Average Expansion Research Articles

Impact of nitromethane additive on ANFO performance.

The article presents an evaluation of the detonation performance of a nitromethane-ammonium nitrate fuel oil energetic material. The brisance and relative strength of this material were assessed using the Hess and Trauzl methods. Both methods confirmed that the shattering effect and relative work increase in a polynomial manner with the increasing content of nitromethane. A significant enhancement in detonation parameters was observed with up to 9% nitromethane addition. The results from the Trauzl and Hess tests indicated that at 9% nitromethane content, the average cavity expansion and brisance were 371cm3 and 10.01mm, respectively. The improved detonation performance is attributed to the introduction of additional nitro groups from nitromethane, replacing fuel oil, as well as the increased density of the energetic material.

DFT and AIMD studies of SnFe2O4 as a promising anode for Li-ion batteries

Tin ferrite (SnFe2O4) is considered as a perspective lithium ion battery anode, owing to its low cost, large theoretical capacity, low toxicity, structural stability, and easy synthesis method. Prior research has been done on the performance of lithium storage in SnFe2O4. However, the electrochemical processes that take place during the lithiation-delithiation cycle of LIBs have not been explained in depth yet. In order to understand the discharge mechanism in the LixSnFe2O4 anode (x = 0 to 2), we systematically investigated its electrochemical characteristics, structural and electronic properties, average formation energies, open-circuit voltages, diffusion coefficient, and volume expansion using density functional theory. According to our calculations, an increase in Li concentration x up to 1.125 leads to enhanced stability of the LixSnFe2O4 systems. During this process, Li+ ions prefer to be intercalated at the octahedral 16c sites, inducing the displacement of Sn2+ ions from tetrahedral sites 8a to 16c and 48f sites. However, for 1.125 < x < 2, lithium ions tend to occupy the less stable sites 48f , which reduces the stability of LixSnFe2O4 systems.Additionally, the calculated lithium intercalation voltage for full lithiation Li1.125SnFe2O4 is equal to 1.5 V, and the distortion of the LixSnFe2O4 system occurs at a voltage of 0.75 V, which is in well agreement with experimental results. The Li-coefficient diffusion on SnFe2O4 at 300 K is calculated by ab initio molecular dynamic simulation and equal to 8.22 × 10−8 cm2/s, which indicates the excellent mobility of Li ions in SnFe2O4. Considering all these results, we can suggest SnFe2O4 as a promising negative electrode material for lithium-ion batteries.

Evaluating water balance components in a tropical ecological zone under land use changes

Water availability for domestic, institutional, and agricultural production is threatened by the continuous change in land use land cover (LULC). These changes in LULC features affect the dynamics of the hydrological processes such as surface runoff, infiltration, and evapotranspiration, resulting in variations in water availability especially, for human consumption and crop yield. Therefore, the Soil and Water Assessment Tool (SWAT) hydrological model was deployed to simulate the Pra River Basin (PRB)’s water balance response to changing LULC from 1986 to 2020. Open and closed forests reduced from an area of 11,071 km2 to 5902 km2 and 5125 km2 to 4990 km2 while settlement and cropland increased from 1100 km2 to 2392 km2 and 5303 km2 to 9320 km2 representing an average annual expansion rate of +24.7 km2/yr and +118 km2/yr respectively over the three decades. The growth in settlement and cropland resulted in an upsurge of more than 33 % and 20 % in surface runoff and water yield respectively, but decreases of over 4 % and 17 % in evapotranspiration and baseflow respectively. These changes have resulted in a seasonal increase in surface runoff, baseflow, and evapotranspiration (ET) during the wet season but a decrease during the dry season. The PRB has experienced a dramatic decline in forest areas, chiefly in areas where settlement and farmlands have been expanded. The areas where surface runoff and water yield showed significant upsurge and reduction in ET are the northwestern and southern enclaves of the basin. These findings can aid in effectively planning and managing land use to control the gradually depleting water resources in the basin.

