Bamboo Biochar Research Articles

Regulatory mechanism of bamboo biochar dosage on cadmium accumulation in Salix psammophila: insights from rhizosphere microbial communities, assembly processes, and interactions

Soil amendments play a pivotal role in regulating rhizosphere microbial communities, which is essential for maintaining robust plant growth under adverse environmental conditions. However, the microbial mechanisms that underlie the impact of biochar on phytoremediation performance remain incompletely understood in the context of different application rates. Here, we compared the phytoremediation performance, rhizosphere microbial community characteristics, and microbial interactions in Salix psammophila across different biochar application rates (1%, 3%, 5%, and 7%) in Cd-contaminated soil. Applying 5% biochar increased plant biomass by 10.02%, root activity by 183.82%, and Cd accumulation by 13.65%. Lower biochar rates (1% and 3%) decreased Cd accumulation in plants by 21.89% and 42.05%, respectively, compared to the control. Rhizosphere soil properties and Cd content, except for nitrogen, showed a gradient change with increasing biochar application rates. This was accompanied by an elevation in the Chao1 index for the bacterial community, although the fungal community remained unaffected in terms of diversity and structure. Null-model analyses indicated that fungal community assembly was mainly driven by ecological drift, explaining its unresponsiveness to biochar application. Applying 1% biochar enhanced microbial network stability while reducing bacterial network complexity. Conversely, 3% biochar application resulted in the lowest microbial network stability. Biochar application, except 3%, reduced the proportion of bacteria-fungi associations, suggesting increased independence between two microbial kingdoms. Random forest and piecewise structural equation models revealed that phytoremediation performance is influenced by microbial network stability, complexity, and bacteria-fungi associations. Fungal complexity and stability, along with bacterial stability, were identified as key predictors of phytoremediation performance. Our findings reveal potential mechanisms by which biochar influences phytoremediation through altering microbial interactions. For long-term microbial stability and cost-effectiveness, a 1% biochar application is recommended for phytoremediation. Conversely, for rapid Cd accumulation in plants, a 5% biochar application is optimal.Graphical

Drying Shrinkage Properties and Engineering Performance for Cement Mortar Containing Bamboo Biochar Powder (BCP)

Drying shrinkage, the reduction in volume as a material like cement mortar dries, can result in cracks and decreased durability. Bamboo biochar powder (BCP) serves as a substitute for cement in mortar, affecting its drying shrinkage characteristics. Research has shown that BCP in cement mortar can alleviate drying shrinkage by absorbing and retaining moisture. This study aims to assess the chemical and physical properties of BCP, determine the mechanical attributes of bamboo biochar mortar with varying percentages of cement replacement, and investigate the impact of BCP on mortar shrinkage in indoor and outdoor tropical conditions. BCP, derived from Gigantocholoa Abociliata species and sized at 75 µm, was used to replace cement rates of 0%, 5%, 10%, 15%, and 20%. Sixty cube samples (50x50x50mm) were employed for density, ultrasonic pulse velocity (upv), compressive strength, and water absorption tests. Additionally, thirty prism samples (100x100x400mm) were employed to assess drying shrinkage during outdoor and indoor exposure, spanning up to 150 days. The experimental data indicates a consistent trend as the percentage of cement replacement increases in the mortar mix, density, and compressive strength decrease, while UPV and water absorption increase. The lowest shrinkage strain was observed during indoor exposure with 5% cement replacement, attributed to BCP acting as a filler, creating strong bonding properties, and reducing shrinkage. Conversely, the highest strain was noted during outdoor exposure with 20% cement replacement, resulting from higher moisture loss. In summary, a 5% replacement of cement with BCP in mortar offers the most effective reduction in shrinkage strain.

