Average Deposition Research Articles

Sedimentary laminae in muddy inner continental shelf sediments of the East China Sea: Formation and implications for geochronology

The sedimentary rhythm is well developed in the environment which is controlled by strong seasonal climate changing condition. This rhythm is important for sediment core dating purpose. In this study, we examine muddy sediments on the inner continental shelf of the East China Sea that are influenced under seasonal change of the East Asian monsoon. We use Ensemble Empirical Mode Decomposition (EEMD) method to process sediment grain size and X-radiograph negatives grayscale value data in three sediment cores from this area and use the results to analyze the patterns of sedimentary variability and the causes of cyclic variability of the sedimentary process. The variability in the grain size and grayscale values of the core sediments has three components: the high-frequency variability, low-frequency variability and a secular trend. Among these components, the high-frequency component reflects variability on annual time scale can be well recognized, we suggest that the annual variability is derived from seasonal variation in the sediment flux from the Yangtze River to the sea, as well as the East Asian monsoon's impact on the sedimentary dynamics of the East China Sea's inner continental shelf. However, the other variability is hard to identify which cycles there are. This variability may reflect decadal winter monsoon oscillation and human activity of dam construction in the Yangtze River. Each annual variability presents a varve in the sediment sequence, which can be used to determine the sediment deposition rate and accurately date the core sediment. We found that the average deposition rates of the three cores from north to south on the inner shelf were 3.1 cm/yr, 1.0 cm/yr, 0.9 cm/yr, indicating that the Yangtze-derived sediment decreased with the increasing distance from the Yangtze estuary to the shelf. The deposition rate of each core varies over time, and the maximum deposition rate can be 3–5 times greater than the minimum rate. The sediment ages obtained from varve chronology and radiometric dating are fairly consistent on a centennial scale, differing only by 2–5 years. Thus, varve counting is a useful supplementary approach to radiometric age dating for constructing chronologies for core sediment in shelf seas influenced by monsoons.

Physical and chemical properties of deposited airborne particulates over the Arabian Red Sea coastal plain

Abstract. Mineral dust is the most abundant aerosol, having a profound impact on the global energy budget. This research continues our previous studies performed on surface soils in the Arabian Peninsula, focusing on the mineralogical, physical and chemical composition of dust deposits from the atmosphere at the Arabian Red Sea coast. For this purpose, aerosols deposited from the atmosphere are collected during 2015 at six sites on the campus of the King Abdullah University of Science and Technology (KAUST) situated on the Red Sea coastal plain of Saudi Arabia and subjected to the same chemical and mineralogical analysis we conducted on soil samples. Frisbee deposition samplers with foam inserts were used to collect dust and other deposits, for the period December 2014 to December 2015. The average deposition rate measured at KAUST for this period was 14 g m−2 per month, with lowest values in winter and increased deposition rates in August to October. The particle size distributions provide assessments of < 10 and < 2.5 µm dust deposition rates, and it is suggested that these represent proxies for PM10 (coarse) and PM2. 5 (fine) particle size fractions in the dust deposits.X-ray diffraction (XRD) analysis of a subset of samples confirms variable amounts of quartz, feldspars, micas, and halite, with lesser amounts of gypsum, calcite, dolomite, hematite, and amphibole. Freeze-dried samples were re-suspended onto the Teflon® filters for elemental analysis by X-ray fluorescence (XRF), while splits from each sample were analyzed for water-soluble cations and anions by ion chromatography. The dust deposits along the Red Sea coast are considered to be a mixture of dust emissions from local soils and soils imported from distal dust sources. Airborne mineral concentrations are greatest at or close to dust sources, compared to those through medium- and long-range transport. It is not possible to identify the exact origin of deposition samples from the mineralogical and chemical results alone. These aerosol data are the first of their kind from the Red Sea region. They will help assess their potential nutrient input into the Red Sea, as well the impact on human health, industry, and solar panel efficiency. These data will also support dust modeling in this important dust belt source area by better quantifying dust mass balance and optical properties of airborne dust particles.

