Base Of Aquifer Research Articles

Thermally Significant Fluid Seepage Through Thick Sediment on the Juan de Fuca Plate Entering the Cascadia Subduction Zone

AbstractWe use heat flux measurements colocated with seismic reflection profiles over a buried basement high on the Juan de Fuca plate ∼25 km seaward of the deformation front offshore Oregon to test for the presence of hydrothermal circulation in the oceanic crust. We also revisit heat flux data crossing a buried basement high ∼25 km seaward of the deformation front ∼150 km north, offshore Washington. Seafloor heat flux is inversely correlated with sediment thickness, consistent with vigorous hydrothermal circulation in the basement aquifer homogenizing temperatures at the top of the basement. Heat flux immediately above the summit of the basement highs is greater than expected solely from conduction. Fluid seepage at rates of ∼2.6–5.4 cm yr−1 in a 1–1.5 km‐wide conduit through ∼800–1,300 m thick sediment sections above these basement highs can explain these observations. Observations of thermally significant fluid seepage through sediment >225 m thick on oceanic crust are unprecedented. High sediment permeability, high fluid overpressure in the basement, or a combination of both is required to drive fluid seepage at the observed rates. We infer that rapid seepage occurs because the basement highs rise above the low permeability basal sediment with their tops protruding into the base of high permeability Nitinat or Astoria Fan sediment. Seepage from basement highs penetrating into the submarine fans can affect the thermal state of crust entering the subduction zone.

Water–Rock Interactions Driving Groundwater Composition in the Pra Basin (Ghana) Identified by Combinatorial Inverse Geochemical Modelling

The crystalline basement aquifer of the Pra Basin in Ghana is essential to the water supply systems of the region. This region is experiencing the ongoing pollution of major river networks from illegal mining activities. Water management is difficult due to the limited knowledge of hydrochemical controls on the groundwater. This study investigates its evolution based on analyses from a previous groundwater sampling campaign and mineralogical investigation of outcrops. The dominant reactions driving the average groundwater composition were identified by means of a combinatorial inverse modelling approach under the hypothesis of local thermodynamical equilibrium. The weathering of silicate minerals, including albite, anorthite, plagioclase, K-feldspar, and chalcedony, explains the observed median groundwater composition in the transition and discharge zones. Additional site-specific hypotheses were needed to match the observed composition of the main recharge area, including equilibration with carbon dioxide, kaolinite, and hematite in the soil and unsaturated zones, respectively, and the degradation of organic matter controlling the sulfate/sulfide content, thus pointing towards kinetic effects during water–rock interactions in this zone. Even though an averaged water composition was used, the inverse models can “bridge” the knowledge gap on the large basin scale to come up with quite distinct “best” mineral assemblages that explain observed field conditions. This study provides a conceptual framework of the hydrogeochemical evolution for managing groundwater resources in the Pra Basin and presents modelling techniques that can be applied to similar regions with comparable levels of heterogeneity in water chemistry and limited knowledge of aquifer mineralogy. The combinatorial inverse model approach offers enhanced flexibility by systematically generating all plausible combinations of mineral assemblages from a given pool of mineral phases, thereby allowing for a comprehensive exploration of the reactions driving the chemical evolution of the groundwater.

Co-Occurrence of Earthquake and Climatic Events on Groundwater Budget Alteration in a Fractured Carbonate Aquifer (Sibillini Mts.—Central Italy)

The combination of several factors related both to human pressure as well as natural issues could lead to a marked alteration of the groundwater budget terms and a decrease in groundwater availability. The basal aquifer of the Sibillini Mts. is a strategic resource of drinking water in the central sector of Apennine (Italy). The seismic sequence that occurred in this area in 2016 induced transient and sustained modifications in the aquifer settings. Springs located on the western side of the Sibillini Mts. were characterized by an increased discharge, while in contrast, the eastern springs suffered an intense drop in their groundwater discharge. In 2017, a drought period started immediately after the exhaustion of the seismic sequence effect. The comparison between the recharge and discharge of the major springs in the 2000–2020 period allowed the definition of the different responses of the aquifer to the co-occurrence of earthquakes and climatic events. The hydrodynamic alteration triggered by the earthquake induced a huge depletion of the groundwater stored in the eastern sector of the basal aquifer (at least 50 × 106 m3). The scarce recharge occurring in the following drought period (more than 30% of the average annual value) was not enough to restore the groundwater resources, causing a serious drinking water supply crisis in the main tapped springs in the eastern sector of the aquifer.

