Basal Reflections Research Articles

Mineral composition of xenoliths of transformed tholeiitic basalts in ore-hosting rocks of the Rudnogorskoe iron ore deposit, Eastern Siberia

Research subject. Variously-altered tholeiitic basalt xenoliths in ore-hosting rocks from the Rudnogorskoe iron ore deposit, the Angaro-Ilim region of Eastern Siberia. Aim. To identify the sequence of mineral transformations during the formation of magnetite ores. Materials and methods. The mineral composition of weakly-altered and hematitized xenoliths of tholeiitic basalts in skarned rocks and relics of basaltic hyaloand lithoclasts in varying degrees magnetitized volcaniclastites were studied. Minerals were identified using a powder X-ray diffractometer with the determination of the quantitative ratios of mineral phases by SHIMADZU XRD-6000 and DRON-2.0 diffractometers and using the microscopic (Olympus BX51) and electron microscopic (Tescan Vega 3 sbu with an Oxford Instruments Xact energy-dispersive analyzer) and IR spectroscopic (Spectrum One IR Fourier-spectrometer and a Multiscope microscope, PerkinElmer) research methods. Results. In xenoliths of weakly-altered tholeiitic basalts, volcanic glass is smectitized and partially replaced by secondary aggregates of chlorite and carbonate. In hematitized xenoliths, the smectite-hematite mineral association contains skarn epidote and garnet. Smectite aggregates, partially transformed into magnetite mass, are present in the magnetitized volcaniclastites. The studied smectites are classified as saponite according to the obtained values of basal reflections d001 in the range of 14.76–15.23 Å and calculated crystal chemical formulas. The differences in the morphology, chemical composition, and IR spectrometric characteristics of smectites reflect the varying degrees of transformation of the tholeiitic basalts in multi-stage ore-forming processes.

Seismic geomorphology and evolution of Mid-Late Miocene deepwater channels offshore Taranaki Basin, New Zealand

Deepwater channels play a significant role in deep marine environments by transporting sediments to deep marine environments, but they are also hydrocarbon reservoirs. In contrast, traditional seismic interpretation techniques have provided insights into these features; intricate channel-fill heterogeneities present challenges in revealing small features or associated elements. This study integrates high-resolution 3D seismic data, relative time geologic models (RGT), spectral decomposition, and geobody to identify the Middle-late Miocene submarine channels, their evolution, and their associated deposition elements. The geomorphologic and stratigraphic analysis results have revealed four depositional elements in the study area. These include (1) channel complexes, (2) distributary channels, (3) frontal splay channel complexes, and (4) crevasse splays. However, the channels lack constructional levee development outside the channel banks, which is linked to the limited sediment supply to deep areas. The identified channels are characterized by a narrow to wide width (0.37 km to 1.92 km), a low to high degree of sinuosity, medium incision depths, and lateral migration. The channel fill geometries are highly variable, displaying horizontal to sub-horizontal, lateral accretion, divergent, and inclined reflection packages. Most channels originate as large and wide channels from the northeast and prograde southwest direction of the Taranaki coastline, and they have evolved differently at different development stages. The channel fills exhibit a variable basal amplitude reflection, ranging from medium to high, indicating the presence of sand-prone and mixed facies, such as sand and mudstone. The spectral decomposition maps show variable color intensity, which implies different facies associations within the channels. The channel evolution is likely to be controlled by the interplay of sediment discharge, faults, sea level changes, variable gravity flow strength, and the type of materials supplied from the shelf edge.