An efficient computational fluid-particle dynamics method to predict deposition in a simplified approximation of the deep lung

High-fidelity simulations of the complete airway tree are still largely beyond current computational capabilities. Towards large-scale simulations of the human lung, the current study introduces a numerical methodology to predict particle deposition in a simplified approximation of the deep lung during a full breathing cycle. The geometrical model employed consists of an idealised bronchial tree that represents generations 10 to 19 of the conducting zone and a heterogeneous acinar model created using a space-filling algorithm. The computational cost of the coupled simulation is reduced by taking advantage of the flow similarity across the central conducting regions in order to decompose the bronchial tree into representative subunits. Topological information is used to account for the correct gravitational force on the particles in the representative bifurcations, emulating their transport characteristics in the actual bronchial tree. Eventually, airflow and particle transport are simulated in a single representative bifurcation and a single acinar model, resulting in great savings in computational cost.An Eulerian-Lagrangian approach has been used for solving the flow and particle equations during sinusoidal breathing in the decomposed domain. The resulting deposition estimates agree rather well with the known deposition trends reported in the literature, while offering additional insights. For 1−5μm particles, deposition during exhalation is comparable to deposition upon inhalation, suggesting the use of breath-hold maneuvers to further increase sedimentation of these particles. Airway orientation relative to gravity was found to have a significant impact on deposition rates, especially for particles above 2μm and to be higher in the more distal generations, due to the wider range of angles relative to the direction of gravity. In the acinus, particles in the 2−5μm range have a quite high average deposition efficiency that reaches approximately 75% and shows considerable variation (12.4%) due to airway orientation. Finally, a simplified semi-analytical approach is introduced that can lead to even further reduction in computational costs, while incurring only a small loss in accuracy.

Nanodiamond arrays on glass for quantification and fluorescence characterisation

Quantifying the variation in emission properties of fluorescent nanodiamonds is important for developing their wide-ranging applicability. Directed self-assembly techniques show promise for positioning nanodiamonds precisely enabling such quantification. Here we show an approach for depositing nanodiamonds in pre-determined arrays which are used to gather statistical information about fluorescent lifetimes. The arrays were created via a layer of photoresist patterned with grids of apertures using electron beam lithography and then drop-cast with nanodiamonds. Electron microscopy revealed a 90% average deposition yield across 3,376 populated array sites, with an average of 20 nanodiamonds per site. Confocal microscopy, optimised for nitrogen vacancy fluorescence collection, revealed a broad distribution of fluorescent lifetimes in agreement with literature. This method for statistically quantifying fluorescent nanoparticles provides a step towards fabrication of hybrid photonic devices for applications from quantum cryptography to sensing.

Atmospheric deposition of polycyclic aromatic compounds and associated sources in an urban and a rural area of Chongqing, China

Monthly bulk (dry + wet) deposition samples were collected at an urban and a rural site in Chongqing, southwestern China during May 2014 to April 2015 for analyzing the contents of parent polycyclic aromatic hydrocarbons (PPAHs) and three types of substituted PAHs (SPAHs) including oxygenated PAHs (OPAHs), nitrated PAHs (NPAHs) and methyl PAHs (MPAHs). Annual average (±standard deviation) deposition fluxes of ΣPPAHs, ΣOPAHs, and ΣMPAHs were 536 ± 216; 221 ± 118, and 131 ± 41.9 ng/m2/d, respectively, in the urban area, and 347 ± 185, 160 ± 112, and 85.2 ± 32.0 ng/m2/d, respectively in the rural area. Deposition of ΣNPAHs (6.01 ± 3.93 and 3.91 ± 4.84 ng/m2/d) were about two orders of magnitude lower than those of ΣPPAHs. In the urban area, temporal variations of PPAHs and MPAHs fluxes were positively correlated with particle deposition, while the trends of OPAHs and NPAHs were probably controlled by secondary formation. In the rural area, SPAHs and PPAHs deposition fluxes had similar temporal trends but differed from particle deposition. High relative humidity in Chongqing likely played an important role in facilitating the partitioning of OPAHs to atmospheric aerosols and resulting in the relatively high OPAHs level in winter. Principle component analysis identified secondary formation (21.7%) and combustion emission (52.7%) as two important contributors to polycyclic aromatic compounds (PACs) deposition fluxes in urban area.

