The risk of sudden water pollution is one of the biggest obstacles to ensuring the safety of river basin water environments. While external pressure factors such as illegal discharge have been extensively studied with regard to their impact on the risk of sudden pollution, the influence of the river network topology has received limited attention. To fill this gap, extensive computational experiments were conducted in this study to investigate the effects of river network topology on the potential risk of sudden pollution. Based on the real-world characteristics of dendritic river networks, we used optimal channel networks to generate various river network topologies, represented by seven indicators that encompass morphology, connectivity, and structure. The water quality model simulated the spatial and temporal responses of the samples to a wide range of sudden pollution scenarios, and quantified the associated risk of sudden pollution using three proxy indicators: the maximum standard-exceeding multiple, proportion of standard-exceeding river length, and duration of exceedance. The results showed that among the seven indicators, the average outlet path (Do) and geometric fractal dimension (Dg) had a significant impact on risk. This is because network topology alters hydrological signatures such as discharge, velocity, and travel time. Moreover, multi-group analysis of structural equations revealed that the aspect ratio influences the impact of structural and connectivity indicators on risk by modulating pollution range and concentration. This study revealed the topological factors of the risk of sudden water pollution in dendritic river networks, emphasizing the regulatory role of topology in potential sudden water pollution risk and providing valuable insights for river management and planning.
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