Basaltic Andesite Research Articles

Mineralogy, fluid inclusion and stable isotope characteristics of the Inlice (Konya, Turkey) high sulfidation epithermal gold deposit: Implications for hydrothermal evolution and ore genesis

The Inlice high sulfidation epithermal gold deposit with 262,300 oz of gold ore is located in the Erenlerdağ-Alacadağ Volcanic Complex (EAVC) at the northern part of central Taurides. The volcanic succession of the study area is stratigraphically represented by andesite, block and ash flow, basaltic andesite lava flow and andesite lava flow. The deposit consists of seven neighboring mineralized veins termed Ana East, Ana West, West, Discovery, Güllü, Merkez and North Zone and is associated with an andesite (ca 8–9 Ma). Hydrothermal alteration from the innermost to the outermost parts of the deposit includes silicification, advanced argillic, intermediate argillic and propylitic. At the surface, quartz veins related to silicification are exposed as linear topographic relief trending mainly northwest-southeast and secondarily northeast-southwest and east-west. Deep drill core samples, including magnetite, quartz, biotite and anhydrite, imply the presence of potassic alteration in depth (50 to 970 m) possibly related to a porphyry Cu system. Ore assemblages are described as hypogene and supergene. The hypogene ore mainly includes pyrite (Py-I and Py-II) and enargite, and to a lesser extent chalcopyrite, sphalerite and marcasite. The supergene ore incorporates hematite and goethite, and minor covellite, chalcocite, malachite and native copper. Hypogene gold precipitation is associated with the mineral association of Py-II, chalcopyrite and enargite, while enargite mineral is a major host for gold (up to 600 ppm). Supergene oxidation resulted in the development of a secondary enrichment zone for gold (up to 14 g/t) extending to a depth of about 45 m.Microthermometric measurements show that the silicification associated with the mineralization was formed at homogenization temperatures ranging between 147 and 360 °C and salinities up to 6.5 wt% NaCl. This suggests that the fluid mixing and/or fluid dilution processes were important factors controlling the precipitation of gold. δ34S isotope compositions are between −0.9 and − 9 ‰, and further indicate a significant involvement of magmatic components into the hydrothermal fluids. Thus, it is concluded that at Inlice the hydrothermal fluids responsible for the alteration and mineralization processes were derived by relatively dilute fluids formed by the mixing of magmatic fluids with meteoric waters.

Major, trace elements and Sr–Nd–Pb isotopes systematics of mafic dykes from the Figuil (northern Cameroon) and Léré (southwestern Chad) areas

In this study, field descriptions of the dolerite dykes cross‐cutting the Pan‐African basement (DPB) and the dolerite and gabbroic dykes cross‐cutting the Cretaceous sedimentary basin (DGCSB) are used together with petrographic, bulk‐rock geochemistry, as well as Sr–Nd–Pb isotopic data to constrain the geodynamic setting and origin of these mafic (basanite, basalt and basaltic andesite in composition) rocks that outcrop in the Figuil–Léré area. The DPB dykes are alkaline with SiO2 of 46.63–49.03 wt% and MgO of 3.93–7.11 wt%. In contrast, the DGCSB dykes are subalkaline with SiO2 ranging between 50.24 and 53.16 wt% and MgO fluctuating between 5.22 and 7.90 wt%, comparable to dykes described in other regions of the Cameroon Line (CL). The rocks studied belong to the tholeiitic series and were emplaced in within‐plate basalts (WPB) and mid‐ocean ridge basalts (MORBs) setting. The variations in major and trace elements from the basanite to basaltic andesite compositions are dependable with fractional crystallization (FC) of different mineral phases such as opaque minerals, olivine, clinopyroxene, amphibole and alkali feldspar. Most samples exhibit negative Nb–Ta and positive Sr anomalies, which together with the negative correlation between MgO and 87Sr/86Sr, and isotopic ratio of 206Pb/204Pb <19.5 (18.27–19.49) suggests interactions of crustal components. Nevertheless, this contamination seems limited because there is a positive correlation between SiO2 and 143Nd/144Nd plot and low Ba contents (72–210 ppm) of the samples compared to the mid‐continental crust (259–628 ppm). Trace element modelling proposes a derivation of the Figuil–Léré dykes from parental melts generated by 4%–15% partial melting of a source containing garnet peridotite in the mixed lithospheric–asthenospheric mantle. The isotopic data of the dykes studied with hybrid magma composition are characterized by more radiogenic 87Sr/86Sr, 143Nd/144Nd and 206Pb/204Pb isotopic ratios with a dominant mixing of depleted MORB mantle (DMM)–enriched mantle 1 (EM1)–enriched mantle 2 (EM2), like those of other mafic dykes of the CL.