An experimental investigation of nano clay and functionalized nano graphene oxide effects on ablation of carbon/phenolic nanocomposites

This work aims to study thermal stability and ablative behaviors of Carbon/Phenolic composites containing nano clay, nano graphene oxide and hybrid additives. To this end a detailed explained and illustrated process is involved to synthesize factionalized graphene oxide based on Hummers method. The XRD test result shows a major shift in basal plane reflection to below 2θ = 20° in the provided spectrum, which indicates achievement in the functionalization process. Prepared nanoparticles suspensions are then mixed by resol resin with desire wt% to outcome nanocomposites. An in-depth analysis of SEM images with focus on the dispersion, morphology, and interaction of the nanofillers with the resin matrix reveals that nanoparticles are dispersed properly with no agglomeration. 200 gr/m2 carbon woven fabric is then impregnated with prepared nanocomposites employing an own made prepreg machine to use to construct standard flexural as well as oxy acetylene test specimens. Using bending test, thermogravimetric analysis and oxyacetylene torch test, effects of different percentages of considered nanoparticles on the mechanical properties, thermal stability and ablative of carbon/phenolic composites are assessed and the results are reported. According to the results, adding only 0.1 wt% of nano graphene oxide increases char yield around 5% and remain back surface temperature under 100°C during flame test. Moreover samples with 0.2 wt% of nano clay and hybrid (0.05 wt% nano graphene oxide and 0.1 wt% nano clay) additives provides best reaming amount of solid.

Revising the Basal Permittivity of the South Polar Layered Deposits of Mars With a Surficial Dust Cover

AbstractBright basal reflections from the Mars Advanced Radar for Subsurface and Ionosphere Sounding (MARSIS) have been proposed to be consistent with permittivities characteristic of a wet material beneath the south polar layered deposits (SPLD). The characterization of a recently formed impact crater highlight the existence of a several meters thick ice‐poor layer associated to a unit blanketing a large portion of the SPLD. We revise the radar propagation model used to invert the basal permittivity by including a surficial thin layer. We find that the inverted basal permittivity is highly sensitive to the properties of such a layer, with solutions ranging from common dry rocks to an unambiguously wet base. We advocate toward a better characterization of the surficial cover to assess the wet or dry nature for the base, and possibly reconcile most of the literature on the topic.

The last remnants of the Italian Apennine glaciers: 3-D modeling of the Lower Calderone Glacieret by the IDW spatial interpolation of GPR data

Abstract We present a quantitative ground-penetrating radar (GPR) analysis of the Lower Calderone Glacieret to highlight the recent evolution of one of the southernmost glacial systems in Europe. The Upper and Lower Calderone Glacierets are the last two perennial ice bodies in the Apennine Mountains (Italy), and their continuous monitoring is important for glaciology, hydrology and climate science. We applied a proprietary auto-picking algorithm to track reflections accurately and objectively within three pseudo-3-D GPR data sets that were acquired over the Lower Glacieret in different years. After the time-to-depth conversion, the basal reflections were projected onto the normal versors of a 3-D topographic model of the survey area, at the different GPR trace positions. We then applied an Adjusted Inverse-Distance Weighted Spatial Interpolation method to extrapolate the ice-bedrock interface within the areas not directly covered by the GPR profiles and compare it with the topographic surface to recover the glacieret volume. In this paper, we critically examine the accuracy of the reconstructed models, including possible issues related to the challenging survey areas, such as local artifacts in the interpolated interface caused by irregular GPR coverage. We further discuss the various advantages of the implemented procedure with respect to more traditional glacier monitoring techniques.

Corrensite and associated smectites in the Teschenite Association Rocks from the Podbeskydí Area (Czech Republic and Poland)