A biochar-based amendment improved cadmium (Cd) immobilization, reduced its bioaccumulation, and increased rice yield

Cadmium (Cd) contamination of soil threatens human health, food security, and ecosystem sustainability. The in situ stabilization of Cd has been recognized as a potentially economical technology for the remediation of Cd-contaminated soil. Recently, biochar (BC) and activated carbon (AC) have received widespread attention as eco-friendly soil amendments that are more beneficial for plant growth, soil health, and remediation of contaminated soil. An experiment was performed in a paddy field to investigate the effects of two different types of BC (maize straw biochar and bamboo biochar) and AC (coconut shell activated carbon) in combination with rape organic fertilizer (R), calcium magnesium phosphate fertilizer (P), and fulvic acid (F), respectively, on soil Cd immobilization, Cd accumulation in rice, and yield. The results indicated that the BC/AC-based amendments reduced soil bioavailable Cd (DTPA-Cd) and brown rice Cd by 9.58%–27.06% and 19.30%–71.77%, respectively. The transformation of exchangeable Cd (Ex-Cd) to carbonate-bound Cd (Ca-Cd), Fe-Mn oxide bond (Ox-Cd), and residual (Re-Cd) in soil accounted for the mitigation of Cd uptake and enrichment by rice. Additionally, BC-/AC-based amendments altered soil physicochemical properties, which significantly increased the soil pH and cation exchange capacity (CEC), total nitrogen (TN), total phosphorus (TP), soil organic carbon (SOC), and dissolved organic carbon (DOC), directly promoting soil health. All BC-/AC-based amendments significantly increased FeIMP and MnIMP concentrations by 47.31%–160.34% and 25.72%–73.09% in the Fe/Mn plaque (IMP), respectively. Maize straw and bamboo biochar-based amendments significantly increased rice yield by 10.46%–20.41% and 9.94%–16.17%, respectively, while coconut shell-activated carbon severely reduced rice yield by 65.06%–77.14%. The correlation analysis revealed that leaf Cd and IMP primarily controlled Cd uptake by rice, and soil pH, Eh, CEC, SOC, IMP, and TP influenced DTPA-Cd in soil. This field study demonstrated that maize straw and bamboo biochar-based amendments not only reduced soil DTPA-Cd in paddy fields but also decreased the accumulation of Cd in brown rice, as well as improved rice yield, which has potential application in Cd-contaminated agriculture fields. Coconut shell-activated carbon severely decreased rice yields, which is not appropriate for rice production.

Removal of tetracycline from aqueous solution via Fenton process using iron-impregnated bamboo biochar

Abstract Tetracycline (TC) is a pharmaceutical that has been used extensively that its presence in water sources causes detriment to both aquatic life and human health. TC is not completely removed in wastewater treatment processes and could enter the environment through effluent and sludge. This study evaluated the potential of iron-impregnated bamboo biochar (Fe-biochar) as catalyst in the removal of tetracycline from aqueous solution via Fenton process. Characterization via Fourier transform infrared (FTIR) and energy dispersive X-ray spectroscopy (EDX) analyses verified the successful iron impregnation on biochar. TC removal was determined at 357nm absorbance through UV-Visible spectroscopy. Highest TC removal of 63.24% was achieved under conditions of 75 mg Fe-biochar, 0.45 M H2O2, and pH 5. Experimental data were assessed using the three factors Box-Behnken response surface experimental design where Fe-biochar dosage, H2O2 concentration, and solution pH were found to be significant parameters in TC removal. Furthermore, it was determined that the data fitted well in a reduced-cubic model with high coefficient of determination (R2 = 0.9990) which indicates good regression. The optimum conditions were found to be 39.44 mg Fe-biochar dosage, 0.05 M H2O2, and pH 4, with TC removal efficiency of 33.90%. Overall, the results of this study suggested that Fe-impregnated bamboo biochar can be used as an effective catalyst in removing tetracycline from aqueous solution via heterogeneous Fenton process.

PREPARATION AND CHARACTERIZATION OF BAMBOO PEEL BIOCHAR BY USING SLOW PYROLYSIS FOR THE REMOVAL OF CD AND PB IN SOIL (BRASSICA CAMPESTRIS)

The experiment was conducted at the University of Haripur, nursery. There are two groups in the research heavy metals and biochar. Cadmium(Cd) and Lead (Pb) spiked with soil different concentrations of 0.5 ppm and 300 ppm in plastic pots after fifteen-day amendment with various application rates of biochar (2.5 mg/kg, 3.5 mg/kg, 5 mg/kg). Brassica campestris are harvested after 45 days for two days air dry and heated in an oven to remove the moisture for powdered form is obtained and weighs 0.5-gram roots and shoots separately and the sample is ready for digestion. The 5mg/kg application rate of biochar has enhanced nitrogen (N), potassium (K), and phosphorus (P). The bioaccumulation factor is higher than the bioaccumulation coefficient because biochar adsorbed the cadmium and lead on their surface and transfer to the shoot was reduced. Cadmium and Lead reduced the Brassica campestris roots and shoots and damaged the overall structure of the plant. The pH and EC play an important role in overall research of biochar-enhanced physical parameters compared to those without bamboo peel biochar. Brassica campestris is grown in the winter season in the presence of sunlight and a lot of water is needed it also can absorb in root and shoot parts of plants. The biochar is higher than cadmium and lead because it is rich in micro-nutrients and growth parameters. The FTIR result showed that the bamboo peel biochar decreased by 45% as compared to raw bamboo peel because it has a large surface area to immobilize Cd and Pb in the soils.

