Basaltic Trachyandesite Research Articles

Petrogenetic and tectonic implications of major and trace element and radiogenic isotope geochemistry of Pliocene to Holocene rocks from the Tacaná Volcanic Complex and Chiapanecan Volcanic Belt, southern Mexico

New major and trace element, and Sr, Nd and Pb isotope data for samples from the Volcán Tacaná, along with the published data from the Tacaná Volcanic Complex (TVC) and Chiapanecan Volcanic Belt (CVB), were used to better constrain the petrogenesis of the Pliocene to Holocene volcanism in southwestern Mexico. The TVC volcanic rocks sampled in this study were andesite, whereas the literature samples included, besides andesites, one subalkali basalt and a few dacites. The CVB housing the prominent El Chichón volcano, on the other hand, showed more alkalic magmatic products (trachyandesite and basaltic trachyandesite) but also included a few basalts and dacites. The enclaves and lithic fragments sampled from both TVC and CVB showed wide SiO2 compositions similar to the volcanic products. The CVB rocks are more enriched in REE, LILE, and HFSE than the TVC. The combined data of volcanic rocks were evaluated through conventional multi-element diagrams as well as subduction- or crust-sensitive parameters. Although the TVC constitutes the northern end of the Central American Volcanic Arc (CAVA), some chemical differences were documented between them such as the TVC rocks have higher LILE, REE, HFSE, and combined ratio parameters. More importantly, the CVB seems to be significantly different from both TVC and CAVA as well as from other continental arcs such as higher LILE, REE, HFSE, and distinct isotopic signature, which may indicate that the origin of the CVB volcanism represents a direct action of the abundant strike-slip faults and extensional system prevalent in this area. Finally, the relationship of basic and evolved rocks from the CVB, especially on isotope-isotope diagrams, also suggests that the lower crust may have contributed to evolved magmas during the ascent of basic magmas through the crust.

Rock Magnetic, Petrography, and Geochemistry Studies of Lava at the Ijen Volcanic Complex (IVC), Banyuwangi, East Java, Indonesia

Lava has complex geochemical characteristics based on differences in eruption centers, eruptive events, and flow emplacement. Characterization of lava is useful for understanding the geological conditions of a volcanic region. To complement geochemical methods, rock magnetic methods are being used to analyze lava. To explore the potential uses of rock magnetic methods for lava characterization, a series of magnetic measurements were completed in lava samples from eight locations in the Ijen Volcanic Complex (IVC) in Banyuwangi, East Java, Indonesia. These locations were grouped into two eruption centers: Ijen Crater and Mount Anyar. The magnetic measurements included frequency-dependent magnetic susceptibility, thermomagnetic, anhysteretic remanent magnetization (ARM), isothermal remanent magnetization (IRM), and hysteresis curve analyses. These measurements were supplemented using X-ray fluorescence, petrography analyses, and Scanning Electron Microscopy with Energy Dispersive Spectroscopy (SEM-EDS). Based on their lithology, lava samples were categorized into basalt, basaltic andesite, and basaltic trachyandesite. The dominant magnetic mineral contained in the sample was iron-rich titanomagnetite and titanium-rich titanomagnetite with a magnetic pseudo-single-domain and small amounts of superparamagnetic grain minerals in some samples. The significant difference in mass specific susceptibility (χLF) is caused by differences in the crystallization process. The differences in susceptibility frequency dependence (χFD) highlighted the differences in the magma cooling rate, demonstrated by the differences in the percentage of opaque mineral groundmass. The rock magnetic method was proven to support the geochemistry and petrography methods used to characterize lava and identify the causes of differences in lava characteristics.

Petrogenesis of lamprophyre and associated diabase dykes in Wadi Mandar-Um Adawi area, South Sinai, Egypt

The mafic dykes in Wadi Mandar-Wadi Um Adawi area are as follows: (1) calc-alkaline lamprophyre (i.e., kersantite and spessartite), (2) diabase, and (3) alkaline lamprophyre (i.e., camptonite). The field relations reveal that the emplacement of calc-alkaline lamprophyres preceded the diabase dykes, while alkaline lamprophyres emplaced later than the diabase dykes. Calc-alkaline are basaltic andesite, basaltic trachyandesite to basalt, while the diabase dykes and alkaline lamprophyres are basaltic in composition. These dykes are characterized by metaluminous character. Calc-alkaline lamprophyres and diabase dykes show transitional affinity from calc-alkaline to alkaline, while the alkaline lamprophyres exhibit more strong alkaline character. The mafic dykes were crystallized under temperature 1100–1150 °C and pressure 3–5 kbars in a high oxygen fugacity conditions. Fe-Ti oxides in the dykes are represented by ilmenite and Ti-magnetite. The chemistry of the sulfides hosted in those mafic dykes suggests a magmatic-hydrothermal origin for these minerals. The geochemical behavior of high field strength elements and large ion lithophile elements in these dykes excludes the derivation of diabase or alkaline lamprophyre either by partial melting or fractional crystallization from calc-alkaline lamprophyre. The parental magmatic sources of the studied dykes were generated from crustal material with addition of mantle-derived melt during the post-collisional stage. The mafic dykes in Wadi Mandar-Wadi Um Adawi area were generated from different magmatic sources by partial melting and subsequent fractional crystallization. In addition, the crustal contamination/assimilation process has a prominent role in the magmatic evolution of diabase and alkaline lamprophyre dykes.

