H2-mediated microbial electrosynthesis (MES) could run under a high current density, but the low solubility of H2 limited its performance. Reducing the H2 bubble size facilitates H2 gas-liquid mass transfer and it has been reported to be realized on superaerophobic electrodes. Therefore, we adopted a CoP nanowire-modified nickel foam (CoP-NiF) as the superaerophobic cathode in a H2-mediated MES reactor to enhance the methane production from CO2. The CoP nanowire modification reduced the average diameter of H2 bubbles from∼300 μm to∼100μm, thereby exhibiting a 129% enhancement of the H2 mass transfer coefficient (KLa=0.32min-1). The maximum CH4 production rate with CoP-NiF cathode exhibited a 27% improvement (2.31 L/L/d) at a high current density of 166.67 A/m2. More importantly, a coulombic efficiency higher than 80% was achieved in the reactor. These results demonstrated that using superaerophobic cathodes is an efficient way to enhance the performance of H2-mediated MES reactors.
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