Atmospheric Dry Deposition Fluxes and Sources of Polycyclic Aromatic Hydrocarbons in Lanzhou Valley, Northwest China

The atmospheric dry deposition flux pollution levels were determined and the sources apportioned for 15 US EPA priority polycyclic aromatic hydrocarbons (PAHs) collected at 13 sampling sites in the Lanzhou valley using passive sampling techniques. The results are as follows. The annual atmospheric dry deposition fluxes ranged from 7.48 to 53.94 μg·(m2·d)-1, with a mean of 18.65 μg·(m2·d)-1. The highest flux levels for both the heating and non-heating seasons, 60.85 μg·(m2·d)-1 and 47.03 μg·(m2·d)-1, respectively, appeared at the traffic site (Donggang Bridge), where the heaviest traffic in the Lanzhou valley occurs. The lowest flux levels of 8.16 μg·(m2·d)-1 and 6.80 μg·(m2·d)-1 for the heating and non-heating seasons, respectively, were found at Baita Mountain, which has a higher percentage of vegetation cover. Meanwhile, the flux levels at the background site (Guantangou Mountain) were significantly lower than those of the other sampling sites. For dry deposition, the PAH components Phe, Flua, Flu, and Pyr were dominant in the heating and non-heating periods, and the sums of the percentages of 3- and 4-ring PAHs were 87.53% for the heating season and 82.73% for the non-heating season. Moreover, the percentage of 5- and 6-ring PAHs for the non-heating period was higher than that for the heating period, which may be because the lighter PAHs were easily volatilized, and thus escaped. Furthermore, the sources of atmospheric dry deposition were identified by principal component analysis (PCA). The results of source apportionment showed that the main atmospheric PAH dry deposition in the Lanzhou valley were from vehicle exhaust emissions, coal combustion, and the coking industry. In further detail, coal combustion and the coking industry contributed most of the PAH dry deposition emissions during the heating period except for the traffic area site of Donggang Bridge, whereas vehicle exhaust was the dominant contributor during the non-heating season. In addition, the annual average dry deposition velocities of atmospheric PAHs were calculated using the dry deposition model for three sites: 0.20 cm·s-1 downtown (Environmental Protection Agency of Lanzhou; JCZ), 0.15 cm·s-1 in an industrial area (Lanyuan Hotel of Xigu; LLH), and 0.17 cm·s-1 in a traffic area (the Staff Hospital of Gansu Province; ZGH), of which the latter two were relatively lower because of comprehensive meteorological factors such as wind speed, temperature, and land use categories. Regarding the dry deposition flux values of the 3- and 4-ring PAHs, the simulated values were a bit larger than the observed values, but all were at the same level of magnitude. However, the simulated flux values were closer to their observed values for 4-ring PAHs than for 3-ring PAHs, which indicated that 3-ring PAHs were lost more easily than 4-ring PAHs were during monitoring.

A 13-year study of dissolved organic carbon in rainwater of an agro-industrial region of São Paulo state (Brazil) heavily impacted by biomass burning

This work presents the first comprehensive study of DOC in rainwater in a tropical agro-industrial region in central São Paulo State. The DOC concentrations ranged from 15 to 4992μmolCL−1, with an overall volume weighted mean (VWM) of 288±17μmolCL−1 (n=881). The number of fire spots accumulated within each year of this study was positively correlated to the VWM concentration of DOC in rainwater. During the whole study period, higher VWM DOC concentrations were found during the dry months, despite the phasing out of agricultural fires in sugar cane plantations. The evidence suggested that inputs of atmospheric soluble organic carbon from biomass burning exceeded those from vehicular fuel combustion and biogenic sources. In most cases, dilution of DOC according to precipitation volume was minimal, showing that in-cloud processes were dominant for this species. In contrast, most of the volatile dissolved organic carbon (VDOC) appeared to be removed from the atmosphere in the first milliliter or so of rain, showing a dominance of below-cloud scavenging. VDOC contributed a significant fraction of the DOC for 62% of the samples analyzed, ranging from 5.1 to 488μmolCL−1 (n=552). The average wet deposition flux of DOC was 49kgCha−1yr−1, with VDOC accounting for 10% of the total. This dissolved carbon flux is higher than the estimated world average (34kgCha−1yr−1). The DOC in the rainwater was mostly labile (75% on average) and rapidly bioavailable (within days to weeks), in contrast to refractory dissolved carbon found in rainwater from regions where fossil fuel combustion is the dominant source. The findings of this work indicate that biomass burning can lead to important atmospheric inputs of readily available organic matter to land and to the open ocean.