This study reports on the relatively common presence of the clay mineral corrensite in Teschenite Association Rocks of Early Cretaceous age. Significant quantities of corrensite were noted in monchiquite dikes and pillow lavas, pyroxene-rich rocks (teschenites), picrites, and also in the associated tuffs and tuffites including hyaloclastite breccias, and in strongly albitised calcareous shale enveloping small volcanic bodies. In addition to the transformation of primary mafic minerals such as forsteritic olivine, Ca-Fe-Mg clinopyroxenes, and amphiboles into clay associations, secondary zeolitisation (analcimisation), carbonatisation, silicification, and serpentinisation were also observed. The main clay mineral within the investigated rocks was smectite close to montmorillonite and saponite, but chlorite and serpentinite subgroup minerals were also present. The corrensite-bearing rocks were macroscopically indistinguishable from their smectitised or chloritised equivalents. Corrensite itself formed extremely thin (<1 μm) wrinkled sheets, present both in the rock matrix and the amygdaloid cavities, where it was younger than albite but older than calcite. The presence of corrensite was proven through powder X-ray diffraction analyses; a sequence of basal reflections at 28–29 Å, 14.25 Å, 7.15 Å, etc., were recorded, which after the application of ethylene glycol slightly expanded to 31 Å, 15.5 Å, 7.83 Å, etc. According to the interlayer distances, behaviour of corrensite after ethylene glycolation, the chemical classification criteria, and geological setting the analysed mineral was a HC-type corrensite of hydrothermal origin. The results of wavelength dispersive spectroscopy (WDS) microanalyses yielded an empirical average formula (K0.12Na0.01Ca0.15)Σ0.28(Mg4.84Fe2+1.65Fe3+1.34Mn2+0.02Al0.82)Σ8.95(Si5.86Ti0.10Al2.03P0.01)Σ8.00O20(OH9.89,F0.11) Σ10.00 . nH2O. Elevated Ti content can be explained either by presentce of nanosize TiO2 particles or a substitution of Ti (up to 0.33 apfu) for tetravalent silicon. The abundance of clay minerals in the Teschenite Association Rocks revealed that they were overprinted by several metamorphic events. Corrensite occurrences narrowed the metamorphic conditions to a temperature interval of 60 to 300 °C, which overlaps both zeolite and prehnite-pumpellyite metamorphic facies. The presence of smectites and corrensite in contact and hydrothermally altered sediments, as well as potassium metasomatites, proved that significant hydrothermal activity took place at the contact zones of magmatic/volcanic bodies.

Science results from sixteen years of MRO SHARAD operations

In operation for >16 years to date, the Mars Reconnaissance Orbiter (MRO) Shallow Radar (SHARAD) sounder has acquired data at its nominal 300–450 m along-track and 3-km cross-track resolution covering >55% of the Martian surface, with nearly 100% overlap in coverage at that scale in the polar regions and in a number of smaller mid-latitude areas. While SHARAD data have opened a new window into understanding the interior structures and properties of Martian ices, volcanics, and sedimentary deposits up to a few kilometers in depth, they have also led to new revelations about the deeper interior and the behavior of the planet's ionosphere. Here we summarize the data collected by SHARAD over this time period, the methods used in the analysis of that data, and the resulting scientific findings. The polar data are especially rich, revealing complex structures that comprise up to several dozen reflecting interfaces that extend to depths of 3 km, which inform the evolution of Martian climate in the late Amazonian period. SHARAD observations of mid-latitude lobate debris aprons and other glacier-like landforms detect strong basal reflections and low dielectric loss, confirming that they are ice-rich debris-covered glaciers. In other mid-latitude terrains, SHARAD data demonstrate the presence of widespread ground ices, likely at lower concentrations. SHARAD signals also probe non-icy materials, mapping out stacked lava flows, probing low-density materials thought to be ash-fall deposits, and occasionally penetrating sedimentary deposits, all of which reveal the structures and interior properties diagnostic of emplacement processes. SHARAD signals are impacted by their passage through the Martian ionosphere, revealing variations in time and space of the total electron content linked with the remanent magnetic field. Advanced techniques developed over the course of the mission, which include subband and super-resolution processing, coherent and incoherent summing, and three-dimensional (3D) radar imaging, are enabling new discoveries and extending the utility of the data. For 3D imaging, a cross-track spacing at the nominal 3-km resolution is more than sufficient to achieve good results, but finer spacing of 0.5 km or less significantly improves the spatially interpolated radar images. Recent electromagnetic modeling and a flight test show that SHARAD's signal-to-noise ratio can be greatly improved with a large (∼120°) roll of the spacecraft to reduce interference with the spacecraft body. Both MRO and SHARAD are in remarkably fine working order, and the teams look forward to many more years in which to pursue improvements in coverage density, temporal variability in the ionosphere, and data quality that promise exciting new discoveries at Mars.

Can Clay Mimic the High Reflectivity of Briny Water Below the Martian SPLD?

