The recently demonstrated trapping and laser cooling of 133Ba+ has opened the door to the use of this nearly ideal atom for quantum information processing. However, before high-fidelity qubit operations can be performed, a number of unknown state energies are needed. Here, we report measurements of the 2P3/2 and 2D5/2 hyperfine splittings, as well as the 2P3/2 ↔ 2S1/2 and 2P3/2 ↔ 2D5/2 transition frequencies. Using these transitions, we demonstrate high-fidelity 133Ba+ hyperfine qubit manipulation with electron shelving detection to benchmark qubit state preparation and measurement (SPAM). Using single-shot, threshold discrimination, we measure an average SPAM fidelity of {mathcal{F}}=0.99971(3), a factor of ≈2 improvement over the best reported performance of any qubit.