Exposure to coarse and fine particulate matter at and around major intra-urban traffic intersections of Ilorin metropolis, Nigeria

This study aims to determine the seasonal variations and composition of suspended particulate matter in different sizes PM1.0, PM2.5, PM10 and the total suspended particles (TSP) emitted at major intra-urban traffic intersections (TIs) of Ilorin metropolis. The concentration levels of PM (PM1.0, PM2.5, PM10) obtained at the TIs during the rush hours (45.1, 77.9, and 513 μg/m3) are higher than the levels obtained for the non-rush hour periods (42.3, 62.7, and 390 μg/m3). The average on-road respiratory deposition dose (RDD) rates of PM1.0, PM2.5 and PM10 during the dry period at TIs types was found to be about 24%, 9% and 25% higher than those obtained during the wet period. Based on EF values calculated, Pb and Zn were anthropogenically-derived while Fe, Mn, Cr, Cu and Mg were of crustal source. Principal component analysis (PCA) has been applied to a set of PM data in order to determine the contribution of different sources. It was found that the main principal factors extracted from particulate emission data were related to exhaust and non-exhaust emissions such as tyre wears, oil and fuel combustion sources.

Spruce-fir forest changes during a 30-year nitrogen saturation experiment

A field experiment was established in a high elevation red spruce (Picea rubens Sarg.) – balsam fir (Abies balsamea) forest on Mount Ascutney Vermont, USA in 1988 to test the nitrogen (N) saturation hypothesis, and to better understand the mechanisms causing forest decline at the time. The study established replicate control, low and high dose nitrogen addition plots (i.e., 0, 15.7 and 31.4kgNH4Cl-Nha−1yr−1). The treatments began in 1988 and continued annually until 2010, but monitoring has continued to present. During the fertilization period, forest floor C:N, net in situ N mineralization, spruce foliar Ca%, and live spruce basal area decreased with increasing N addition, while foliar spruce N% and forest floor net nitrification increased with increasing N addition. The control plots aggraded forest floor N at a rate equal to the sum of the net in situ N mineralization plus average ambient deposition. Conversely, N addition plots lost forest floor N. Following the termination of N additions in 2010, the measured tree components returned to pre-treatment levels, but forest floor processes were slower to respond. During the 30year study, site surface air temperature has increased by 0.5°C per decade, and total N deposition has decreased 5.5 to 4.0kgNha−1yr−1. There have also been three significant drought years and at least one freeze injury year after which much of the forest mortality on the N addition plots occurred. Given that there was no control for the air temperature increase, discussion of the interactive impacts of climate and change and N addition is only subjective. Predicted changes in climate, N deposition and other stressors suggest that even in the absence of N saturation, regeneration of the spruce-fir ecosystem into the next century seems unlikely despite recent region-wide growth increases.

Bathymetry and siltation rate for Dokan Reservoir, Iraq

AbstractThe Dokan Reservoir dam is a concrete cylindrical arch with gravity abutments, located on the Lesser Zab River about 60 km from the city of Sulaimani in north‐eastern Iraq. A bathymetric survey was conducted in November 2014 for a period of 10 days, using an echo sounder of 200‐kHz single beam. The survey results indicated an annual average sediment deposition of 3.8 million m3. Thirty‐two sediment samples were collected from the reservoir bed. The ratio of gravel, sand, silt and clay was 15:14:48:23, respectively. The reservoir bed is covered mainly with silt. The sediments are composed of silty clay (77.6%), silty sandy clay (10%), sandy gravely silty clay (1.2%) and gravely sandy silty clay (1%).