Exploring for groundwater in sub-Saharan Africa: Insights from integrated geophysical characterization of a weathered basement aquifer system, central Malawi

Study RegionMkonga village, ∼35 km southwest of the capital city of Lilongwe on the central plains in Malawi, Africa, located at the crest of a local topographic-high characterized by crystalline basement. Study FocusGroundwater aquifer systems in the shallow buried crystalline basement are geologically complex reservoir targets with historically low drilling success rates. Understanding the basement weathering profiles and their implications for aquifer architecture is crucial for drilling productive wells. This is particularly critical in developing countries where water demands are rising. This study employs an integrated approach of 2-D seismic reflection and 2-D electrical resistivity imaging, constrained by borehole data to characterize the local basement aquifers in the crystalline-dominated terranes of central Malawi. New Hydrological Insights for the RegionThe integrated geophysical and borehole data reveal a layered weathering profile: shallow thin laterite and sub-lateritic layers, the saprolite, the saprock, and the fractured/fresh basement. We identify four potential water-bearing zones consisting of the base of the sub-laterite layer, the saprolite, the saprock and the fractured basement. The most productive boreholes are those that intersect low resistivity anomalies (< 20 ohm-m) that are collocated with strong but discontinuous reflectors. These targets are interpreted to represent water-bearing zones that connect the saprolite and saprock to recharge pathways at the base of the sub-laterite.

Characterization of the productivity of basement aquifers at Bagoué region (North of Côte d’Ivoire)

This study aims to characterize the productivity of basement aquifers based on a database built by pumping test and drilling report from eighteen boreholes exploited in Bagoue region of Cote d’Ivoire. By using last version of a tool to assist in pumping test interpretation suggested by the French Mining and Geological Survey, Transmissivity parameter values of confined aquifers were determined through the well-known Theis method. In the same approach, critical yield value of borehole was determined at the equivalence point of linear and quadratic pressure drop from short-term pumping test data. Geostatistical analysis and kriging of transmissivity of aquifers were realized. Then, it was elaborated few predictive equations between hydrodynamic and hydraulic parameters based on their relationship level. Comparison of aquifers productivity and boreholes hydraulic capacity ended the methodology. Transmissivity ranged from 9.10-7 to 4.10-5 m2.h-1 while specific yield of boreholes reached between 0.34 and 23.07 m3.h-1. Yields from exploited boreholes varied between 0.5 m3.h-1 and 12 m3.h-1 with an average reaching 3.44 m3.h-1. Critical yield varied between 2.11 and 18.8 m3.h-1 with an average of 6.95 m3.h-1. According to geostatistical analysis of Transmissivity, its spatial spreading adjusted spherical model with a range reaching 0.13 meters. Findings highlighted 44 % of aquifer areas characterized by low value of transmissivity with great value of exploited outflow. That suggests a short-term availability of drinking water for living communities. In the same way, 11.11 % of boreholes were established into aquifer areas characterized by great transmissivity and low outflow values that suggests a better supply environment with long-term groundwater availability.