Increase in per capita cropland imbalance across countries from 1985 to 2022: A threat to achieving Sustainable Development Goals

Sustainable Development Goal 2 (SDG 2, zero hunger) highlights that global hunger and food insecurity have worsened since 2015, driven in part by growing imbalance. Addressing the challenge of achieving SDG 2 in the face of rapid global population growth requires sustained attention to global and national cropland changes. Accurately quantifying the correlation between population and cropland area (i.e., SDG 2.4.1 per capita cropland) and analyzing the trends of global cropland imbalance are essential for a comprehensive understanding of SDG 2. In this study, we utilized a new global 30 m land-cover dynamic dataset (GLC_FCS30D) to analyze cropland dynamics, quantify per capita cropland and its changes across various countries and levels of development. Our results indicate that the global cropland area expanded by 0.944 million km2 from 1985 to 2022, with an average expansion rate of 2.42 × 104 km2/yr. However, the global per capita cropland area decreased from 0.347 ha in 1985 to 0.217 ha in 2022, mainly due to a higher population increase of nearly 65% in the same period. In the context of globalization, cropland expansion and per capita cropland exhibited spatial imbalances globally, particularly in developing countries. Developing countries saw an increase in total cropland area by 7.09% but a significant decrease in per capita cropland area by 37.38%. From a temporal perspective, the global imbalance has been steadily increasing with the Gini index rising from 0.895 in 1985 to 0.909 in 2022. Consequently, this study reveals an increasing imbalance across various countries, which threatens the attainment of the targets of SDG 2.

Expansion of Naturally Grown Phyllostachys edulis (Carrière) J. Houzeau Forests into Diverse Habitats: Rates and Driving Factors

Moso bamboo (Phyllostachys edulis (Carrière) J. Houzeau), which is native to China, is considered to be an invasive species due to its powerful asexual reproductive capabilities that allow it to rapidly spread into neighboring ecosystems and replace existing plant communities. In the absence of human intervention, it remains poorly understood how indigenous moso bamboo forests naturally expand into surrounding areas over the long term, and whether these patterns vary with environmental changes. Using multi-year forest resource inventory data, we extracted moso bamboo patches that emerged from 2010 to 2020 and proposed a bamboo expansion index to calculate the average rate of patch expansion during this period. Using the first global 30 m land-cover dynamic monitoring product with a fine classification system, we assessed the expansion speeds of moso bamboo into various areas, particularly forests with different canopy closures and categories. Using parameter-optimized geographic detectors, we explored the significance of multi-factors in the expansion process. The results indicate that the average expansion rate of moso bamboo forests in China is 1.36 m/y, with evergreen broadleaved forests being the primary area for invasion. Moso bamboo expands faster into open forest types (0.15 &lt; canopy closure &lt; 0.4), shrublands, and grasslands. The importance of factors influencing the expansion rate is ranked as follows: temperature &gt; chemical properties of soil &gt; light &gt; physical properties of soil &gt; moisture &gt; atmosphere &gt; terrain. When considering interactions, the primary factors contributing to expansion rates include various climate factors and the combined effect of climate factors and soil factors. Our work underscores the importance of improving the quality and density of native vegetation, such as evergreen broadleaved forests. Effective management strategies, including systematic monitoring of environmental variables, as well as targeted interventions like bamboo removal and soil moisture control, are essential for mitigating the invasion of moso bamboo.

Re-evaluating the cosmological redshift: Insights into inhomogeneities and irreversible processes

Understanding the expansion of the Universe remains a profound challenge in fundamental physics. The complexity of solving general relativity equations in the presence of intricate, inhomogeneous flows has compelled cosmological models to rely on perturbation theory in a homogeneous Friedmann-Lemaître-Robertson-Walker background. This approach accounts for a redshift of light encompassing contributions from both the cosmological background expansion along the photon's trajectory and Doppler effects at emission due to peculiar motions. However, this computation of the redshift is not covariant, as it hinges on specific coordinate choices that may distort physical interpretations of the relativity of motion. In this study we show that peculiar motions, when tracing the dynamics along time-like geodesics, must contribute to the redshift of light through a local volume expansion factor, in addition to the background expansion. By employing a covariant approach to redshift calculation, we address the central question of whether the cosmological principle alone guarantees that the averaged local volume expansion factor matches the background expansion. We establish that this holds true only in scenarios characterised by a reversible evolution of the Universe, where inhomogeneous expansion and compression modes compensate for one another. In the presence of irreversible processes, such as the dissipation of large-scale compression modes through matter virialisation and associated entropy production, the averaged expansion factor becomes dominated by expansion in voids that can no longer be compensated for by compression in virialised structures. Furthermore, for a universe in which a substantial portion of its mass has undergone virialisation, adhering to the background evolution on average leads to significant violations of the second law of thermodynamics. Our approach shows that entropy production due to irreversible processes during the formation of structures plays the same role as an effective, time-dependent cosmological constant (i.e. dynamical dark energy) without the need to invoke new unknown physics. Our findings underscore the imperative need to re-evaluate the influence of inhomogeneities and irreversible processes on cosmological models, shedding new light on the intricate dynamics of our Universe.