AbstractIt has recently been suggested that clay minerals, which are widespread on the Martian surface, could be the possible source of the basal bright reflections detected by MARSIS at Ultimi Scopuli, instead of briny water. This hypothesis is based on dielectric measurements on a wet Ca‐Montorillonite (STx‐1b) sample conducted at 230 K, which reported permittivity values (apparent permittivity of 39 at 4 MHz) compatible with the median value of 33 retrieved by MARSIS 4 MHz data inversion in the high reflectivity area. These experimental results are, however, incompatible with well‐established dielectric theory and with laboratory measurements on clays, at MARSIS frequency and Martian temperatures, reported in the literature. Here, we replicate the experiment using a setup to precisely control the rate of cooling/warming and the temperature inside and outside the clay sample. We found that the rate of cooling, the position of the temperature sensor and, consequently, the thermal equilibrium between the sample and the sensor play a fundamental role in the reliability of the measurements. Our results indicate that even for a large water content in the clay sample, at 230 K and 4 MHz, the apparent permittivity is only 8.4, dropping to 4.1 at 200 K, ruling out clays as a possible source of the bright reflections detected by MARSIS at the base of the SPLD.

Sequestration of Oxyanions of V(V), Mo(VI), and W(VI) Enhanced through Enzymatic Formation of Fungal Manganese Oxides

Biogenic Mn oxides (BMOs) have become captivating with regard to elemental sequestration, especially at circumneutral pH conditions. The interaction of BMOs with oxyanions, such as vanadate (V), molybdate (VI), and tungstate (VI), remains uncertain. This study examined the sequestration of V(V), Mo(VI), and W(VI) (up to ~1 mM) by BMOs formed by the Mn(II)-oxidizing fungus, Acremonium strictum KR21-2. When A. strictum KR21-2 was incubated in liquid cultures containing either Mo(VI) or W(VI) with soluble Mn2+, the oxyanions were sequestered in parallel with enzymatic Mn(II) oxidation with the maximum capacities of 8.8 mol% and 28.8 mol% (relative to solid Mn), respectively. More than 200 μM V(V) showed an inhibitory effect on growth and Mn(II) oxidizing ability. Sequestration experiments using preformed primary BMOs that maintained the enzymatic Mn(II) oxidizing activity, with and without exogenous Mn2+, demonstrated the ongoing BMO deposition in the presence of absorbent oxyanions provided a higher sequestration capacity than the preformed BMOs. X-ray diffraction displayed a larger decline of the peak arising from (001) basal reflection of turbostratic birnessite with increasing sequestration capacity. The results presented herein increase our understanding of the role of ongoing BMO formation in sequestration processes for oxyanion species at circumneutral pH conditions.

Partially‐Saturated Brines Within Basal Ice or Sediments Can Explain the Bright Basal Reflections in the South Polar Layered Deposits

AbstractStrong radar reflections have been previously mapped at the base of the Martian South Polar Layered Deposits. Here, we analyze laboratory measurements of dry and briny samples to determine the cause of this radar return. We find that liquid vein networks consisting of brines at the grain boundaries of ice crystals can greatly enhance the electrical conductivity, thereby causing strong radar reflections. A brine concentration of 2.7–6.0 vol% in ice is sufficient to match the electrical properties of the basal reflection as observed by Mars Advanced Radar for Subsurface and Ionospheric Sounding (MARSIS). When brine is mixed with sediments, the brine‐ice mixture in the pores must be 2–5 times more concentrated in salt, increasing the brine concentration to 6.3–29 vol%. Our best fit of the median observed MARSIS value suggests a salt‐bulk sample concentration of ∼6 wt%. Thus, salt enhancement mechanisms on the order of a magnitude greater than the Phoenix landing site are needed. To form brine, the basal reflector must reach a temperature greater than the eutectic temperature of calcium perchlorate of 197.3 ± 0.2 K, which may be possible if more complex thermal modeling is assumed. Colder metastable brines are possible, but stability over millions of years remains unclear. Conversely, gray hematite with a concentration of 33.2–59.0 vol% possess electrical properties that could cause the observed radar returns, but require concentrations 2–3 times larger than anywhere currently detected. We also argue that brines mixed with high‐surface‐area sediments, or dry red hematite, jarosite, and ilmenite cannot create the observed radar returns at low temperatures.

