and Na and Ca losses. The intensity of K-metasomatism is related to precious and base-metal mineralization, showing increasing K trends toward the ore veins. The alteration index (AI) and chlorite-carbonate-pyrite index (CCPI) reveal that argillic, sericitic, and propylitic alteration types are the main zones of alteration surrounding ore veins indicating that AI increases and CCPI decreases toward more proximal to the structures linked to these ore systems. Determination of mass changes in altered rocks surrounding selected epithermal deposits suggest Si, K, and Al gains and Na and Ca losses increasing in intensity toward ore veins, consistent with alteration zoning from the silicic and K-metasomatic (sericite and argillic) inner zones to the propylitic (Fe-rich chlorite alteration) outer zone typical of epithermal ore systems. Data from this study show that the intensity of K-metasomatism in the acidic rocks is greater than in the intermediate and mafic rocks, where it is related to high to intermediate sulfidation epithermal systems. We suggest that exploration can be focused on highly altered volcanic rocks (especially andesite-dacite) with both high intensity of K-metasomatism and higher Pb, Zn, Ag, Au, Ba and Rb and lower Sr.

Exploration-resource assessment of productive felsic volcanic centers in the Paleoproterozoic Penokean Volcanic Belt of northern Wisconsin, Michigan and east-central Minnesota, USA

Five productive felsic volcanic centers have been identified in the Paleoproterozoic Penokean Volcanic Belt (PVB). Each center hosts at least one potentially economic polymetallic volcanogenic massive sulfide (VMS) deposit. To date, these drill-defined (inferred + indicated + measured) resources collectively contain over 93 million tonnes of VMS-style, base (Cu, Pb, Zn) and precious metal (Ag, Au) mineralization including nearly 4 million ounces of gold. This does not include smaller, less defined (mostly inferred) deposits in the belt that would increase the total to at least 150 million tonnes. From this resource base only 1.73 million tonnes of actual ore production has occurred. However, previous positive feasibility studies completed on the Crandon (1994), Lynne (1995) and most recently (2020) Back Forty deposits verify a total of approximately 44 million tonnes, or 47% of the total drill-defined resource base, are potentially minable reserves. Currently the PVB resource base remains as unrealized new wealth.Mineral resource assessments completed in 1996 and 2007 collectively suggest there is a high probability of at least 4 to 22 (average ~13) or more VMS deposits remaining to be discovered in the Ladysmith-Rhinelander complex and to a lesser extent the Wausau complex of the PVB. These newly discovered VMS deposits will fill out the tonnage distribution for this belt by following a natural geometric (log normal) progression consistent with established grade-tonnage models. It is postulated that among these will be one giant (>100 million tonnes) deposit. If verified, potentially economic VMS mineralization hosted by the PVB would be comparable to other productive Paleoproterozoic greenstone belts in the Canadian Shield such as Flin Flon (>200 million tonnes) or even approach that of the prolific Neoarchean Abitibi (~775 million tonnes).Exploration to date suggests that many of these undiscovered VMS deposits will be identified in five, highly permissive felsic volcanic centers. These centers, which comprise less than 2% of the known belt, are distributed within the Highway 8 intra-arc rift basin of the 1,880 to 1,860 Ma old Ladysmith Rhinelander volcanic complex. Exact aerial boundaries are poorly defined. However, extrapolation of geophysical, drill hole and rare outcrop data provides a reasonable estimate. Each productive center is stratigraphically associated with major, district-scale, commonly mineralized, meta-argillite formations or formational groups. Felsic centers are identified in the Wausau complex but have thus far been barren of significant VMS-style mineralization as is the adjacent Wausau basin.Future exploration for new VMS deposits should be focused within the productive felsic centers where a number of prospective targets and prospects have been previously identified. Other significant felsic centers likely exist within the Highway 8 basin particularly in Cambrian sandstone-covered areas along the western and eastern margins of the belt. Additionally, at least one felsic center may be present in the Milaca complex which could have VMS potential.Of particular note is the VMS potential of a second mostly Cambrian sandstone-covered, greenstone belt in the Marshfield subterrane (Eau Claire complex). Geophysical data suggest possible back-arc or intra-arc rift basins may be present and historical drilling has identified at least one VMS occurrence. This highly prospective volcanic complex is essentially new hunting ground with its own deposit tonnage distribution of potentially supergene-enriched VMS deposits. Based on criteria set out in a 2007 mineral assessment, this belt has the potential to host at least 1 to a maximum of 15 deposits.

