Basal Unit Research Articles

Late Cambrian-early Ordovician extensional magmatism, uplift and sedimentation of the N Gondwana margin: new field, geochemical and geochronological data from the peri-Gondwanan Central Sakarya Terrane, Sakarya Zone, NW Turkey

ABSTRACT The timing and mechanism of the crustal extension that caused blocks of continental crust to rift and drift northwards from the northern Gondwana margin during the Early Palaeozoic are currently debated. Here, we present new field, geochemical and U-Pb zircon data from peri-Gondwanan Central Sakarya terrane in NW Turkey to shed light on the timing and petrogenesis of extensional magmatism and subsequent passive margin development of the northern Gondwana margin. Our 1/25.000 scale mapping of a selected area (250 km2) has revealed a south-vergent thrust stack comprising three slices. The Middle Slice of the thrust stack consists of a gneiss-amphibolite complex that has a basement-cover type stratigraphy (before regional metamorphism). The basement unit consists of meta-granitoids, intruded by meta-syenite and banded amphibolites, with geochemical characteristics reflecting I&S-type, A-type and within plate alkaline/transitional-type magmatism, respectively. The cover meta-clastic sediments have amphibolite lenses with MORB and back-arc basin-type geochemistry. Meta-granitoid bodies yielded zircon U-Pb ages of 507 ± 16 Ma, 503 ± 12 Ma, and 488 ± 2.6 Ma (Late Cambrian-Early Ordovician), whereas the meta-syenites gave ages of 473.9 ± 5.7 Ma and 471.4 ± 2.5 Ma (late Early Ordovician); also, age of the banded amphibolite was dated as 473.3 ± 4 Ma. The youngest detrital zircon population in the pebbly quartzite sample within cover meta-sediments (458 ± 3 Ma) constrains the maximum depositional age to around early Late Ordovician. The late Early Ordovician bimodal magmatism, a key focus of our study, is interpreted to have formed in response to the Rheic Ocean rifting along the northern margin of Gondwana. The Late Cambrian granitic magmatism, a precursor to bimodal magmatism, can be explained by lithospheric thinning and upwelling of the asthenosphere to form anatectic silicic melts. The unconformity between the basement and cover units may represent the initiation of a new phase of extension at the N Gondwana margin that culminated in the northward drifting of the Central Sakarya and the opening of Palaeotethys, associated with back-arc basic magmatism in Late Ordovician-Silurian.

6861 Pre- And Peri-Operative Predictors Of Glycemic Outcomes From Total Pancreatectomy And Islet Auto-Transplantation

Abstract Disclosure: E.N. Haddad: None. M. Lansang: None. H. Xiao: None. R. Walsh: None. R. Simon: None. B.A. Hatipoglu: None. K. Zhou: None. Background: There is a lack of information regarding the immediate post-operative period as a predictor of early and long-term insulin independence after total pancreatectomy and islet auto-transplantation (TPIAT). This study examined the baseline and peri-operative variables that are associated with one-year and longer-term insulin independence following TPIAT. Methods: This was a retrospective study of 46 TPIAT patients in a single hospital system between 2010 and 2022. Perioperative variables were compared between short- (one year) and long-term (last follow up outside of year one) insulin-independent versus dependent patients. Multivariable models were used to adjust for clinically important variables. Results: The median age of the cohort at time of TPIAT was 38.5 years (IQR 30, 49). Patients were predominantly white (91%) and 50% were female. Nine (20%) and seven (15%) patients achieved short- and long-term insulin independence, respectively. The patients were followed for a median of 2.8 years (IQR 1.0, 4.7). There were no significant differences in patient demographics (age, sex, ethnicity), duration of pancreatitis, HbA1c, or mixed meal testing results (area under c-peptide curve from 0 to 4 hours) between those achieving insulin independence and those who did not. Short term insulin-independence was associated with higher median transplanted islet equivalents (IEQ)/kg (6,981 vs 4,493, p=0.02), lower units of basal insulin on discharge (7 vs 12, p=0.009), and lower rates of discharge from the hospital with an insulin regimen (67% vs 100%, p=0.006). Short-term insulin independence was also associated with decreased median insulin use in the immediate 24-hour post-operative period (14.3 vs 45.3 units, p=0.03), though this was not statistically significant when adjusting for patient weight (0.23 vs 0.56 units/kg, p=0.13). The odds of having short term insulin independence increased by 80% for every 1,000 increase in IEQ/kg (OR 1.80, CI 1.18 to 3.12, p=0.005) and decreased by 32% for every additional basal unit of insulin on discharge (OR 0.68, CI 0.42 to 0.91, p=0.003). This was no longer statistically significant after adjusting for sex, age, mixed meal testing area under c-peptide curve at 4 hours, and HbA1c. Long-term insulin independence was also associated with transplanted IEQ/kg and basal insulin units at discharge in univariable analysis. None of the patients on insulin or any other antihyperglycemic medication prior to surgery achieved short- or long-term insulin independence. Conclusion: Short- and long-term insulin independence after TPIAT is associated with a higher transplanted IEQ/kg and fewer units of basal insulin at discharge. Immediate post-operative variables can be used to inform the discussions clinicians have with their patients regarding glycemic prognosis following TPIAT. Presentation: 6/2/2024