Using MARSIS signal attenuation to assess the presence of South Polar Layered Deposit subglacial brines

Knowledge of the physical and thermal properties of the South Polar Layer Deposits (SPLD) is key to constrain the source of bright basal reflections at Ultimi Scopuli detected by the MARSIS (Mars Advanced Radar for Subsurface and Ionosphere Sounding) radar sounder. Here we present a detailed analysis of attenuation, based on data acquired by MARSIS at 3, 4, and 5 MHz. We show that attenuation is frequency dependent, and that its behavior is consistent throughout the entire region. This suggests that the SPLD are compositionally homogeneous at Ultimi Scopuli, and our results are consistent with dust contents of 5 to 12%. Using these values as input, and plausible estimates of surface temperature and heat flux, we inferred basal temperatures around 200 K: these are consistent with perchlorate brines within liquid vein networks as the source of the reflections. Furthermore, extrapolation of the attenuation to higher frequencies explains why SHARAD (Shallow Radar) has thus far not detected basal reflections within the SPLD at Ultimi Scopuli.

GBaTSv2: a revised synthesis of the likely basal thermal state of the Greenland Ice Sheet

Abstract. The basal thermal state (frozen or thawed) of the Greenland Ice Sheet is under-constrained due to few direct measurements, yet knowledge of this state is becoming increasingly important to interpret modern changes in ice flow. The first synthesis of this state relied on inferences from widespread airborne and satellite observations and numerical models, for which most of the underlying datasets have since been updated. Further, new and independent constraints on the basal thermal state have been developed from analysis of basal and englacial reflections observed by airborne radar sounding. Here we synthesize constraints on the Greenland Ice Sheet's basal thermal state from boreholes, thermomechanical ice-flow models that participated in the Ice Sheet Model Intercomparison Project for CMIP6 (ISMIP6; Coupled Model Intercomparison Project Phase 6), IceBridge BedMachine Greenland v4 bed topography, Making Earth Science Data Records for Use in Research Environments (MEaSUREs) Multi-Year Greenland Ice Sheet Velocity Mosaic v1 and multiple inferences of a thawed bed from airborne radar sounding. Most constraints can only identify where the bed is likely thawed rather than where it is frozen. This revised synthesis of the Greenland likely Basal Thermal State version 2 (GBaTSv2) indicates that 33 % of the ice sheet's bed is likely thawed, 40 % is likely frozen and the remainder (28 %) is too uncertain to specify. The spatial pattern of GBaTSv2 is broadly similar to the previous synthesis, including a scalloped frozen core and thawed outlet-glacier systems. Although the likely basal thermal state of nearly half (46 %) of the ice sheet changed designation, the assigned state changed from likely frozen to likely thawed (or vice versa) for less than 6 % of the ice sheet. This revised synthesis suggests that more of northern Greenland is likely thawed at its bed and conversely that more of southern Greenland is likely frozen, both of which influence interpretation of the ice sheet's present subglacial hydrology and models of its future evolution. The GBaTSv2 dataset, including both code that performed the analysis and the resulting datasets, is freely available at https://doi.org/10.5281/zenodo.6759384 (MacGregor, 2022).

Numerical simulations of radar echoes rule out basal CO2 ice deposits at Ultimi Scopuli, Mars

The principal objective of the radar sounder MARSIS experiment is to look for ice and water in the Martian subsurface. One particular focus of investigations, since 2005, has been the search for basal liquid water in the south polar layered deposits (SPLD). Anomalously strong basal echoes detected from four distinct areas at the base of the deposits at Ultimi Scopuli have been interpreted to indicate the presence of bodies of liquid water in this location, beneath a 1.5 km thick cover of ice and dust. Other explanations for the bright basal reflections have been proposed, however, including the possibility of constructive interference in layered media. Here, we test this mechanism through simulations of MARSIS radar signals propagating in models of CO2-H2O ice sequences. We then compare the results to real MARSIS data acquired over Ultimi Scopuli, finding that no CO2-H2O ice model sequence reproduces the set of real data. The results of our work have implications in relation to the global CO2 inventory of Mars.