Contemporaneous alkaline and calc-alkaline series in Central Anatolia (Turkey): Spatio-temporal evolution of a post-collisional Quaternary basaltic volcanism

This study focuses on spatio-temporal evolution of basaltic volcanism in the Central Anatolian post-collisional Quaternary magmatic province which developed along a NE-SW orientation in Turkey. This magmatic province consists of the stratovolcanoes Erciyes (ES) and Hasandag (HS), and the basaltic volcanic fields of Obruk-Zengen (OZ) and Karapınar (KA). The investigated samples range between basic to intermediate in composition (48–56wt% SiO2), and exhibit calc-alkaline affinity at ES whereas HS, OZ and KA are alkaline in composition. Based on new KAr ages and major element data, the oldest basaltic rock of ES is 1700±40ka old and exhibits alkaline character, whereas the youngest basaltic trachyandesite is 12±5ka old and calc-alkaline in composition. Most ES basaltic rocks are younger than 350ka. All samples dated from HS are alkaline basalts, ranging from 543±12ka to 2±7ka old. With the exception of one basalt, all HS basalts are ~100ka or younger in age. KAr ages range from 797±20ka to 66±7ka from OZ. All the basalt samples are alkaline in character and are older than the HS alkaline basalts, with the exception of the youngest samples. The oldest and youngest basaltic samples from KA are 280±7ka and 163±10ka, respectively, and are calc-alkaline in character. Based on thermobarometric estimates samples from OZ exhibit the highest cpx-liqidus temperature and pressure. For all centers the calculated crystallization depths are between 11 and 28km and increase from NE to SW. Multistage crystallization in magma chamber(s) located at different depths can explain this range in pressure. Harker variation diagrams coupled with least-squares mass balance calculations support fractional crystallization for ES and, to lesser extend for HS, OZ and KA. All basaltic volcanic rocks of this study are enriched in large-ion lithophile elements (LILE) and light rare earth elements (LREE). The lack of negative anomalies for high field strength elements (HFSE; Y, Yb) and the La/Nb >1 favor a shallow lithospheric source for ES, HS, OZ and KA basaltic volcanic rocks, whereas some samples bear the trace element signature of an asthenospheric mantle source. The lithospheric mantle beneath Central Anatolia may have not been affected from asthenospheric mantle directly. Negative Nb-Ta-Ti anomalies and a positive Pb spike of ES, HS, OZ and KA may be ascribed to crustal contamination or as the imprints of the previous subduction processes. According to this study, and previous studies, the effect of subduction and/or crustal contamination in Central Anatolia decreased from the Miocene to the Quaternary, and the origin of the Quaternary basaltic rocks mainly derived from subduction-related magmas enriched with sediment input rather than to slab-derived fluids. Our calculated eruption ages for the four basaltic complexes show that spatial differences predominate, whereas temporal trends are difficult to discern due to limited age resolution. According to the available geochronological, petrological and geochemical data, alkaline and calc-alkaline volcanism occurred simultaneously from distinct parental magmas.

Hainan mantle plume produced late Cenozoic basaltic rocks in Thailand, Southeast Asia

Intraplate volcanism initiated shortly after the cessation of Cenozoic seafloor spreading in the South China Sea (SCS) region, but the full extent of its influence on the Indochina block has not been well constrained. Here we present major and trace element data and Sr-Nd-Pb-Hf isotope ratios of late Cenozoic basaltic lavas from the Khorat plateau and some volcanic centers in the Paleozoic Sukhothai arc terrane in Thailand. These volcanic rocks are mainly trachybasalts and basaltic trachyandesites. Trace element patterns and Sr-Nd-Pb-Hf isotopic compositions show that these alkaline volcanic lavas exhibit oceanic island basalt (OIB)-like characteristics with enrichments in both large-ion lithophile elements (LILE) and high field strength elements (HFSEs). Their mantle source is a mixture between a depleted Indian MORB-type mantle and an enriched mantle type 2 (EMII). We suggest that the post-spreading intraplate volcanism in the SCS region was induced by a Hainan mantle plume which spread westwards to the Paleozoic Sukhothai arc terrane.