New constraints on the tectonic history of the basement of the Western Cordillera and coastal forearc of Ecuador

The Western Cordillera and forearc of the Northern Andes (north of 5° S) are constructed from allochthonous terranes floored by oceanic crust. A paucity of accurate geochronological data from the ultramafic and mafic basement sequences of the Western Cordillera and Coastal region of Ecuador has lead to distinct differences in published tectonic models, with different allochthonous units and contrasting timelines of accretion and collision. We present new zircon UPb and groundmass 40Ar/39Ar dates of the basement units, which have been combined with new whole rock geochemical and isotopic data to constrain their tectonic histories prior to and during their accretion to South America. Ultramafic and mafic rocks with oceanic plateau affinities can be divided into two plateau sequences, where an inboard, younger plateau (85–92 Ma; Pallatanga Block) is sutured against South America, and was modified by a pre-accretionary intra-oceanic arc (Pilatón-Pujilí arc) that was terminated by the accretionary process. An older, outboard oceanic plateau sequence (∼120 Ma) forms the basement to a series of coastal blocks within the present forearc (Piñon, San Lorenzo, Pedernales and probably the Esmeraldas blocks). The outer plateau also hosts a pre-accretionary intra-oceanic arc (Pascuales – San Lorenzo arc), which remained active during and post-accretion (San Lorenzo – Rio Cala arc). Coeval changes in palaeomagnetic declination, the onset of rapid exhumation (>1 km/My) of the Early Cretaecous continental margin and sedimentation within the newly formed retro-arc foreland basin and foreland region supports a model where both oceanic plateau sequences accreted to South America in a single accretion event at 75–70 Ma. Thus, it is likely that the accreted oceanic plateau was composite, and included both the younger and older plateau sequences prior to accretion. We test an alternative model where the inner (younger) and outer (older) oceanic plateaus accrete in sequence, although this fails to account for the timing of block rotations in the forearc.

Unravelling the evolution of a continental rift by a multi-proxy provenance study (Albertine Rift, Uganda)

Sedimentary provenance analysis has rarely been applied to continental rifts, because source-rock terrains are assumed to be uniform and supply systems stable and closely connected to the formation of graben shoulders. Here, we test the suitability of multi-proxy sedimentary provenance analysis to unravel the evolution of a segment of the East African Rift System from its sedimentary record, where an extreme relief has been created and a continent-wide drainage system has been affected. Multi-proxy techniques include petrographic-mineralogical analysis (framework, heavy mineral spectra, zircon morphology, and colour), as well as single-grain garnet geochemistry, Zr-in-rutile thermometry, and geochronological methods (detrital zircon U–Pb ages). Published data are compiled and complemented by new U–Pb detrital zircon data of rift sediments. Because a comprehensive database of basement source-rock compositions from East Africa is missing, published modern river sand compositions have been added to provide endmember source fingerprints. The selected Albertine Rift is surrounded by four main source terrains within the East African Basement, which cannot be separated clearly by individual provenance indicators. Most useful were heavy mineral spectra, garnet composition, and with limitation Zr-in-rutile thermometry showing different metamorphic overprint. U–Pb detrital zircon spectra assisted well in detecting juvenile magmatism of different orogenic events, but repeated inheritance in younger units prevented a strict allocation. Petrographic maturity turned out to be more dependent on multi-cycle detritus as on climate shift. Applying endmember composition to rift sediments, three evolutionary stages of the Albertine Rift could be identified which coincide with basin-scale unconformities. Moreover, we could prove a large, southwest trending drainage network in East Africa during the Miocene, which was destructed step-wise by ongoing rifting. Extreme uplift of the Rwenzori Mountains up to 5109 m could be documented by a specific set of provenance indicators justified by modern river sand. Three main lessons can be drawn from this study: (1) basement units can be only reliably characterized by a combination of provenance-sensitive parameters, and here, the frequently used U–Pb detrital zircon ages are not sufficient; (2) it is possible to define subunits, e.g., individual fault-blocks within the rift; and (3) chemical weathering is unproblematic when applying a multi-parameter approach even in a tropical setting.Graphical abstract

Palaeozoic Amotape Group in the Colán District:

The Amotape Gr. Consists of metasedimentites with varying degrees of metamorphism and Paleozoic intrusions, exposed as isolated blocks that form an NNE-SSW belt, separating the Meso-Cenozoic depocenters of the Talara (west) and Sechura and Tumbes basins (east) along the Pacific margin of NW Perú. We describe three metamorphic/tectonic episodes that produced sub-planar structures (cleavages, fractures) affecting the rocks of the Amotape Gr, allowing this unit to be classified as a fractured reservoir. Field survey and multi-scale subsurface data from the Colán region, evidence a secondary porosity system associated with fracture networks that affect both the basin fill and the basement units. This configures a complementary unconventional exploration target. Sandstone levels in lateral contact with leptometamorphic rocks of the Amotape Gr. define good reservoir potential due to the preferentially brittle mechanical behavior of the basement, which develops abundant fractures. The porosity values of the Amotape Gr range between 4.62% and 1.23%, while permeabilities are on the order of 0.519-0.016 mD. Elevated trapping positions seem to be successfully sealed by Cretaceous units. The reservoir properties define a complementary play concept that could be extended to other positions of the technical basement in the Talara Basin and analogous regions.

Soil–water contamination assessment due to dumpsite-impacted leachates in a metamorphic environment

Environmental contamination is a complex issue that significantly impacts human health and ecological systems, especially in developing countries like Nigeria. This study explores the interplay between surface-subsurface soil-rock resistivity and subsurface geotechnical properties, along with multiple soil-water pollution indices at and around the Old Owo-Ikare road (OOIR) dumpsite in southwestern Nigeria. Water samples from five wells and one stream were collected and analyzed, alongside twelve soil samples from four trial pits at varied depths for geoenvironmental assessment. Analyzed hydrogeochemical parameters include Na, Ca, Mg, K, Cr, Pb, Zn, Ni, Mn, Fe, and cations (NO, SO4, Cl) in the water samples. Nine dipole-dipole electrical resistivity tomography (ERT) profiles and six Schlumberger vertical electrical sounding (VES) points were used to determine surface–subsurface resistivity distribution. Water analysis results showed elevated levels of K, Ni, Cr, and Pb concentrations. Geotechnical tests indicated that most dumpsite soil meets good landfill material criteria with low permeability (5.92×10−6 to 1.49×10−4cm/s). ERT and VES inverted models revealed four lithologic layers with two main curve types (HA and QA). Elevated heavy metal levels in the dumpsite soil and inverted resistivity models suggested leachate contamination in the topsoil and weathered bedrock units. Despite relatively lower heavy metal concentrations compared to other Nigerian and Ghanaian dumpsites, multi-pollution indices indicated significant contamination in both water and soil samples, posing moderate to very high environmental risks based on World Health Organisation standards. Additionally, human health risk assessment suggested a risk of cancer and non-cancer-related diseases from prolonged well water consumption. Therefore, ongoing monitoring and remediation efforts are essential to forestall imminent pollution in uncovered areas.

Continent-derived metasediments (Cimes Blanches and Frilihorn) within the ophiolites around Zermatt: relations with the Mischabel backfold and Mont Fort nappe (Pennine Alps)

The region surrounding Zermatt (SW Switzerland and NW Italy) displays some classic examples of imbrications between continental and oceanic units. In particular, the studied units, called Cimes Blanches and Frilihorn or Faisceau Vermiculaire, consist of a set of thin bands of continent-derived metasediments intercalated at different levels within the ocean-derived units. These bands are locally reduced to only one meter thick but can be traced for several tens to more than one hundred kilometers across the Pennine Alps. The mechanisms leading to such imbrications are a long-standing and still-debated question. Based on detailed mapping and structural analysis of key areas, we present new data on the structure and stratigraphy of the Faisceau Vermiculaire in the area surrounding Zermatt, with particular focus on the Täschalpen sector, where the Faisceau Vermiculaire is locally in contact with basement units. Our observations allow: (i) to confirm the presence of widespread breccias of probable Jurassic age in the Faisceau Vermiculaire; (ii) to interpret the contacts between the Faisceau Vermiculaire and the overlying non-ophiolitic Schistes Lustrés (Série Rousse) as stratigraphic; (iii) to show that the stratigraphy of the Faisceau Vermiculaire and associated Série Rousse contrasts strongly with the cover of the Siviez-Mischabel nappe and that these sequences originate from different paleogeographic domains (Prepiemont basin and Briançonnais platform respectively); (iv) to interpret as stratigraphic the contact of the Faisceau Vermiculaire and the Série Rousse with the basement forming the Alphubel anticline; the local unconformity is interpreted as the result of the activity of synsedimentary Jurassic normal paleofaults; (v) to highlight the trace of a major Jurassic normal fault, that should have marked an abrupt thinning of the paleomargin; it corresponds now to the contact between the Faisceau Vermiculaire (and associated Série Rousse) and the Siviez-Mischabel basement in the hinge of the Mischabel backfold. We propose a new tectonic scheme for the structure of the Faisceau Vermiculaire and adjacent units involving an early northward folding of the Faisceau Vermiculaire with the Série Rousse and the ophiolitic Schistes Lustrés of the Tsaté nappe, followed by major backfolding responsible for the southward emplacement of these units above the HP Zermatt-Saas and Monte Rosa nappes. Our study at regional scale shows that the group formed by the Alphubel basement, the Faisceau Vermiculaire and the Série Rousse share a tectonic position and stratigraphic sequences identical to those of the Mont Fort nappe, which outcrops on the other side of the Dent Blanche klippe. It leads to the proposition that this group constitutes the eastern extension of the Mont Fort nappe.