Expansion and characterization of immune suppressive CD56(bright)Perforin(-) regulatory-like natural killer cells in chronic graft-versus-host disease

Background: Chronic graft-versus-host disease (cGvHD) is a major cause of morbidity and mortality after Hematopoietic Stem Cell Transplantation (HSCT). Previously, in large patient cohorts, we identified increased numbers of CD56brightPerforin− regulatory-like NK cells (NKreg-like) associated with cGvHD suppression. Thus, we hypothesized that NKreg-like cells may be a potential candidate for cGvHD cell therapy. Aim: To expand NKreg-like cells while maintaining regulatory phenotype and function. Methods: Total NK cells were first expanded with IL-2, which was then combined with rapamycin, Transforming Growth Factor Beta 1 (TGF-β1), NECA (Adenosine A2A receptor (A2AR) agonist), metformin, or dexamethasone, to prevent change in cell phenotype/function. The functional characteristics were evaluated via T cell suppression assays and the phenotype was measured using flow cytometry. The optimal expansion protocol was compared in terms of function and metabolism for three NK expansion media, and cells from cord vs. peripheral blood. Further, expanded NKreg-like cell gene expression was characterized using bulk RNA sequencing. Finally, NKreg-like cells were differentiated from CD34+ hematopoietic stem and progenitor cells (HSPCs) and compared in terms of proliferation and function. Results: The expansion of total NK cells found the addition of TGF-β1 and/or NECA with the pulsing of rapamycin in IL-2 containing media to prevent NKreg-like differentiation (up to 200-fold expansion). Expanded NKreg-like cells maintained a phenotype, transcriptome, and T cell suppression similar to freshly isolated NKreg-like cells. NKreg-like expansion was greatest in the Immunocult media (up to 300-fold), and NKreg-like cells from peripheral blood demonstrated significantly greater proliferation than cells isolated from cord blood (65-fold). The metabolic profile of NKreg-like and cytolytic NK cells appeared similar at baseline, though rapamycin induced a shift to oxidative over glycolytic metabolism. Further, we demonstrated that suppressive NKreg-like cells may alternatively be expanded from CD34+ cells isolated from cord blood, reaching an average 340-fold expansion. Conclusions: In conclusion, our studies have optimized two alternative expansion approaches for deriving functional NKreg-like cells. Additionally, evaluating the transcriptomic and metabolic characteristics provides useful information regarding NKreg-like cell function and differentiation. With further optimization and in vivo validation, we may work towards preparing these cells as a therapy for cGvHD.

A Three-Dimensional Morphological Assessment for Evaluating Pre- and Postsurgery in Cervical Laminoplasty

ObjectiveThe efficacy of medical treatments and the changes in radiological imaging before and after treatment have consistently remained pivotal factors. This is particularly critical for surgical procedures, where precise evaluation of disparities pre- and post-surgery or the accuracy of implantation is paramount. Based on three-dimensional morphological interests, we provide an automatic quantification evaluation method that delivers an evident base for assessing the outcomes of a widely employed surgical technique, cervical laminoplasty. MethodsThe sample study included patients who underwent cervical laminoplasty for cervical spondylotic myelopathy/ossification of the longitudinal ligament. We present a superimposition method that facilitates a unique and precise assessment between pre and post-surgery. The degree of expansion was evaluated by the canal volume increase and canal expansion rate after surgery. ResultsThere were 31 patients with 112 vertebral segments measured. The target cervical's pre- and post-operative canal areas were 122.63 ± 30.34 and 196.50 ± 37.10 mm2, respectively (P < 0.001). The average cervical canal expansion rate was 64.42%. The expansion effect of C5 cervical laminoplasty was the maximum (71.01%), and the canal volume of other segments expanded by approximately 60%. The functional outcomes demonstrated significant improvements in symptoms. ConclusionsThe quantification evaluation method can be utilized for any morphology changes before and after laminoplasty, as it does not lead to errors or variations from different inspection machines or human factors. The automatic method delivers an evident base for assessing the outcomes of a widely employed surgical technique.