Geology and radiometric dating of Quaternary monogenetic volcanism in the western Zacapu lacustrine basin (Michoacán, México): implications for archeology and future hazard evaluations

The Zacapu lacustrine basin is located in the north-central part of the Michoacan-Guanajuato volcanic field (MGVF), which constitutes the west-central segment of the Trans-Mexican Volcanic Belt. Geological mapping of a 395 km2 quadrangle encompassing the western margin of the basin, 40Ar/39Ar and 14C radiometric dating, whole-rock chemical and petrographic analyses of volcanic products provide information on the stratigraphy, erupted volumes, age, and composition of the volcanoes. Although volcanism in the MGVF initiated since at least 5 Ma ago, rocks in the western Zacapu lacustrine basin are all younger than ~ 2.1 Ma. A total of 47 volcanoes were identified and include 19 viscous lava flows (~ 40 vol.%), 17 scoria cones with associated lava flows (~ 36 vol.%), seven lava shields (~ 15 vol.%), three domes (~ 6 vol.%), and one maar (~ 2 vol.%). Erupted products are dominantly andesites with 42 km3 (~ 86 vol.%) followed by 4 km3 of dacite (~ 8 vol.%), 1.4 km3 of basaltic trachy-andesite (~ 3 vol.%), 1 km3 of basaltic andesite (~ 2 vol.%), and 0.14 km3 of rhyolite (~ 0.3 vol.%). Eruptive centers are commonly aligned ENE-WSW following the direction of the regional Cuitzeo Fault System. Over time, the high frequency of eruptions and consequent accumulation of lavas and pyroclastic materials pushed the lake’s shore stepwise toward the southeast. Eruptions appear to have clustered through time. One cluster occurred during the Late Pleistocene between ~ 27,000 and ~ 21,300 BC when four volcanoes erupted. A second cluster formed during the Late Holocene, between ~ 1500 BC and ~ AD 900, when four closely spaced monogenetic vents erupted forming thick viscous ‘a’a to blocky flows on the margin of the lacustrine flats. For still poorly understood reasons, these apparently inhospitable lava flows were attractive to human settlement and eventually became one of the most densely populated heartlands of the pre-Hispanic Tarascan civilization. With an average eruption recurrence interval of ~ 900 years during the Late Holocene the western Zacapu lacustrine basin is one of the most active areas in the MGVF and should hence be of focal interest for regional volcanic risk evaluations.

Dynamics and viscosity of ‘a’a and pahoehoe lava flows of the 2012–2013 eruption of Tolbachik volcano, Kamchatka (Russia)

The 2012–2013 flank eruption of Tolbachik volcano (Kamchatka) lasted 9 months and produced 0.54 km3 of basaltic trachyandesite lava, thus becoming one of the most voluminous historical lava effusions of basic composition in subduction-related environments globally. From March to July 2013, the volcano monotonously erupted lava of constant composition (SiO2 = 52 wt%) with a nearly stable effusion rate of 18 m3/s. Despite the uniform eruptive and emplacement conditions, the dominant style of lava propagation throughout that time gradually changed from ‘a’a to pahoehoe. We report results of instrumental field measurements of the ‘a’a and pahoehoe flow dynamics (documented with time-lapse cameras) as well as the lava viscosity determined by flow rate and shear stress (using penetrometer) methods. Maximal propagation velocities of the ‘a’a fronts ranged from 2 to 25 mm/s, and those of the pahoehoe from 0.5 to 6 mm/s. The flow front velocities of both lava types experienced short-period fluctuations that were caused by complex flow mechanics of the advancing flow lobes. Minimal viscosities of lava of the ‘a’a lobes ranged from 1.3 × 105 to 3.3 × 107 Pa s (flow rate method), and those of the pahoehoe from to 5 × 103 to 5 × 104 Pa s (shear stress method). Our data include the first ever measured profiles of viscosity through the entire thickness of actively advancing pahoehoe lava lobes. We have found that both the ‘a’a and pahoehoe flows were fed by identical parental lava, which then developed contrasting rheological properties, owing to differences in the process of lava transport over the ground surface. The observed transition from the dominant ‘a’a to the dominant pahoehoe propagation styles occurred due to gradual elongation and branching of the lava tube system throughout the course of the eruption. Such evolution became possible because the growing lava field, composed of semisolidified flows, provided an environment for shallow subsurface intrusions and internal migrations of lava that, with time, developed into branches of the lava tube system. Based on our data, we propose phenomenological models of the ‘a’a and pahoehoe flow mechanics.

Discovery of modern (post-1850 CE) lavas in south-central British Columbia, Canada: Origin from coal fires or intraplate volcanism?

