Using classical density functional theory (cDFT) with the fundamental measure functional (FMF) approximation, we examine how the entropic force and its integration, the potential of mean force (PMF), between two hard walls in a polydisperse hard-body solvent vary with monomer size polydispersity (whether the solvent consists of spherical monomers or chain molecules formed by freely linked monomers) or the number of monomers in the chain solvent. Molecular dynamics simulations validate the FMF's accuracy in predicting density distributions for five- and seven-component hard sphere fluids in slit geometries, though improvements are possible at high packing fractions. The PMF calculations reveal that increasing monomer size polydispersity or the number of monomers in a chain molecule reduce entropic attraction strength at contact and lower the main potential barrier height. This reduction is due to the system's limited capacity to further increase entropy when both mixing and conformational entropies are already high. For monomer or dimer solvent, the main potential barrier position shows either monotonic or non-monotonic dependence on monomer size polydispersity, depending on bulk packing fractions, while the PMF range shortens with increasing monomer size polydispersity or chain molecule monomer number. These findings could inform the design of tunable materials.
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