Admissibility and mean hyperbolicity for evolution equations

Mean hyperbolic systems permit non-hyperbolic behavior at certain moments during the evolution process T(t,s), owing to non-fixed error hyperbolic degree ε(t,s). Despite the coexistence of compression and expansion behaviors in generalized stable and unstable subspaces, mean hyperbolic systems admit fixed average contraction and expansion rates measured at sufficiently long time. To discuss the relationship between admissibility and mean hyperbolicity for evolution equations, our main goal is to construct admissible function classes and invariant decomposition with generalized stable and unstable subspaces. As applications, the mean hyperbolicity of damped wave equations with variable coefficients and the roughness of mean hyperbolicity are presented.

Time-lapse imaging of morula compaction for selecting high-quality blastocysts: a retrospective cohort study.

Before blastocyst development, embryos undergo morphological and metabolic changes crucial for their subsequent growth. This study aimed to investigate the relationship between morula compaction and blastocyst formation and the subsequent chromosomal status of the embryos. This retrospective cohort study evaluated embryo development (n = 371) using time-lapse imaging; 94 blastocysts underwent preimplantation genetic testing for aneuploidy (PGT-A). The embryos were classified as fully (Group 1, n = 194) or partially (Group 2, n = 177) compacted. Group 1 had significantly higher proportions of good- and average-quality blastocysts than Group 2 (21.6% vs. 3.4%, p = 0.001; 47.9% vs. 26.6%, p = 0.001, respectively). The time from the morula stage to the beginning and completion of compaction and blastocyst formation was significantly shorter in Group 1 than in Group 2 (78.6 vs. 82.4h, p = 0.001; 87.0 vs. 92.2h, p = 0.001; 100.2 vs. 103.7h, p = 0.017, respectively). Group 1 embryos had larger surface areas than Group 2 embryos at various time points following blastocyst formation. Group 1 blastocysts had significantly higher average expansion rates than Group 2 blastocysts (653.6 vs. 499.2μm2/h, p = 0.001). PGT-A revealed a higher proportion of euploid embryos in Group 1 than in Group 2 (47.2% vs. 36.6%, p = 0.303). Time-lapse microscopy uncovered a positive relationship between compaction and blastocyst quality and its association with embryo ploidy. Hence, compaction evaluation should be prioritized before blastocyst selection for transfer or cryopreservation.

Pressure dependence of phase transformation, thermal expansion and barocaloric property in a polycrystalline Ni54Mn23Ga23 alloy

An experimental investigation was conducted to understand the influence of hydrostatic pressure on phase transition, thermal expansion and barocaloric property of a polycrystalline Ni54Mn23Ga23 alloy. Two pressure ranges of 0–1.28 GPa and 0–0.74 GPa were selected for thermal expansion and barocaloric property measurements due to the different test limits of instrumentals. The pressure dependence of fourteen parameters was studied systematically. It was found that the sample experiences a martensitic transformation (MT) near room temperature and the response of MT peak temperature (TM) to pressure is about 15.89 K/GPa. The phase transition strain (λtr), transformation width (ΔTtr) relative volume change (|ΔV/V|) and maximum adiabatic temperature change (ΔTad)max increase linearly with pressure and their shifting rates are about 0.071 %/GPa, 7.5 K/GPa, 0.211 %/GPa and 12.2 K/GPa, respectively. Simultaneously, applying hydrostatic pressure can also enhance the barocaloric property of the sample, leading to a large increase in the absolute value of the maximum entropy change (|ΔS|max), the refrigerating capacity (RC) and their reversible values. On cooling, the sensitivities of the reversible RC and its proportion to pressure are around 185.52 J/kg GPa and 16.7 %/GPa, respectively. Finally, the average linear expansion coefficient (αave) of both martensite and austenite phases keeps unchanged while in the MT region it decreases from -99.84×10–6/K to -86.04×10–6/K with increasing pressure from 0 to 1.28 GPa. These findings indicate that applying hydrostatic pressure can effectively adjust the phase transformation, thermal expansion and barocaloric property of Ni-Mn-Ga alloys, which are meaningful for their application in solid-state refrigeration.