We describe three unusual lavas in the Northern Cordillera in south-central British Columbia, Canada, occurring as spatter, scoria and blocks over small ~400m2 areas. The lavas coat and weld cobbles and pebbles in glacial till and are vesicular and glassy with microlites of clinopyroxene and plagioclase, and xenocrysts of quartz, feldspar or clinopyroxene. Chemically the lavas are basaltic trachyandesite (55–61wt% SiO2) with trace element patterns similar to average British Columbia upper crust, except for having higher V and lower Zr, Hf, Nb, Th and U. Melting experiments and plagioclase-melt thermometry on the glasses, and phase equilibrium in simple systems, require liquidus temperatures of 1150–1300°C. Interaction of the liquids with carbonaceous matter at low pressure formed Fe metal spherules and SiC. Radiocarbon ages of charcoal and dendrochronology show the lavas are modern, emplaced in the last ~120years. The similar bulk composition of these lavas to several other Quaternary-aged volcanic centers in the North American Cordillera, some of which show recent seismic activity, could suggest a possible tectonic origin, but the deposits are unusually small and show no central vent for emplacement. Conversely, the balance of evidence would suggest an origin from coal fires or hot gas venting, but is less consistent with the observed calc- and per-alkaline lava compositions, and the lack of known local coal-bearing strata as a heat source. Other anthropogenic origins for the lavas are considered less plausible.

U-Pb geochronology, Sr-Nd geochemistry, petrogenesis and tectonic setting of Gandab volcanic rocks, northeastern Iran

Abstract This paper addresses U-Pb geochronology, Sr-Nd geochemistry, petrogenesis and tectonic setting in the Gandab volcanic rocks. The Gandab volcanic rocks belong to the Sabzevar zone magmatic arc (northeastern Iran). Petrographically, all the studied volcanic rocks indicate porphyritic textures with phenocrysts of plagioclase, K-feldespar, hornblende, pyroxene, and magnetite which are embedded in a fine to medium grained groundmass. As well, amygdaloidal, and poikilitic textures are seen in some rocks. The standard chemical classifications show that the studied rocks are basaltic trachy andesite, trachy andesite, trachyte, and trachy dacite. Major elements reveal that the studied samples are metaluminous and their alumina saturation index varies from 0.71 to 1.02. The chondrite-normalized rare earth element and mantle-normalized trace element patterns show enrichment in light rare earth elements (LREE) relative to heavy rare earth elements (HREE) and in large ion lithophile elements (LILE) relative to high field strength elements (HFSE). As well they show a slightly negative Eu anomaly (Eu/Eu* = 0.72 – 0.97). The whole-rock geochemistry of the studied rocks suggests that they are related to each other by fractional crystallization. LA-MC-ICP-MS U-Pb analyses in zircon grains from two volcanic rock samples (GCH-119 and GCH-171) gave ages ranging of 5.47 ± 0.22 Ma to 2.44 ± 0.79 Ma, which corresponds to the Pliocene period. In four samples analysed for Sr and Nd isotopes 87Sr/86Sr ratios range from 0.704082 to 0.705931 and εNd values vary between +3.34 and +5. These values could be regarded to as representing mantle derived magmas. Taking into account the comparing rare earth element (REE) patterns, an origin of the parental magmas in enriched lithospheric mantle is suggested. Finally, it is concluded that Pliocene Gandab volcanic rocks are related to the post-collision environment that followed the Neo-Tethys subduction.

Geochemical and Sr-Nd-Pb isotope characteristics of the Miocene to Pliocene volcanic rocks from the Kandilli (Erzurum) area, Eastern Anatolia (Turkey): Implications for magma evolution in extension-related origin

This paper presents Sr-Nd-Pb isotopic and whole-rock geochemical data of Miocene to Pliocene volcanic rocks in the Eastern Anatolia (Turkey) aiming to unravel their sources and evolutionary history. The wide compositional range of lavas and pyroclastics includes basaltic andesite, basaltic trachyandesite, trachyandesite, andesite and trachydacite. These calc-alkaline volcanics are enriched in large ion lithophile elements and light rare earth elements and depleted in the high field strength elements. Sr-Nd isotope data indicate low values for 87Sr/86Sr(i) (0.70432–0.70464) and high values for 143Nd/144Nd(i) (0.51272–0.51282). Further, these data are within the mantle array of the isotope ratio diagram. The lead (Pb) isotopic compositions (206Pb/204Pb(i)=18.33 to 18.62, 207Pb/204Pb(i)=15.51 to 15.60, 208Pb/204Pb(i)=38.10 to 38.45) reveals the presence of an enriched source. The main petrological processes involved fractional crystallization and the mixing of at least two fractionated magmas having same source characteristics. All evidence supports the findings that the Kandilli volcanic rocks were derived from a partial melting of the both spinel and garnet bearing subcontinental lithospheric mantle, which had been previously metasomatized by mostly fluids derived from subducted slab during the collisional and post-collisional extension-related geodynamic setting in the Eastern Anatolia region of Turkey.