Effect of Hg pollution in ex-gold mining soil ameliorated with bamboo biochar on vegetative growth of corn (Zea mays L.)

Effect of Hg pollution in ex-gold mining soil ameliorated with bamboo biochar on vegetative growth of corn (Zea mays L.)

Reclaiming selenium from water using aluminum-modified biochar: Adsorption behaviors, mechanisms, and effects on growth of wheat seedlings

Although selenium is an essential nutrient, its contamination in water poses serious risks to human health and ecosystems. In this study, aluminum-modified bamboo biochar (Al-BC) was developed to reclaim Se(VI) from water. Compared to pristine biochar (BC), Al-BC had a larger specific surface area (176 m2/g) and pore volume (0.180 cm³/g). The modification, achieved by loading AlOOH and Al2O3 particles onto the surface, enabled Al-BC to achieve a maximum adsorption capacity of 37.6 mg/g for Se(VI) within 2 h and remove 99.6% of Se(VI) across a pH range of 3–10. The main adsorption mechanism of Se(VI) involved electrostatic attraction, forming outer-sphere complexes between Se(VI) and AlOOH sites on the biochar. The bioavailability of Se sorbed on the spent biochar (Al-BC-Se) was thus evaluated. It was discovered that Al-BC-Se successfully released Se(VI), which impacted the growth of wheat seedlings. The Se content reached 134 μg/g dry weight (DW) in wheat shoots and 638 μg/g DW in roots, significantly exceeding normal selenium content (<40 μg/g DW). By successfully applying the modified biochar to capture selenium from water through adsorption and then reusing it as an essential nutrient in soil, this study suggests the promising feasibility of the "removal-collection-reuse" approach for the circular economy of selenium in wastewater.

Curing Effect on the Strength of Cement Mortar with Bamboo Biochar

Curing Effect on the Strength of Cement Mortar with Bamboo Biochar

Co-application of biochars and Piriformospora indica improved the quality of coastal saline soil and promoted the growth of forage.

Soil quality is defined as the ability of soil to maintain the soil environment and the biosphere. Due to the limitation of salt and alkali stress, soil quality can be reduced, which in turn affects agricultural production. Biochar is widely used in saline-alkali land improvement because of its special pore structure and strong ion exchange ability, while Piriformospora indica is widely used in saline-alkali land improvement because it can symbiose with plants and improve plant stress resistance. However, the synergistic effect of combined biochar application and inoculation of P. indica on the quality of saline-alkali soil and plant development is uncertain. Hence, we investigated the combined influences of biochar and P. indica on the soil physicochemical characteristics, as well as the growth and chlorophyll florescence of sorghum-sudangrass hybrids (Sorghum bicolor × Sorghum sudane) in our study. The results indicated that after applying biochar and P. indica together, there was a considerable drop in soil pH, conductivity, Na+, and Cl- concentrations. Meanwhile, the soil organic matter (SOM), available phosphorus (AP), and alkaline hydrolyzable nitrogen (AN) increased by 151.81%, 50.84%, and 103.50%, respectively, when the Bamboo biochar was combined with 120 ml/pot of P. indica. Eventually, sorghum-sudangrass hybrid biomass, transpiration rate, and chlorophyll content increased by 111.69%, 204.98%, and 118.54%, respectively. According to our findings, using P. indica and biochar together can enhance soil quality and plant growth. The results also provide insights to enhance the quality of saline-alkali soils and the role of microorganisms in nutrient cycling.

Performances of a novel BAF with ferromanganese oxide modified biochar (FMBC) as the carriers for treating antibiotics, nitrogen and phosphorus in aquaculture wastewater.