Main results of the diamond, precious metal, and base metal mineral resource base reproduction using the declarative principle of licensing

The article presents the results of geological exploration for diamonds, precious metals, and base metals, conducted in the Russian Federation in consistence with licenses granted based on the declarative principle, beginning from the moment this mechanism was introduced. Key aspects of changes in the legislative regulation of this mechanism are represented. The information on the planned and factual financing of these works, on the number of the issued licenses, and on the respective increase in the resources and reserves of precious metals is provided. Specific (unit) indicators of the mineral reserve increase and of the respective costs were proposed, based on which the effectiveness of geological exploration was determined for projects performed in administrative subjects of the Russian Federation in consistence with the licenses granted by the declarative principle. Problems in implementation of the mechanism were identified. Recommendations for elimination of these problems are proposed.

Mineralogy, Fluid Inclusion, and C-O-Sr Isotope Geochemistry to Unravel the Evolution of the Magmatic-Hydrothermal System at the Igoudrane Silver-Rich Deposit (Imiter District, Eastern Anti-Atlas, Morocco)

The Igoudrane mine with a total production of 700,000 t of ore grading 485 g/t Ag is currently one of the most productive mines in the Imiter district of the eastern Anti-Atlas in Morocco. The silver-rich ± base metal deposit occurs dominantly as vein- and hydrothermal breccia-hosted orebodies at the interface between the lower Ediacaran turbidites of the Saghro Group and the unconformably overlying, dominantly felsic volcanic, and volcaniclastic rocks of the late Ediacaran Ouarzazate Group. Higher-grade ores are lithologically hosted by the uppermost organic-rich black shale unit and structurally controlled by the intersection of subvertical NW- and NE-trending fault systems. Ore-related hydrothermal alteration includes, in order of decreasing abundance, carbonatization, silicification, sericitization, and chloritization. Three primary paragenetic stages of veining and associated silver ± base metal mineralization have been recognized: (1) early pyrite + quartz + Ag-bearing sulfides and sulfosalts; (2) main Ag-bearing sulfides and sulfosalts + calcite ± fluorite ± dolomite; and (3) late quartz + calcite + base-metal sulfides (galena, sphalerite, pyrite, chalcopyrite). Irrespective of the ore stage, the dominant Ag-bearing ore minerals are Ag-Hg amalgam, argentite, freibergite, acanthite, polybasite, pyrargyrite, and proustite. Fluid inclusion data show a trend of decreasing temperatures with time, from the main silver stage (Th = 180 ± 12 °C) to late base-metal stage (Th = 146 ± 7 °C), consistent with fluid mixing, cooling, and/or dilution. The coexistence of aqueous-rich and vapor-rich fluid inclusions together with variations in bulk salinity (NaCl + CaCl2) of the mineralizing fluids during the main silver stage, at similar temperatures, indicate that boiling and subsequent degassing occurred during the main ore-forming event due to a pressure decrease. Calculated δ18Ofluid values along with REE+Y and Sr isotope constraints suggest that the ore-forming fluids originated from a predominantly magmatic source, although incursion of meteoric waters during collapse of the hydrothermal system could have contributed to deposition. The post-ore, base-metal quartz-carbonate-dominated mineralization was deposited from dilute Ca-Na-Cl-bearing fluids at temperature below 150 °C. Overall, fluid–rock interaction with the black shales along major faults and thin permeable horizons, boiling-degassing—with subsequent fluid mixing, cooling, and/or dilution—were the main mechanisms of silver deposition.