Preoperative and Postoperative Predictors of Insulin Independence From Total Pancreatectomy and Islet Autotransplantation

ObjectiveThis study examined the preoperative and postoperative variables associated with 1 year and long-term insulin independence following total pancreatectomy and islet autotransplantation (TPIAT). Methods46 TPIAT patients from 2010 to 2022 in a single hospital system were retrospectively analyzed. Pre- and postoperative variables were compared between short-term (1 year) and long-term (last follow-up after year 1) insulin-independent versus -dependent patients. ResultsNine (20%) and seven (15%) patients achieved short- and long-term insulin independence, respectively. The patients were followed up for a median of 2.8 years (interquartile range [IQR] 1.0, 4.7). Short-term insulin independence was associated with higher median transplanted islet equivalents (IEQ) per kg (6981 vs 4493, P = .02), lower units of basal insulin on discharge (7 vs 12, P = .009), and lower rates of discharge with an insulin regimen (67% vs 100%, P = .006). Odds of short-term insulin independence increased by 80% for every 1000 increase in IEQ per kg (OR 1.80, CI 1.18-3.12, P = .005) and decreased by 32% for every additional basal unit of insulin on discharge (OR 0.68, CI 0.42-0.91, P = .003) on average. Long-term insulin independence was also associated with transplanted IEQ per kg. No patient on antihyperglycemic medication before surgery achieved insulin independence. ConclusionShort- and long-term insulin independence after TPIAT is associated with higher transplanted IEQ per kg and immediate postoperative variables that can be used to inform the discussions clinicians have with their patients regarding glycemic prognosis following TPIAT.

Saline and hydrocarbon-bearing fluids detected in shallow aquifers of southern New Brunswick, Canada: Natural occurrence, or deep migration along faults and industrial wellbores?

Unconventional hydrocarbon production has sparked public concerns for several years, especially regarding potential potable groundwater contamination by hydrocarbons, brines, and various chemicals related to hydraulic fracturing operations. One possible contamination mechanism is upward migration of deep-seated contaminants over large vertical distances, through preferential pathways such as leaky well casings or permeable geological faults. In New Brunswick (Canada), thermogenic hydrocarbons and brackish water were previously reported in shallow water wells, some of them located close to unconventional gas wells or to major faults, but the exact origin of these fluids remained uncertain. The objective of this paper is to determine whether the presence of these fluids is the result of migration from the deep (>1 km) hydrocarbon bearing units (via natural or anthropogenic migration pathways), or whether they rather originate within the shallow aquifer (<100 m) or from intermediate zone. Tracking fluid origin was achieved by fingerprinting compositional and isotopic values of three indicators: 1) water isotopic signature (including tritium (3H), radiocarbon (14CDIC), δ18OH2O, δ2HH2O), 2) salinity (including Na, Ca, K, SO4, Cl, Br, 87Sr/86Sr), and 3) hydrocarbons (compositional data and δ13CCH4). These various analyses were conducted, when relevant, on samples of different matrices composing the hydrogeological system, namely shallow groundwater (12–90 m depth), shallow bedrock gas (8–131 m), and intermediate zone evaporitic rocks (173–332 m); they were compared with previously published values for deep basin brines and gases (1940–3168 m) from the hydrocarbon bearing Carboniferous Albert Formation. This unique suite of indicators, analytes and matrices allowed drawing the conclusion that thermogenic gas and high salinities present in the sampled wells were naturally occurring and originating from shallow and intermediate-zone bedrock units. Results obtained through this approach did not provide any evidence that hydrocarbon wells in this area have acted as preferential migration pathways for deep-seated fluids towards shallow aquifers.