Eclogite trace in evolution of Late Cenozoic alkaline basalt volcanism on the southwestern flank of the Baikal Rift Zone: Geochemical features and geodynamic consequences

Eclogitized material from the oceanic lithosphere are the most likely source of alkaline basalt magmas in the formation of Late Cenozoic volcanic areas on the southwestern flank of the Baikal Rift Zone. Basaltic trachyandesites of the early stage of volcanism (Pg32 ~ 28–23 Ma) are rich in high field strength elements (HFSE), P2O5, F, Zn, Ga, Sr, Sn, and light rare earth elements (LREE); they are characterized by high values of the following ratios: Fe/Mn = 72–77, Sm/Yb = 7.7–8.5, Sr/Y = 57–63, and Ga/Sc = 2.1–2.3. At this stage, magmas are formed under conditions with a 2–8% degree of partial melting of the mantle substrate enriched with the material of the eclogite source (50–70%) (Cpx/Grt = 1.5–1.7). Basaltoid magmas of the final stage of volcanism (N13–N21 ~ 6–4 Ma) are formed from melting (1.5–4%) of a less fertilized mantle (Cpx/Grt = 2.1–3.1, Fe/Mn = 62–71, Sm/Yb = 3.5–4.6, Sr/Y = 29–44, Ga/Sc = 1.0–1.4). The directed variations of the compositions of the successive basaltoid magmas, which were formed in the Late Cenozoic, create an “eclogite trace” in this area.

Clinopyroxene composition of volcanics from the Manipur Ophiolite, Northeastern India: implications to geodynamic setting

The volcanic section of the Manipur Ophiolite (MO), representing the crustal portion of the Neo-Tethyan oceanic lithosphere occurs as basalt, basaltic trachyandesite, and dacite in the Gamnom-Phangrei sector, Manipur, at 25°01′N–25°09′N and 94°24′E–94°27′E. They associate with cherts and ultramafics. The clinopyroxene compositions of basalt and basaltic trachyandesite, obtained through electron microprobe analyzer, were used as a petrogenetic indicator to identify the parent magma-types and their tectonic settings. Based on the variable content of major oxides, they are classified as high- and low-Ti clinopyroxenes. High Ti and Al contents with relatively lower silica saturation are observed in the former group and vice versa in the latter. The TiDCpx/rock values in low- and high-Ti clinopyroxene are comparable with island-arc basaltic andesite and MORB, respectively, which confirms that the clinopyroxene composition is primarily related to the host magma-type and its tectonic setting. Clinopyroxene thermometry (ranging 1150–605 °C) suggests progressive differentiation of the parent magmas. Several bivariate and tectonic discrimination diagrams depict MORB (non-orogenic setting) and island-arc boninitic magma affinities (orogenic setting) for the high- and low-Ti clinopyroxenes, respectively. The coexistence of both MORB and island-arc boninitic magma-types in the volcanic section of Manipur Ophiolite as characterized by their varying Ti, Al, and Si contents may indicate either juxtaposition of rocks formed in diverse tectonic settings (i.e., due to transformation of tectonic setting from mid-ocean ridge to supra-subduction zone) or, a change in magma composition in a subduction zone setting. However, field relationships coupled with the mineral–chemical signatures implies a supra-subduction zone setting for the evolution of the crustal section of MO.

GEOCHEMICAL CHARACTERISTICS OF THE ERENLERDAGI VOLCANICS, KONYA, CENTRAL TURKEY

Late Miocene to Pliocene volcanism produced lava domes with mafic microgranular enclaves (MMEs), nuée ardentes and pyroclastic fall and flow (ignimbrites) deposits in the WSW and NW of Konya city. All samples are predominantly high K-calc alkaline in composition but calc-alkaline and shoshonitic composition also exist. The felsic volcanics are mainly dacite, andesite, basaltic trachyandesite and rare trachyandesite in compositon. But, the MMEs have basaltic andesite and andesite compositon. SiO2 increases with decreasing TiO2, FeOt, MgO and CaO, suggesting fractional crystallization of mafic minerals. All samples have fractionated chondritenormalised REE pattern (La/YbN: 6.7-18.1), and negative Eu anomaly (Eu/Eu*: 0.67- 0.89), indicating plagioclase fractionation. In primitive mantle-normalized spider diagram, the samples show an enrichment in large ion litophile elements (LILE) such as Cs and Ba, and depletion in high field strength elements (HFSE), e.g. Dy and Y. They show negative Nb, Ta and Ti anomalies, indicating a subduction signature for their genesis. Based on geochemical data, the volcanics are suggested to have been formed by Assimilation-Fractional Crystallization (AFC) and/or magma mixing process. Various geotectonic diagrams imply volcanic arc to post collisional setting for the samples.