Mineral chemistry and apatite Sr isotope signatures record overprinting mineralization in the Duobaoshan porphyry Cu deposit, Heilongjiang Province, NE China

Porphyry copper deposits can be deformed by subsequent magmatic-tectonic-metamorphic evolution, resulting in the remobilization of pre-existing ores and the consequent overprinting mineralization. This process might potentially increase the ore grade and/or resource. We focus on the Duobaoshan porphyry Cu (Mo) deposit, two periods were identified in this study, i.e., porphyry period (including Stage 1: potassic alteration; 2: propylitic alteration, and 3: chlorite-sericite alteration and porphyry mineralization) and overprinting period (including Stage 4–1: ductile–brittle deformation; Stage 4–2 and Stage 4–3: overprinting mineralization). Metal sulfide veins occur along the schist in Stage 4–2 and Stage 4–3, features that differ from the typical porphyry mineralization of Stage 3 (veinlets, stockworks, and dissemination). Here, we present in situ Sr isotope data for apatite and compositions of chlorite, epidote, and apatite to reveal the source and nature of fluids and mechanism of precipitation during overprinting mineralization. The in situ 87Sr/86Sr ratios of apatite from Stages 3, which range from 0.7030 to 0.7046, are slightly higher than those observed in the Ordovician granodiorite. Meanwhile, the Sr isotope ratios for apatite from Stages 4–2 and 4–3 are 07033–0.7040 and 0.7013–0.7045 respectively. These ratios broadly consistent with those of the surrounding Ordovician granodiorite and basaltic andesite, suggesting that the ore-forming fluids for all these stages originated from magmatic sources. Chlorite in Stage 4–2 has a higher Mn, Co, Ni, Zn content compared to chlorite in Stage 3, 4–3, whereas epidote and apatite in Stage 4–2 have higher Ca, Sr, Pb content compared to those in Stage 3, 4–3, implying that the fluids in Stage 4–2 underwent strongly water–rock reactions and extracted metal elements from surrounding rocks. Copper was only detected in Stage 4–3 chlorite (15.13–500.20 ppm) and epidote (7.91–19.29 ppm), indicating a high concentration of copper in the fluid, and due to the pre-existing magnetite dissolution, chlorite, epidote, and apatite in Stage 4–3 exhibit high V and Fe relative to other stages. Fluid mixing likely occurred during Stage 3, leading to the precipitation of copper. Strong water-reaction in Stage 4–2 produce changes in fluid natures that facilitate sulfide deposition during this stage. While in Stage 4–3, copper precipitation is controlled by a combination of rising pH and changing sulfur content and valence. Our study highlights that in the Duobaoshan deposit, late magmatic-hydrothermal fluids remobilized pre-existing ore bodies, and the copper precipitation mechanisms differed during the main copper mineralization events.

The geochemical characteristics of Cretaceous volcanics in southern Hainan Island and implications for tectonic evolution in the South China Sea

The southeastern Eurasian plate, where the South China Sea (SCS) is located, lies in a complex tectonic setting between the Pacific and Tethys tectonic belts. It is widely accepted that the tectonics of the SCS area were influenced by subduction in the late Mesozoic, but there is still controversy over whether it was paleo-Pacific subduction or Tethyan subduction. Volcanic activity in the south of Hainan Island was intense during the Cretaceous, and geochemical analysis of the collected basaltic andesite, andesite and rhyolite samples in this study indicate those intermediate-acid series igneous rocks are high-K calc-alkaline or calc-alkaline. Some andesites have high MgO contents and Mg# values (2.04–5.34 wt% and 36.83–55.29; Mg# = 100× Mg2+/(Mg2+ + TFe2+). Light rare earth elements (LREEs) and large ion lithophile elements (LILEs) are enriched in all the samples, but high field strength elements (HFSEs) are depleted. The negative Eu anomalies are more obvious in the rhyolites than andesites. The geochemical characteristics of the volcanic arc igneous rocks show that the mid-Cretaceous tectonic setting of Hainan Island can be classified as an Andean active continental margin. During the mid-Cretaceous, intermediate volcanism occurred in Hainan Island and its adjacent areas. The zircon-saturation temperatures of the acid volcanic rocks in study area exhibit relatively low values (ranging from 746°C–790°C). Unlike igneous rocks forming in the coastal area east of the South China Block at the same time, no A-type granitoids with alkaline dark minerals appear in Hainan Island. During the late Mesozoic, the western SCS, where Hainan Island was located, may not have been affected by the subduction of the paleo-Pacific Plate, but rather Neotethyan subduction which dominated the Cretaceous magmatic and tectonic activities along the western margin of the SCS. This finding helps to understand the late Mesozoic tectonic evolution of the southeastern edge of the Eurasian plate.