In this paper, a biological aerated filter (BAF) based on ferromanganese oxide-biochar (FMBC) was constructed to investigated the removal performance and mechanism for conventional pollutants and four kinds of antibiotic, in contrast of conventional zeolite loaded BAF (BAF-A) and bamboo biochar filled BAF (BAF-B). Results showed that the average removal efficiency of total nitrogen (TN), total phosphorus (TP) and antibiotics in a FMBC-BAF (named by BAF-C) were 52.97 ± 2.27%, 51.58 ± 1.92% and 70.36 ± 1.00% ~ 81.65 ± 0.99% respectively in running period (39-100 d), which were significantly higher than those of BAF-A and BAF-B. In the BAF-C, the expression of denitrification enzyme activities and the secretion of extracellular polymeric substance (EPS) especially polyprotein (PN) were effectively stimulated, as well as accelerated electron transfer activity (ETSA) and lower electrochemical impedance spectroscopy (EIS) were acquired. After 100 days of operation, the abundance of nitrogen, phosphorus and antibiotic removal functional bacteria like Sphingorhabdus (4.52%), Bradyrhizobium (1.98%), Hyphomicrobium (2.49%), Ferruginibacter (7.80%), unclassified_f_Blastoca tellaceae (1.84%), norank_f_JG30-KF-CM45 (6.82%), norank_f_norank_o_SBR1031 (2.43%), Nitrospira (2.58%) norank_f_Caldilineaceae (1.53%) and Micropruina (1.11%) were enriched. Mechanism hypothesis of enhanced performances of nutrients and antibiotics removal pointed that: The phosphorus was removed by adsorption and precipitation, antibiotics removal was mainly achieved through the combined action of adsorption and biodegradation, while nitrogen removal was realized by biologic nitrification and denitrification in a FMBC-BAF for aquaculture wastewater treatment.

The dual role of biochar in boosting phenol biodegradation and anti-inhibition performance against hazardous substrate

Enhancing the biodegradation of hazardous recalcitrant organic compounds from wastewater has garnered increasing attention. Herein, bamboo biochar was screened for subsequent investigation as it considerably enhanced hazardous phenol removal efficiency by 125.68 % over the biochar-free system at 700 mg/L. Besides, the influencing factors were optimized, including biochar dosage and phenol concentration. However, the phenol removal rate decreased by 75.91 % within 15 hours when utilizing biochar oxidized by H2O2, perhaps due to eliminating aromatic clusters on biochar. Combined with FTIR analysis, CO and -OH on aromatic clusters of biochar were recognized as the underlying contributors to facilitating electron transfer in phenol biodegradation. Furthermore, the ortho-disubstituted benzene ring was discovered on biochar, which may originate from catechol, an intermediate during phenol degradation, suggesting that biochar also serves as a site for phenol biodegradation. Moreover, the fabricated biochar-sodium alginate microspheres enhanced anti-inhibition to phenol over suspended bacteria by 192.15 %. The system also eliminated 99.93 % of phenol after the seven recycles at 1258.75 mg/L, exhibiting excellent reusability. This work provides valuable insights into bioaugmentation strategies for bio-degrading phenol using biochar.

Utilization of bamboo biochar as a multi-functional filler of flexible poly(L-lactide)-b-poly(ethylene glycol)-b-poly(L-lactide) bioplastic

Biodegradable poly(L-lactide)-b-poly(ethylene glycol)-b-poly(L-lactide) (PLLA-PEG-PLLA) triblock copolymer could potentially be used in bioplastic applications because it is more flexible than PLLA. However, investigations into modifying PLLA-PEG-PLLA with effective fillers are still required. In this work, bamboo biochar (BC) was used as an eco-friendly and cost-effective filler for the flexible PLLA-PEG-PLLA. The influences of BC addition on crystallization properties, thermal stability, hydrophilicity, and mechanical properties of the PLLA-PEG-PLLA were explored and compared to those of the PLLA. The PLLA-PEG-PLLA matrix and BC filler were found to have strong interfacial adhesion and good phase compatibility, while the PLLA/BC composites displayed weak interfacial adhesion and poor phase compatibility. For the PLLA-PEG-PLLA, the addition of BC induced a nucleation effect that was characterized by a decrease in the cold crystallization temperature from 76 to 71–75 °C and an increase in the crystallinity from 18.6 to 21.8–24.0%; however, this effect was not observed for the PLLA. When compared to pure PLLA-PEG-PLLA, the PLLA-PEG-PLLA/BC composites displayed greater thermal stability, tensile stress, and Young’s modulus. Temperature at maximum decomposition rate (Td,max) of PLLA end-blocks increased from 315 to 319–342 °C. Ultimate tensile stress of PLLA-PEG-PLLA matrix improved from 14.5 to 16.2–22.6 MPa and Young’s modulus increased from 220 to 280–340 MPa. Based on the findings, the crystallizability, thermal stability, and mechanical properties of the flexible PLLA-PEG-PLLA bioplastic were all enhanced by the use of BC as a multi-functional filler.