Rotation of crustal domains related to Gondwanide deformation in the Neoproterozoic–Cambrian Sauce Chico Complex (Argentina), southwestern margin of the Río de la Plata Craton: Insights from AMS data

The tectonic evolution of the Ventania System fold and thrust belt and the origin of its curvature have been the subject of debates for decades. The Gondwanide Orogeny generated the mylonitization of its Tonian–middle Cambrian basement (i.e., Sauce Chico Complex), accompanied by an intense hydrolysis which produced secondary muscovite (i.e., sericite), and the folding of the overlying Paleozoic sedimentary cover. To evaluate the structural and tectonic evolution of the Ventania System as a result of the interaction of its basement with the Río de la Plata Craton, we studied the anisotropy of magnetic susceptibility (AMS) and rock magnetism on samples of the Sauce Chico Complex. Rock magnetic studies suggest that paramagnetic minerals are the main carriers in the entire Sauce Chico Complex. We suggest that our results reflect secondary muscovite generation due to mylonitization. AMS data reveal that the orientation of the magnetic foliation coincides to a large extent with the rock foliation. However, magnetic and rock foliation orientations are not uniform among the different sampled units, displaying strikes between N 320° (NW) and N 345° (NNW) on average. Localities with different orientations are separated by regional strike-slip structures, referred to as tear faults, which have also been reported and interpreted by previous authors. According to this, we suggest that the variations detected between the orientation of the magnetic and rock foliations of the different basement units may be the result of the rotation of crustal blocks bounded by tear faults. We also propose the existence of a new tear fault not previously recognized. Furthermore, a tear fault of regional character, known as the Sauce Chico Tear Fault, juxtaposes two distinct crustal domains. The differential displacement of such domains could have contributed not only to different structural styles between blocks on both sides of the Sauce Chico Tear Fault, but also to the curved shape of the Ventania System during the progression of the Gondwanide deformation.

Revisiting the depositional age and provenance characteristics of metasedimentary rocks from the basement units in the Central Pontides (N Turkey): New constraints for tectonic evolution of the southern Black Sea region

The pre-Jurassic tectonic evolution of the Central Pontides in northern Turkey is still poorly understood due to the lack of detailed geochemical and geochronological data from the basement units. Therefore, this study reports for the first time combined whole rock geochemistry, trace element data and U-Pb ages for detrital zircons, and Ar-Ar geochronological data from the metasedimentary rocks of the Devrekani Massif, Geme Complex, and the Serveçay Unit to better understand their provenance, depositional age characteristics, and tectonic evolutions. The detrital zircon U-Pb data of metasedimentary units from the Devrekani Massif, Geme Complex, and the Serveçay Unit yield ca. 191, 185 and 298 Ma maximum depositional ages (youngest age peaks), respectively. The Devrekani Massif is dominated by Permo-Carboniferous-aged detrital zircons (67 %), whereas Neoproterozoic and Devonian-aged detrital zircons are more common in the Geme Complex (47 %) and the Serveçay Unit (53 %). These distinct age distributions clearly indicate that the Devrekani Massif may has been deposited in a dissimilar location compared to the Geme Complex and the Serveçay Unit. Furthermore, in contrast to the Devrekani Massif, the source area of the metasedimentary rocks from the Geme Complex is comparable with that of the Serveçay Unit. Lastly, the obtained detrital zircon U-Pb and mica Ar-Ar ages suggest that the Devrekani Massif and the Geme Complex were deposited and metamorphosed during the Early and Middle Jurassic, respectively. The Serveçay Unit was deposited and metamorphosed in the Permian.

The high-resolution map of Oxia Planum, Mars; the landing site of the ExoMars Rosalind Franklin rover mission

ABSTRACT This 1:30,000 scale geological map describes Oxia Planum, Mars, the landing site for the ExoMars Rosalind Franklin rover mission. The map represents our current understanding of bedrock units and their relationships prior to Rosalind Franklin’s exploration of this location. The map details 15 bedrock units organised into 6 groups and 7 textural and surficial units. The bedrock units were identified using visible and near-infrared remote sensing datasets. The objectives of this map are (i) to identify where the most astrobiologically relevant rocks are likely to be found, (ii) to show where hypotheses about their geological context (within Oxia Planum and in the wider geological history of Mars) can be tested, (iii) to inform both the long-term (hundreds of metres to ∼1 km) and the short-term (tens of metres) activity planning for rover exploration, and (iv) to allow the samples analysed by the rover to be interpreted within their regional geological context.

Ice? Salt? Pressure? Sediment deformation structures as evidence of late-stage shallow groundwater in Gale crater, Mars

Persistence of near-surface water during the late evolution of Gale crater, Mars, would have been fundamental for maintaining a habitable environment. Sedimentation in aqueous conditions is evident during the early stages of crater infilling, where accumulation of lower Mount Sharp group strata is characterized by fluviolacustrine sedimentary rocks. The basal unit of the Siccar Point group—the Stimson formation—which unconformably overlies the Mount Sharp group and represents conditions postdating the exhumation of Aeolis Mons, is characterized by accumulation of aeolian strata under arid conditions. Water was largely absent near the surface during its deposition. At the Feòrachas outcrop, discovery of soft sediment deformation structures in aeolian Stimson strata challenges the notion that Gale crater was devoid of water during its later depositional phase. We identified deformed wind-rippled and vertically laminated sandstones, hosted within erosion-resistant ridges forming boxwork patterns. Broadly, these structures are diagnostic of water (as liquid or as ice) in the shallow subsurface. Comparison with Earth analogues suggests formation by subsurface fluid escape, freeze-thaw processes, or evaporite deformation. Regardless of the mechanism, these structures signify the presence of water at or near the surface much later than previously documented and may extend the habitability window in Gale crater.