GEOCHEMICAL CHARACTERISTICS OF THE MAFIC ENCLAVES AND THEIR HOSTS FROM NEOGENE ERENLERDAGI VOLCANITES, AROUND YATAGAN VILLAGE AND SAĞLIK TOWN (KONYA), CENTRAL TURKEY

Late Miocene to Pliocene volcanism is represented by development of lava domes, nuée ardentes and pyroclastic fall and flow (ignimbrites) deposits in the WSW and NW of Konya city. The lava dome contains various mafic microgranular enclaves (MMEs), which have various size (a few cm to a few meters), shape (ellipse/sphere to rounded), with a well-developed chilly zone. The MMEs samples are situated on mostly basaltic andesite and andesite, and a few MME samples on basaltic trachyandesite area while the host rocks are concentrated on dacite and andesite areas. The felsic samples have more fractionated chondrite-normalised REE pattern (La/YbN: 9.5-18.1) than MMEs (6.7-16.0) ones, but both have slightly developed negative Eu anomaly (Eu/Eu*: 0.67-0.89 in felsic rocks, 0.68-0.87 in MMEs). In primitive mantlenormalized spider diagram, the MMEs and felsic rocks have negative Nb, Ta, P and Ti anomalies, indicating some subduction component in their genesis. Based on geochemical data, the MMEs are suggested to have been formed by hybridization of basic magma mingled with partially crystallized felsic magma.

Elemental and Sr-Nd-Pb isotope geochemistry of the Florianópolis Dyke Swarm (Paraná Magmatic Province): crustal contamination and mantle source constraints

The Florianópolis Dyke Swarm is located in Santa Catarina Island, comprising also the adjacent continental area, and belongs to the Paraná Magmatic Province (PMP). The dyke outcrops in the island are 0.1–70m thick and most of them are coast-parallel (NE-SW trending), with subordinate NW-SE trending. The vast majority of the dykes has SiO2 varying from 50 to 55wt% and relatively high-Ti (TiO2>3wt%) contents and these rocks were divided using the criteria commonly used to distinguish the different magma-types identified in the volcanic rocks from the PMP. The Urubici dykes (Sr>550μg/g) are the most abundant and some of them experienced crustal contamination reaching to 10%, as evidenced by low P2O5/K2O (0.30–0.21), high (Rb/Ba)PM (1.0–2.2), and radiogenic Sr and Pb isotope compositions (87Sr/86Sri up to 0.70716 (back to 125Ma) and 206Pb/204Pbm up to 19.093). The Pitanga (Sr<550μg/g) and the basaltic trachyandesite dykes are less abundant and almost all of them were also substantially affected by at least 15% of crustal assimilation, evidenced by high (Rb/Ba)PM (up to 2.6) and Sr (87Sr/86Sri=0.70737–0.71758) and Pb (206Pb/204Pbm=18.446–19.441) isotope ratios, as well as low P2O5/K2O values (0.30–0.18). The low-Ti (TiO2<2wt%) dykes are scarce and show a large compositional variability (SiO2: 50.4–64.5wt%), with similar geochemical characteristics of the low-Ti volcanic rocks (Gramado-Palmas) from southern PMP, although the most primitive dykes show hybrid characteristics of Ribeira and Esmeralda magmas. The presence of granitic xenoliths with border reactions and dykes with diffuse contacts indicate that crustal contamination probably occurred by assimilation from re-melted the host rocks. Considering only the high-Ti Urubici dykes that were not affected by crustal contamination, the Sr, Nd and Pb isotope mixing modelling indicates the participation of a heterogeneous metasomatized (refertilized) subcontinental lithospheric mantle (SCLM). This mantle source was originated by partial melting of a depleted sublithospheric mantle (DMM – Depleted Mantle MORB), which was hybridized by addition of pyroxenite (<5%) and carbonatite (up to 2%) melts. The isotope mixing modelling also points to a significant participation (up to 50%) of Archean SCLM, not evidenced in the mantle sources of the northern PMP high-Ti Pitanga flows (dominated by Neoproterozoic SCLM).

Iron and Zinc isotope fractionation during magmatism in the continental crust: Evidence from bimodal volcanic rocks from Hailar basin, NE China