Geochronology and Geochemistry of the Early Paleozoic Ore‐host Volcanic Sequence in the Kalatag Area, East Tianshan, NW China: Implications for the Tectonic Evolution

AbstractThe East Tianshan contains many late Paleozoic magmatic and polymetallic deposits. Recent studies demonstrate that the early Paleozoic volcanic rocks discovered in the northern region of East Tianshan can be subdivided into the Daliugou, Hongliuxia and Kalatag formations. Here, we report zircon U‐Pb ages of volcanic rocks and quartz diorite porphyry, together with whole‐rock geochemical and Sr‐Nd isotope data of early Paleozoic volcanic rocks, in order to investigate their petrogenesis and geodynamic setting. Zircon U‐Pb analyses of the rocks suggest that the Kalatag Formation formed at ca. 438–413 Ma. Geochemical characteristics of the early Paleozoic volcanic rocks exhibit typical subduction‐related features. They have high Mg#(44–75), positiveεNd(t) values (0.25–7.88), low87Sr/86Sr ratios (0.70457 to 0.70588) and young two‐stage Hf isotope model ages (551–446 Ma), consistent with a depleted mantle origin with limited crustal contamination. The basaltic andesite and andesite have relatively high MgO contents (6.1–9.4 wt%), suggesting that they belong to high‐magnesian andesites. They were most likely derived from the partial melting of mantle peridotite caused by the addition of fluids released by subducted oceanic slab. Based on regional geology, geochemical characteristics and previous studies, we infer that the southward subduction of the Junggar Ocean slab resulted in the generation of early Paleozoic volcanic rocks and arc setting‐related metallogenic systems in the Kalatag area.

3D Visualization of Geothermal System Structure Based on Inversion Model of Gravity Data. Case Study: Mt. Salak Region, West Java

The geothermal power plant located in Gunung Salak plays a crucial role in increasing the electricity supply transmitted to the Java-Bali region, as the energy demand continues to rise. The objective of this research is to determine the 3D subsurface structure of Gunung Salak, specifically the distribution of the reservoir as the target for geothermal energy using the Gravity method. Gravity data, including gravity disturbance (gd), geoid, and Digital Elevation Model (DEM), were obtained from the ICGEM website with a total of 48740 data each. Based on the results of the residual anomaly map, the low anomalies beneath Gunung Salak have values from -5.15 to -1.88 mGal, which are suspected to be associated with the magma chamber. The high anomalies beneath the manifestations have values from 0.92 to 5.01 mGal, indicating andesitic basalt intrusive rocks believed to be the reservoir rock. Through the 3D inversion modeling of the subsurface structure of the Gunung Salak geothermal system, a clay cap with a density from 2.47 to 2.5 g/cc at depths of 0 to 700 m and andesitic basalt rock as the reservoir with a density from 2.74 to 2.91 g/cc at depths of 700 to 3000 m have been identified.

Monitoring the Thermal Activity of Kamchatkan Volcanoes during 2015–2022 Using Remote Sensing

The powerful explosive eruptions with large volumes of volcanic ash pose a great danger to the population and jet aircraft. Global experience in monitoring volcanoes and observing changes in the parameters of their thermal anomalies is successfully used to analyze the activity of volcanoes and predict their danger to the population. The Kamchatka Peninsula in Russia, with its 30 active volcanoes, is one of the most volcanically active regions in the world. The article considers the thermal activity in 2015–2022 of the Klyuchevskoy, Sheveluch, Bezymianny, and Karymsky volcanoes, whose rock composition varies from basaltic andesite to dacite. This study is based on the analysis of the Value of Temperature Difference between the thermal Anomaly and the Background (the VTDAB), obtained by manual processing of the AVHRR, MODIS, VIIRS, and MSU-MR satellite data in the VolSatView information system. Based on the VTDAB data, the following “background activity of the volcanoes” was determined: 20 °C for Sheveluch and Bezymianny, 12 °C for Klyuchevskoy, and 13–15 °C for Karymsky. This study showed that the highest temperature of the thermal anomaly corresponds to the juvenile magmatic material that arrived on the earth’s surface. The highest VTDAB is different for each volcano; it depends on the composition of the eruptive products produced by the volcano and on the character of an eruption. A joint analysis of the dynamics of the eruption of each volcano and changes in its thermal activity made it possible to determine the range of the VTDAB for different phases of a volcanic eruption.