One-step high-efficiency microwave synthesis of N-doped bamboo biochar for tetracycline degradation

N-doped bamboo biochar (NBB) was successfully synthesized through one-step, rapid pyrolysis (e.g., 10 min) using urea and urea nitrate impregnated bamboo particles exposed to low power (e.g., 460 W) microwave radiation. NBB-460 exhibited high specific surface area of 876.1 m2/g and outstanding catalytic performance for tetracycline hydrochloride (TCH) degradation. The TCH degradation efficiency reached to 94.3 % with the optimized catalytic condition (i.e., 0.2 g/L NBB-460, 3 mM PMS, 50 mg/L TCH, 25 ℃, without pH regulation). The density functional theory calculation showed that the graphitic nitrogen and pyridinic nitrogen of NBB-460 served as active sites for peroxymonosulfate activation and TCH degradation. The quenching test, electron paramagnetic resonance spectra, and electrochemical measurements indicated that tetracycline hydrochloride underwent degradation via radical (O2•−), non-radical (1O2) pathways, and surface electron transfer. This study introduces an energy-efficient and time-effective method for converting biomass to N-doped biochar as highly efficient peroxymonosulfate activator for environmental applications.

Bamboo biochar helps minimize Brassica phytotoxicity driven by toxic metals in naturally polluted soils of four mine zones

Researchers have recently become interested in utilizing biochar amendment as an organic approach to enhance soil quality and minimize the mobility of toxic metals (TMs), which can help grow TM-tolerant plant species in polluted areas. A pot experiment was conducted to examine the efficacy of bamboo biochar (BB) in reducing the phytotoxicity of four unique mine-contaminated soil types. According to a completely randomized design (CRD), in four replications on Brassica juncea, a five-level bamboo biochar treatment (0 % Control, 2.5 % BB, 5 % BB, 7.5 % BB, and 10 % BB) was administered in naturally contaminated areas of Sarcheshmeh, Gol-Gohar, Chadormalu, and Anguran mines. The data show that Bamboo Biochar (BB) increased soil enzymatic activities (58 %), reformed soil structure, including pH (7 %) and electrical conductivity (EC) (51 %), and decreased the availability of TMs (Zn (37 %), Pb(34 %), Cd(51 %), Cu(34 %)), preventing accumulation in roots (42 %) and translocation to shoots (38 %). The phytochelatin (79 %), ascorbic acid (56 %), glutathione contents (57 %), and antioxidant (51 %) and glyoxalase activities (71 %) in B. juncea ultimately enhanced root-shoot dry biomass (44 %) and overall tolerance to TMs in mine-polluted soil (43 %). BB at 10 % might be used as a reliable soil amendment and natural metal immobilization adsorbent in the soil, as well as a suitable option for reducing oxidative stress caused by TMs in B. juncea plants, which are strong phytoremediation candidates in polluted soils. Future research endeavors might aim to discover cost-effective, efficient, and natural substances that can enhance and diminish environmental toxicity, eliminate soil contamination caused by heavy metals, and ultimately enhance human well-being. Keywords: Biochar Application; Soil amendment; Plant stress tolerance; Toxic metal; Phytoremediation

Enhancing solid-phase extraction of tetracyclines with a hybrid biochar sorbent: A comparative study of chlorella and bamboo biochars