Pan-African granitic magmatism of the Kaoko Belt: Tectonic perspective from its South American connection and insights into the crustal architecture of SW Gondwana

The Kaoko Belt in northwestern Namibia formed during the assembly of Gondwana in the Neoproterozoic to Cambrian Pan-African orogenic cycle. The belt has a complex tectonic architecture, in which a variety of basement units and metasedimentary associations became juxtaposed along shear zones and experienced widespread intrusive magmatism, generally confined to its western domain. We present a large new dataset of whole-rock geochemical and isotope data, as well as U-Pb zircon ages, encompassing a wide variety of granitoids and subordinate basic rocks across the Kaoko Belt. This is complemented by whole-rock isotope analyses from various basement and metasedimentary units and by a compilation of data from the literature. The new dataset strengthens previous models that correlate the granitoids in the Kaoko Belt to the coeval Florianópolis Batholith in the South American Dom Feliciano Belt, which we use to shed new light on the tectonic organization and evolution of the Pan-African orogenic cycle in the Neoproterozoic. The similarities in the compositional range of granitoids from both sub-domains of the Western Kaoko Belt, namely the Orogen Core and the Coastal Terrane, suggest that the entire zone comprises a heterogeneous but comparable and consistently diverse association of rocks. The comparison to South America underscores that, while the granitoids have “crust-like” isotopic signatures, these are in sharp contrast with those of the mostly Archean to Paleoproterozoic basement rocks of both the Kaoko and Dom Felicano belts. This suggests that the magmatic sources of the intrusive magmatism of the Kaoko Belt are likely a mixture of autochthonous crustal melting with an important mantle-derived input at some point after the Paleoproterozoic. This input was probably driven by accretionary orogeny and/or rifting that took place in the Tonian, Ediacaran, or both. The presence of more juvenile associations in the western domain of the Kaoko Belt may indicate an isotopic boundary within the belt that mirrors the tectonic configuration of the Dom Feliciano Belt in South America. This isotopic border, which would correspond to the Puros Shear Zone, could have acted as a terrane boundary from the earliest stages of the tectonic evolution of the Kaoko Belt.

Metamorphic evolution and geological significance of Early Palaeozoic high‐pressure granulites from the East Kunlun (NW China)

AbstractGranulites and eclogites are useful for revealing the thermal and tectonic evolution of orogens. Early Palaeozoic granulites and associated eclogites in the East Kunlun Orogenic Belt (EKOB) display contrasting metamorphic age. Such asynchronous granulite–eclogite associations have rarely been reported, and the geological significance of their existence remains to be further explored. In this study, petrological and geochronological techniques were used to investigate two felsic and two mafic granulites collected from the Qingshuiquan area in the eastern section of the EKOB. These rocks record similar P–T paths, which are characterized by a peak stage within suprasolidus and high‐pressure (HP) granulite facies conditions (750–832°C and 10.1–12.0 kbar), followed by an initial decompression and cooling stage to subsolidus conditions (600–748°C and 6.5–8.6 kbar), and then a stage of further retrogression under greenschist facies conditions. The protoliths to these granulites are of volcanic and sedimentary origin and suggested to be a component of the continental basement unit. Metamorphic P–T paths indicate that these rocks experienced peak metamorphism at a depth of ~40 km, then cooling and uplift to a depth of ~25 km, and eventually experienced low‐grade retrogression at shallow crustal levels. Cathodoluminescence images and compositional data demonstrate that the zircons in these rocks are of metamorphic origin and they crystallized at or near peak conditions. SIMS U–Pb dating of representative zircon grains yield concordant metamorphic ages of c. 490–520 Ma, with a peak value of 505 Ma on the probability density curve. These ages are similar to other 480–530 Ma ages typically retrieved from EKOB granulites and associated rocks, and are markedly older than the 400–450 Ma ages retrieved from eclogites and their host rocks. The HP granulites and eclogites of the EKOB do not show overprinting relationships. Such asynchronous characteristics imply that the two rock types formed in distinct tectonic settings and at different stages of a protracted subduction–collision process. The studied granulites are suggested to have formed in the root of a continental arc during a stage of Proto‐Tethys Ocean subduction. The formation of the eclogites could be attributed to subsequent deep continental subduction.