Epitaxial growth of Cu(001) thin films onto Si(001) using a single-step HiPIMS process

We report on a new route to grow epitaxial copper (Cu) ultra-thin films (up to 150 nm thick) at ambient temperature on Si(001) wafers covered with native oxide without any prior chemical etching or plasma cleaning of the substrate. It consists of a single-step deposition process using high power impulse magnetron sputtering (HiPIMS) and substrate biasing. For a direct current (DC) substrate bias voltage of −130 V, Cu/Si heteroepitaxial growth is achieved by HiPIMS following the Cu(001) [100]//Si(001) [110] orientation, while under the same average deposition conditions, but using conventional DC magnetron sputtering, polycrystalline Cu films with [111] preferred orientation are deposited. In addition, the intrinsic stress has been measured in situ during growth by real-time monitoring of the wafer curvature. For this particular HiPIMS case, the stress is slightly compressive (−0.1 GPa), but almost fully relaxes after growth is terminated. As a result of epitaxy, the Cu surface morphology exhibits a regular pattern consisting of square-shaped mounds with a lateral size of typically 150 nm. For all samples, X-ray diffraction pole figures and scanning/transmission electron microscopy reveal the formation of extensive twinning of the Cu {111} planes.

Acid rain footprint three decades after peak deposition: Long-term recovery from pollutant sulphate in the Uhlirska catchment (Czech Republic)

The granitic Uhlirska headwater catchment with a size of 1.78km2 is located in the Jizera Mountains in the northern Czech Republic and received among the highest inputs of anthropogenic acid depositions in Europe. An analysis of sulphate (SO42–) distribution in deposition, soil water, stream water and groundwater compartments allowed to establish a SO42– mass-balance (deposition input minus surface water export) and helped to evaluate which changes occurred since the last evaluation of the catchment in 1997. The determined SO42– concentrations decreased in the following order: wetland groundwater>groundwater from 20m below ground level (bgl)>groundwater from 30m bgl>stream water>groundwater from10m bgl>hillslope soil water>wetland soil water>bulk deposition with median values of 0.24, 0.21, 0.17, 0.15, 0.11, 0.07, 0.03 and 0.01mmolL−1, respectively. Our results show that average deposition reductions of 62% did not result in equal changes of the sulphate mass-balance, which changed by only 47%. This difference occurs because sulphate originates from internal sources such as the groundwater and soil water. The Uhlirska catchment is subject to delayed recovery from anthropogenic acid depositions and remains a net source of stored sulphur even after three decades of declining inputs. The wetland groundwater and soil water provide environmental memories of legacy pollutant sulphate. Elevated stream water sulphate concentrations after the unusually dry summer 2015 imply importance of weather and climate patterns for future recovery from acidification.

Bulk deposition of organic and inorganic nitrogen in southwest China from 2008 to 2013

China is regarded as one of the nitrogen deposition hotspots in the world. Measurements to-date have focused mainly on the North China Plain, ignoring the fact that atmospheric chemical and physical properties vary across the country and that there may be other hotspots regions that should be investigated. For this reason we have conducted a six year study, measuring the bulk deposition of reduced (NH4-N), oxidized (NO3-N), and dissolved organic nitrogen (DON) at three contrasting sites in the Sichuan province, southwest China. The study sites were a high altitude forest in the Gongga Mountains (GG), an agriculture dominated region in Yanting (YT) and an urban site in the mega city Chengdu (CD). The annual average bulk deposition fluxes of total dissolved nitrogen (TDN) were 7.4, 23.1 and 36.6 kg N ha−1 yr−1 at GG, YT and CD sites, respectively, during the study period 2008 to 2013. The contributions of NH4-N, NO3-N and DON to the TDN were in the range of 48.4–57.8%, 28.8–43.7%, and 8.0–15.6%, respectively. DON bulk deposition was mainly dominated by agricultural activities. TDN bulk deposition fluxes showed increasing trends at the agricultural and urban sites from 2008 to 2013, but there was little change at the remote forest (GG) site. While reduced N dominated bulk N deposition at all the three sites, its contribution showed a decreasing trend, suggesting a gradual increase in the importance of oxidized N. These results reveal the value of long term monitoring in detecting changes in the atmospheric chemical composition of this rapidly changing region, and their inclusion in the policy debate regarding which sources should be controlled in order to reduce the long term impacts of N deposition, especially for southwest China, where there are few measurements of N deposition.