Hydrochemical Characterization of Surface Water and Groundwater in the Crystalline Basement Aquifer System in the Pra Basin (Ghana)

The quality of groundwater resources in the Pra Basin (Ghana) is threatened by ongoing river pollution from illegal mining. To date, there are very limited data and literature on the hydrochemical characteristics of the basin. For the first time, we provide regional hydrochemical data on surface water and groundwater to gain insight into the geochemical processes and quality for drinking and irrigation purposes. We collected 90 samples from surface water (rivers) and groundwater (boreholes) and analysed them for their chemical parameters. We performed a water quality assessment using conventional water quality rating indices for drinking water and irrigation. Cluster and factor analysis were performed on the hydrochemical data to learn the chemical variations in the hydrochemical data. Bivariate ion plots were used to interpret the plausible geochemical processes controlling the composition of dissolved ions in surface water and groundwater. The water quality assessment using Water Quality Index (WQI) revealed that 74% of surface water and 20% of groundwater samples are of poor drinking quality and, therefore, cannot be used for drinking purposes. For irrigation, surface water and groundwater are of good quality based on Sodium Adsorption Ratio (SAR), Wilcox diagram and United States Salinity (USSL) indices. However, Mn and Fe (total) concentrations observed in most surface water samples are above the acceptable limit for irrigation and therefore require treatment to avoid soil acidification and loss of availability of vital soil nutrients. Manganese and iron (total) are identified as the main contaminants affecting the basin’s water quality. The hierarchical cluster analysis highlights the heterogeneity in the regional hydrochemical data, which showed three distinct spatial associations based on elevation differences. Groundwater composition chemically evolves from a Ca–HCO3 to a Na–HCO3 and finally to a Na–Cl water type along the flow regime from the recharge to the discharge zone. The bivariate ion plot and the factor analysis underscore silicate weathering, carbonate dissolution and ion exchange as the most likely geochemical processes driving the hydrochemical evolution of the Pra Basin groundwater. Going forward, geochemical models should be implemented to elucidate the dominant reaction pathways driving the evolution of groundwater chemistry in the Pra Basin.

Application of Environmental Isotopes and Hydrochemistry to Identify the Groundwater Recharge in Wadi Qanunah Basin, Saudi Arabia

The current study focuses on the Wadi Qanunah basin, which is considered one of Makkah Al-Mukarramah’s most important watersheds. It is located in the southwestern part of the Al Qunfudhah governorate. The identification and characterization of the recharging sources for the quaternary aquifer is one of the most important goals of this study. In this context, different methods will be applied for the identification of the different factors impacting groundwater. Such methods will be based on the integration of geographic information system (GIS) and modern hydrochemical methods ranging from graphical plots, bivariate and multivariate analysis to geochemical modeling. The salinity of the groundwater studied varied from fresh to brackish, according to the seasonal influx of dilute runoff and the dissolution of the weathered rocks, as well as the cementing materials within the aquifers’ matrix. Ionic ratios indicated that ion exchange, silicate weathering and evaporation played a significant role in the enrichment of the groundwater with major constituents including calcium, sodium, magnesium, sulphate and chloride. Furthermore, four factors accounted for 73.92% of the total variance, calculated using SPSS’s statistical program. These factors accounted for leaching and dissolution, silicate and carbonate weathering, anthropogenic effects and evaporation. The δ18O vs. δD, TDS vs. δ18O and δ18O vs. d-excess relationships revealed that local rainfall is the main recharging source for groundwater; some samples were affected by evaporated rainfall, while others with lower salinity (&lt;1000 mg/L) were diluted through seepage from the underlying fractured basement aquifer. Netpath geochemical modeling was applied to calculate the amount of evaporation or dilution which had affected an initial body of water as it moves from the upstream to downstream. The output of this program is consistent with what has been proved by stable isotopes, where the groundwater extracted from the final water is a mixture of an enriched recent precipitation with depleted older water. This study is an attempt to shed light on the assessment of groundwater and the extent at which it is affected by various factors in order to benefit from it in a way that ensures its sustainability.

