AbstractWe present a combined experimental and theoretical analysis of the transport properties of silicon nanowire (NW) transistors. The NWs are grown by catalytic chemical vapour deposition and are later deposited on pre‐patterned oxidized silicon substrates that provide the device source and drain electrodes. A back gate configuration is used for our study. Through a controlled nickel diffusion, parts of the nominally undoped NWs are turned into nickel silicide NWs, thus pro‐ viding a direct metallic nanolead to the semiconducting wire. The transistors obtained with NWs of 10‐30 nm diameters display p‐type behaviour, current densities up to 0.8 MA/cm2, and on/off current ratios of up to 107. The subthreshold characteristics show a strong hysteresis. The simulation based on a drift‐diffusion approach indicates that traps at the interface between the NWs and SiO2 are responsible for such behaviour. (© 2008 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)