Implementing streambank erosion control measures in meandering streams: design procedure enhanced with numerical modelling

ABSTRACTDike structures have been used in many streams to control streambank erosion by redirecting the flow away from the banks towards the centre of the channel. In this study, the 2D finite-element surface water modelling system (FESWMS) was used to enhance the design of dike structures in two meandering stream reaches along the Raccoon River, Iowa, USA. FESWMS was used to find the optimal number and spacing between the dikes and to access their overall performance in controlling river-bank erosion in the study reaches. The study included also field measurements for model calibration and verification. The model results showed that the proposed dike structures, consisting of alternate five bendway weirs and four spurs at each site with a spacing of about 50 m, successfully reduced the flow velocity along the outside bank and increased the conveyance of the flow to the stream centre. The average lengths of the spurs and bendway weirs were about 16 and 32 m, respectively. The estimated velocity and Froude number values along the outside riverbank where the dikes were constructed were less than 1.0 m/s and 0.3, respectively, which are within the recommended values for erodible channel stability design. Site visits one year after the dike construction showed that the dikes were successful in controlling streambank erosion by allowing incoming sediment to deposit between the dikes and along the bank line. Sediment transport measurements at the study sites showed that the maximum deposition was about 0.8 m, which is much higher than a typical averaged deposition value of about 0.3 m/year. Further, recent Google Earth pictures for the sites showed that the bank slope lines almost recovered back in their original profiles and that the dikes became part of the restored banks, a strong indication of the success of the proposed dikes design.

Comparing the electrophoretic deposition process of graphene oxides synthesized through different methods

Graphene oxide (GO) is synthesized through two different chemical methods, namely modified improved method (MIM) and modified Hummers method (MHM). Electrophoretic deposition of GO obtained from those methods is performed on the Fluorine doped tin oxide glass substrates by dispersing GO sheets in acetonitrile and applying voltage. UV–vis and Raman spectroscopies show that pristine graphite is less oxidized in the MIM. However, X-ray diffraction patterns indicate that d-spacing of GO sheets is more increased in the MIM (d-spacing of 0.94nm vs. 0.77nm). Also, Fourier-transformed infrared spectroscopy reveals that GO synthesized through the MIM contains more CO functional groups on its surface. As a result, current density-time diagrams and field emission scanning electron microscope (FESEM) cross-sectional images of electrophoretically deposited GO films are indicative of higher average deposition rate in the MIM compared to MHM (~5.1nm/s vs. ~1.8nm/s). FESEM images of the two films show that surface roughness of the MIM film is lower than that of MHM film as well.

Quantitative study on nitrogen deposition and canopy retention in Mediterranean evergreen forests.

To assess the impact of nitrogen (N) pollutants on forest ecosystems, the role of the interactions in the canopy needs to be understood. A great number of studies have addressed this issue in heavily N-polluted regions in north and central Europe. Much less information is available for the Iberian Peninsula, and yet this region is home to mountain forests and alpine grasslands that may be at risk due to excessive N deposition. To establish the basis for ecology-based policies, there is a need to better understand the forest response to this atmospheric impact. To fill this gap, in this study, we measured N deposition (as bulk, wet, and throughfall fluxes of dissolved inorganic nitrogen) and air N gas concentrations from 2011 to 2013 at four Spanish holm oak (Quercus ilex) forests located in different pollution environments. One site was in an area of intensive agriculture, two sites were influenced by big cities (Madrid and Barcelona, respectively), and one site was in a rural mountain environment 40km north of Barcelona. Wet deposition ranged between 0.54 and 3.8kgNha-1year-1 for ammonium (NH4+)-N and between 0.65 and 2.1kgNha-1year-1 for nitrate (NO3-)-N, with the lowest deposition at the Madrid site for both components. Dry deposition was evaluated with three different approaches: (1) a canopy budget model based in throughfall measurements, (2) a branch washing method, and (3) inferential calculations. Taking the average dry deposition from these methods, dry deposition represented 51-67% (reduced N) and 72-75% (oxidized N) of total N deposition. Canopies retained both NH4+-N and NO3-N, with a higher retention at the agricultural and rural sites (50-60%) than at sites located close to big cities (20-35%, though more uncertainty was found for the site near Madrid), thereby highlighting the role of the forest canopy in processing N pollutant emissions.