Neoarchean magmatism and Rhyacian reworking in the northeast of the Amapá Block, southeastern Guiana Shield, Brazil: Geochemistry, U–Pb geochronology, and Hf–Nd isotopes

This study investigates the age, geochemical nature, sources, and Rhyacian reworking of the Neoarchean magmatism at the northeastern portion of the Amapá Block, southeastern Guiana Shield (northeast Amazonian Craton). This block consists of a large Archean continental landmass strongly reworked during the Transamazonian orogeny (2.26–1.95 Ga). We provide the very first geochemical results for Archean basement units of the Amapá Block, which are the Mesoarchean Tumucumaque and Neoarchean Guianense complexes, and Neoarchean Mungubas Granite. The first two exhibited geochemical affinity with enriched TTG-type and hybrid granitoids, respectively, while the Mungubas Granite showed affinity with biotite granites. Such affinity with C-type granitoids indicates that the genesis of these units involves partial melting of crustal sources. LA-MC-ICP-MS zircon U–Pb and Lu–Hf, and whole-rock Sm–Nd data were obtained for the Neoarchean Mungubas Granite and Guianense Complex. In both units, zircon U–Pb dating provided a distribution of dates that span ∼50 Ma forming two groups with distinct mean 207Pb/206Pb ages of ∼2.70 Ga and ∼2.65 Ga, respectively. The older age is considered as the crystallization/emplacement age of the Mungubas Granite and the Guianense orthogneiss protolith, while the younger one is ascribed to concealed Pb loss. The recognition of Mesoarchean inherited zircon core and xenocryst with ages of 2.84 Ga and 2.99 Ga suggest that these units reworked older basement rocks from the Amapá Block. Subchondritic ԐHf(2.70 Ga) of zircon and ԐNd(2.70 Ga) of whole-rock, along with their respective Hf-TDMC (3.6–3.2 Ga) and Nd–TDM (3.6 Ga) model ages, for both units, reflect the substantial crustal reworking of predominant Paleoarchean sources during the Neoarchean in the northeastern Amapá Block. In addition, U–Pb dating on titanite crystals from the Guianense orthogneiss yielded an unprecedented ∼2.05 Ga age, arguing that a Late Rhyacian metamorphic event affected the Archean orthogneisses. This 2.05 Ga event coincides with the emplacement of Rhyacian granitoids in the area, as well as with the 2.06–2.04 Ga late orogenic HT granulite facies and amphibolite facies metamorphic events identified, respectively, at the northern border and in the central-southern portion of the Amapá Block.

Late Triassic to Early Jurassic anatectic magmatism in the Chiapas Massif Complex, southern Mexico: New evidence for the onset and mode of crustal extension in western equatorial Pangea

During the Triassic, continental breakup started in western equatorial Pangea, while active continental margins developed along North and South America’s Pacific borders. Besides many uncertainties about how peri-Gondwanan terrains of Mexico evolved during and after Pangea’s amalgamation, the apparent absence of Late Triassic magmatism has been an enigmatic feature of Mexico’s geology. Here, we present the first documented occurrences of Late Triassic igneous rocks and a coeval high-grade metamorphic event in southern Mexico, as well as evidence for subsequent Early Jurassic ductile deformation and magmatism. Samples come from the Chiapas Massif Complex (CMC), a crystalline basement of the southern Maya Block. Field evidence suggests that garnet-bearing leucogranitic stocks intruded a former structural boundary between different Precambrian-Paleozoic basement units. High-precision Sm-Nd garnet-whole-rock ages (ID-TIMS partial dissolution techniques) and U-Pb geochronology on zircon rims (LA-ICPMS) revealed Norian igneous crystallization ages for the leucogranites (∼221–213 Ma). Isotope and geochemical data indicate that these granites originated from crustal reworking by anatexis. A garnet-bearing leucosome from a migmatite yielded a slightly younger Sm-Nd age (∼204 Ma), indicating cooling soon after the peak conditions of the anatectic event. Additionally, monazite from a mylonitized leucogranite yielded an Early Jurassic U-Pb age (∼179 Ma), indicating ductile deformation. Nearly coeval zircon ages from an undeformed pink granite and a nearby volcaniclastic sequence (∼184–189 Ma) further imply contrasting erosion levels during the Early Jurassic. The new data support models for regional stretching of eastern and southern Mexico, where crustal extension during the gravitational collapse of a collisional orogen in paleo-northern Mexico led to continental rifting and the breakup of Pangea. In the CMC, crustal extension is reflected by Norian anatectic crustal melts and migmatites, as well as Early Jurassic plutonic and extrusive magmatism that are localized in certain fault-bounded blocks with different erosion levels compared to adjacent blocks.