Assessing regional variation in yield from weathered basement aquifers in West Africa and modelling their future groundwater development and sustainability

A data-driven modelling approach was applied to quantify the potential groundwater yield from weathered crystalline basement aquifers in West Africa, which are a strategic resource for achieving water and food security. To account for possible geological control on aquifer productivity, seven major geological domains were identified based on lithological, stratigraphic, and structural characteristics of the crystalline basement. Extensive data mining was conducted for the hydrogeological parameterisation that led to the identification of representative distributions of input parameters for numerical simulations of groundwater abstractions. These were calibrated to match distributions of measured yields for each domain. Calibrated models were then applied to investigate aquifer and borehole scenarios to assess groundwater productivity. Considering the entire region, modelling results indicate that approximately 50% of well-sited standard 60-m-deep boreholes could sustain yields exceeding 0.5 L/s, and 25% could sustain the yield required for small irrigation systems (> 1.0 L/s). Results also highlighted some regional differences in the ranges of productivities for the different domains, and the significance of the depth of the static water table and the lateral extent of aquifers across all geological domains. This approach can be applied to derive groundwater maps for the region and provide the quantitative information required to evaluate the potential of different designs of groundwater supply networks.

The Ibadan Hydrogeophysics Research Site (IHRS)—An Observatory for Studying Hydrological Heterogeneities in A Crystalline Basement Aquifer in Southwestern Nigeria

Crystalline basement aquifers are important drinking water sources in Nigeria and several sub-Saharan African countries. However, an understanding of their local flow and transport processes and pathways is missing due to limited research. The implication has been their suboptimal management, with frequently reported dry wells and groundwater contaminations. To address this challenge, the Ibadan Hydrogeophysics Research Site was established in 2019 as the first field-scale hydrogeological research laboratory in Nigeria to advance understanding of the geologic, hydraulic, and hydrogeochemical variabilities within crystalline basement aquifers. The over 22,500 m2 research site with a 50 m × 50 m area used for active hydraulic testing is located within the University of Ibadan campus and is instrumented with four initial test wells extending through the weathered and fractured zones to a depth of 30 m each. Preliminary hydrogeological and geophysical studies focused on obtaining a conceptual model and knowledge of hydraulic heterogeneities to aid in detailed experimental and numerical studies. A combination of lithological logs and electrical resistivity revealed areas with subvertical fractures as low-resistivity zones (&lt;200 Ωm), and a pumping test revealed a hydraulic conductivity range of 1.9 × 10−10 to 7.2 × 10−6 m/s. The drawdown–time curve shows flow from single-plane vertical fractures. The results of this study will serve as a basis for further targeted field and numerical studies for the investigation of variability in groundwater flow in complex crystalline basement aquifers. The presented field site is posed to support the adaptation and development of field methods for studying local heterogeneities within these aquifers in Nigeria.

Influence of nonuniform recharge on groundwater flow in heterogeneous aquifers

&lt;abstract&gt;&lt;p&gt;The composition of soils in aquifers is typically not homogeneous, and soil layers may be cracked or displaced due to geological activities. This heterogeneity in soil distribution within aquifers affects groundwater flow and water level variations. In the present study, we established a two-dimensional (2D) mathematical model that considers the influence of surface recharge on groundwater flow in heterogeneous sloping aquifers. By considering temporal variations in surface recharge, slope angle and aquifer heterogeneity, the simulated results are expected to better reflect real conditions in natural aquifers. The effects of aquifer heterogeneity on groundwater flow and water levels are particularly significant in sloping aquifers. The study's findings indicate that even when the soil composition remains constant, variations in groundwater level and flow may be considerable, depending on factors such as soil alignment, slope angle of the aquifer's base layer and the direction of water flow.&lt;/p&gt;&lt;/abstract&gt;

Contribution of Geophysical Prospecting (1D) to Characterize a Precambrian Basement Aquifers Agadez Region (North, Niger)

Contribution of Geophysical Prospecting (1D) to Characterize a Precambrian Basement Aquifers Agadez Region (North, Niger)

Hydrogeochemistry and stable isotopes of groundwater in the Sudano-Sahelian zone: A case of the Mayo Bocki watershed in North Cameroon