Characterization of the Stone Masonries and Evaluation of the Environmental Impact in Panamá Viejo: A Contribution for the Conservation of the Monumental Complex

A fundamental step in the best preservation of heritage materials is investigating their chemical and physical characteristics, and understanding how they interact with the surrounding environment. For this reason, the stone masonry of the monumental UNESCO site of Panamá Viejo was subjected to a thorough study to characterize the materials and evaluate their state of conservation. Additionally, potential outcrops were explored in order to identify sites for the supply of raw materials. The methodological approach encompassed mineralogical-petrographic investigations using stereomicroscopy, polarized light microscopy (PLM), X-ray powder diffraction (XRPD), scanning electron microscopy and energy dispersive X-ray spectrometry (ESEM-EDS) and X-ray fluorescence (XRF). The results revealed that the masonries primarily consists of polygenic breccia, basaltic andesite, rhyodacite, tuffite, and rhyolite. In addition, at the potential quarries, breccia and basaltic andesite were identified. The porous structure was studied using mercury intrusion porosimetry (MIP). Possible issues due to salt dissolution/crystallization cycles were considered. Consequently, ion chromatography (IC) was conducted on samples exhibiting alteration patinas to study the presence of soluble salts. In assessing the state of conservation, prevalent forms of deterioration included biological colonization, detachments, material loss, potential salt weathering, and chromatic alteration. In conclusion, the outcomes of this work provide a valuable resource for the current and future preservation of this site.

Coexisting Nb-enriched basalts and arc volcanic rocks in the northern Qiangtang Terrane, China: Implications for the effects of ambient mantle on subduction zone magmatism

The petrogenesis of Nb-enriched basalts (NEBs) is controversial. NEBs are generally considered to form by melting of either a mixed enriched and depleted mantle source or a mantle wedge metasomatized by adakitic melts. Here we present geochronological, petrological, geochemical, and Sr-Nd-Os isotope data for Early Permian volcanic rocks from the Tuotuohe area in the northern Qiangtang Terrane, China. The studied volcanic rocks can be divided into two groups: arc basalts and basaltic andesites in the lower sequence and NEBs in the upper sequence. Zircon grains from one basaltic andesite sample in the lower sequence yielded a concordia age of 302.0 ± 1.1 Ma. The geochemical and isotopic characteristics suggest that the NEBs were derived from a mixed source consisting of enriched mid-oceanic ridge basalts (MORB)- to oceanic-island basalt-like ambient mantle and slab-derived fluids, whereas the arc basalts and basaltic andesites originated from a source made of the MORB-type ambient mantle modified by slab-derived melts. We propose for the first time that the Nb enrichment of the NEBs was most likely inherited from high-Nb ambient mantle and is independent of the addition of slab-derived components. In addition to slab-derived components, the nature of the ambient mantle is also an important factor controlling the diversity of arc magmatism. Our new findings show that the Late Carboniferous−Early Permian magmatism in the northern Qiangtang Terrane was related to northward subduction of the Paleo-Tethys Ocean, suggesting that subduction might have occurred in at least the Early Permian rather than in the previously thought Middle Permian.

Within-plate magmatism in the southern Borborema Province (NE Brazil): Mantle plumes associated with the Nuna-Columbia and Rodinia breakup?

Formation and fragmentation of landmasses, such as the Nuna/Columbia and Rodinia supercontinents, are influenced by mantle plume activity during rifting and breakup. In the Borborema Province, NE Brazil, within-plate magmatism at ca. 1.6 and at ca. 0.8 Ga is evidenced by the formation of mafic-ultramafic volcanic and plutonic rocks, mafic-ultramafic layered intrusions, and A-type granite intrusions. The Paulistana and Santa Filomena complexes, located in the Riacho do Pontal Orogen, southern Borborema Province, correspond, respectively, to metaplutonic/volcanic-sedimentary and metavolcanic-sedimentary sequences. These sequences are composed of metamorphic rocks of the greenschist to amphibolite facies whose basement corresponds to the Paleoproterozoic rocks of the Itaizinho Complex, which is located in the southern portion of the São Pedro Terrane. The combined analysis of new field, petrographic and geochemical data obtained for the metavolcanic rocks of the São Pedro Terrane and Riacho do Pontal Orogen aided the determination of their tectonic setting. Whole-rock geochemical analyses revealed the predominance of andesites, basaltic andesites and tholeiitic alkali basalts generated in a within-plate environment (E-MORB) with shallow melting of the metavolcanic rocks of the Itaizinho Complex. In the Riacho do Pontal Orogen, basaltic to alkali-basaltic tholeiites are the dominant metavolcanic rocks of the Paulistana and Santa Filomena complexes. Tectonic setting discriminant diagrams indicate within-plate (E-MORB/OIB), deep and shallow melting environments, respectively. This study, combined with data available in the literature, suggests that the metavolcanic rocks of the Itaizinho Complex and metavolcanic rocks of the Paulistana/Santa Filomena complexes were formed in an extensional setting related to Calymmian (1631 Ma) and Tonian (882 Ma) mantle plumes, respectively, precursor to the oceanic crust between the São Pedro Terrane and the São Francisco Craton, represented by the metabasalts of the Monte Orebe complex, which underwent re-accretion and reworking during the Brasiliano-Pan-African Orogeny.