From 3.4 Ga TTG generation to 2.9 Ga crustal anatexis: The Archean crustal evolution of Porteirinha Complex (SE, Brazil)

The Porteirinha Block (PB) provides an important record of the origin and evolution of South American crust. The PB records the generation of Paleoarchean TTG, Mesoarchean anatexis, and Paleoproterozoic crustal reworking. It is exposed as a basement inlier in the Araçuaí Orogen as a result of a tectonic involvement of the continental margins of São Francisco Congo Paleocontinent (PSFC) during the collisional processes of Gondwana amalgamation at the Neoproterozoic. The PB basement unit is the Porteirinha Complex (PC), which consists of TTG orthogneisses, migmatites, amphibolites, metaultramafics rocks and Neoarchean granitoids. In this paper, we discuss the evolution of the TTG orthogneisses and migmatites from PC based on field, geochronological and whole-rock geochemistry data. Zircon U–Pb ages (LA-ICP-MS) show a complex and polycyclic evolution of these rocks. Concordant ages were obtained for crystallization of TTG magma at ca. 3.4 Ga and the geochemical signature supports the idea of TTG generation by partial melting of hydrated mafic crust under garnet-amphibolite facies conditions. Zircon U–Pb ages also suggest crustal reworking events at 3.1 Ga. Metatexite and diatexite domains related to partial melting of TTG orthogneisses are individualized. The migmatites record processes of crustal anatexis and melt generation that occurred between 2.8 and 2.9 Ga (LA-ICP-MS, U–Pb in zircon) and are linked to crustal reworking and heat generation events recognized regionally. The new data presented in this work allow us to establish correlations between Archean and Paleoproterozoic units of the PB and those that occur regionally, particularly those related to Gavião block, where a series of stages and events of early crustal evolution are shared.

Marinoan glaciation in the Indian subcontinent - Anatomy and global implications

Detailed sedimentological analysis of the Pokaran Boulder Bed, representing the most basal unit of the Neoproterozoic-Lower Cambrian Marwar Supergroup, clearly indicates its glacial origin. The glacial sediments are interpreted as an ice-contact submarine fan deposit. Based on the detrital and inherited zircon population of the Marwar Supergroup sediments and interlayered pyroclastic deposits, a Marinoan cryochron of the Cryogenian Period is envisaged for the Pokaran Boulder Bed. The well-preserved Ediacaran elements in the post-glacial sedimentary succession also support a Cryogenian to Early Cambrian age of the Marwar Supergroup. The glacial deposition at the base of the Marwar Supergroup strengthens the regional correlation between the studied sediments with the Lesser Himalayan Blaini-Krol-Tal sediments and the Haqf Supergroup of Oman. The available zircon ages and paleomagnetic data of the Malani Igneous suite, along with the Marinoan glacial deposits, detrital zircon ages, and Ediacaran fossil elements of the Marwar Supergroup add significant information to the Neoproterozoic Earth history.

Geologic Map of the Bedford 30- x 60-minute Quadrangle, Indiana

The Geologic Map of the Bedford 30- x 60-minute Quadrangle shows the Mississippian and lower Pennsylvanian bedrock units and the overlying Pleistocene and Holocene deposits distributed over eight counties. The mapped area includes five physiographic divisions of the Southern Hills and Lowlands Region in south-central Indiana. Bedrock units and unconsolidated deposits were characterized by outcrop field observations, and new and archived borehole data. Bedrock data was consolidated into a single mapping database, which was then processed using gridding and contouring tools in ArcGIS Pro, resulting in rock formation contact lines, mappable at 1:100,000 scale. Additional information used to delineate contacts for unconsolidated deposits was based upon Indiana Department of Natural Resources water well database and soils data from the Soil Survey Geographic (SSURGO) database. Light detection and ranging (LiDAR) digital elevation models were also used to identify landforms and refine contacts between surficial units. The mapped bedrock units, from east to west, range in age from the Borden Group (lower Mississippian) to the Raccoon Creek Group (Lower Pennsylvanian) with the strike oriented generally from northwest to southeast. Quaternary deposits are found in river and stream valleys and filling the Wabash and Scottsburg lowlands with glacial deposits. Quaternary sediments were mostly deposited during the last two major advances of the Laurentide Ice Sheet into south-central Indiana. Brief summaries of all mapped bedrock units and unconsolidated deposits are listed on the map sheet, with more detailed descriptions in the accompanying pamphlet. Bedrock survey drill hole data points are also displayed on the map with corresponding links to expanded drill hole information for each of the survey drill holes listed in the pamphlet. In addition to the map and pamphlet, a composite spatial data set that conforms to the standardized database schema known as GeMS (Geologic Map Schema) is also available for download from this site. Both ESRI-licensed geodatabase and open shapefile versions of the spatial data set are available for download. Metadata records associated with each element within the spatial data set contain detailed descriptions of their purpose, constituent entities, and attributes. This geologic map was funded in part through the STATEMAP program supported by the U.S. Geological Survey under Cooperative Agreement No. G21AC10646.