Paleoredox conditions, hydrothermal history, and target vectoring in the MacMillan Pass base-metal district, Yukon, Canada: 1 – Lithogeochemistry of proximal and distal shales

ABSTRACT The MacMillan Pass District in Yukon, Canada, hosts the Tom and Jason clastic sediment-hosted Zn-Pb-Ag-(Ba) deposits. Bulk geochemical paleoredox proxies (Eu/Eu*, Ce/Ce*, Mo, Re/Mo, and Ni/Co) indicate anoxic–dysoxic water column and sulfidic porewater conditions persisted during the Late Devonian deposition of the Lower Earn Group host rocks. Positive Eu/Eu* anomalies (up to 3.31) in sulfide mineralization at the Tom deposit are consistent with relatively high temperature (probably &amp;gt;250 °C), reducing, acidic hydrothermal fluids that infiltrated laterally through unconsolidated sediments proximal to the hydrothermal upflow zone and/or exhaled at the seafloor as moderate- to high-density brines. Molybdenum and U enrichment factors (relative to upper continental crust) and Mo/organic C values are consistent with a moderately restricted basin; Mo/C values fall between those of the Black Sea (highly restricted) and the Framvaren Inlet (moderately restricted). A Ba-rich shale was identified in rocks that are distal and time-equivalent units to the Pb-Zn mineralization; based on the bulk chemical compositions and on previous S and Sr isotope studies, we interpret the baryte in this unit to be largely hydrothermal in origin and perhaps remobilized and reprecipitated during hydrothermal base-metal mineralization.

Toxic effects of thallium acetate by acute exposure to the nematode C. elegans

BackgroundThallium (Tl) is a toxic metalloid and an emerging pollutant due to electronic devices and dispersal nearby base-metal mining. Therefore, Tl poses a threat to human health and especially the long-term impact on younger individuals exposed is still unknown. This study aimed to evaluate the toxic effects of thallium acetate in C. elegans in early larval stages, considering physiological and behavioral endpoints, as well as the Tl absorption and bioaccumulation. MethodsCaenorhabditis elegans (C. elegans) was exposed to Thallium acetate (50, 100, 150, 200, 250, 500, and 1000 μM) in the L1 larval stage, with the purpose to observe the toxic effects invoked until adulthood. Transgenic worms strains were transported GFP, reporters to DAF-16 and were used to verify the antioxidant response. ICP-MS quantified total Tl+ concentration to evidence Tl uptake and bioaccumulation. ResultsThallium acetate caused a significant reduction in the number of living worms (p < 0.0001 in 100–1000 μM), a delay in larval development (p < 0.01; p < 0.001 and p < 0.0001 in 100–1000 μM) through the larval stages, and egg production in the worm's uterus was reduced. Thallium acetate also induced behavioral changes. Additionally, thallium acetate activated antioxidant pathway responses in C. elegans by translocating the DAF-16 transcription factor and activation of SOD-3::GFP expression. The Tl+ quantification in worms showed its absorption in the L1 larval stage and bioaccumulation in the body after development. ConclusionsThallium acetate reduced survival, delayed development, caused behavioral changes, induced responses inherent to oxidative stress, and serious damage to the worm's reproduction. In addition, C. elegans absorbed and bioaccumulated Tl+. Together, our results highlight the impacts of Tl+ exposure in the early stages of life, even for a short period.

Trace element fingerprints of Ni–Fe–S–As minerals in subduction channel serpentinites