Geological Structure Features and Rocks Composition of Kronotsky Volcano, the Largest Stratovolcano in the Frontal Zone of the Eastern Volcanic Belt of Kamchatka

Based on the results of 2020‒2022 field works, this paper presents a characterization of the geological structure and whole rock composition of Kronotsky volcano, one of the poorly studied eruptive centers of the Eastern Volcanic Belt (EVB) of Kamchatka. The volume of the volcanic edifice is estimated at 350 km3, that significantly exceeds the volumes of other stratovolcanoes of the frontal zone of EVB. Rocks of a volcano are presented by low-K, high-Fe tholeiitic basalts and basaltic andesites (SiO2 = 47.04–53.15 wt %; K2O = = 0.24‒0.65 wt %; FeO*/MgO = 1.2‒2.89). The basalts show extremely low contents of silica, potassium, titanium, and phosphorus in comparison with rocks of other frontal volcanoes of Kamchatka. The revealed petrochemical features were used to clarify the belonging of the objects located at the junction of Kronotsky and Krasheninnikov volcanic edifices. The obtained data will serve as the background for further petrological and geochemical studies of the volcano, and also may be used for reconstruction the sequence of volcanic events in this area, including clarification of the history of Kronotsky Lake formation.

Alkaline magmas in shallow arc plutonic roots: a field and experimental investigation of hydrous cumulate melting in the southern Adamello batholith

Despite the first-order importance of crystallisation–differentiation for arc magma evolution, several other processes contribute to their compositional diversity. Among them is the remelting of partly crystallised magmas, also known as cumulate melting or ‘petrological cannibalism’. The impact of this process on the plutonic record is poorly constrained. We investigate a nepheline-normative dyke suite close to the Blumone gabbros, a large amphibole-gabbro unit of the Tertiary Southern Alpine Adamello igneous complex. The compositions of the studied dykes are characterised by low SiO2 (43–46 wt. %), MgO (5.0–7.2 wt. %), Ni (18–40 μg/g), and high Al2O3 (20.2–22.0 wt. %) contents. Phenocrystic plagioclase in these dykes exhibits major, trace, and Sr isotope compositions similar to Blumone cumulate plagioclase, suggesting a genetic link between the nepheline-normative dykes and the amphibole-gabbro cumulates. We tested this hypothesis by performing saturation experiments on a nepheline-normative dyke composition in an externally heated pressure vessel at 200 MPa between 975 and 1100 °C at fO2 conditions close to the Ni–NiO buffer. Plagioclase and spinel are near-liquidus phases at and above 1050 °C, contrasting with the typical near-liquidus olivine ± spinel assemblage in hydrous calc-alkaline basalts. The alkaline nature of the dykes results from the abundance of amphibole in the protolith, consistent with melting of amphibole-gabbro cumulates. We modelled the heat budget from the repeated injection of basaltic andesite into a partly crystallised amphibole-gabbro cumulate. The results of this model show that no more than 7% of the cumulate pile reaches temperatures high enough to produce nepheline-normative melts. We propose that such nepheline-normative dykes are a hallmark of hydrous cumulate melting in subvolcanic plumbing systems. Therefore, ne-normative dykes in arc batholiths may indicate periods with high magma fluxes.

Modeling decompression paths in a basaltic andesite magma using the nucleation and growth of plagioclase microlites

Plagioclase microlites in a magma nucleate and grow in response to melt supersaturation (Δϕplag). The resultant frozen plagioclase crystal size distribution (CSD) preserves the history of decompression pathways (dP/dt). SNGPlag is a numerical model that calculates the equilibrium composition of a decompressing magma and nucleates and grows plagioclase in response to an imposed Δϕplag. Here, we test a new version of SNGPlag calibrated for use with basaltic andesite magmas and model dP/dt for the ca. 12.6 ka Curacautín eruption of Llaima volcano, Chile. Instantaneous nucleation (Nplag) and growth (Gplag) rates of plagioclase were computed using the experimental results of Shea and Hammer (J Volcanol Geotherm Res 260:127–145, 10.1016/j.jvolgeores.2013.04.018, 2013) and used for SNGPlag modeling of basaltic andesite composition. Maximum Nplag of 6.1 × 105 cm h−1 is achieved at a Δϕplag of 44% and the maximum Gplag of 27.4 μm h−1 is achieved at a Δϕplag of 29%. Our modeled log dP/dtavg range from 2.69 ± 0.09 to 6.89 ± 0.96 MPa h−1 (1σ) with an average duration of decompression from 0.87 ± 0.25 to 16.13 ± 0.29 h assuming a starting pressure Pi of 110–150 MPa. These rates are similar to those derived from mafic decompression experiments for other explosive eruptions. Using assumptions for lithostatic pressure gradients (dP/dz), we calculate ascent rates of < 1–6 m s−1. We conducted a second set of Monte Carlo simulations using Pi of 15–30 MPa to investigate the influence of shallower decompression, resulting in log dP/dtavg from 2.86 ± 0.49 to 6.00 ± 0.86 MPa h−1. The dP/dt modeled here is two orders of magnitude lower than those calculated by Valdivia et al. (Bull Volcanol, 10.1007/s00445-021-01514-8, 2022) for the same eruption using a bubble number density meter, and suggests homogeneous nucleation raises dP/dt by orders of magnitude in the shallow conduit. Our modeling further supports the rapid-ascent hypothesis for driving highly explosive mafic eruptions.