The Basal Detectability of an Ice‐Covered Mars by MARSIS

AbstractThe detection of anomalously strong relative basal reflectivity beneath the Martian South Polar Layered Deposits (SPLD) from the Mars Advanced Radar for Subsurface and Ionosphere Sounding (MARSIS) has led to hypotheses suggesting the presence of basal materials such as liquid water. Here, we propose a forward approach to assess whether such a high signal could be produced by a Martian terrain currently exposed at the surface without liquid water. We convert existing MARSIS surface reflectivity measurements into a basal reflectivity as if it were overlaid by an SPLD‐like ice deposit. 0.3%–2% of the surface could produce basal reflections of magnitude similar to the SPLD measurements in the assumption of a 10% impure ice. An ice loss tangent 0.01 is required to prevent any of the current Martian surface from producing a bright SPLD‐like basal reflection. The detected bright terrains are gathered within volcanic constructs of diverse geologic epoch.

Assessing the role of clay and salts on the origin of MARSIS basal bright reflections

Anomalously bright basal reflections detected by MARSIS at Ultimi Scopuli have been interpreted to indicate the presence of water-saturated materials or ponded liquid water at the base of the South Polar Layered Deposits (SPLD). Because conventional models assume basal temperatures (≤200 K) much lower than the melting point of water, this interpretation has been questioned and other explanations for the source of the bright basal reflections have been proposed, involving clay, hydrated salts, and saline ices. Combining previous published data, simulations, and new laboratory measurements, we demonstrate that the dielectric properties of these materials do not generate strong basal reflections at MARSIS frequencies and Martian temperatures. Plausible candidates remain perchlorates and chlorides brines that exhibit a strong dielectric response at much lower temperatures than other materials. This explanation might require that metastability could be maintained for a long period of time on a geological scale.

Mechanical Activation of Smectite-Based Nanocomposites for Creation of Smart Fertilizers

This research presents the mechanical creation of smart fertilizers from a mixture of smectite and urea in a 3:2 ratio by using the planetary milling technique. The smectite–urea composites show intercalation between urea and mineral, which increases steadily with increasing activation time. A shift of X-Ray Diffraction basal reflections, intensities of Fourier transform infrared spectroscopy (FTIR) peaks, and weight losses in thermogravimetric analysis (TG) document the systematic crystallo-chemical changes of the composites related to nitrogen interaction with activation. Observations of the nanocomposites by scanning electron microscopy (SEM) and transmission electron microscopy (TEM) corroborate the inference. Nitrogen intercalates with smectite in the interlayer space and remains absorbed either within micro-aggregates or on the surface of activated smectites. Soil leaching tests reveal a slower rate of nitrogen than that of traditional urea fertilizers. Different forms of nitrogen within the composites cause their differential release rates to the soil. The formulated nanocomposite fertilizer enhances the quality and quantity of oat yield.

A Novel Approach to the Detection and Imaging of Candidate Martian Subglacial Water Bodies by Radar Sounder Data

Research based on Mars Advanced Radar for Subsurface and Ionosphere Sounding (MARSIS) data detected unusual radar bright basal reflections located at about 1.5 km depth in a Mars region denoted as Ultimi Scopuli. These reflections were interpreted as a signature of subglacial liquid water even though this interpretation is still being debated in the literature. In this article, we propose a novel approach to the detection and imaging of candidate subglacial liquid water from radar sounding data. The approach combines the radar echo power traces with a suitable digital elevation model to provide a bidimensional representation of the surface. Even if the imaging method reconstructs a representation of the surface, we prove that it can be used to identify subsurface bright reflections in icy regions. Imaging is feasible even if the basal interface is not directly included in the processed data for image generation. To support this experimental evidence, we show that a relationship exists between the value of the reflected echo power originating from the englacial layers and the basal-to-surface-echo-power ratio. The observed relationship holds on both Ultimi Scopuli radar sounding data acquired on Mars and Lake Vostok data acquired on Earth. Our results show that the 2-D imaging provides an alternative way for locating candidate subglacial liquid water bodies on Mars over large areas also where the basal interface is not directly measured. The proposed approach complements previous research for further evaluation of the actual presence of liquid water on Mars.