Groundwater is the main source of water supply for domestic, agricultural and industrial uses, especially in the sahelian regions. The present study is carried out in the basement aquifers of the Mayo Bocki catchment, Cameroon. It aims to determine the controlling factors of groundwater mineralization and to assess the relative mobility of chemical elements in the aquifers. The methodology adopted was based on conventional geochemical classifications and multivariate statistical analyses. The results revealed that these waters are characterised by low to medium mineralization in both the altered and fractured aquifers. The average concentration of cations followed the trend Ca2+ > Na+ > Mg2+ > K+ while that of anions was HCO3− > NO3− > Cl− > SO42−. The predominant hydrochemical facies was Ca Mg- HCO3 (77%). The acquisition of mineralization by groundwater in this basin involves several natural geochemical processes, including hydrolysis of silicates, dissolution of carbonate minerals, base exchange and leaching. In addition, the chemical inputs used in agriculture make a significant contribution to the chemical signature of these waters. Stable isotopes (18O, 2H) have shown that the water masses in the reservoirs are derived from rainwater and that their chemistry is not influenced by evaporation process. The predominant chemical alteration type in the area under study is monosiallitization. During this weathering process, the behaviour of chemical elements varies from one rock to another. In general, altered rock forms (granite, basalt, trachyte, schist and clay) are enriched in K2O, Na2O, P2O5, Al2O3, SiO2 and depleted in CaO, MgO, MnO, F2O3, SO3, Cl. The relative mobility of the constituents in the aqueous phase revealed that Mn, Zn, Sr, Ca, Na and Mo are the most mobile elements while Al, Th, Cs, Fe are the least mobile elements.

TENEURS EN NITRATES DANS LES AQUIFERES DISCONTINUS DU SOCLE DU DAMAGARAM MOUNIO (EST DU NIGER)

The basement of Damagaram Mounio, study area, outcrops in the eastern part of the Zinder region. It is a very populated area and where the problem of water resources is acute. In addition to the low availability of this water resource, its quality remains questionable in several areas. Thus, the contents of certain chemical parameters, including nitrates in particular, greatly exceed the drinking water standards for human consumption, hence the present study, which has as its main objective, the determination of the percentages of boreholes whose the waters have nitrate levels above the WHOstandard. The methodological approach based on the sampling of hydraulic structures capturing the aquifers of the basement, the analysis of the physicochemical and isotopic parameters of the waters of several boreholes, the determination of the characteristics of the nitrates, made it possible to lead to several interesting results.Thus, the nitrate contents of the waters of the Damagaram Mounio basement aquifers vary from 0.22 to 313.3 mg/L, with an average of 72.23 mg/L, and a standard deviation of 62.23. This study made it possible to show that 32% of the modern structures sampled have nitrate levels above the admissible limit value for drinking water, set at 50 mg/L, according to the standards of the World Health Organization (WHO) these waters are unfit for human consumption. The spatial distribution of nitrate levels in groundwater in the area showed that these are more accentuated between the towns of Damagaram Takaya and Birni Kazoe, which are characterized by values ​​above 100 mg/l. The relation between nitrate contents and water electrical conductivity values ​​showed that the mineralization of groundwater in the area is controlled by nitrate ions. Furthermore, the isotopic levels of Nitrogen 15 (15N), obtained in the waters of the area, vary from 0 to 7.2, thus showing that these nitrates could come from the nature of the soil (quagmire around water points) and chemical fertilizers (ureas and fertilizers used in the study area).

Reaction of the carbonate Sibillini Mountains Basal aquifer (Central Italy) to the extensional 2016–2017 seismic sequence

Hydrogeological perturbations in response to earthquakes are widely described worldwide. In carbonate aquifers, a post-seismic discharge increase is often attributed to an increase of bulk permeability due to co-seismic fracturing and the attention on the role of faults to explain the diversion of groundwater is increasing. We focus on the reaction of carbonate hydrogeological basins to extensional seismicity, taking as an example the effects of the Central Italy 2016–2017 seismic sequence, on the Basal aquifer of the Sibillini Mountains area. Geo-structural, seismological and ground deformation data were collected and merged with artificial tracer tests results and with a 4-years discharge and geochemical monitoring campaign. The main NNW-directed groundwater flow was diverted to the west and a discharge deficit was observed at the foot-wall of the activated fault system with a relevant discharge increase, accompanied by geochemical variations, at the fault system hanging-wall. The observed variations are consistent with the combined action of a permeability increase along the activated fault systems, which modified the predominant pre-seismic along-strike regional flow, and with hydraulic conductivity increase due to fracturing, determining a fast aquifers emptying. We show that the prevailing mechanism depends on the aquifer systems position with respect to the activated faults.