This study presents Fe–Zn isotope data for a suite of well–characterized bimodal volcanic rocks from Hailar Basin, northeast China to understand the mechanism of Fe isotope fractionation in highly differentiated igneous rocks. The samples range from basaltic trachyandesites to trachytes–rhyodacites, and rhyolites. The δ56Fe values increase with increasing SiO2 contents with the rhyolites having the highest δ56Fe (up to 0.64±0.02‰) among the previously reported data for igneous rocks at a similar SiO2. The lack of correlation between δ56Fe and Rb/La argues against the effect of fluid exsolution on Fe isotopes. The δ56Fe do not show a clear correlation with δ66Zn and radiogenic isotopes, suggesting that thermal diffusion or crustal contamination cannot produce the high δ56Fe in Hailar volcanic rocks.Fe isotopic variation in Hailar volcanic rocks can be explained by two steps of magmatism. During the first step, partial melting of basaltic trachyandesites with an average δ56Fe of 0.09±0.14‰ produced trachytes–rhyodacites with an average δ56Fe of 0.24±0.27‰. Modelling using rhyolite–MELTS shows that Fe isotopes can be fractionated by preferential partitioning of isotopically different Fe3+ and Fe2+ between the solid residue and partial melt. The second step involves formation of rhyolites with significantly high δ56Fe through partial melting or extensive crystallization of crust materials, during which isotopically heavy Fe preferentially partition into the rhyolitic melt. Therefore, fractionation of Fe isotopes between melts and minerals can result in high δ56Fe in SiO2-rich igneous rocks and apparent Fe isotope heterogeneity within the continental crust.

Quaternary basaltic volcanism in the Golden Trout Volcanic Field, southern Sierra Nevada, California

The Golden Trout Volcanic Field (GTVF) produced the only Quaternary eruptions of mafic magma within the southern Sierra Nevada block. Approximately 38×106m3 of basalt, trachy-basalt, basaltic trachy-andesite, and basaltic andesite (50.1–56.1% SiO2, 1.1–1.9% K2O, and 5.4–9.1% MgO) was erupted from four vents within a ~10km2 portion of the GTVF, which also includes rhyolite domes that are not considered in this study. The vents include, from oldest to youngest: Little Whitney Cone, South Fork Cone, Tunnel Cone, and unglaciated Groundhog Cone. Little Whitney Cone is a 120m-high pile of olivine-CPX-phyric scoria produced during a Strombolian-style eruption overlying two columnar jointed lava flows. Tunnel Cone formed through a Hawaiian-style eruption along a 400m-long north-south trending fissure that excavated at least three 25–65m-wide craters. Crater walls up to 12m high are composed of plagioclase-olivine-phyric spatter-fed flows that dip radially away from the crater center and crumble to form Tunnel Cone's steep unconsolidated flanks. South Fork Cone is a 170m-high pile of plagioclase-olivine-phyric scoria that formed during Strombolian to violent Strombolian eruptions. South Fork Cone overlies the South Fork Cone lava, a 9.5km-long flow (~12×106km3) that reached the Kern River Canyon to the west. Scoria and airfall deposits originating from South Fork Cone are located up to 2km from the vent. Groundhog Cone is a 140m-tall cinder and spatter cone breached on the north flank by a 13×106m3 lava flow that partially buried the South Fork Cone lava and extends 7.5km west to Kern River Canyon. Incompatible trace element concentrations and ratios show vent-specific trends but are unsystematic when plotted in terms of all mafic GTVF vents, implying that GTVF basalts were derived from a lithospheric mantle source and ascended through thick granitic Sierra Nevada crust as discrete batches that underwent different degrees of crustal contamination, differentiation, and magma mixing. Clinopyroxene-liquid thermobarometry calculations of the oldest and most primitive GTVF sample indicate that most clinopyroxene crystals record nucleation conditions of 1172–1196°C and 896–1115MPa. These pressures correspond to depths equivalent to, or up to 10km shallower than, the Moho in this region. Deposits from the oldest GTVF vents are more primitive and homogeneous in terms of major and trace element concentrations, phenocryst textures and compositions, and their general absence of crustal xenoliths and xenocrysts compared to younger eruptive products. The eruption rate of the GTVF (~0.05km3/Myr) is two orders of magnitude less than neighboring and contemporaneous Big Pine and Coso volcanic fields to the north and east, respectively. We interpret these differences to result from a relative lack of strain in the GTVF region of the southern Sierra Nevada block, which limits magma accumulation and ascent.

Geochemistry, petrology, and mineralization in volcanic rocks located in south Neyshabour, NE Iran

This paper presents the new geochemical isotopes Sr and Nd, and the mineralization data for the south Neyshabour volcanic rocks located in NE Iran. Based on the chemical classifications, the studied rocks are basaltic trachy andesite, trachy andesite, trachyte, and trachy dacite in composition. All the analyzed volcanic rocks display enrichment in light rare earth elements (LREE) relative to the heavy rare earth elements (HREE), have significant negative Ti and Nb anomalies, and have a positive U anomaly. The tectonic discrimination diagrams for the volcanic rocks in the studied area show a post-collisional arc environment. These characteristics are the specifications of the subduction-related volcanic rocks generated in a post-collisional setting. The initial 87Sr/86Sr ratios ranging from 0.70408 to 0.70593and the eNdi values between +3.34 and +5 for the four samples analyzed indicate that the studied rocks are derived from a lithospheric mantle source. Finally, it is concluded that these volcanic rocks should have formed in a post-collisional environment that followed the Neo-Tethys subduction. There are strong evidence for copper mineralization in these volcanic rocks. The main copper oxide minerals are malachite and atacamite. The copper sulfide minerals such as chalcocite, minor bornite, and covellit are also present. Chalcocite is the most abundant sulfide ore mineral present in this area. This mineralization is observed as open space filling and thin veinlets, and it is partially controlled by linear structures and fault zones. Based on the identified characteristics, this ore deposit is hydrothermal. Carbonate alteration is frequently seen in the area but argillic alteration is very low, and this issue displays a hydrothermal solution with an alkaline pH.