Origins of magmatism in the Okinawa Trough: Fe–Sr–Nd–Pb–Hf isotopic constraints

ABSTRACT The Okinawa Trough is an incipient back-arc basin formed by the subduction of the Philippine Sea Plate beneath the Eurasian Plate and is a natural laboratory for studying basin evolution, magmatism, and crust-mantle interactions during the early stages of back-arc spreading. Back-arc spreading and recent magmatism are occurring mainly in the Middle Okinawa Trough (MOT) and Southern Okinawa Trough (SOT). In order to investigate the magmatism in the Okinawa Trough, volcanic rock samples from the MOT and SOT were analysed for Fe – Sr – Nd – Pb – Hf isotopic compositions. The Fe isotopic compositions of basaltic andesite samples from the SOT are similar to or lower than MORBs. The fluid/melt derived from the subducted slab, especially the fluid dehydrated from slab serpentinites and sediment-derived melts, entered the overlying depleted mantle wedge and participated in magma generation, which resulted in the low δ56Fe values of the SOT basaltic magmas. The δ56Fe values of volcanic rocks from the MOT increase with increasing SiO2 contents, suggesting a gradual enrichment of heavy Fe isotopes during the evolution of the magma as it ascended to the surface. While the Sr – Nd – Pb – Hf isotopic compositions do not vary significantly, suggesting that the different samples are the products of different degrees of crystal fractionation of comagma. The fractional crystallization of olivine, pyroxene, and ilmenite minerals, which enrich in light Fe isotopes, resulted in the gradual increase in Fe isotopic values of magma during its evolution. The dacites and rhyolites from the southernmost Okinawa Trough have the similar δ56Fe values with the basaltic andesite and the basalt from the SOT and MOT, accompanied by significantly lower Nd and Hf isotope ratios relative to basalts, reflecting that the contamination of crustal materials would not change the magma in Fe isotope compositions evidently. Compared with the MOT, the volcanic rocks from the SOT was more affected by subduction components on their underlying mantle, and those from the southernmost experienced more contamination by crustal materials in the evolving magma.

Petrogenesis of metavolcanics and detrital zircon geochronology of the Mesoarchean western Iron Ore Group supracrustals, Singhbhum Craton (India): Evidence for an intracontinental extension setting

The Singhbhum Craton of eastern India, consisting of well-preserved Paleo- to Mesoarchean granitoids, volcanic and sedimentary rocks, is an excellent archive of early earth processes. In this contribution, we investigated the geological evolution of the Noamundi-Jamda-Koira IOG Basin (WIOG) using detrital zircon U-Pb ages, whole rock geochemical and Nd isotopic data on metavolcanic rocks from this belt including the Jagannathpur volcanics. The metavolcanics of the WIOG and Jagannathpur are compositionally basaltic andesites with enriched LREE and negative anomalies of Nb-Ta and Ti. The ratios of crustal contamination sensitive elements such as La/Sm, Sm/Nd, Nb/La, Th/Yb and Nb/Yb are close to that of bulk continental crust. The Nd isotopic composition of these basaltic andesites are broadly chondritic (εNdt = +0.93 to −1.20). The geochemical and isotopic signatures are consistent with significant assimilation of Paleoarchean granitoids of the Singhbhum Craton. The overlapping geochemical and isotopic compositions support the view that Jagannathpur volcanics is an eastward extension of the ∼3.04 Ga WIOG metavolcanics and shouldn’t be considered as a separate stratigraphic unit. The presence of pillowed structures, vesicularity, absence of volcanic breccia, and their association with clastic sediments clearly indicate a subaqueous and shallow marine eruption for the WIOG basaltic andesites. The deposition of clastic sediments before basaltic magmatism points towards lithospheric thinning and basin opening. The detrital zircon ages from the WIOG ranges from 3.51 to 2.96 Ga and the detritus was mainly sourced from the adjacent Singhbhum granite and Bonai granite. The petrogenesis of the WIOG metavolcanics can be attributed to assimilation-fractional crystallisation of a depleted mantle derived tholeiitic mafic-ultramafic magma in an intracontinental extension setting.

How is carbonate crust digested by magma?