High entropy alloys amenable for laser powder bed fusion: A thermodynamics guided machine learning search

Although there is considerable research interest in high-entropy alloys (HEAs), only a small fraction of the potential compositional space was explored hitherto. While additive manufacturing techniques such as the laser powder bed fusion (LPBF) can be gainfully employed to accelerate discovery of new HEAs with promising properties, the printability of such alloys could restrict such an exploration. Keeping this in view, a machine learning (ML) based alloy design strategy, which takes thermodynamic parameters such as the liquid temperature range (LR), liquid viscosity (LV), average expansion (AE) during the solidification of the alloy, and shear/bulk moduli ratio (G/B) of solidified alloy into account, is developed for assessing the printability of HEAs using LPBF. First, a printability evaluation chart that has six different printing capacity regions is obtained by considering LR, LV, AE, G, and B. Then, ML is utilized to predict the candidate chemical compositions within them that are amenable to LPBF. On this basis, an alloy with the composition Co7.5Cr7.5Nb7.5Ni10.0Ti67.5 (at%) was identified, and its process window range and printability were validated through experiments. The range of thermodynamic parameters suitable for the manufacturability was determined as LV >5.5 mPa•s, LR >1600 ℃, AE <25%, and G/B <0.5. The effects of thermodynamic parameters on the printing process window was systematically investigated. Furthermore, Shapley Additive exPlanations (SHAP) algorithm was utilized to evaluate the influence of various elements on the thermodynamic parameters, which could, in turn, guide the chemical composition design so as to achieve HEAs with good printability. This work provides the thermodynamic parameter index for LPBF and offers opportunities to use ML for accelerating the design of HEAs that are amenable to LPBF.

A Topology Control Algorithm Taking into Account Energy and Quality of Transmission for Software-Defined Wireless Sensor Network

The efficient use of energy in wireless sensor networks is critical for extending node lifetime. The network topology is one of the factors that have a significant impact on the energy usage at the nodes and the quality of transmission (QoT) in the network. We propose a topology control algorithm for softwaredefined wireless sensor networks (SDWSNs) in this paper. Our method is to formulate topology control algorithm as a nonlinear programming (NP) problem with the objective to optimizing two metrics, maximum communication range, and desired degree. This NP problem is solved at the SDWSN controller by employing the genetic algorithm (GA) to determine the best topology. The simulation results show that the proposed algorithm outperforms the Max Power algorithm in terms of average node degree and energy expansion ratio.

Decoding the spread of non-indigenous fishes in the Mediterranean Sea

The ocean is dynamically changing due to the influence of climate processes and human activities. The construction of the Suez Canal in the late nineteenth century opened the Pandora’s box by facilitating the dispersal of Red Sea species in the Mediterranean Sea. In this study, we developed an open-source spatio-temporal numerical analysis framework to decodify the complex spread of Mediterranean non-indigenous fish species (NIS) that entered through the Suez Canal. We utilized 772 historical detection records of 130 NIS to disentangle their dynamic spread through space and time. The results indicated that species follow a north-westward trajectory with an average expansion time step of 2.5 years. Additionally, we estimated the overall time for a NIS to reach the Central Mediterranean Sea from the Suez Canal at approximately 22 years. Based on the analysis, more than half of the introduced fishes have been established in less than 10 years. Finally, we proceeded in the cross-validation of our results using actual spread patterns of invasive fishes of the Mediterranean Sea, resulting up to 90% of temporal and spatial agreement. The methodology and the findings presented herein may contribute to management initiatives in highly invaded regions around the globe.

Back-reaction of long-wavelength cosmological fluctuations as measured by a clock field

We consider the back-reaction of cosmological fluctuations on the local expansion rate averaged over a space-like hypersurface of constant value of a clock field. We show that in the infrared limit, the fluctuations lead to a decrease in the average expansion rate, measured at a fixed value of the clock field, compared to what would be obtained in a homogeneous universe. We work in the context of Einstein gravity coupled to perfect fluid matter.