Groundwater recharge and dating in crystalline basement aquifers of Vea catchment: An integrated environmental tracers’ approach

The crystalline basement aquifers host significant groundwater resources for the communities in Vea catchment for public and irrigational water supply. As part of measures to understand the hydrogeological processes of the area, multi-tracers (SF6, CFC-12, CFC-11, 3H, δ18O and δ2H) were employed to elucidate the groundwater residence time, recharge mechanism and mixing process of the shallow groundwater. Ambient concentrations of these tracers were taken from 10 sampling locations in the Vea catchment of Upper East Region of Ghana. A purge and trap method was used to take the samples and electron capture detector gas chromatography (GC-ECD) was used to analytically measure the SF6 and CFCs gases in the groundwater. The SF6, CFC-11 and CFC-12 dating complimented with 3H revealed that the groundwater age in the catchment was relatively young ranging from 5 to 42 years with a mean age of 23 years. This corroborates well with the stable isotopes data , which showed that the catchment receives modern recharge from meteoric origin. The results also indicated that the estimated SF6 ages were younger compared to the CFCs ages, suggesting additional inputs of SF6 from terrigenous sources. Similarly, a comparison of 3H and CFCs showed little variations in ages in some wells, a possible indication of CFCs degradation. The conceptual groundwater flow model developed showed three groundwater flow regimes along the topographical line. Despite some uncertainties in age interpretations, the multi-environmental tracers have been successfully used to date shallow groundwater in the Vea catchment. To reduce the uncertainties in the age determination, the use multi tracer approach is highly recommended.

Quantification of Soil Deep Drainage and Aquifer Recharge Dynamics according to Land Use and Land Cover in the Basement Zone of Burkina Faso in West Africa

Groundwater is a vital water supply for local populations and ecosystems globally. With the continuous population growth, the anthropic pressure on groundwater is ever increasing, thus reducing the amount of available water resource. Yet, estimating the impact of anthropogenic activities on aquifer recharge is still a significant challenge for research, especially in basement aquifers. This study aims to improve the actual knowledge of deep drainage and deep aquifer recharge pathways and dynamics in the basement as affected by land use/land cover (LULC). The methodology used in this study accounted for hydraulic processes in soil layers within both unsaturated and saturated zones in an integrated approach. An experimental setup consisting of three (3) experimental plots, respectively under natural vegetation (NV), cropped millet (CM) and cropped groundnut (CG) on which deep drainage was monitored during the years 2020 and 2021. The results show significant differences between the LULC types after two years of implementation. Deep drainage is improved under CM and CG plots located in the central valley, as compared to the NV plot located in the ridge zone. Deep drainage is estimated at 8%, 24% and 25% of the annual rainfall, respectively for NV, CM and CG. The ratio between the recharge value obtained by the water table fluctuation (WTF) method and the deep drainage tends to 1 for the CM and CG plots, highlighting a rapid water transfer between unsaturated and saturated zones. The central valley, which seems to be a preferential recharge pathway, provides promising insights under specific conditions for the implementation of artificial recharge infrastructures.

Quality and hydrochemical assessment of groundwater in geological transition zones: a case study from N.E. Nigeria.

