This study aimed to analyze the photocatalytic degradation of Reactive Red 195, a textile dye belonging to the class of azo dyes. For this, a polymer membrane of Ecovio® (polymeric blend formed by PBAT/PLA) was obtained by the electrospinning technique, with the incorporation of semiconductors titanium dioxide (TiO2-R) and magnetite iron oxide (Fe3O4-M). The hydrophobic nature of the membrane required the treatment with sodium hydroxide (NaOH), in this way, the membranes were characterized with and without the semiconductors, as well as, with or without the alkali treatment. The techniques used for characterization were: contact angle analysis, infrared spectroscopy with Fourier transform (FT-IR), thermogravimetrics (TGA), X-ray diffraction (XRD), and differential exploratory calorimetry (DSC). The contact angle analysis of the membrane surface showed that it was hydrophobic before treatment with NaOH, with an average contact angle of 121.45 ± 1.44° and consequently low humidity. After treatment, there was a change in the surface with a change of the average contact angle value to 80.68 ± 1.52° and an increase in wetness. The FT-IR spectroscopy identified bands characteristic of the Ecovio® functional groups in the polymer blend, and discreet changes occurring after alkaline treatment. The TGA analysis showed that the incorporation of two semiconductors and the alkaline treatment resulted in a decrease in thermal stability for both the PLA polymer and the PBAT due to the possible interaction of the TiO2-R and Fe3O4-M semi-conductors with the polymers that we can promote a lower arrangement of fibers. The DSC analysis indicated possible changes in the polymer's structure due to the presence of semiconductors and alkaline treatment. A decrease in melting calories of the treated membranes compared to the untreated membrane indicates possible hydrolysis of the polymers. In the DRX analysis, an increase in the intensity of the peaks of the polymer membrane containing the semiconductors and subjected to alkaline treatment was observed. However, comparing membranes containing the semiconductors with pure membranes (without the semiconductors) subjected or not to alkaline treatment, possibly an alteration in crystallinity had a greater relationship with the incorporation of the two semiconductors in the pure membrane subjected to alkaline treatment continued to have predominantly amorphic characteristics. After obtaining and characterizing the membrane, studies were conducted to evaluate its potential in the photodegradation of the Reactive Red 195, using an Ecovio® polymer membrane incorporated with TiO2-R and Fe3O4-M, and treated with an alkaline solution. The results showed degradation above 80% after 24 h, in addition, the potential for reuse of this membrane was analyzed in 4 cycles of photocatalytic degradation, which showed that in all the cycles using the same membrane, the degradation remained above 80%, but at the end of the fourth cycle, a membrane still intact but visually more fragile was noted. Kinetic studies have shown that degradation follows the pseudo-first-order kinetic model. After the degradation cycles, the Fourier transform infrared spectroscopy (FT-IR) showed no new bands. Thus, the polymer membrane proved promising for the photodegradation of Reactive Red 195 given its efficiency, ease of separation from the reaction medium, and the possibility of reuse for several cycles.
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