A variety of base-metal minerals (BMM) may form during hydration-dehydration of ultramafic rocks within subduction zones. However, the trace element fingerprints of these minerals and their relation to different stages of the subduction cycle are still unexplored. Here, we present the first comprehensive in situ analysis by Laser Ablation Inductively Coupled Plasma Mass Spectrometry (LA-ICP-MS) of (semi)-metals (Ni, Fe, As, Sb, Co, Bi, Te, Pb, Cd, Se, Cu, Zn, and Mn) and precious metals (Os, Ir, Rh, Pt, Pd, Au, and Ag) for Ni–Fe–S–As minerals in subducted serpentinites from the La Cabaña area (South-Central Chile). The targeted rocks are medium- and high-pressure serpentinites recording the entire cycle of burial-exhumation within a subduction zone. A first stage of hydration of upper mantle peridotites within the mantle wedge led to formation of lizardite after magmatic olivine at ~300 °C. This stage was followed by prograde hydration (i.e., antigoritization at ~320–400 °C; <1GPa) and subsequent partial dehydration (formation of prograde olivine at ~600 °C and 1.1 GPa) within the subduction channel, and final exhumation of the serpentinites and incorporation in the accretionary prism still in the stability field of antigorite (>300 °C). The Ni–Fe–S–As minerals in these serpentinites include Ni-Fe-rich sulfides [pentlandite (Ni,Fe)9S8), smythite (Fe9S11), heazlewoodite (Ni3S2), millerite (NiS)], arsenides [orcelite (Ni5-xAs2), nickeline (NiAs) and maucherite (Ni11As8)] and, to a lesser extent, alloy (awaruite, Ni3Fe) and sulfarsenides (gerdorffite, NiAsS). Their abundance, morphology and chemistry strongly vary with the degree of serpentinization and style of deformation of the host rock. Thus, euhedral grains of heazlewoodite ± awaruite ± magnetite formed in equilibrium with lizardite when magmatic olivine was hydrated within the mantle wedge. Once the lizardite-olivine serpentinites were incorporated into the subduction serpentinite channel, the infiltration of hotter (S-As-Sb)-bearing fluids promoted antigoritization under static regime and precipitation of orcelite and pentlandite in equilibrium with antigorite. Channelling of fluids in zones of focussed strain enhanced further antigoritization in some schistose serpentinites at decreasing fO2 and fS2, resulting in the transformation of pentlandite into a second generation of heazlewoodite–awaruite–magnetite. After relic olivine exhaustion, fO2 and fS2 increased promoting the replacement of the secondary heazlewoodite to millerite. No significant variations in terms of trace elements were observed during these mineral replacements associated to hydration upon prograde metamorphism and/or increasing of strain. In contrast, partial dehydration of serpentinites under high-pressure conditions (> 1GPa) generated Ni-rich awaruite in equilibrium with the prograde assemblage antigorite-metamorphic olivine. These awaruites are depleted in trace elements, indicating substantial (semi)-metal and precious metal mobility during high P-T metamorphism within the subduction channel. During the final stage of deformation linked to exhumation inside the accretionary prism some orcelite grains formed during early antigoritization recrystallized without substantial change in trace element concentration. At this stage, nickeline singularly enriched in gold formed in equilibrium with the recrystallizing orcelite. These results demonstrate that Ni–Fe–S–As minerals formed or modified during the entire subduction cycle of upper mantle rocks have their own characteristic trace element signature (i.e., depletion in precious metals and enrichment in As, Sb, Te, Bi and Pb) that distinguish them from magmatic counterparts.

Characterizing the spatial distributions of soil biota at a legacy base metal mine using environmental DNA

Characterizing the distribution of biota in response to contaminants is a critical element of site risk assessments. In this study we investigated the spatial distributions of biota and soil chemistry data in surface soil from Sunny Corner, a legacy base metal sulfide mine, Australia. Our results showed that copper (Cu), zinc (Zn), arsenic (As) and lead (Pb) in the surface soil exceeded Australian national soil quality guidelines and posed risks to the environment. Environmental (e)DNA metabarcoding of prokaryote and eukaryote composition confirmed the suggestion of environmental risk posed by these elements collectively explaining 72.9 % and 60.5 % of the total variation in the composition of soil prokaryotes and eukaryotes, respectively. Prokaryotic taxa from the phyla Gemmatimonadetes, Verrucomicrobia and Deinococcus-Thermus showed similar spatial patterns to As and Pb, and were positively correlated. Eukaryotic taxa from the phylum Chlorophyta had similar positive correlations with As and Pb in the soil. In contrast, Amoebozoa and Cercozoa, were sensitive to metals and metalloids, having higher relative abundances in soils with lower concentrations of contaminants. Our study shows that metabarcoding is a promising ecological approach for rapid, large scale assessment of contaminated and potentially impacted sites.