Respirable size-selective sampler for end-of-shift quartz measurement: Development and performance

ABSTRACTAims of this study were to develop a respirable size-selective sampler for direct-on-filter (DoF) quartz measurement at the end-of-shift (EoS) using a portable Fourier transform infrared (FTIR) spectrometer and to determine its size-selective sampling performance. A new miniaturized sampler has been designed to have an effective particle deposition diameter close to the portable FTIR beam diameter (6 mm). The new sampler (named the EoS cyclone) was constructed using a 3D printer. The sampling efficiency of the EoS cyclone was determined using polydisperse glass sphere particles and a time-of-flight direct reading instrument. Respirable dust mass concentration and quartz absorbance levels of samples collected with the EoS cyclone were compared to those collected with the 10-mm nylon cyclone. The EoS cyclone operated at a flow rate of 1.2 l min−1 showed minimum bias compared to the international standard respirable convention. The use of the EoS cyclone induced respirable dust mass concentration results similar but significantly larger (5%) than those obtained from samples collected with 10-mm nylon cyclones. The sensitivity of the DoF-FTIR analysis in estimating quartz was found increased more than 10 times when the samples were collected with the EoS cyclone. The average particle deposition diameter was 8.8 mm in 60 samples. The newly developed user friendly EoS cyclone may provide a better sampling strategy in quartz exposure assessment with faster feedback.

Quartz micro-balance results of pulse-resolved erosion/deposition in the JET-ILW divertor

A set of quartz crystal microbalances (QMB) was used at JET with full carbon wall to monitor mass erosion/deposition rates in the remote areas of the divertor. After introduction of the ITER- like wall (ILW) in JET with beryllium main wall and tungsten divertor, strong reduction of the material deposition and accompanied fuel retention was observed. Therefore the existing QMB electronics have been modified to improve the accuracy of frequency measurements by a factor of ten down to 0.1Hz which corresponds to 1.4ngcm−2. The averaged deposition rates of 1.2–3ngcm−2s−1 and erosion rates of 5.6–8.1ngcm−2s−1 were observed in the inner divertor of JET -ILW with the inner strike point positions close to the bottom edge of vertical tile 3 and at the horizontal tile 4 respectively. The erosion with averaged rates of ≈2.1ngcm−2s−1 and ≈120ngcm−2s−1 were observed in the outer divertor for the outer strike point positions at tile 5 and tile 6 respectively.

Sputter deposition of Titanium and Nickel thin films in radio frequency magnetron discharge characterized by optical emission spectroscopy and by Rutherford backscattering spectrometry

By using a homemade dual magnetron sputtering system, two combined investigations by Optical emission spectroscopy and by Rutherford backscattering spectrometry were performed on a Radio-Frequency discharge for Titanium and Nickel deposited in pure Argon gas. Line intensities of various species present in the plasma were compared to the Argon emission line I of 696.5nm for different gas pressure and power density values. The electron temperature was also determined from the collisional radiative model and then correlated to the gas pressure and the power density. It was found that the sputtering pressure alters the spectrum intensity of Nickel, but has no obvious effect on that of Titanium during sputtering. The variation of average deposition rate as a function of gas pressure was experimentally determined via the Rutherford backscattering technique and then correlated to the variation of electron temperature of (Titanium-Argon) and (Nickel-Argon) discharges versus gas pressure.

Atmospheric deposition exposes Qinling pandas to toxic pollutants.

The giant panda (Ailuropoda melanoleuca) is one of the most endangered animals in the world, and it is recognized worldwide as a symbol for conservation. A previous study showed that wild and captive pandas, especially those of the Qinling subspecies, were exposed to toxicants in their diet of bamboo; the ultimate origin of these toxicants is unknown. Here we show that atmospheric deposition is the most likely origin of heavy metals and persistent organic pollutants (POPs) in the diets of captive and wild Qinling pandas. Average atmospheric deposition was 199, 115, and 49g·m-2 ·yr-1 in the center of Xi'an City, at China's Shaanxi Wild Animal Research Center (SWARC), and at Foping National Nature Reserve (FNNR), respectively. Atmospheric deposition of heavy metals (As, Cd, Cr, Pb, Hg, Co, Cu, Zn, Mn, and Ni) and POPs was highest at Xi'an City, intermediate at SWARC, and lowest at FNNR. Soil concentrations of the aforementioned heavy metals other than As and Zn also were significantly higher at SWARC than at FNNR. Efforts to conserve Qinling pandas may be compromised by air pollution attendant to China's economic development. Improvement of air quality and reductions of toxic emissions are urgently required to protect China's iconic species.