The real-time, accurate detection of muscle activation onset (MAO) is significant for EMG-triggered control strategies in embedded applications like prostheses and exoskeletons. This paper investigates sEMG signals using the generalized autoregressive conditional heteroskedasticity (GARCH) model, focusing on variance. A novel feature, the likelihood of conditional heteroskedasticity (LCH) extracted from the maximum likelihood estimation of GARCH parameters, is proposed. This feature effectively distinguishes signal from noise based on heteroskedasticity, allowing for the detection of MAO through the LCH feature and a basic threshold classifier. For online calculation, the model parameter estimation is simplified, enabling direct calculation of the LCH value using fixed parameters. The proposed method was validated on two open-source datasets and demonstrated superior performance over existing methods. The mean absolute error of onset detection, compared with visual detection results, is approximately 65 ms under online conditions, showcasing high accuracy, universality, and noise insensitivity. The results indicate that the proposed method using the LCH feature from the GARCH model is highly effective for real-time detection of muscle activation onset in sEMG signals. This novel approach shows great potential and possibility for real-world applications, reflecting its superior performance in accuracy, universality, and insensitivity to noise.