Genesis and open-system evolution of Quaternary magmas beneath southeastern margin of Tibet: Constraints from Sr-Nd-Pb-Hf isotope systematics

Post-collisional volcanic rocks on the Tibetan Plateau and its margins contain valuable information about the geodynamic processes associated with this Cenozoic continent-continent collision. The Quaternary Tengchong volcanic field at the southeastern margin of the Tibetan Plateau formed high-potassium calc-alkaline volcanic rocks. Herein, we present comprehensive Nd-Sr-Pb-Hf isotopic and elemental data for trachybasalts, basaltic trachyandesites, and trachyandesites from four Quaternary Tengchong volcanoes (Maanshan, Dayingshan, Heikongshan, and Laoguipo) in order to understand their magma genesis and evolution as well as tectonic significance. Good correlations between SiO2 content and the ratios 87Sr/86Sr, 143Nd/144Nd, 206Pb/204Pb, and 177Hf/176Hf for these Quaternary volcanics strongly suggest that the combined assimilation and fractional crystallization (AFC) was an important process in the origin of basaltic trachyandesites and trachyandesites. High Y and Yb contents and low Sr/Y ratios of these basaltic trachyandesites and trachyandesites are uncharacteristic of adakites that formed by partial melting of eclogitic lower crust or partial melting of basaltic oceanic crust with eclogite as a restite. A combined assimilation-fractional crystallization model is proposed for these basaltic trachyandesites and trachyandesites. Nd-Sr-Pb-Hf isotopes for the uncontaminated Tengchong magma (trachybasalts with SiO2<52.5wt.% and MgO>5.5%wt.%) reflect a heterogeneous enriched mantle source. High Th/U, Th/Ta, and Rb/Nb ratios and Nd-Sr-Pb-Hf isotope characteristics of the uncontaminated magmas suggest that the enriched mantle beneath Tengchong formed as a result of subduction of clay-rich sediments, which probably came from the Indian continental plate. Partial melting of the enriched mantle was generated by deep continental subduction coupled with recent regional extension in the Tengchong area.

Petrogenesis of Late Cenozoic basaltic rocks from southern Vietnam

Major and trace element concentrations, and Sr–Nd–Hf–Pb isotopic compositions of Late Cenozoic (4.1 to 13.8Ma) basaltic rocks from southern Vietnam have been determined to understand the nature of their mantle source. The volcanic rocks are composed of tholeiite basalt, alkaline basanite, trachybasalt, basaltic trachyandesite, and trachyandesite. The alkaline rocks show light rare earth element (LREE) enrichment, with (La/Yb)N=10.3–29.8. The tholeiite basalts are distinguished by much lower values (8.8–9.5) of (La/Yb)N. On a primitive mantle-normalized trace element distribution diagram, they show oceanic island basalt (OIB)-like large-ion lithophile element enrichment without high field strength element depletion. However, some samples exhibit positive anomalies in K and Pb and negative anomalies in Sm, suggesting K-rich residual amphibole in the source. The samples contain Sr (87Sr/86Sr=0.703794–0.704672), Nd (ɛNd=+1.7-5.7), Hf (ɛHf=+4.0–10.9), and Pb (206Pb/204Pb=18.23–18.75; 207Pb/204Pb=15.53–15.59; 208Pb/204Pb=38.32–38.88) isotopes, plotting among OIBs, with depleted mid-ocean ridge basalt mantle-enriched mantle type 2 (DMM-EM2) characteristics. There are no discernible isotopic differences between tholeiite and the alkaline series, reflecting the same source. The Nd and Hf isotopic compositions are coupled, and plot along the mantle–crust array, ruling out the possibility of lithospheric mantle in the source. Plots of NiO against the Fo numbers of olivines from the basaltic rocks are within the range of Hainan and Hawaiian basalt olivines, implying that hybrid pyroxenite is present in the source. Also note that the estimated primary melt compositions fall within the experimental field defined by partial melting of silica-poor eclogite and peridotite. The effective melting pressure (Pf) and melting temperature (T) of the primary melts are Pf=29.6–32.8kbar and T=1470–1480°C. We suggest that Vietnamese basaltic rocks may be produced by the Hainan plume from recycled eclogitic oceanic crust.