Primary geochemical haloes and alteration zoning applied to gold exploration in the Zarshuran Carlin-type deposit, northwestern Iran

The Zarshuran gold deposit as sediment-hosted Carlin-type has a total reserve of 120 million metric tonnes and an average grade of 3.5 g/t Au. The dominant hydrothermal alterations associated with gold mineralization are argillic and silicic as well as decalcification of the carbonate host rocks. The exploration geochemistry was applied to characterize the mineralization in the subsurface and peripheries of the open-pit mine at Zarshuran in order to enhance the proved reserves of the gold ores. A sampling network of a 10 × 10 m grid (n = 1720) was applied to almost unweathered surface outcrops to determine the primary geochemical haloes in the study area. Initially, the cut-off grades utilized in the exploratory data analysis were applied to identify the threshold values of the trace elements with lognormal distribution. Then, the central log ratio transformation was used to determine the robustness against outliers to characterize the closure problems with compositional data during Principle Component Analysis (PCA). The supra-ore and near-ore geochemical haloes are recognized by the indicator elements like As-Sb-Hg-Te-Au-Ag-Fe-Mn-Ba-F which are associated with mineral assemblages such as arsenical pyrite, orpiment, realgar, cinnabar, barite, and fluorite. The sub-ore geochemical haloes are characterized by index element association like Cu-Mo-Bi-W-Sn-Co-Ni-V-Cr. The ores at Zarshuran are enriched in Au, As, Sb, Ag, Te, Tl, Zn, Pb, and F but depleted in Cu, W, and Sn, as were observed in many other Carlin-type gold deposits. The enrichment factor of indicator elements (except S, Ag, and Sb) gradually decreases in value from the highly altered and mineralized zones (in proximity of the mine) toward the zones with least alteration and mineralization (in the distal parts of the mine). According to PCA analysis, two main types of ore mineralization occurred at Zarshuran, (1) Au mineralization associated with As, Sb, and Hg, and (2) Cu-Zn-Pb base-metal mineralization related to Ag. The ore-forming index was used to determine the primary axial haloes in both shallow (<−80 m) and deep (>−120 m) levels. The results of this study show that the main ore body may extend eastwardly and downwardly to greater depths, as was verified by the data obtained from diamond drill cores in the eastern part of the mine.

Gold in Paleoproterozoic (2.1 to 1.77 Ga) Continental Magmatic Arcs at the Tapajós and Juruena Mineral Provinces (Amazonian Craton, Brazil): A New Frontier for the Exploration of Epithermal–Porphyry and Related Deposits

This review paper aims to integrate geological, tectonic and metallogenetic data, including new data, and propose a regional model for the gold (and base metal) mineralization in the south Amazonian Craton to support the mineral exploration concerning magmatic–hydrothermal deposits. The Proterozoic evolution of the Amazonian Craton comprises the accretion of terrains to the Archean Carajás Mineral Province. In the Tapajós and Juruena mineral provinces, located at the south part of the Amazonian craton, a long-lived ocean–continent subduction event produced ca. 2.0 to 1.77 Ga continental magmatic arcs. Extensive lava flows, volcaniclastic, sedimentary, and plutonic rocks were originated during at least four major orogenic magmatic events (ca. 2.1, 1.9, 1.88, and 1.80 Ga) and two post- to anorogenic events (ca. 1.87 and 1.77 Ga). Gold mineralization occurs in: (i) alluvial/colluvial occurrences, (ii) orogenic carbonate–sulfide-rich quartz veins in shear zones, (iii) stockworks, veins, and dissemination in granites, (iv) contact of basic dikes, (v) well-preserved high-, intermediate- and low-sulfidation epithermal mineralization, and (vi) porphyry-like and intrusion-related gold systems associated with late- to post-orogenic epizonal granites. The estimated historical gold production, mainly in secondary deposits, is over 27 Moz at the Tapajós and 6 Moz at the Juruena provinces. A total resource of over 5 Moz Au is currently defined in several small to large primary gold deposits. Andesite to rhyolite, volcaniclastic, and clastic sedimentary rocks (1.96–1.88 Ga) host epithermal (high-, intermediate-, and low-sulfidation) Au–(Ag–Pb–Zn) mineralization, whereas Au–Cu and Cu–Mo–Au mineralization is hosted in sub-volcanic tonalitic to granitic plutons. Advanced argillic alteration (alunite, pyrophyllite, enargite) associated with high-sulfidation mineralization occurs in ring volcanoes around nested volcanic calderas. This zone grades outward to propylitic or chlorite alteration, often covered by silica caps with vuggy silica. Lava flows and volcaniclastic rocks within faults or associated with volcanic edifices and rhyolitic domes host low- and intermediate-sulfidation mineralization. Low-sulfidation alteration zones typically have adularia and illite or sericite. Chalcopyrite, sphalerite, galena, pyrite, digenite, and manganiferous calcite are related to intermediate-sulfidation gold mineralization. Late- to post-orogenic evolved oxidized I-type granitoids host alkalic-type epithermal and porphyry-like gold mineralization. Porphyry-style hydrothermal alteration is analogous to those of modern systems, with inner sodic and potassic (potassic feldspar ± biotite or biotite) alterations grading to propylitic, muscovite-sericite, chlorite–sericite, and chlorite alterations. Potassic alteration zones are the locus of Cu–Mo mineralization, and gold-rich zones occur in muscovite/sericite–quartz–pyrite alteration. The Paleoproterozoic epithermal and porphyry-like mineralization in these large provinces defines a new frontier for the exploration of world-class gold deposits in the worldwide Proterozoic arc-related magmatic terrains.