Magma’s volatile budget depends on deep magmatic sources, the degree of differentiation and degassing conditions, and volatile input from the assimilated crust. It is, therefore, important to know the exact mechanism by which the crust is assimilated into magma to understand volatile budgets and eruption behavior. To explore reactions between carbonate, calc–silicate, or skarn xenoliths and basaltic andesite magma, we studied ten calc–silicate xenoliths from the 1994, 1998, 2006, and 2010 Merapi eruptions and four sediment samples of local Javanese carbonate crust. An in situ electron probe microanalysis of the 1994–2010 calc–silicate xenolith minerals and glasses suggests that calcite is a minor and metastable mineral phase in association with wollastonite. In addition, carbonate melts quenched to calcic glasses (32 ± 7 wt% SiO2; 38 ± 3 wt% CaO), similar to experimental glasses produced by crust–melt interaction experiments. Thermodynamic modeling using rhyolite MELTS (version 1.2.0) predicts the production of highly silicic (up to ∼84 wt% of SiO2) and CaO-rich (up to ∼25 wt%) melts during partial melting of calc–silicate material. The observed mechanism of calc–silicate xenolith assimilation is the generation of highly silicic (77 ± 4 wt% of SiO2) melts in association with idiomorphic diopside [Wo49En29; 57 ± 3 Mg# = Mg/(Mg+Fe2+)] and other calcic pyroxenes (Wo54-82 En2-21; 16–43 Mg#) due to partial melting of xenolith and incongruent dissolution reactions. We hypothesize that the rate-limiting process is the subsequent mixing of the produced crustal melts with representative resident andesitic melt (average 65 wt% SiO2) through chemical diffusion, which explains major and volatile (Cl) element contents in the Merapi glass products. In addition to high Sr contents and radiogenic 87Sr/86Sr and elevated CO2, Ba, Co, Cr, Cu, V, Zn, and Zr contents in the magmatic minerals and associated glasses, the recrystallized and residual metamorphic sphene, quartz, garnet, and apatite predicted by rhyolite-MELTS or Magma Chamber Simulator modeling during wallrock melting and residual metastable calcite and wollastonite are important tracers of calc–silicate crust assimilation. The disequilibrium process of calc–silicate crustal assimilation can, thus, be well predicted by dissolution experiments and thermodynamic modeling using rhyolite-MELTS or Magma Chamber Simulator. The rate of calc–silicate crustal assimilation is still unconstrained without adequate high-temperature kinetic time-series experiments. We predict that the crustal assimilation rate is controlled by the Si–Al diffusion and associated convection in the hydrous silicate magma.

Geochronology, Eruption Sequence and Geochemistry of Mid–Late Jurassic Volcanics South of Manzhouli: Petrogenesis and Implications for Mesozoic Tectonic Regime Transformation

AbstractTo the south of Manzhouli, Hulunbuir, Inner Mongolia, experienced a tectonic regime transformation from compression to extension in the mid‐Mesozoic. Based on systematic research of the volcanics, petrology, volcanic facies, chronology and geochemistry of rocks in the Buridun area, two stages of volcanics are identified. The first stage named the trachyte series was formed in the late Middle Jurassic (167–163 Ma), its eruption rhythm is pyroxene trachyandesite–trachyandesite–trachyte, and its origin rock is basic volcanics from thickened lower crust, with a tectonic setting in the collision orogeny after the closure of the Mongolia Okhotsk Ocean (MOO). The second stage is a bimodal volcanic rock, formed in the early Late Jurassic (163–160 Ma). The eruption rhythm of basic volcanics in this stage is basaltic andesite–basalt–olivine basalt, which comes from the metasomatized lithospheric mantle, the acidic volcanics of which being characterized by the eruption rhythm of sedimentary‐explosive‐overflow facies, which came from the partial melting of newly formed lower crust, and this shows the characteristics of A‐type granite; the tectonic setting is extension of the lithosphere after collision and closure of the MOO. The changes in the formation age and tectonic setting of the two stages of volcanics demonstrate that the transition time from the compressive system to the extensional system south of Manzhouli is about 163 Ma.

Deciphering the sources and processes feeding young monogenetic volcanoes from the Michoacán Guanajuato Volcanic Field (Mexico): A study case of El Astillero and El Pedregal