Expansion Kinetics of Flexible Polymers upon Release from a Disk-Shaped Confinement.

A general theory is developed to explain the expansion kinetics of a polymer released from a confining cavity in a d-dimensional space. At beginning, the decompressed chain undergoes an explosive expansion while keeping the structure resembling a sphere. As the process continues, the chain transitions to a coil conformation, and the expansion significantly slows down. The kinetics are derived by applying Onsager's variational principle. Computer simulations are then conducted in a quasi-two-dimensional space to verify the theory. The average expansion of the chain size exhibits a distinctive sigmoidal variation on a logarithmic scale, characterized by two times and associated exponents that represent the fast and the slow dynamics, respectively. Through an analysis of the kinetic state diagrams, two important universal behaviors are discovered in the two expansion stages. The intersection of the expansion speed curves allows us to define the crossover point between the stages and study its properties. The scaling relations of the characteristic times and exponents are thoroughly investigated under different confining conditions, with the results strongly supporting the theory. Additional calculations conducted in a three-dimensional (3D) space demonstrate the robustness of the proposed theory in describing the kinetics of polymer expansion in both 2D and 3D spaces.

Observations of polar mesospheric summer echoes resembling kilometer-scale varicose-mode flows

Abstract. The mesosphere and lower thermosphere (MLT) region represents a captivating yet challenging field of research. Remote sensing techniques, such as radar, have proven invaluable for investigating this domain. The Middle Atmosphere Alomar Radar System (MAARSY), located in northern Norway (69∘ N, 16∘ E), uses polar mesospheric summer echoes (PMSEs) as tracers to study MLT dynamics across multiple scales. Chau et al. (2021) recently discovered a spatiotemporally highly localized event showing a varicose mode (simultaneous upward and downward movements), which is characterized by extreme vertical velocities (|w|≥3σ) of up to 60 m s−1 in the vertical drafts. Motivated by this finding, our objective is to identify and quantify similar extreme events or comparable varicose structures, i.e., defined by quasi-simultaneous updrafts and downdrafts, that may have been previously overlooked or filtered out. To achieve this, we conducted a thorough manual search through a MAARSY dataset, considering the PMSE months (i.e., May, June, July, August) spanning from 2015 to 2021. This search has revealed that these structures do indeed occur relatively frequently with an occurrence rate of up to 2.5 % per month. Over the 7-year period, we observed and recorded more than 700 varicose-mode events with a total duration of about 265 h and documented their vertical extent, vertical velocity characteristics, duration, and their occurrence behavior. Remarkably, these events manifest throughout the entire PMSE season with pronounced occurrence rates in June and July, while the probability of their occurrence decreases towards the beginning and end of the PMSE seasons. Furthermore, their diurnal variability aligns with that of PMSEs. On average, the observed events persisted for 20 min, while the varicose mode caused an average expansion of the PMSE layer by a factor of 1.5, with a maximum vertical expansion averaging around 8 km. Notably, a careful examination of the vertical velocities associated with these events confirmed that approximately 17 % surpassed the 3σ threshold, highlighting their non-Gaussian velocity distribution and extreme nature.

Phase diagram study of Na2O–ThO2–P2O5 system and investigation of thermo physical properties of quaternary compounds

The subsolidus phase relations in Na2O–ThO2–P2O5 pseudo ternary system were determined at 1223 K. Synthesis of all the phases, used for drawing phase diagram, was carried out by solid state route. Formation of ternary and quaternary compounds in Na2O–ThO2, Na2O–P2O5, ThO2–P2O5 and Na2O–ThO2–P2O5 systems was confirmed at 1223 K. With the help of these compounds and phase analysis of number of synthetic mixtures, prepared by reacting different mol fractions of Na2O, ThO2 and P2O5 at 1223 K, phase diagram was drawn and phase boundaries were established. No ternary compound was identified in Na2O–ThO2 system. Formation of three quaternary phosphates, Na2Th(PO4)2, NaTh2(PO4)3 and Na5Th(PO4)3 was confirmed at 1223 K. XRD pattern of monoclinic Na5Th(PO4)3, synthesized for the first time and found iso structural with Na5Th(AsO4)3 and its lattice parameters were obtained by Le Bail method. Thermogravimetric studies of quaternary phosphates were carried out in air to investigate their thermal stability. All the three compounds decompose to ThO2 at 1673 K. Two step weight loss in TG curve of Na2Th(PO4)2 confirmed its decomposition to ThO2 via NaTh2(PO4)3 as an intermediate. To calculate thermal expansion coefficients, high temperature XRD (HT-XRD) data of Na2Th(PO4)2, NaTh2(PO4)3 and Na5Th(PO4)3 was collected in air between the temperature range of 298–1173 K. All these compounds exhibit positive thermal expansion with the average volume expansion coefficient values ranging between 30 and 60 × 10−6 K−1. Heat capacities of these compounds were measured in the temperature range of 308–873 K using Differential Scanning Calorimetry (DSC) technique.