Impact assessment of ephemeral discharge of contamination downstream of two legacy base metal mines using environmental DNA

Mining and processing metalliferous ores can degrade the environment well beyond the footprint of the mine, particularly where on-site containment and post-mining remediation has been insufficient to prevent releases of solid and aqueous mine wastes. In this study, we investigated the potential of sediment and water chemistry coupled with environmental (e)DNA metabarcoding to evaluate discrete and cumulative ecological impacts of two legacy base metal (copper (Cu), zinc (Zn), lead (Pb)) mines (Peelwood and Cordillera) which discharge metals via ephemeral tributaries into perennial Peelwood Creek. Although the two mine streams exceeded Australian guidelines for sediment and freshwater quality for Cu, Zn and Pb, Peelwood Creek had relatively low sediment and water metal concentrations, suggesting a low potential for environmental toxicity. Although sediment and water chemistry defined the extent of biological impacts, metabarcoding showed that Peelwood and Cordillera mines had discrete impacts and Peelwood mine was the main source of contamination of Peelwood Creek. Metabarcoding showed that prokaryotes can be good indicators of metal contamination whereas eukaryotes did not reflect contamination impacts in Peelwood Creek. Metabarcoding results showed that benthic communities downstream of Cordillera mine were less impacted than those below Peelwood mine, suggesting that Peelwood mine should be considered for further remediation.

Geology, mineralogy, and sulfur isotopes of the Mowana copper deposit, Matsitama Schist Belt, NE Botswana

AbstractThe Mowana hydrothermal Cu deposit is located within the Matsitama–Motloutse Complex in the southwestern part of the Zimbabwe Craton in the northeastern part of Botswana. This study aims to document the characteristics of the mineralization based on geology, quartz textures, ore mineralogy, chlorite geothermometry, and sulfur isotope analyses. The deposit is hosted by the NNE‐striking and nearly vertically dipping (70–80°) Bushman Lineament, within the graphitic schist lenses in the carbonaceous and argillaceous metasedimentary rocks of the Neoarchean to Paleoproterozoic Matsitama Sedimentary Group. The hydrothermal alteration of the host rocks is characterized by silicification, chloritization, epidotization, sericitization, hematite, and calcite alteration. Based on the alteration mineral assemblage, the main mineralization stage is attributed to near neutral pH fluids at temperatures between ~200 and ~340°C. The base metal mineralization of the Mowana deposit was evolved in at least two vein types. The first mineralization type, represented by the quartz+calcite±K‐feldspar veins and breccias is characterized by the precipitation of principal chalcopyrite with pyrite, minor bornite, and trace amounts of galena. The Type 2 veins represented by the quartz+calcite±fluorite veins, host appreciable amounts of galena. The supergene mineralization widely distributed in the shallow levels of the deposit is manifested by the significant presence of chalcocite, bornite, covellite, anglesite, malachite, and hematite. The temperature obtained from the chlorite geothermometry in the Type 1 veins indicate that the mineralization associated with chlorite alteration formed at a temperature ranging from 340 to 400°C. The ore mineral assemblage: pyrite, bornite, and chalcopyrite, paired with the chlorite geothermometry data indicate that the Type 1 veins formed at an intemediate to high sulfidation state. Sulfur isotopic ratios determined on the sulfides indicate the magmatic S and/or leaching of the host metasedimentary rocks and closed system reduction of seawater sulfate as the sources of S.