Biochar, a sustainable sorbent derived from pyrolyzed biomass, has garnered attention for its efficacy in solid-phase extraction (SPE) of antibiotics, with a particular focus on tetracyclines (TCs). Despite its recognized potential, the intricate separation mechanisms operative in biochar-based SPE systems have not been fully deciphered. This investigation contrasts chlorella biochar against commercial bamboo biochar, harnessing an array of analytical methodologies-microstructure characterization, adsorption thermodynamics, competitive adsorption kinetics, H+ back titration, and selectivity adsorption studies-complemented by a Box-Behnken design for the optimization of chlorella/bamboo-SPE and subsequent application in the analysis of animal-derived foodstuffs. The study unveils that a hybrid sorbent, integrating nitrogen-doped microporous chlorella biochar with mesoporous bamboo biochar in a 95/5 mass ratio, markedly diminishes irreversible adsorption while enhancing selectivity, surpassing the performance of single biochar SPE systems. The elucidated separation mechanisms implicate a partition model, propelled by oxygen-rich functional groups on chlorella biochar and the rapid adsorption kinetics of bamboo biochar, all orchestrated by electrostatic interactions within the mixed biochar framework. Moreover, the synergy of mixed biochar-SPE with high-performance liquid chromatography (HPLC) demonstrates exceptional proficiency in detecting TCs in animal viscera, evidenced by recovery rates spanning 80.80 % to 106.98 % and RSDs ranging from 0.24 % to 14.69 %. In essence, this research not only sheds light on the multifaceted factors influencing SPE efficiency but also propels the use of biochar towards new horizons in environmental monitoring and food safety assurance.

Fe(III)-modified bamboo biochar for the removal of phosphate from synthetic and field stormwater runoff

Fe(III)-modified bamboo biochar for the removal of phosphate from synthetic and field stormwater runoff

Removal of metronidazole using a novel ZnO–CoFe2O4@Biochar heterostructure composite in an intimately coupled photocatalysis and biodegradation system under visible light

The intimate coupling of photocatalysis and biodegradation (ICPB) technology has received much attraction because of the advantages of both photocatalytic reaction and biological treatment. In this study, ZnO–CoFe2O4@BC (ZCFC) with p-n heterojunction was prepared and used in an ICPB system to degrade metronidazole (MNZ) wastewater. The microstructure, morphology, and optical behavior of heterojunctions in ZCFC were investigated using SEM, XRD, UV–vis, FTIR, and XPS techniques. The results showed that ZCFC inherited the advantages of bamboo biochar's large pore size, and its large pore structure could provide a habitat for bacterial colonization in ICPB, thus shortening the internal mass transfer distance. The degradation of MNZ and chemical oxygen demand (COD) by the ICPB system was 86.8% and 58.5%, respectively, which was superior to single photocatalysis (72.5% for MNZ and 43.8% for COD) and single biodegradation (23.5% for MNZ and 20.1% for COD). In ICPB, photocatalysis and biodegradation showed a synergistic effect in the removal of MNZ, and the order of the major reactive oxygen species (ROS) leading to reduced toxicity of MNZ to the biofilm was •OH > h+ > O2•-. High-throughput sequencing analysis showed continuous evolution of biofilm structures in ICPB enriched a variety of functional species, among which the electroactive bacteria Alcaligenes and Brevundimonas played an important role in the degradation of MNZ. In this study, we investigated the possible mechanism of photocatalytic and microbial synergistic degradation of MNZ in the ICPB system and proposed a new technology for degrading antibiotic wastewater that combines the advantages of photocatalysis and biodegradation.

Investigation of kinetics and thermodynamics of methylene blue dye adsorption using activated carbon derived from bamboo biomass

This research paper aimed to evaluate the potential of activated carbon (AC) made from non-torrefied and torrefied bamboo biochar samples for the purpose of adsorbing methylene blue solution. The process involved impregnating bamboo biochar with a 5 M potassium hydroxide (KOH) solution at a 1:4 ratio of biochar to KOH, followed by carbonization at 800 °C, 900 °C, and 1000 °C to produce activated carbon samples. The samples were then characterized using techniques such as XRD, FESEM-EDX, FTIR, FE-TEM, and BET analysis to study their respective phase, surface morphology, elemental composition, functional groups, and structural and surface properties. The results showed that the torrefied bamboo AC exhibited a specific surface area of 366 m2/g and a total pore volume of 0.24 m3/g. Kinetic analyses showed adsorption following a pseudo-second-order model, with a capacity of 83.3 mg/g according to the Langmuir model and a favorability constant of 0.52 from the Freundlich model. Thermodynamic studies revealed the process to be spontaneous and endothermic, with changes in enthalpy and entropy of 77,810.73 kJ/mol and 269.9 kJ/mol·K, respectively. These findings highlight the effectiveness of bamboo-derived AC as a sustainable adsorbent for MB dye removal, offering a promising solution for water pollution control.