An assessment of the geomorphodiversity and land use/cover change (LUCC) effects associated with landslides in Meghalaya, India

AbstractThe Shillong Plateau in the Eastern Himalayas is exposed to high seismicity, neo‐tectonic activity and orographic precipitation that aggravated landslides in the region by affecting hillslope processes. Landscape development is influenced by landslide phenomenon and depends upon geomorphic processes and geomorphodiversity (GmD). It is linked intimately with geomorphology, hydrology and soil type. This study uses a remote sensing and GIS‐based approach to assess the spatial linkage between GmD and landslide distribution in Meghalaya (India). GmD index (GmDI) is developed using geological, morphometric and geomorphological parameters and analysed with landslide distribution. The landslide distribution considering land use/cover change (LUCC) is also examined. The result shows that the region with high‐relief, valley and depression zone, mainly along the Dauki fault, have a high to a very high GmDI. About 61% of landslide localities are in zones of high GmDI, concentrated in the central and eastern parts of Meghalaya. Density analysis of the very high class (class 5) of GmD confirms the same. Most of these landslides occur in dense and light‐vegetated landmasses. However, the LUCC analysis reveals a significant increase in the built area on steeper slopes (average expansion ratio of 2.30 for slopes &gt;15°) between 2017 and 2022, indicating a rising threat of landslides in urban areas of Meghalaya. The study presents the importance of GmD in active tectonic regions with particular reference to landslide potential and recent LUCC. It can aid decision‐makers in planning sustainable developments and risk mitigation strategies for landslide hazards and geoconservation.

Influences of removable gas injection methods on the temperature field and gas composition of the underground coal gasification process

In this paper, the effects of changing the injection position of a gasification agent on temperature fields and gas compositions are investigated through an experimental model of the underground gasification of coaxial coal. A 3D model of the temperature field is constructed based on the experimental temperature parameters using kriging interpolation; the 900 °C isothermal surface is used as the reference plane to define the oxidation zone, and its plane and volume expansion rate are analyzed. The underground coal gasification experiment is divided into five stages according to the injection location. The average expansion rates of the oxidation zone in each stage are 2.04 cm/h, 1.93 cm/h, 3.44 cm/h, 3.68 cm/h, and 3 cm/h along the X-direction and 0.69 cm/h, 0.09 cm/h, 0.56 cm/h, 1.69 cm/h, and 1.01 cm/h along the Z-direction; the expansion rate along the X-direction is greater than that along the Z-direction. The expansion volumes of the oxidation zone after the five stages increase from 0.0097 m3 to 0.0168 m3, 0.0321 m3, 0.0521 m3 and 0.0657 m3. An analysis of the expanded volume of the oxidation zone compared with the volume of the cavity shows that both features are similar in shape and that the final volume of the cavity is smaller than the final expanded volume of the oxidation zone; the volume of the cavity is approximately 77.3 % of the expanded volume of the oxidation zone. The formation of a cavity requires the temperature to reach the conditions for the oxidation reaction of the coal and the rupture and flaking of the ash layer that accumulates after the reaction by the actions of certain stresses, such as thermal. The composition of the product gas and the strength of the chemical reactions involved are evaluated based on stoichiometric conservation. A short period after a shift in the injection position of the gasifier greatly impacts the chemical equilibrium of the UCG process with a large change in the strength of the chemical reaction, followed by a relatively small change when the gasification process stabilizes.