The use of ion current signals generated during the combustion process of mixed gas as a function of initial mixture composition, temperature and pressure to detect cylinder combustion states is the most recent approach in the design, development, and optimisation of automotive engine combustion control. This paper aims to design predictive identification and computationally fast and accurate ion current models for obtaining combustion information in the engine cylinder in real time. To build a more comprehensive ion current calculation model, the effect of the flame ionisation process, the geometry of the spark plugs, and the combustion pressure and temperature are considered in the new building ion current model. The simulation ion current waveform, which has a double-peak structure, is in good agreement with the experiment values; thus, the ion current model has the potential to be used for real-time control and optimisation of engine cylinder combustion.