Sustainable management of groundwater resources in geological transition zones (GTZ) is essential due to their complex geology, increasing population, industrialization, and climate change. Groundwater quality monitoring and assessment represent a viable panacea to this problem. Therefore, there is a great need to investigate groundwater resources in terms of their chemistry and pollution to ascertain their quality and implement robust pollution abatement strategies. This study focused on the characterization of groundwater in a typical geological transition zone in northeastern Nigeria. Eighty-seven (87) groundwater samples were collected from dug wells and boreholes during the 2017 dry season. pH, conductivity, and total dissolved solids (TDS) were measured in situ using a multiparameter probe, while major cations and anions were measured using atomic absorption spectrometry and ion chromatography, respectively. Data were analyzed using descriptive statistics, principal component analysis (PCA), water quality index, and standard hydrochemical plots. TDS ranged between 95 and 1154 mg L-1 in basement terrains and between 49 and 1105 in sedimentary areas. pH ranged between 6.8 and 7.7 mg L-1 in basement terrains and between 5.0 and 6.5 in sedimentary areas, suggesting a moderately acidic to alkaline low mineralized groundwater. Calcium (2.6-128.0 mg L-1) was the dominant cation in the basement areas, suggesting silicate weathering/dissolution, while sodium (1.9-106.0 mg L-1) dominated the sedimentary zones due to base exchange reactions. The PCA analysis suggests that mineral dissolution (mostly silicate weathering) controls the hydrochemistry of the basement aquifers, while ion exchange and albite weathering, with some influence of anthropogenic factor, control the sedimentary aquifers. The water quality index revealed that the basement setting was predominated by poor to unsuitable groundwater, while the sedimentary terrain was characterized by potable groundwater. The dominant hydrochemical facie in the basement areas was Ca2+-(Mg2+)-HCO3- characteristic of recharge meteoric water. The Na+- (K+)-HCO3- facie characterized the sedimentary zones, indicative of cation exchange reactions, while the mixed water facie typifies the geological contact zones. The shallow nature of the basement groundwaters makes them more susceptible to geogenic and anthropogenic pollution compared to the sandstone aquifers. However, the basement aquifers have better irrigation indices (Kelly ratio and soluble sodium percent) as compared to the sandstone aquifers, which exhibit poor Kelly ratios (< 1) and soluble sodium percent (> 50) ratings. Results from the study clearly highlight the poor-unsuitable groundwater quality in parts of the studied GTZ and can be very instrumental to the policymakers in implementing sustainable water treatment strategies and cleaner production technologies in GTZ to forestall the incidence of water-related diseases.

Controls on Timing of Hydrothermal Fluid Flow in South-Central Kansas, North-Central Oklahoma, and the Tri-State Mineral District

Paleozoic sedimentary rocks in the southern midcontinent of the United States have been affected by multiple events of deformation and fluid flow, resulting in petroleum migration, thermal alteration, Mississippi Valley-type mineralization, and a complex diagenetic history. This record is a hidden history of how cratonal settings respond to tectonic and non-tectonic drivers. The aim of this contribution is to better understand the controls on fluid migration in Paleozoic strata to evaluate whether hydrothermal activity is forced by tectonic or non-tectonic processes. This paper summarizes and vets the distribution of published dates related to thermal events in the southern midcontinent. In addition, we present new U-Pb dates obtained by laser ablation–inductively coupled plasma–mass spectrometry (LA-ICP-MS) on calcite cements that were formed from hydrothermal fluids. These are from three samples from the Berexco Wellington KGS 1-32 core in Sumner County, Kansas; an ore sample from the Tri-State Mineral District, Neck City, Missouri; and a core sample from the Blackbird 4-33 well in Osage County, Oklahoma. Previous studies of these calcite samples provided evidence for hydrothermal fluid flow, with one of the Wellington samples possibly recording vertical hydrothermal fluid flow out of the basement. The sample from the Tri-State Mineral District (Missouri) yields a mid-Cretaceous age of 115.6±3.1 Ma. This age falls into the timing of the Sevier Orogeny along the west coast and the development of its foreland basin in the midcontinent. Calcites from the Mississippian interval in the Wellington KGS 1-32 core yield dates of 305±10.5 Ma and 305.1±9.1 Ma. Calcite in Mississippian strata from the Blackbird 4-33 core yields a date of 308.6±2.5 Ma. These dates from Mississippian calcite cements indicate hydrothermal fluid flow in the Late Pennsylvanian that coincides with the timing of the Marathon-Ouachita Orogeny or the Ancestral Rocky Mountains Orogeny. A calcite sample from the Ordovician Arbuckle Group from the Berexco Wellington KGS 1-32 core yielded an age of 5.6±1.6 Ma, coinciding with a time after high elevation uplift of the Rocky Mountains was already far advanced. We propose that this hydrothermal fluid flow may have been associated with increased meteoric recharge and increased regional fluid pressure in a basement aquifer that activated local seismic events far into the continental interior. The distribution of ages of hydrothermal fluid flow confirms a syntectonic driver during the Ouachita Orogeny and Ancestral Rocky Mountains Orogeny deformation. Continuation of hydrothermal fluid flow well into the Permian and tailing off early in the Triassic indicates a post-tectonic driver, where uplifted areas continued to provide the recharge from gravity-driven fluid flow, until the mountains were mostly beveled by the early part of the Triassic. A dearth of Triassic and Jurassic hydrothermal events suggests Gulf of Mexico rifting and extension were less important. Rejuvenation of hydrothermal fluid flow in the Cretaceous and continuing into the Paleogene indicates that elevation and regional flexure from both the Sevier and Laramide events continued to drive hydrothermal fluid flow far from the main sites of mountainous uplift and deformation. Finally, hydrothermal fluid flow associated with more recent uplift of the Rocky Mountains may have been activated by recharge events that pressurized a regional basement aquifer and triggered seismic activity.