Effect of zeolite and bamboo biochar as CO2 absorbant in concrete

Carbon dioxide (CO2) is one of the major air pollutants that enter the atmosphere. There is a large release of carbon dioxide into the atmosphere as a result of burning fossil fuels in the cement manufacturing industries and many other industries, as well as emissions from gridlock. This increase in CO2 concentration in the atmosphere leads to various ill effects and global warming. To reduce the CO2 level in the atmosphere, efforts were made to prepare concrete that can absorb CO2 by addition of zeolite and bamboo biochar. These materials were chosen because zeolite and bamboo biochar have large pore volume and large specific surface area and so they can absorb more CO2. Zeolite is having more oxygen content and bamboo biochar is having more carbon content which helps in CO2 absorption. In this work, Zeolite is substituted for fine aggregate in the varying ratios of 25% and 50% and bamboo biochar is substituted for cement in the ratios of 0.5%, 1% and 1.5%. The strength properties and CO2 absorbing capacities of various zeolite and bamboo biochar concrete ratios were compared and it was found that concrete with 50% zeolite and 1% bamboo biochar (ZB5) was the optimal mix. The optimal mix was found based on compressive strength, split tensile strength, water absorption, impact strength, amount of CO2 absorption and depth of CO2 penetration in concrete. This optimal mix has a compressive strength of 38.49 MPa which is 7.48% higher than conventional concrete and also has a split tensile strength of 4.39 MPa which is 15% higher than conventional concrete. It was also found that the optimal mix absorbed 1.2 g of CO2 per day and that the depth of CO2 penetration was 15 mm when the concrete cube was kept in the carbonation chamber for 7 days. This study provided necessary information on the addition of zeolite and bamboo biochar in the concrete which enhances both strength properties and CO2 absorption. This study is important because now-a-days the current CO2 emission in the atmosphere is mainly due to several man-made activities. This ZB concrete provides a solution to reduce the amount of CO2 in the atmosphere and can be used in the concrete pavements, sewer pipelines, parapet walls and the environments with higher CO2 concentration and emission.Graphical

Microorganisms facilitated the saline‐alkali soil remediation by biochar: Soil properties, microbial communities, and plant responses

AbstractSaline‐alkali soil degradation is a significant environmental problem with a negative impact on sustainable agroforestry development. Therefore, efficient remediation methods are urgently required. A potential solution to this problem is using biochar produced from bamboo waste and inoculated with plant growth‐promoting microbes as cleaner production materials for saline‐alkali soil. The present study investigated the potential of combining biochar, microbes, and dwarf bamboo to improve saline‐alkali soil. Different application rates (1%, 3%, and 5% of soil mass) of biochar were added to coastal saline soil planted with dwarf bamboo (Pleioblastus argenteastriatus) in pot experiments. Soil physicochemical properties, microbial communities, and plant responses were systematically studied. Bamboo and microbial‐modified biochar effectively decreased soil pH and electrical conductivity and increased soil nutrient contents. Compared with untreated soil, the relative abundance of the dominant bacterial phyla Acidobacteria, Actinobacteria, and Chloroflexi, and dominant fungal phyla Basidiomycota increased after applying biochar and modified biochar. With the increase in application concentration, the antioxidant activities of modified biochar decreased, biochar peroxidase and catalase content decreased, and the malondialdehyde content of bamboo biochar and microbial‐modified bamboo biochar decreased. The biomass of bamboo with added biochar and modified biochar was significantly higher than that of untreated soil. Comprehensive correlation and redundancy analyses showed that the bacterial and fungal communities were greatly affected by soil factors, especially soil pH, electrical conductivity, total organic carbon, potassium, and sodium ions. The findings of this study suggest that 5% bamboo biochar and 3% modified biochar benefit soil remediation, improve the stress resistance of dwarf bamboo, and enhance plant growth. Therefore, combined biochar–microbe remediation has great potential for the sustainable improvement of saline‐alkali soil.