LIBERAÇÃO LENTA DO ÓLEO DE COPAÍBA ADSOLUBILIZADO EM HIDRÓXIDOS DUPLOS LAMELARES: UM MATERIAL PROMISSOR PARA POMADAS CUTÂNEAS

SLOW-RELEASE OF COPAIBA OIL ADSOLUBILIZED INTO LAYERED DOUBLE HYDROXIDES: A PROMISING MATERIAL FOR SKIN OINTMENTS. In this work, Zn/Al layered double hydroxides intercalated with dodecyl sulfate ion (DS) in molar ratios (Zn2+/Al3+) 2:1, 3:1 and 4:1 were synthesized by co-precipitation method and then they were adsolubilized with essential oil of copaiba in the concentrations of 3, 5, 10, 13 and 15% wt/wt to be used as carriers in therapeutic ointments for skin injury treatments. The XRD results showed a diffraction pattern corresponding to the structure of LDHs with the presence of diffraction peaks referring to the basal reflection planes. Typical stretching and vibration bands of copaiba essential oil in FTIR spectra confirmed the adsolubilization process. The oil release plateau in the ointment was above 80% at normalized values in a time of approximately 20 h, the time required for dissolution and release of molecules adsorbed in the layered structure of the material for molar ratios 2:1 and 3:1 and the release of the solubilized molecules in the interlayer space. In contrast, LDH with a 4:1 molar ratio showed slower release and did not reach the plateau in 48 h, as this material has the ability to retain oil molecules in the LDH for longer, causing a slower release in relation to other molar ratios. The analysis for the non-intercalated copaiba oil showed a gradual increase in the concentration of the oil in the ointment, indicating a different curve profile.

Radar-Sounding Characterization of the Subglacial Groundwater Table Beneath Hiawatha Glacier, Greenland.

Radar‐sounding surveys associated with the discovery of a large impact crater beneath Hiawatha Glacier, Greenland, revealed bright, flat subglacial reflections hypothesized to originate from a subglacial groundwater table. We test this hypothesis using radiometric and hydrologic analysis of those radar data. The dielectric loss between the reflection from the top of the basal layer and subglacial reflection and their reflectivity difference represent dual constraints upon the complex permittivity of the basal material. Either ice‐cemented debris or fractured, well‐drained bedrock explain the basal layer's radiometric properties. The subglacial reflector's geometry is parallel to isopotential hydraulic head contours, located 7.5–15.3 m below the interface, and 11 ± 7 dB brighter than the ice–basal layer reflection. We conclude that this subglacial reflection is a groundwater table and that its detection was enabled by the wide bandwidth of the radar system and unusual geologic setting, suggesting a path for future direct radar detection of subglacial groundwater elsewhere.

Deriving Melt Rates at a Complex Ice Shelf Base Using In Situ Radar: Application to Totten Ice Shelf

AbstractA phase‐sensitive radar (ApRES) was deployed on Totten Ice Shelf to provide the first in situ basal melt estimate at this dynamic East Antarctic ice shelf. Observations of internal ice dynamics at tidal time scales showed that early arrivals from off‐nadir reflectors obscure the true depth of the ice shelf base. Using the observed tidal deformation, the true base was found to lie at 1,910–1,950‐m depth, at 350–400 m greater range than the first reflection from an ice‐ocean interface. The robustness of the basal melt rate estimate was increased by using multiple basal reflections over the radar footprint, yielding a melt rate of 22 ± 2.1 m a−1. The ApRES estimate is over 40% lower than the three existing satellite estimates covering Totten Ice Shelf. This difference in basal melt is dynamically significant and highlights the need for independent melt rate estimates using complementary instrumentation and techniques that rely on different sets of assumptions.