El Astillero and El Pedregal monogenetic volcanoes formed ∼500–700 CE in the Tancítaro region in the southern part of the Michoacán-Guanajuato volcanic field, only 25 km to the SW of the historic Paricutin volcano. The ∼6-year-long eruption was characterized by a change from explosive to effusive activity, accompanied by a shift in the location of the active vents. Initial activity was Strombolian-explosive and first formed the El Astillero cone before turning effusive with the emission of several lava flows. Then, a new vent located 2 km to the ENE opened and produced the purely effusive (non-explosive) El Pedregal lava flow field. As the eruption progressed, the bulk magma composition (major and trace elements) changed from basaltic andesite to andesite (SiO2 = 52–59 wt%), which is also reflected in a successive change in the petrography of the erupted tephras and lavas. However, the El Pedregal lava sequence shows small Mg# reversals followed by a marked final reversal to more mafic compositions. Likewise, 87Sr/86Sr (0.70388–0.70403), 143Nd/144Nd (0.512836–0.512742), 206Pb/204Pb (18.632–18.671), 207Pb/204Pb (15.583–15.598), 208Pb/204Pb (38.376–38.450), 176Hf/177Hf (0.28301–0.28290), and 187Os/188Os (0.1258–0.1865) isotope ratios changed systematically as the eruption progressed, and record a final shift to a distinct isotopic signature. The spatio-temporal proximity of both vents and the petrographic and geochemical characteristics of their magmas suggest a comagmatic evolution that can be explained by a combination of variable degrees of magma recharge, magma mixing, and fractional crystallization of subduction-modified mantle melts. A similar combination of magmatic processes for the genesis and evolution of these magmas has also been proposed for other young monogenetic volcanoes in the Michoacán-Guanajuato volcanic field (e.g., Paricutin, Jorullo, and the Tacámbaro cluster). Accordingly, primitive magmas in the Trans-Mexican Volcanic Belt are subduction-modified mantle melts that evolve largely by crystal fractionation and pass through the crust without significant assimilation.

Chemical weathering detection in the periglacial landscapes of Maritime Antarctica: New approach using geophysical sensors, topographic variables and machine learning algorithms

The chemical weathering intensity in Antarctica is underestimated. As the chemical weathering intensity increases, hydrological, geochemical and geophysical changes occur in the different environmental spheres and at their interfaces through reactions and energy flows. Thus, once chemical weathering rates are understood and estimated, they can be used to predict and assess changes and trends in different environmental spheres. Few studies on the chemical weathering intensity have been performed in Antarctica. We used radiometric and magnetic properties associated with terrain attributes and the chemical degree of alteration of the igneous rock to model the chemical weathering intensity in Maritime Antarctica by using machine learning. Then, we related the chemical weathering intensity and geophysical variables with periglacial processes. To do this, gamma-spectrometric and magnetic readings were carried out using proximal-field sensors at 91 points located on different lithologies in a representative area of Maritime Antarctica. A qualitative analysis of chemical alteration for the different lithologies was carried out based on field observations and rock properties, and the levels of the chemical weathering degree were established. The geophysical data associated with terrain attributes were used as input data in the modeling of the weathering intensity. Then, the levels of the rock weathering degree were used as the “y” variable in the models. The results indicated that the C5.0 algorithm had the best performance in predicting the weathering intensity, and the most important variables were eTh, 40K, 40K/eTh, 40K/eU, the magnetic susceptibility and terrain attributes. The contents of radionuclides and ferrimagnetic minerals in different lithologies, concomitantly with the intensity at which chemical weathering occurs, determine the contents of these elements. However, the stability and distribution of these elements in a cold periglacial environment are controlled by periglacial processes. The chemical weathering intensity prediction model using gamma-spectrometric and magnetic data matched the in situ estimate of the chemical degree of alteration of the rock. The pyritized andesites showed the highest intensities of weathering, followed by tuffites, diorites, andesitic basalts and basaltic andesites, and the lowest weathering intensity was shown by undifferentiated marine sediments. This work highlighted the suitability of using machine learning techniques and proximal-field sensor data to study the chemical weathering process on different rocks in these important and inhospitable areas of the cryosphere system.

Experimental insight into basaltic andesite lava dome oxidation textures at La Soufrière, St Vincent

Abstract Petrological analysis of the 2020–21 La Soufrière lava dome reveals ubiquitous oxidation textures. Comparison of the natural dome rock to subsequent explosive scoria phases highlights the lack of any oxidation features in the latter, indicating that oxidation processes affected only the dome-forming magma, either during pre-eruptive storage or upon emplacement. To investigate the causes of oxidation we present a series of one-atmosphere experiments, using fresh natural basaltic andesite scoria as a starting material. Experiments were performed at 900 and 1020°C and at oxygen fugacities between NNO − 2 and air. Experimental results show that iron oxide nanolites nucleate on the rims of pyroxene microlites and phenocrysts under all experimental conditions except at NNO − 2. Orthopyroxene phenocrysts become unstable at 1020°C, at and above NNO + 2. Olivine symplectites form in all experiments at and above NNO. Titanomagnetite co-exsolves titanohematite and an Mg–Fe–Al spinel (pleonaste–magnesioferrite) at and above NNO + 2. Well-developed Mg–Fe–Al spinel trellis exsolution lamellae in titanomagnetite phenocrysts, as seen in the dome, only form in the presence of air at 900°C. The combination of textures and compositions observed in the natural dome indicates that oxidation of the dome magma occurred during emplacement at Earth's surface, with air percolating through the dome at temperatures ≤900°C.