Hydrogeochemistry of the groundwater system of the transboundary basement and volcanic aquifers of the Bulal catchment, Southern Ethiopia

The evaluation of groundwater geochemistry of transboundary aquifers has an important role in the management and sustainable use of groundwater resources in arid and semi-arid regions. This study presents the results of an integrated hydrogeochemical study of the Bulal transboundary aquifers located in the Borena zone, along the Ethiopia-Kenya border. The main aquifers are basic volcanic rocks, subordinate felsic pyroclastic deposits, and metamorphic basement rocks. These aquifers are overlain by alluvio-lacustrine sediments, eluvial soil and regolith. The groundwaters are dominated by Na+ and HCO3− and mixed water types. Silicate weathering and evaporation are the dominant hydrogeochemical processes controlling the chemistry of the groundwaters in most parts of the catchment. However, dissolution of evaporitic minerals might have also played a significant role in adding major ions into the groundwater system. Groundwater in the volcanic aquifers are Na–HCO3, Ca–Mg–HCO3, Na–Ca–HCO3 and Na–Cl–SO4 water types while Ca–Mg–HCO3, Na–Ca–Cl–SO4 and Ca–Mg–SO4 water types are dominant in the metamorphic basement aquifers. The groundwater in the catchment mainly evolved from Na–HCO3 in the west, Ca–Mg–HCO3 in the north, and Na–Ca–Cl–SO4 in the central east and southeast to Na–Ca–HCO3 type in the southern low-lying areas along the groundwater flow direction. The study has significant implications for the management of groundwater quality in the region.

Krypton‐81 Dating Constrains Timing of Deep Groundwater Flow Activation

AbstractKrypton‐81 dating provides new insights into the timing, mechanisms, and extent of meteoric flushing versus retention of saline fluids in the subsurface in response to changes in geologic and/or climatic forcings over 50 ka to 1.2 Ma year timescales. Remnant Paleozoic seawater‐derived brines associated with evaporites in the Paradox Basin, Colorado Plateau, are beyond the 81Kr dating range (&gt;1.2 Ma) and have likely been preserved due to negative fluid buoyancy and low permeability. 81Kr dating of formation waters above the evaporites indicates topographically‐driven meteoric recharge and salt dissolution since the Late Pleistocene (0.03–0.8 Ma). Formation waters below the evaporites (up to 3 km depth), in basal aquifers, contain relatively young meteoric water components (0.4–1.1 Ma based on 81Kr) that partially flushed remnant brines and dissolved evaporites. We demonstrate that recent, rapid denudation of the Colorado Plateau (&lt;4–10 Ma) activated deep, basinal‐scale flow systems as recorded in 81Kr groundwater age distributions.