Intermetallic aluminide compounds possess several potential advantages compared to alloyed steels, like enhanced oxidation resistance, lower density and the omittance of critical raw materials. Iron aluminides, compared to other transition metal–aluminides of TM3-Al type, although having a higher density compared to titan-aluminides, have a lower density compared to nickel-aluminides, but also a higher ductility than both alternatives, making this material potentially effective in ballistic protection application. Density–wise, this material may be a worthy alternative to armour steels, which was the aim of this study. Two materials, Fe3Al intermetallic compound (F3A-C) and Armox 500 armour steel were ballistically tested against tungsten-carbide (WC) armour-piercing ammunition, in accordance with STANAG 4569. After ballistic testing, microhardness and metallographic testing were performed, revealing differences in strain hardening, crack propagation mode and exit hole morphology. F3A-C ballistic resistance is similar to that of armour steel, in spite of the lower tensile and impact mechanical properties, relying on a considerably higher strain hardening rate, thermal properties and a lower density.
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